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===================== Product Identification ===================== Product ID:RUST FOIL 2675 CAGE:84591 CAGE:84591 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC CAS:64742-53-6 RTECS #:PY8036000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAUSES IRRITATION: MAY BE SKIN DEFATTER UPON PROLONGED OR REPEATED CONTACT. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:OIL MIST INHALATION MAY CAUSE DIZZINESS, NAUSEA AND DIFFICULTY BREATHING. Medical Cond Aggravated by Exposure:SENSITIVE DRY SKIN. ======================= First Aid Measures ======================= First Aid:SKIN CONTACT: WASH SKIN WITH WARM WATER, REMOVE FLUID SOAKED CLOTHING & SHOES. LAUNDER BEFORE REUSE. EYE CONATCT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MIN, CALL A PHYSICIAN. ING ESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:275F,135C Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE OR FOAM. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER. Unusual Fire/Explosion Hazard:HOT VAPORS FORM EDXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:IN CASE OF SPILL, CONTAIN AND RECOVER BULK LIQUID. SOAK UP RESIDUE WITH SAND, EARTH, OTHER INERT MATERIAL. PUT IN A SUITABLE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLW WARNINGS EVEN AFTER CONTAINER IS EMPTIED. AVOID BREATHING MISTS OR VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF ENGINEERING AND OTHER CONTROLS ARE NOT ADEQUATE TO REDUCE AIRBORNE EXPOSURE TO BELOW PERMISSIBLE EXPOSURE LIMITS. Ventilation:LOCAL EXHAUST RECOMMENDED. Other Protective Equipment:USE AS REQUIRED TO AVOID SKIN CONTACT. Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>500F,>260C Vapor Pres:<0.5 Vapor Density:>1 Spec Gravity:0.89 Evaporation Rate & Reference:<1 (BUTYL=1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR AMBER LIQUID WITH MILD HYDROCARBON ODOR. Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDANTS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE AND OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:H0-2A LUBRIPLATE HYDRAULIC OIL Preparer's Name:JAMES R KONTAK CAGE:73219 CAGE:73219 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL Ingred Name:ADDITIVES Ingred Name:ZINC COMPOUND Fraction by Wt: <2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION. INGESTION: LOW TOXIC. MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING INGESTION MAY CAUSE MILD TO SEVERE PULMONARY INJURY. IF IN JECTED BY HIGH PRESSURE UNDER SKIN, DELAY OF MEDICAL ATTENTION MAY CAUSE LOSS OF AFFECTED PART OF THE BODY. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/CLEAR WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: IMMEDIATELY REMOVE FROM EXPOSURE. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:415-480F Lower Limits:0.9 Upper Limits:7 Extinguishing Media:FOAM, DRY CHEMICAL, CO2/WATER SPRAY (FOG) Fire Fighting Procedures:COOL EXPOSED CONTAINERS W/WATER. USE AIR SUPPLIED BREATHING EQUIPMENT FOR ENCLOSED/CONFINED SPACES. Unusual Fire/Explosion Hazard:DON'T STORE/MIX W/STRONG OXIDANTS. EMPTY CONTAINERS RETAIN RESIDUE. DON'T CUT, DRILL, GRIND/WELD AS THEY MAY EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER LIQUID, WASH REMAINDER W/SUITABLE PETROLEUM SOLVENT/ADD ABSORBENT. KEEP PETROLEUM OUT OF SEWERS & WATER COURSES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DON'T HANDLE/STORE NEAR HEAT, SPARKS, FLAME/STRONG OXIDANTS. Other Precautions:AVOID BREATHING OIL MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NOT NEEDED Ventilation:LOCAL EXHAUST: USED TO CAPTURE FUMES & VAPORS. Other Protective Equipment:OIL RESISTANT APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEANS THOROUGHLY AFTER CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>550F Vapor Pres:<0.01 Vapor Density:>5 Spec Gravity:0.87-0.89 Evaporation Rate & Reference:(BUTYL ACETATE=1): <0.01 Solubility in Water:NEGLIGIBLE Appearance and Odor:TRANSPARENT AMBER LIQUID W/MINERAL OIL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS; LIQUID CHLORINE, CONCENTRATED OXYGEN Stability Condition to Avoid:HEAT, SPARKS, FLAME Hazardous Decomposition Products:SULFUR DIOXIDE; CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ABSORBED MATERIAL AT AN APPROVED WASTE DISPSOAL FACILITY/SITE IAW/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR 1440 B-1/2,1440 B 2,ACCELERATOR Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGENATED TERPHENYLS CAS:61788-32-7 RTECS #:WZ6535000 Fraction by Wt: 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 PPM ACGIH TLV:0.5 PPM; 9596 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9596 Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 55% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:1,3 DIPHENYL GUANIDINE, CAS:102-06-7 RTECS #:MF0875000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- EYES:SEVERELY IRRITATING. SKIN:TOXIC BY SKIN ABSORPTION. MAY BE A SENSITIZER. INHALE:DUST MAY IRRITATE & MAY BE ABSORBED THROUGH LUNGS. ORAL:M AY BE HARMFUL IF SWALLOWED. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, REDNESS, SENSITIZATION Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:SEEK MEDI CAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:315F,157C Extinguishing Media:WATER FOG, CARBON DIOXIDE, SAND, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:MAY CAUSE DECOMPOSITION OF MANGANESE DIOXIDE RESULTING IN OXIDIATION AND POSSIBLE IGNITION OF HYDROCARBON VEHICLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROTECTIVE EQUIPMENT. SCOOP SPILL INTO CONTAINER FOR DISPOSAL. WASH SPILL AREA WITH A SUITABLE SOLVENT AFTER PICK UP IS COMPLETE. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID BREATHING DUSTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:GENERAL VENTILATION Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:N1. THIS PRODUCT IS A KIT CONSISTING OF TWO PARTS: ACCELERATOR AND BASE COMPOUND. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:644F,340C Spec Gravity:1.97 Evaporation Rate & Reference:NOT RELEVANT Appearance and Odor:PASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN AND MANGANESE COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT IS A NONHAZARDOUS WASTE. CONSULT LOCAL AND STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FOGPRUF LENS SOLUTION, MSA P/N12650 CAGE:55799 CAGE:55799 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 15% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:SUCCINIC ACID, SULFO-1,4-BIS(2-ETHYLHEXYL)ESTER, SODIUM SALT;(DIOCTYL SODIUM SULFOSUCCINATE). LD50 ORAL (RAT):1900 MG/KG CAS:577-11-7 RTECS #:WN0525000 Fraction by Wt: 2% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >80% ===================== Hazards Identification ===================== LD50 LC50 Mixture:(SEE INGRED) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE AND MUCOUS MEMBRANE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:ISOPROPANOL: EYE:IRRITATION. INGEST:DIZZINESS, INCOORDINATION, HEADACHE, CONFUSION, STUPOR, COMA, ABDOMINAL PAIN, VOMITING, DIARRHEA. INHAL:IRRITATION OF EYES, NOSE, THROAT. DIOCTYL SODIUM SULFOSUCCIN ATE: EYE:IRRITATION. INGEST:DIARRHEA. INHAL:NOT APPLICABLE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:HOLD EYELIDS OPEN & FLUSH EYES W/LG AMTS OF H*2O FOR AT LEAST 15 MIN. OCCASNLY LIFT UPPER & LOWER LIDS. GET IMMED TREATMENT BY MD. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE TWO GLASSES OF H*2O & ENCOURAGE VOM. HOLD VICTIM'S HEAD LOW TO AVOID ASPIRATION OF VOM. GET IMMED TREATMENT BY MD. INHAL:OVEREXPOS BY THIS ROUTE IS UNLIKELY. IF OVEREXP SOMEHOW OCCURS, REMOVE FROM EXPOS. GIVE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:110F,43C Lower Limits:2.0% Upper Limits:12.7% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON SAND AND SCOOP TO CONTAINER FOR PROPER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED PLACE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:FOR USE ONLY AS DIRECTED ON LABEL INSTRUCTIONS. Supplemental Safety and Health VAP PRESS:18 MM HG/20C. FIRST AID:ARTIFICIAL RESPIRATION IF NEEDED. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET IMMEDIATE TREATMENT BY A PHYSICIAN. SKIN:WASH WITH SOAP AND WATER. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:190F,88C Vapor Pres:SUPP DATA Vapor Density:>11 Spec Gravity:<1 Solubility in Water:COMPLETE Appearance and Odor:BLUE-GREEN PERFUMED LIQUID. Percent Volatiles by Volume:98% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF SURPLUS PRODUCT AS HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PROPYLENE GLYCOL INDUSTRIAL Resp. Party Other MSDS Num.:HCR002107 CAGE:UO143 CAGE:UO143 Contract Num:SP0450-01-M-D388 CAGE:4N760 Contract Num:SP0450-01-M-D619 CAGE:4N760 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 = Wt:99. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES- SLIGHT EYE IRRITANT. INHALATION, SKIN AND INGESTION- NO SIGNIFIGANT SIGNS OR SYMPTOMS INDICATIVE OF ANY ADVERSE HEALTH HAZARD ARE EXPECTED TO OCCUR AS A RESULT OF EXPOSURE TO INHALATION/ SKIN CONTACT/SKIN ABSORPTION/INGESTION. CHRONIC: NO CHRONIC HEALTH EFFECTS ARE EXPECTED FROM NORMAL USE. Explanation of Carcinogenicity:NOT APPLICABLE. Effects of Overexposure:EYES- MAY CAUSE MINOR EYE IRRITATION. Medical Cond Aggravated by Exposure:THIS MATERIAL OR ITS EMISSIONS MAY AGGRAVATE PRE-EXISTING EYE DISEASE. ======================= First Aid Measures ======================= First Aid:EYES- IMMEDIATELY RINSE WITH CLEAN WATER FOR 20-30 MINUTES. RETRACT EYELIDS OFTEN. OBTAIN EMERGENCY MEDICAL ATTENTION IF PAIN, BLINKING, TEARS OR REDNESS PERSIST. INHALATION, SKIN AND INGESTION- NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS OF NORMAL USE. AFTER ADEQUATE FIRST AID, NO FURTHER TREATMENT IS REQUIRED UNLESS SYMPTOMS REAPPEAR. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=99.4C, 211.F Autoignition Temp:=371.1C, 700.F Lower Limits:2.4 Upper Limits:17.4 Extinguishing Media:USE CARBON DIOXIDE, ALCOHOL TYPE FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION. FIGHT FIRE FROM SAFE DISTANCE/PROTECTED LOCATION. HEAT MAY BUILD PRESSURE/RUPTURE CLOSED CONTAINERS, SPREADING FIRE, INCREASING RISK OF BURNS/INJURY. USE WATER SPRAY/FOG FOR COOLING. AVOID FROTHING/STEAM EXPLOSION. BURNING LIQUID MAY FLOAT ON WATER. (SUPP) Unusual Fire/Explosion Hazard:HEAT FROM FIRE CAN GENERATE FLAMMABLE VAPOR. WHEN MIXED WITH AIR AND EXPOSED TO IGNITION SOURCE. VAPORS CAN EXPLOSDE IF CONFINED. VAPORS MAY TRAVEL LONG DISTANCES ALONG GROUND BEFORE IGNITING/FLASHING BACK TO VAPOR SOURCE. FINE SPRAYS/MISTS MAY BE COMBUSTIBLE AT TEMPERATURES BELOW NORMAL FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:SPREAD GRANULAR COVER. IMPOUND/RECOVER LARGE LAND SPILL. SOAK UP SMALL SPILL WITH INERT SOLIDS. USE SUITABLE DISPOSAL CONTAINERS. ON WATER, MATERIAL SOULBLE/ MAY FLOAT OR SINK. MAY BIODEGRADE. CONTAIN /MINIMIZE DISPERSION/COLLECT. DISPERSE RESIDUE TO REDUCE AQUATIC HARM. REPORT PER REGULATORY REQUIREMENTS. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ======================Handling and Storage ====================== Handling and Storage Precautions:HYGROSCOPIC. USE DRY NITROGEN OR LOW DEW POINT AIR FOR TANK PADDING. KEEP DRUMS TIGHTLY CLOSED TO PREVENT CONTAMINATION STORE AT 65-90 F. Other Precautions:DECONTAMINATION PROCEDURES: CLEAN EQUIPMENT WITH WATER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION EQUIPMENT IS RECOMMENDED UNDER ANTICIPATED CONDITIONS OF NORMAL USE WITH ADEQUATE VENTILATION. Ventilation:NO SPECIAL VENTILATION IS RECOMMENDED UNDER ANTICIPATED CONDITIONS OF NORMAL USE BEYOND THAT NEEDED FOR NORMAL COMFORT CONTROL. SHIELD Other Protective Equipment:NO DATA PROVIDED BY MANUFACTURER Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. WASH HANDS BEFORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING/WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK. Supplemental Safety and Health FIREFIGHTING CONTINUED: ALTHOUGH SOLUBLE, MAY NOT BE PRACTICAL TO EXTINGUISH FIRE BY WATER DILUTION. NOTIFY AUTHORITIES IF LIQUID ENTERS SEWER/PUBLIC WATERS. ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:=185.C, 365.F Melt/Freeze Pt:=-60.C, -76.F Vapor Pres:< 0.1 @ 77F Vapor Density:2.6 Spec Gravity:1.04 @ 60-90F Viscosity:46 CPS@ 77F Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS VISCOUS LIQUID. ALMOST ODORLESS. Percent Volatiles by Volume:SLIGHT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURE AND SEVERE OXIDIZING CONDITIONS Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER HAZARDOUS VAPORS/GASES. =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY MANUFACTURER. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL SOLIDS AT PERMITTED SITES. USE REGISTERED TRANSPORTERS. BURN CONCENTRATED LIQUIDS, DILUTING WITH CLEAN, LOW VISCOSITY FUEL. AVOID FLAMEOUTS. COMPLY WITH ALL APPLICABLE FEDERAL, STATE AND LOCA L REGULATIONS. AVOID OVERLOADING PLANT BIOMASS. ASSURE EFFLUENT COMPLIES WITH APPLICABLE STANDARDS. =================== MSDS Transport Information =================== Transport Information:DOT HAZARDOUS MATERIAL PROPER SHIPPING NAME: NOT REGULATED. DOT HAZARD CLASS: NOT REGULATED. UN/NA ID NO.: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311/312 HAZARD CATAGORIES: NONE KNOWN TO APPLY. SECTION 313: NO CHEMICALS IN THIS PRODUCT EXCEED THE DE MINIMUS REPORTING LEVEL ESTABLISHED BY SARA TITLE III, SECTION 313 AND 40 CFR 372. Federal Regulatory Information:COMPREHENSIVE ENVIRONMENTAAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA): NO CHEMICALS IN THIS PRODUCT ARE SUBJECT TO THE REPORTING REQUIREMENTS OF CERCLA. State Regulatory Information:CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 - PROPOSITION 65: BASED ON INFORMATION CURRENTLY AVAILABLE, THIS PRODUCT IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS CARC INOGENS OR REPRODUCTIVE TOXINS UNDER CALIFORNIA PROPOSITION 65 AT LEVELS WHICH WOULD BE SUBJECT TO THE PROPOSITION. IF YOU REFORMULATE OR FURTHER PROCESS THIS PRODUCT, YOU SHOULD FURTHER EVALUATE THIS PRODUCT BASED UPON SUCH REFORMULATION OR PROCESSING, AS WELL AS UPON ITS FINAL COMPOSITION AND USE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMMONIUM FLUORIDE 40 % SOLUTION CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM FLUORIDE (SARA III) CAS:12125-01-8 RTECS #:BQ6300000 Fraction by Wt: 40.0% OSHA PEL:2.5 MG F/M3 ACGIH TLV:2.5 MG F/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:WATER;CAS #7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60.0% ===================== Hazards Identification ===================== Effects of Overexposure:INH:MAY IRRIT TO RESP TRACT;ING:MAY CAUSE SALIVATION,VOMIT DIARRHEA;SKIN/EYES;MAY IRRITATE/BURN SEV. ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.CALL MD;INGEST:DO NOT INDUCE VOMIT.GIVE LG QTY OF MILK/WATER.IMMED TRANSPRT TO HOSP;SKIN:FLUSH W/PLENTY WATER.COVR BURN W/50-50 WATER/MGSO*4 PASTE,UNIT L HELP ARRVS;EYES:FLUSH W/H*2O.IMMED GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE H*20 TO COOL EXPD CONTRS. USE SCBA & FULL PROT.CLTHG. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA.USE PROTECTV EQUIP & RESP PROTECTION FM VAP.DIKE & COVER ACID SPILL W/SODA ASH/LIME.CONTAIN & RECOVER LIQ IF POSS.ABSORB W/VERMCLT,SAND/EARTH.SCOOP UP W/NON-SPARKING TOOLS & PLACE IN CL OSED CONTNRS PENDING DISPOSAL.DO NOT FLUSH TO SEWR ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTNRS AT COOL,DRY,VENTAILATED PLACE.PROTECT AGAINST PHY DAMAGE. Other Precautions:AVOID BREATHING DUST.USE W/ADEQUATE VENTILATION.KEEP CONTAINRS CLOSED.WASH THOROUGHLY AFTER HANDLING.AVOID SKIN,EYES & CLOTHING CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR RESPIR/SCBA; ESCAPE: GAS MASK Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION Supplemental Safety and Health MSDS FM MFR DATED:10/24/85 CONFORMS TO OSHA HAZ COMM STD;FIRST AID PROCEDURES-SKIN:WASH BURN AREA.COVER W/POULTICE OF 50-50- WATER/MGSO*4 OR 2-1/2% CALCIUM GLUCONATE PASTE THEN TRNSP TO HOSP. ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=108.9C, 228.F Spec Gravity:1.01 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLSS LIQUID,SLIGHT CHARACTRISTC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE WASTE LIQUID OR SOLID IN RCRA APPROVED FACILITY.ENSURE COMPLIANCE W/LOCAL,STATE & FEDERAL REGULATIONS. CWA/CERCLA RQ: 100 LBS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEXMARK PRINT CARTRIDGE 140100A Resp. Party Other MSDS Num.:140100A Preparer's Name:NONE LISTED CAGE:05487 Contract Num:SPO450-99-M-C412 CAGE:79775 CAGE:05487 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLATE COPOLYMER Minumum % Wt:50. Maxumum % Wt:60. Ingred Name:IRON OXIDES Minumum % Wt:35. Maxumum % Wt:45. Ingred Name:POLYPROPYLENE CAS:9003-07-0 RTECS #:UD1842000 < Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR. SIGNIFIGANT EXPOSURE NOT PROBABLE WITH INTENDED USE. SKIN: TONER IS NOT AN IRRITANT & HAS LOW DERMAL TOXICITY. SIGNIFIGANT EXPOSURE NOT PROB ABLE WITH INTENDED USE. EYES: TONER MAYACT AS A MECHANICAL IRRITANT. INGESTED: TONER IS OF LOW ACUTE ORAL TOXICITY. SWALLOWING EXESSIVE AMOUNTS MAY CAUSE SAME TOXIC EFFECTS OF INGESTING ANY INSOLUBLE IRON SALTS. CHRONIC: INHALATION OF IRON OXIDE DUSTS MAY CAUSE SIDEROSIS. RARE INDIVIDUALS MAY NOT A SKIN RASH WITH REPEATED CONTACT. CHRONIC EXPOSURE BY INGESTION OF IRON OXIDES MAY CAUSE CARDIOVASCUL AR, LIVER & BLOOD COMPONENT EFFECTS. Explanation of Carcinogenicity:NO INGREDIENTS ARE LISTED AS OSHA, NTP OT IARC KNOWN OR POTENTIAL CARCINOGENS Effects of Overexposure:INHALAED-RESPIRATORY IRRITATION. EYES-IRRITATION. INGESTED (LARGE DOSES): ABDOMINAL PAIN, SEIZURES, INCREASED HEART & BREATHING RATES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IF BREATHING BECOMES DIFFICULT. SKIN: WASH WITH SOAP & WATER. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPES & PERSISTS. EYES: DO NOT RUB EYES. FLUSH IMMEDIATELY WITH WATER. REMOVE CONTACT & CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS & PERSISTS. INGESTED: IMMEDIATELY RINSE MOUTH OUT WITH WATER. IFWITHIN 30 MINUTES & CONSCIOUS, GIVE SMALL GLASS WATER OR MILK. IF LARGE AMOUNT INGESTED, CONTACT PHYSICIAN OR POISON CONTROL CENTER. DO NOT INDUCE VOMITING UNLESS DIRECTED BY PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NP Extinguishing Media:WATER, FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:FIRE MAY PRODUCE SMALL AMOUNTS OF HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS CARBON DIOXIDE, CARBON MONOIDE, AND UNIDENTIFIED ORGANICS Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:OCCUPATIONAL SPILL: THE VOLUME OF TONER IN A CARTRIDGE IS MINIMAL. IF A DUST CLOUD IS PRESENT DUE TO A SPILL INVOLVING A LARGE NUMBER OF CARTRIDGES, REMOVE ALL SOURCES OF IGNITION SUCH AS OPEN SPARKS, FLAMES OR STATIC DISCHARGE TO PREVENT THE IGNITION OF THE DUST. MINIMIZE DUST GENERATON DURING CLEAN UP. SWEEP UP SPILL WITH NON-METALLIC BROOM & DUST PAN. CONTAIN FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TO AVOID DAMAGE TO CARTRIDGE & ACCIDENTAL CONTACT W/TONER-KEEP OUT OF REACH OF SMALL CHILDREN. STORE IN A COOL, DRY PLACE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MECHANICAL ROOM VENTILATION IS RECOMMENED. Ventilation:NONE REQUIRED WITH INTENDED USE. Other Protective Equipment:NONE REQUIRED FOR INTENDED USE IN PRINTER Work Hygienic Practices:NONE LISTED BY MANUFACTURER. Supplemental Safety and Health NONE LISTED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:SOLUBILITY IS NEGLIGIBLE Appearance and Odor:TONER IS FINELY DIVIDED BLACK POWDER WITH FAINT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:IGNITIION SOURCES IN COMBUSTIBLE ATMOSPHERES OF TONER DUST. THROWING TONER INTO AN OPEN FIRE. Hazardous Decomposition Products:OXIDES OF CARBON, ACID GASES, LOW MOLECULAR WEIGHT ORGANICS. Conditions to Avoid Polymerization:THIS PRODUCT WILL NOT POLYMERIZE. =================== Toxicological Information=================== Toxicological Information:ACUTE TOXICITY: NOT ACUTELY TOXIC. CHRONIC TOXICITY: NOT EXPECTED TO BE CHRONICALLY TOXIC. LONG TERM EXPOSURE TO EXCESSIVE CONCEENTRATIONS OF IRON OXIDE-CONTAINING DUSTS HAS RESULTED IN ACONDITION IDE NTIFIED AS SIDEROSIS, A RELATIVELY PNEUMOCONIOSIS, CAUSED BY DEPOSITION OF IRON PARTICLES IN THE LUNG. INGESTION OF HIGH DOSES OF INSOLUBLE IRON SALTS MAY RESULT IN CARDIOVASCULAR, LIVER AND BLOOD COM PONENT EFFECTS. ===================== Ecological Information ===================== Ecological:NO DATA AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARDED IN ITS PURCHASED FORM, THIS PRODUCT WOULD NOT BE A HAZARDOUS WASTE EITHER BY LISTING OR BY CHARACTERISTIC. IT IS THE RESPONSIBILITY OF THE PRODUCT USER TO DETERMINE A THE TIME OF DISPOSAL WH ETHER A MATERIAL HAS BEEN CONTAIMINATED & SHOULD BE CLASSIFIED AS A HAZARDOUS WASTE. DISPOSAL IS SUB JECT TO LOCAL, STATE & FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:THIS MATERIAL IS NOT REGULATED AS A HAZARDOUS MATERIAL BY THE US DOT. ===================== Regulatory Information ===================== SARA Title III Information:NONE OF THE PRODUCT INGREDIENTS ARE LISTED AS EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT (EPCRA)-SECTION 302: EXTREMELY HAZARDOUS SUBSTANCES (EHS). NONE OF THE PRODUCT COMPONENTS ARE PRESENT A BOVE THE MINIMUM QUANTITIES OF LISTED CHEMICALS IN EPCRA SECTION 313 SUPPLIER NOTIFICATION. Federal Regulatory Information:THIS PRODUCT IS NOT LISTED OR HAZARDOUS WASTE IN ACCORDANCE WITH FEDERAL REGULATION 40 CFR PART 261. TSCA: ALL INGREDIENTS ARE REGISTERED UNDER THE TOXIC SUBSTANCES CONTROL ACT (TSCA) OR UNDER POLYMER EXEMPTION. State Regulatory Information:THIS PRODUCT CONTAINS NO KNOWN MATERIALS WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: CALIFORNIA PROPOSITION 65. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:MYERSON SPECIAL C & B MODELING LIQUID Preparer's Name:JOHN C. CRINION CAGE:EO702 CAGE:04586 CAGE:EO702 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL METHACRYLATE (SARA III) CAS:80-62-6 RTECS #:OZ5075000 Fraction by Wt: <25% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROQUINONE (SARA III) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: <55% PPM OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:UNKNOWN OSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE DIZZINESS, HEADACHE, NAUSEA & LOSS OF CONSCIOUSNESS, EYE, NOSE & THROAT IRRITATION. SKIN: MAY CAUSE ALLERGIC RASH, IRRITATION, ITCHING & SWELLING. Explanation of Carcinogenicity:MUTAGENIC CHANGES HAVE BEEN OBSERVED. Effects of Overexposure:INHALATION: MAY CAUSE DIZZINESS, HEADACHE, NAUSEA & LOSS OF CONSCIOUSNESS, EYE, NOSE & THROAT IRRITATION. SKIN: MAY CAUSE ALLERGIC RASH, IRRITATION, ITCHING & SWELLING. ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING & GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH WITH PLENTY OF WATER. CALL PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF IRRITATION OCCURS, CONTACT PHYSI CIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45F Lower Limits:2.1% Upper Limits:12.5% Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL OR WATER SPRAY Fire Fighting Procedures:WEAR MESA/NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. USE COLD WATER SPRAY TO COOL CONTAINERS. VAPORS MAY TRAVEL TO SOURCE OF IGNITION & FLASH BACK. Unusual Fire/Explosion Hazard:HEAT CAN CAUSE POLYMERIZATION. HEATED, SEALED CONTAINERS CAN EXPLODE. FIGHT FIRE FROM PROTECTED LOCATION. EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. ABSORB SPILL WITH SAND OR VERMICULITE & PLACE IN A CLOSED CONTAINER FOR DISPOSAL. VENTILATE AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T INCINERATE IN CLOSED CONTAINERS. KEEP AWAY FROM HEAT, DIRECT SUNLIGHT, SPARKS & FLAMES. KEEP CONTAINERS CLOSED AFTER EACH USE. Other Precautions:AVOID BREATHING VAPORS & CONTACT W/SKIN. PERMIT AIR SPACE TO EXIST INSIDE STORAGE CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NECESSARY IF GOOD VENTILATION IS MAINTAINED Ventilation:LOCAL EXHAUST: EXPLOSION PROOF EXHAUST VENTILATION. MECHANICAL: PROVIDE MECHANICAL VENTILATION TO KEEP <TLV Other Protective Equipment:SAFETY SHOWER & IMPERVIOUS CLOTHING Work Hygienic Practices:KEEP CONTAINERS CLOSED AFTER EACH USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:214F Vapor Pres:29 Vapor Density:3.5 Spec Gravity:0.952 Evaporation Rate & Reference:(BU AC = 1): 3 Solubility in Water:SLIGHT Appearance and Odor:WATER-CLEAR, COLORLES LIQUID HAVING AN ACRID IRRITATING ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING & REDUCING AGENTS. ACIDS, BASES, UV LIGHT & CONTAMINATION Stability Condition to Avoid:HEAT, AGING, CONTAMINATION, OXYGEN, FREE ATMOSPHERE, DIRECT SUNLIGHT, SPARKS & FLAMES. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISCARDED, THIS MATERIAL IS A HAZARDOUS WASTE RCRA D-001. INCINERATE LIQUID & ABSORBANT IN ACCORDANCE WITH STATE & LOCAL EPA REGULATIONS. DON'T INCINERATE IN CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N5223 YELLOW A/D ENAMEL 13538 Preparer's Name:MIKE LICHATOWICH CAGE:02388 CAGE:02388 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYD RESIN SOLUTION CAS:68459-31-4 Fraction by Wt: 48% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM ACGIH TLV:150 PPM/STEL 200 PPM Ingred Name:BUTYL ACETATE (VAPOR PRESSURE 10 MM HG @ 20C) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 33% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/STEL 200 PPM ACGIH TLV:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POLYESTER/POLYAMINE COPOLYMER Fraction by Wt: 1% Other REC Limits:NONE SPECIFIED Ingred Name:ORGANOPHYLIC CLAY CAS:71011-25-1 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED Ingred Name:COBALT COMPOUNDS (AS CO) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:PROPIETARY INGREDIENTS Other REC Limits:NONE SPECIFIED Ingred Name:VOC: 3.08 LB/GAL RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: SEVERE IRRITATION, LACRIMATION, REDNESS, BLURRED VISION. SKIN: REDNESS, IRRITATION. DEFATTING OF SKIN LEADING TO DERMATITIS. INHALE: NASAL & RESP IRRITATION, CNS DEPRESSION. DIZZINESS, DR OWSINESS, WEAKNESS, FATIGUE, CONFUSION.NAUSEA, HEADACHE, VERTIGO, UNCONSCIOUSNESS, ASPHYXIATION. CHRONIC: DERMATITIS. Effects of Overexposure:INGESTION: GASTROINTESTINAL IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA. TARGET ORGANS: LIVER, KIDNEYS, EYES, SKIN, RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM (CNS). Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET MEDICAL ATTENTION IMMED. SKIN: IMMED FLUSH SKIN W/WATER. IF MATERIAL PENETRATES CLOTHING REMOVE & WASH BEFORE REUSE. GET MEDICAL ATTENTION. EYES : IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES LIFTING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMED. INGESTION: DO NOT INDUCE VOMITING, DRINK WATER. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:72.0F,22.2C Lower Limits:0.8 Upper Limits:7.6 Extinguishing Media:DRY CHEMICAL, FOAM, CO2. Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. WATER USED TO COOL CLSD CNTNRS TO PREVENT BUILDUP & POSSIBLE AUTO IGNITION OR EXPLO EXPOS TO HEAT Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. VAPORS > AIR TRAVEL ALONG GRND TO AN IGNITION SOURCE. ISOLATE FM ALL HEAT TYPES. CLSD CNTNRS MAY EXPLODE EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. DON'T BREATHE VAPORS. AVOID SKIN CONTACT. ABSORB WITH INERT MATERIAL. SHOVEL RECLAIMED INTO DRUMS FOR DISPOSAL. DIKE TO PREVENT FURTHER MOVEMENT & RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. AVOID ROUGH HANDLING. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE (TYPE TC-23C-75) PROPERLY FITTED HALF-MASK OF FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER APPLICATION UNLESS AIR MONITORING KEEPS VAPOR/MIST BELOW APPLICABLE LEVELS. FOLL OW RESPIRATOR MANUFACTURER'S DIRECTIONS. Ventilation:SUFFICIENT VENT IN VOLUME/PATTERN TO KEEP AIR CONCENTRATION BELOW ACGIH'S TLV LIMIT. Other Protective Equipment:CLOTHING AS NEEDED TO PREVENT SKIN CONTACT Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING RESTROOMS. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:251 TO 398F Vapor Density:> AIR Spec Gravity:1.050 Viscosity:70-75 KU Evaporation Rate & Reference:< ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID, ODOR OF SOLVENTS Percent Volatiles by Volume:42.07 Corrosion Rate:MINIMAL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, NITRATES, ALKALIES, ACIDS. Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING. Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TECTYL 275 CAGE:72527 CAGE:0XDH2 CAGE:72527 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETROLEUM DISTILLATES CAS:64742-88-7 Fraction by Wt: 32-42% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:ALIPHATIC PETROLEUM DISTILLATES CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: 30-40% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYLENE GLYCOL MONOBUTYL ETHER CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRIT, STINGING, TEARS, RED, SWELLING. SKIN: IRRIT, RED, BURNING, DRY, CRACKED, DAMAGE. INHAL: LOW TOXICITY, HARMFUL. NOSE/THROAT/RESP TRACT IRRIT, CNS DEPRESS, DIZZY, DROWSY, WEAK, FATIGUE, NAUS EA, HEADACHE, UNCONSCIOUS, DEATH. INGEST: LOW TOXICITY, GI IRRIT, NAUSEA, VOMIT, DIARRHEA. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS, ASTHMA-LIKE CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE: GET FRESH AIR. FLUSH W/WATER FOR 15 MIN, LIFT LIDS. SKIN: REMOVE CONTAM CLOTHES, WASH BEFORE REUSE. WASH W/SOAP & WATER. INHAL: GET FRESH AIR. KEEP WARM/QUIET. ARTIF RESP/OXYGEN IF NEEDED. INGEST : DONT INDUCE VOMIT. ASPIRATION HAZARD.IF UNCONSCIOUS/DROWSY, PLACE ON LEFT SIDE, HEAD DOWN. DONT LEAVE UNATTENDED. GET IMMED MED AID IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:148F,64C Lower Limits:1.0 Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WATER/FOAM MAY CAUSE FROTHING. USE POSITIVE PRESSURE SCBA W/FULL FACE PIECE/TURN-OUT GEAR/CHEMICAL RESISTANT PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:VAPORS ARE >AIR & MAY TRAVEL TO IGNITS. DONT WELD, CUT ON OR NEAR FULL/EMPTY DRUM. CAN IGNITE EXPLOSIVELY, EVEN RESIDUE. ================== Accidental Release Measures ================== Spill Release Procedures:SM: ABSORB LIQUID & TRANSFER TO HOOD. LG: REMOVE IGNITS. STOP SPILL. PREVENT ENTERING BODIES WATER. PUMP/VACUUM TRANSFERRED PRODUCT TO CONTAINERS FOR RECOVERY. ABSORB UNRECOVERABLE MATERIAL. TRANSFER CONTAM ABSORBENT/SOIL TO CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:BOND/GROUND ALL 5 GL PAILS OR LARGER METAL CONTAINERS INCLUDING TANK TRUCKS/CARS WHEN TRANSFERING Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE, FOLLOW ALL HAZARD PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE LIMITS EXCEEDED, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIC CONDITIONS. Ventilation:SUFFICIENT MECHANICAL (GENERAL/LOCAL EXHAUST) TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:IMPERVIOUS CLOTHES/BOOTS. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:315 TO 398F Vapor Pres:0.5 @ 68F Vapor Density:>1 AIR=1 Spec Gravity:0.864 @ 60F pH:NODATA Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER Appearance and Odor:LIQUID, NO ODOR. Percent Volatiles by Volume:55-70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CO, CO2, VARIOUS HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO FEDERAL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WET OR DRY SILVER-ZINC BATTERY,17338 Kit Part:Y CAGE:87362 Contract Num:SP0430-00-D-0322 CAGE:87362 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILVER (SARA 313) (CERCLA) CAS:7440-22-4 RTECS #:VW3500000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MERCURIC OXIDE (SARA 302/313) (CERCLA) CAS:21908-53-2 RTECS #:OW8750000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG (HG)/M3; Z-2 ACGIH TLV:S,0.025 MG(HG)/M3;95 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE WHILE DRY. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE- NO HAZARD IS ANTICIPATED. AFTER ADDITION OF ELECTROLYTE, POTASSIUM HYDROXIDE MIST CAN BURN UPPER RESPIRATORY TRACT. CAN BURN EYES AND SKIN ON CONTACT. INGESTION MAY RESULT I N SEVERE OR PERMANENT INJURY. CHRONIC- MERCURIC OXIDE, SILVER, ZINC BIOACCUMULATE IN HUMAN TISSUE. Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE IN DRY STAGE. IF ELECTROLYTE IS ADDED TO THE BATTERY AND BATTERY LEAKS OR IN FIRE, CAN CAUSE EYES, SKIN, RESPIRATORY TRACT, MOUTH, STOMACH BURNS AND SEVERE IRRITATION. Medical Cond Aggravated by Exposure:NOT RELEVANT ======================= First Aid Measures ======================= First Aid:NONE FOR DRY BATTERY. FOR ELECTROLYTE, GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN /CPR IF NEEDED. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER/MILK. CALL A PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NOT RELEVANT Extinguishing Media:BATTERY CASE WILL BURN. USE DRY CHEMICAL EXTINGUISHER. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:AFTER ELECTROLYTE IS ADDED AND BATTERY IS BEING CHARGED, HYDROGEN GAS IS PRODUCED. BATTERY MAY EXPLODE IF HYDROGEN GAS TRAPPED INSIDE THE BATTERY CASE. ================== Accidental Release Measures ================== Spill Release Procedures:IF BROKEN, COLLECT FOR RECOVERY. DO NOT DRY SWEEP OR USE FORCED AIR. IF BATTERY CONTAINING ELECTROLYTE SHOULD BREAK OPEN, NEUTRALIZE POTASSIUM HYDROXIDE WITH BORIC ACID. DO NOT FLUSH TO SANITARY SEWER . COLLECT FOR DISPOSAL. Neutralizing Agent:FOR ELECTROLYTE, USE BORIC ACID. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE WITH CARE. AVOID FIRE OR INTENSE HEAT. AVOID SHORT CIRCUITING TERMINALS OF WET CELLS AND BATTERIES. Other Precautions:WASH HANDS BEFORE EATING OR DRINKING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. FOR DUST, FUME OR MIST, WEAR NIOSH-APPROVED RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:N1. MANUFACTURER PROVIDED 2 MATERIAL SAFETY DATA SHEETS. ONE FOR BATTERY FLUID, PNI C, AND ONE FOR DRY OR WET BATTERY, PNI B. UNDER NORMAL CONDITIONS OF USE OR SERVICE, THIS BATTERY DOES NOT EXPO SE THE USER TO TOXIC FUMES. PRIOR TO USE, CARE MUST BE TAKEN FILLING A DRY CELL WITH ELECTROLYTE (POTASSIUM HYDROXE). ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Decomp Temp:Decomp Text:NOT KNOWN Spec Gravity:NOT RELEVANT Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NOT RELEVANT Appearance and Odor:PRODUCT IS A DRY BATTERY - NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, SOLVENTS Stability Condition to Avoid:SHORT CIRCUTING POSITIVE AND NEGATIVE TERMINALS Hazardous Decomposition Products:MERCURIC OXIDE FUMES, HYDROGEN GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:CELLS AND BATTERIES CONTAIN SILVER AND SHOULD BE RECYCLED IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALL PURPOSE INSULATION CAGE:FO261 CAGE:FO261 CAGE:75165 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS OXIDE, FIBER GLASS WOOL, LEAD BOROSILICATE GLASS ENAMEL FLUX CAS:65997-17-3 Fraction by Wt: 85-98% Ingred Name:PHENOL, UREA, FORMALDEHYDE RESIN CAS:25104-55-6 Fraction by Wt: 2-15% Ingred Name:KRAFT, FOIL/KRAFT, PSK, FSK, AND VARIOUS METAL BUILDING FACINGS Fraction by Wt: <1-6.7% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF THE UPPER RESPIRATORY TRACT MAY OCCUR. SKIN/EYES: TEMPORARY IRRITATION. INGESTION: MAY CAUSE TEMPORARY IRRITATION TO THE GI TRACT/STOMACH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, SCRATCHY THROAT, COUGHING, CONGESTION, REDNESS. Medical Cond Aggravated by Exposure:PRE-EXISTING CHRONIC RESPIRATORY, SKIN/EYE DISEASES/CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. DRINK WATER TO CLEAR THROAT & BLOW NOSE TO REMOVE FIBERS & DUSTS. SKIN: WASH GENTLY W/SOAP & WARM WATER TO REMOVE DUST & FIBERS. WASH HANDS BEFORE EATING/USING THE RES TROOM. INGESTION: TREAT SYMPTOMATICALLY. RINSE MOUTH W/WATER TO REMOVE FIBERS & DRINK PLENTY OF WATER. EYES: DON'T RUB/SCRATCH. FLUSH W/LARGE AMOUNTS OF WATER FOR 5-15 MINS. (SEE SUPP) ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, WATER, WATER FOG, DRY CHEMICAL Fire Fighting Procedures:USE NORMAL FIRE FIGHTING PROCEDURES TO PREVENT INHALATION OF SMOKE & GASES. Unusual Fire/Explosion Hazard:NO POTENTIAL FOR FIRE/EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:PICKUP LARGE PIECES. VACUUM DUSTS. IF SWEEPING IS NECESSARY, USE A DUST SUPPRESANT SUCH AS WATER. DON'T DRY SWEEP DUST ACCUMULATION/USE COMPRESSED AIR FOR CLEAN-UP. THESE PROCEDURS WILL HELP TO MINIMI ZE POTENTIAL EXPOSURES. ======================Handling and Storage ====================== Handling and Storage Precautions:USE PROTECTIVE EQUIPMENT WHEN HANDLING UNCONTAMINATED MATERIAL. WAREHOUSE STORAGE SHOULD BE IAW/PACKAGE DIRECTIONS, IF ANY. Other Precautions:KEEP DRY & PROTECT FROM ELEMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED DUST/MIST RESPIRATOR(3M 9900 & MOLDEX 200)/EXPOSURE EXCEEDING TEN TIMES, A NIOSH APPROVED HALF MASK RESPIRATOR W/HEPA FILTER CARTRIDGE(MSA COMFO II W/H CARTRIDGES & THE SURVIVAIRHALF MASK W/#1090-00 CARTRIDGES. Ventilation:LOCAL EXHAUST TO REMOVE AIRBORNE DUST & FIBERS. GENERAL DILUTION: TO KEEP AIRBORNE DUST & FIBERS BELOW APPLICABLE LIMITS Other Protective Equipment:BARRIER CREAMS, LOOSE FITTING, LONG SLEEVED CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. USE A VACUUM CLEANER BEFORE REPAIR/MAINTENANCE TO REMOVE DUST/FIBERS. Supplemental Safety and Health APPEARANCE CONT'D: GOLD TO YELLOW FIBROUS GLASS BOARD, BATT, BLANKETT/LOOSE FILL INSULATION W/W/O KRAFT, FSK/OTHER FACINGS, NO SIGNIFICANT ODOR. FIRST AID CONT'D: OBTAIN MEDICAL ATTENTION IN ALL CASES . ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:1300F Solubility in Water:INSOLUBLE Appearance and Odor:(SEE SUPP) Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:PYROLYSIS/BURNING, OF THE RESIN Hazardous Decomposition Products:CO2, CO, CARBON PARTICLES, FORMALDEHYDE & TRACES OF HYDROGEN CYANIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: JET MELT, 3792-LM-TC Cage: 1BY21 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 1BY21 ======================================================= Ingredients ======================================================= Cas: 24937-78-8 POLYMER) % Wt: 60-70 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 68132-00-3 % Wt: 30-40 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- WHEN EMISSIONS ARE PRESENT AT ELEVATED ----------------------------- TO CHARACT VOLATS RELS DURING JET-MELT ----------------------------- FROM SIMULATED BRTHG ZONE OF POLYGUN USER ----------------------------- MEASURED IN PROD'S HEAD SPACE, CHEMS WERE NOT ----------------------------- LOWER LIMS OF ANALYTICAL DETECTION). THESE ----------------------------- PRACTICES ARE USED. HOWEVER, CUSTOMER ----------------------------- OCCUR. FOR THIS REASON, PROD SHOULD BE USED IN ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: YE CONT:VAPS FROM HEATED MATL MAY CAUSE IRRIT. SINGLE EXPOS MAY CAUSE MILD IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELL, PAIN & TEARING. SKIN: BURNS(FROM CONT W/MOLTEN MATL: SIGNS/SYMPS MAY INCL BURNING PAIN, RED & SWOLLEN SKIN & BLISTERS. MILD IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELL & ITCH. INHAL: (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:IRRIT(UPPER RESP): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGH & SNEEZING. VAPS OF HEATED MATL MAY CAUSE RESP SYS IRRIT. INGEST:NOT LIKELY RTE OF EXPOS TO THIS PROD. IRRIT OF GI TIS S: SIGNS/SYMPS CAN INCL PAIN, VOMITUS, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS & BLOOD IN FECES. OTHER HLTH HAZ(SUPDAT) Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE:IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN:IMMEDIATELY FLUSH AFFECTED AREA W/LARGE AMOUNTS OF WATER & COVER W/CLEAN DRESSING. DO NOT ATTEMPT TO REMOVE ADHESIVE. HAVE BURN TREATED BY MD. INHAL:REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL MD. INGEST:DO NOT INDUCE VOMITING. DRINK 2 GLASSES OF WATER. CALL MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: OBSERVE PRECAUTIONS FROM OTHER SECTIONS. COLLECT SPILLED MATERIAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF WASTE PRODUCT IN A SANITARY LANDFILL. SINCE REGULATIONS VARY, CONSULT APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS OR AUTHORITIES BEFORE DISPOSAL. Handling And Storage Precautions: AVOID EYE CONTACT W/VAPOR, SPRAY OR MIST. AVOID SKIN CONTACT W/HOT ADHESIVE & APPLICATOR TIP. AVOID PROLONGED BREATHING OF VAPORS. DO NOT INGEST. Other Precautions: KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: COC Flash Point Text: >450F,>232C Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: PROVIDE APPROPRIATE LOCAL EXHAUST FOR MOLTEN OR EXTRUDED MATERIAL. USE IN A WELL-VENTILATED AREA. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: APPEAR/ODOR:PUNGENT RESINOUS ODOR). EFTS OF OVEREXP:INFO:EXPOS TO THIS MATL IN NORMAL STOR & HNDLG HAS NOT BEEN REPORTED TO CAUSE SIGNIFICANT ADVERSE HLTH EFTS. HOWEVER, UNDER NORMAL PROCESSING CNDTNS , E.G., GRINDING/HEATING, THIS PROD MAYRELS FUMES & VAPS OF VARIABLE COMPOSITION BASED ON SPECIFIC PROCESS ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 Spec Gravity: 1.01 (H*2O=1) Solubility in Water: NIL Appearance and Odor: WAXY SOLID, TRANSLUCENT, SOLID ADHESIVE IN RODS; ODORLESS. (WHEN MOLTEN:(SUPDAT Percent Volatiles by Volume: 0 (WT) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: CARBON MONOXIDE & CARBON DIOXIDE. TOXIC VAPORS, GASES OR PARTICULATES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: JET MELT, 3792-LM-TC Cage: 1BY21 Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV Street: 3M CTR Zipcode: 55144-1000 Label Required IND: Y Date Of Label Review: 10/13/1994 Status Code: C Label Date: 10/13/1994 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE:EYE CONTACT:VAPORS FROM HEATED MATERIAL MAY CAUSE IRRITATION. SINGLE EXPOSURE MAY CAUSE MILD IRRITATION: SIGNS OR SYMPTOMS CAN INCLUDE REDNESS, SWELLING, PAIN & TEARING. SKIN:BURNS (FROM CONTACT W/MOLTEN MATERIAL: SIGNS OR SYMPTOMS MAY INCLUDE BURNING PAIN, RED & SWOLLEN SKIN & BLISTERS. MILD IRRITATION: SIGNS OR SYMPTOMS CAN INCLUDE REDNESS, SWELLING & ITCHING. INHAL:IRRITATION . INGEST:GASTROINTESTINAL IRRITATION. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:03-W-40 CATALYST,WHITE 17875,ISOCYANATE Kit Part:Y CAGE:EO418 CAGE:EO418 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 40.0% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5.0% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 20.0% OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9192 Ingred Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE) CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.2% ACGIH TLV:0.005 PPM; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:BIURET OF 1,6 HEXAMETHYLENE DIISOCYANATE (APPROX <35%) Fraction by Wt: 34.8% ===================== Hazards Identification ===================== Effects of Overexposure:EYES:MODERATE IRRIT;SKIN:POSSIBLE IRRIT BY SOLVENTS;INH:SOLVENT VAPORS CAN CAUSE IRRIT OR NARCOSIS ======================= First Aid Measures ======================= First Aid:SKIN:WIPE OFF WITH A RAG THEN THOROUGH RINSING W/H+2O & WASHING W/MILD SOAP AND WATER,EYES:FLUSH W/WATER FOR AT LEAST 10 MIN & CONSULT AN EYE PHYSICIAN;INH:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDE D. ===================== Fire Fighting Measures ===================== Flash Point:28F(-2.2C)-TOC Lower Limits:1.7 Extinguishing Media:CARBON DIOXIDE,FOAM OR DRY CHEMICALS Fire Fighting Procedures:USE SELF-CNTND BRTHNG APP;CAN USE H*2O SPRAY/FOG EFFECTIVLY. Unusual Fire/Explosion Hazard:CAUTION AGAINST APPLICATION TO HOT SURFACES & USE IN AREAS WHERE SOURCES OF IGNITION MAY BE PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTCTD PERSONS.ELIM IGN SOURCES.USE SAFETY EQUIP.VENTLATE AREA.STOP LEAK W/O RISK;ABSORB SM SPILL W/OIL ABSORBING COMPD/RAGS.PER MFR,FLUSH AREA W/LF AMT H*2O;DIKE LG SPILL.PUMP LIQ TO SALV AGE TANK.SHOVEL UP RESIDUE INTO COVEREDCONTNRS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW FIRE RISK AREA.KEEP CONTNRS TIGHTLY CLOSED.PROTCT FROM PHYSICAL DAMAGE. Other Precautions:AVOID PROLONGED INHALATION OF VAPORS.IF VENTILATION IS POOR,A FRESH AIR SUPPLY MASK IS RECOMMENDED.AVOID PHYSICAL CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR FOR PAINT,LAQUER,ENAMEL & ORGANIC VAPOR. Ventilation:ADEQUATE USING EXHAUST FAN. Other Protective Equipment:USE CARTRIDE TYPE RESPIRATOR W/PARTICULATE FILTERS. Supplemental Safety and Health TWO PART RESIN MODIFIED POLYURETHANE COATING;ITEM WAS UNDER MIL-C-81773.EFFECTV 80232,SPEC CANCELLED.NOW UNDER MIL-C-83286B,TYPE I;THIS DATA DESCRIBES CATALYST; SEE P/N IND "A" FOR BASE DATA. KEY1:F3. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175-331F Vapor Pres:29 Vapor Density:>1.0 Spec Gravity:0.933 Evaporation Rate & Reference:<1(SLWR THAN ETHR) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR THIN WATER WHITE ORGANIC LIQUID-ODOR OF MEK Percent Volatiles by Volume:71.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CORROSIVE OXIDIZING MATERIALS,WATER,ALCOHOLS,ETC. Stability Condition to Avoid:SOURCES OF IGNITION Hazardous Decomposition Products:CO,CO*2 &/OR OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN CLOSED CONTNRS PENDING DISPOSAL.MFR SUGGESTED,DISPOSE IN TIGHTLY CLOSED CONTAINERS & FINALLY DISPOSE BY SANITARY LANDFILL IAW APPLICABLE REGS;HANDLE & DISPOSE IN FULL COMPLIANCE W/ALL FED,STAT E,& LOCAL REGULATIONS CONCERNING WASTE DISPOSAL
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KEATING CLEANSER CAGE:JO370 CAGE:91694 CAGE:JO370 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICON DIOXIDE) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:THIS MATERIAL IS IDENTIFIED AS AN IRRITANT TO EYES AND RESPIRATORY TRACT. SCOURING POWDER IS NOT IRRITATING TO THE SKIN AND IS NOT HARMFUL IF SWALLOWED. SIGNS AND SYMPTOMS:EYE AND MUCOUS MEMBRAN E IRRITATION. Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS. (SUPDAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:AVOID CONTACT WITH EYES. AVOID BREATHING DUST. ======================= First Aid Measures ======================= First Aid:INGESTION:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES:WASH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. INHALATION:GET MEDICAL ATTENTION IF EXCESSIVE INHAL ATION OCCURS. REMOVE VICTIM TO FRESH AIR. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NO FIRE OR EXPLOSIVE HAZARD. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. NO FIRE OR EXPLOSIVE HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL CLEAN-UP PROCEDURES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED AREA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUSTY, WEAR NIOSH APPROVED MASK. Ventilation:LOCAL EXHAUST:NATURAL. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLAN OF CARCIN:1994:ANTICIPATED TO BE CARCINOGEN. ANIMAL:LUNG. ================== Physical/Chemical Properties ================== Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:WHITE POWDER-ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONFORM TO STATE, FEDERAL AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACE DRAIN CLEANER, 5070 CAGE:GURDP CAGE:2Y663 CAGE:GURDP ============= Composition/Information on Ingredients ============= Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT; (SODIUM HYPOCHLORITE) (CERCLA) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: 0-5% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 0-5% OSHA PEL:2 MG/M3, C ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT WITH SKIN, EYES OR MUCOUS MEMBRANES CAN CAUSE BURNS. EXPOSURE TO VAPORS DURING USE MAY BE IRRITATING. SWALLOWING MAY CAUSE BURNS TO MOUTH AND THROAT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN:REMOVE CONTAMINATED CLOTHING, FLUSH SKIN THOROUGHLY W/W ATER. INGEST:DO NOT INDUCE VOMITING! DRINK A GLASSFUL OF MILK OR WATER. CALL MD, POISON CONTROL CENTER OR EMERGENCY ROOM. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . NONFLAMMABLE. Unusual Fire/Explosion Hazard:MAY REACT W/ALUMINUM GENERATING HYDROGEN WHICH IS FLAMMABLE &/OR EXPLOSIVE IF IGNITED. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS MAY BE WASHED DOWN DRAIN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE ONLY IN ORIGINAL CONTAINER. READ ALL DIRECTIONS FOR USE & CAUTIONS ON LABEL BEFORE USING. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DO NOT USE MISTER PLUMBER IN COMBINATION W/OTHER HOUSEHOLD CLEANERS, TOILET BOWL CLEANERS OR DRAIN CLEANERS. DO NOT USE A PLUNGER DURING USE W/MISTER PLUMBER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE NORMALLY NEEDED. DO NOT BREATHE FUMES GENERATED DURING USE. Ventilation:NONE NORMALLY NEEDED. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . NONE NORMALLY NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:HVR/AIR Spec Gravity:1.1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX W/OTHER HOUSEHOLD CLEANERS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE/HYDROGEN GAS IS POSS IF MIXED W/CERTAIN TOILET BOWL CLEANERS/IF CONTACTED W/ALUMINUM CNTNRS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . SMALL SPILLS TO SEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICA GEL FOR DESSICANT CARTRIDGE Preparer's Name:G. RUSSELL CAGE:11426 CAGE:11426 ============= Composition/Information on Ingredients ============= Ingred Name:SILICON DIOXIDE (AMORPHOUS) CAS:67762-90-7 Fraction by Wt: 100% ACGIH TLV:10 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT W/SKIN & EYES MAY RESULT IN IRRITATION. IN THE FORM OF SILICA DUST, INHALATION MAY CAUSE IRRITATION OF EYES, NOSE & THROAT. PROLONGED INHALATION MAY RESULT IN PNEUMOCONIOSIS & IMPAIRED PULMONA RY FUNCTION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS W/LUNG PROBLEMS MAY BE MORE SERIOUSLY AFFECTED. ======================= First Aid Measures ======================= First Aid:EYES/SKIN:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. INHAL:REMOVE TO FRESH AIR. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP UP SMALL SPILL & DISCARD IN SOLID WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. Other Precautions:AVOID CONTACT W/SKIN OR EYES & BREATHING OF DUST. DO NOT INGEST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST RESPIRATOR IF DESIRED. Ventilation:MECHANICAL (GENERAL) IS SATISFACTORY. Other Protective Equipment:NONE. Work Hygienic Practices:WASH AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NEGLIGIBLE Appearance and Odor:ODORLESS BLUE GRANULES. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:OXIDATION. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD IN SOLID WASTE. DISPOSAL MUST BE IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
======================================================= Product ID: 7601 CROSSLINKER Cage: 5D028 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 5D028 Box: 997 Cage: 71984 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE:DIRECT CONTACT IRRITATES SLIGHTLY WITH REDNESS AND SWELLING. SKIN:A SINGLE SHORT EXPOSURE (LESS THAN 24 HOURS) MAY IRRITATE. REPEATED PROLONGED CONTACT (24-48 HOURS) MAY IRRITATE MODERATELY. INHAL :IRRITATES RESPIRATORY PASSAGES AND EYES VERY SLIGHTLY. INGEST:SMALL AMOUNTS TRANSFERRED TO THE MOUTH (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:BY FINGERS DURING USE, ETC. SHOULD NOT INJURE. SWALLOWING LARGE AMOUNTS MAY CAUSE DIGESTIVE DISCOMFORT. COMMENTS:NO KNOWN ADVERSE CHRONIC HEALTH EFFECTS, BUT UNNECESSARY EXPOSURE TO ANY CHEMI CAL SHOULD BE AVOIDED. Medical Cond Aggravated By Exposure: MAY ENHANCE ALLERGIC CONDITIONS. First Aid: EYE:FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WIPE OFF AND FLUSH WITH WATER. GET MD IF IRRITATION DEVELOPS. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) (FP N); IN GEST:CALL MD IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR SALVAGE OR DISPOSAL. REMOVE ALL SOURCES IF IGNITION AND WEAR PROPER PROTECTION EQUIPMENT. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS. CONTACT DOW CORNING IF THERE ARE ANY DISPOSAL QUESTIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED AND AWAY FROM HEAT, SPARKS, AND OPEN FLAME. Other Precautions: PRODUCT EVOLVES MINUTE QUANTITIES OF FLAMMABLE HYDROGEN GAS. DO NOT REPACKAGE OR STORE IN UNVENTED CONTAINERS. ADEQUATELY VENTILATE THE WORK AREA TO MAINTAIN VAPORS WELL BELOW ESTABLISHED FLAMMABILITY LIMITS AND EXPOSURE GUIDELINES. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point Text: 150F,66C Extinguishing Media: WATER FOG, CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: VAPORS ARE HEAVIER THAN AIR AND CAN TRAVEL ALONG THE GROUND TO REMOTE IGNITION SOURCES. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: MECHANICAL EXHAUST RECOMMENDED. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. REMOVE CONTAM CLTHG & SHOES AS SOON AS PRACTICAL & CLEAN (SUPP DATA) Supplemental Safety and Health: CNDTNS TO AVOID:FLAMMABLE HYDROGEN GAS, WHICH CAN FORM EXPLOSIVE MIXTURES IN AIR. HYGIENE PRACT:THOROUGHLY BEFORE REUSE. GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SK IN AS SOON AS PRACTICAL. ESPECIALLY BEFORE EATING OR SMOKING. ======================================================= Physical/Chemical Properties ======================================================= HCC: V4 Vapor Pres: <5 Spec Gravity: 0.97 Appearance and Odor: VERY LITTLE ODOR, LIQUID, SOME COLOR Percent Volatiles by Volume: <5(WT) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: WATER, ALCOHOLS, ACIDIC OR BASIC MATLS, & MANY METALS OR METALLIC COMPOUNDS, WHEN IN CONTACT W/PROD,LIBERATE (SUPP DATA) Materials To Avoid: OXIDIZING MATERIAL CAN CAUSE A REACTION. Hazardous Decomposition Products: SOX, CO2 AND TRACES OF INCOMPLETELY BURNED CO PRODUCTS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 25799 Product ID: 7601 CROSSLINKER Review Date: 01/13/1992 Multiple KIT Number: 0 Review IND: Y Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 7601 CROSSLINKER Cage: 5D028 Company Name: DOW CORNING CORP Street: 3901 S SAGINAW RD PO Box: 997 Zipcode: 48686-0997 Label Required IND: Y Date Of Label Review: 11/18/1991 Status Code: C Label Date: 11/18/1991 Origination Code: G Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: None Contact Hazard: Slight Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: ACUTE:COMBUSTIBLE. KEEP CONTAINER CLOSED AND AWAY FROM HEAT, SPARKS AND OPEN FLAME. DIRECT EYE CONTACT IRRITATES SLIGHTLY WITH REDNESS AND SWELLING. A SINGLE SHORT SKIN EXPOSURE (LESS THAN 24 HOURS) M AY IRRITATE. REPEATED PROLONGED CONTACT(24-48 HOURS) MAY IRRITATE SKIN MODERATELY. INHALATION IRRITATES RESPIRATORY PASSAGES SLIGHTLY. SWALLOWING LARGE AMOUNTS MAY CAUSE DIGESTIVE DISCOMFORT. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & NICKEL & STEEL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-85285B, #17038 TYPE I, 03BK071 CAT PART 2 OF 2 Kit Part:Y Preparer's Name:MIKE SMITH CAGE:FO129 CAGE:FO129 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:C8&10 AROMATIC HYDROCARBON, VAPOR PRESSURE 3 @ 68F CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 15% Other REC Limits:NOT RECOMMENED Ingred Name:ALIPHATIC ISOCYANATE (NOTE: 3-6MTHS STORAGE, FREE MOMOMER CONTENT MAY RISE, MAXIMUM OF 1.6%. MOBAY CEILING LEVEL 0.02) CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 50% Other REC Limits:0.005PPM MFR RECOMED Ingred Name:N-BUTYL ACETATE, VAPOR PRESSURE 13 @ 68F CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:NOT RECOMMENED OSHA PEL:150PPM; STEL 200PPM ACGIH TLV:150PPM; STEL 200PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL N-AMYL KETONE, VAPOR PRESSURE 2.1 @ 68F CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 35% Other REC Limits:NOT RECOMMENED OSHA PEL:50PPM ACGIH TLV:100PPM Ingred Name:VOC = 490 G/L RTECS #:9999999VO Other REC Limits:NOT RECOMMENED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: RESPIRATORY TRACT & NS DEPRESSION (HEADACHE, DIZZY, STAGGERING GAIT, CONFUSION, UNCONSCIOUS, COMA). EYE: IRRIT, TEARING, REDNESS, SWELLING, STINGING. SKIN: SWELLING, REDNESS, RASH. INGEST: CORR OSIVE IN THE MOUTH, STOMACH TISSUE, DIGESTIVE TRACT. VOMIT MAY CAUSE ASPIRATION OF SOLVENT (CHEMICAL PNEUMONITIS). Effects of Overexposure:SKIN: DRYING, DEFATTING, CRACKING. CHRONIC: ISOCYANATE SENSITIZATION. Medical Cond Aggravated by Exposure:ASTHMA & OTHER RESPIRATORY DISORDERS, SKIN ALLERGIES, ECZEMA, DERMATITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYE: FLUSH W/LUKEWARM WATER FOR 15 MINS. INGEST: DONT INDUCE VOMIT. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:76.0F,24.4C Lower Limits:1.00 Upper Limits:7.90 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG, WATER SPRAY. Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE EQUIPMENT. USE WATER TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT & OTHER IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE IGNITION SOURCES. CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HIGH TEMP & OTHER IGNITION SOURCES. STORE IN TIGHTLY CLOSED CONTAINERS & IN WELL VENTILATED AREA. Other Precautions:KEEP CONTAINERS TIGHT & UPRIGHT. SMOKE IN SMOKING AREAS ONLY. DONT HANDLE UNTIL MANUFACTURERS SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN AN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING OR FRESH AIR SUPPLIED). VAPOR PARTICULATE RESPIRATOR (TC23C NIOSH/MSHA) MAY BE APPROPRIATE WHERE AIR MONITORING DEMONSTRATES VAPOR LEVELS BELOW TEN TIMES EXPOSURE LIMITS. Ventilation:EXHAUST VENTILATION. Other Protective Equipment:USE LONG SLEEVE & LEG CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING, SMOKING, DRINKING. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:260-335F Vapor Density:>AIR Spec Gravity:0.97239 pH:NA Evaporation Rate & Reference:0.27 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:58.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS & SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:MOISTURE, MATERIAL WHICH REACT W/ISOCYANATES & HIGH TEMPERATURES. Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. EMPTY CONTAINERS HAVE PRODUCT RESIDUE & FLAMMABLE VAPORS. DONT INCINERATE CLOSED CONTAINERS. EPA CODE: D001, F003, F005. WASTE CHARACTERI STICS: IGNITABLE, REACTIVE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRESSURE CAR WASH Preparer's Name:JOEL POCHRON CAGE:19321 CAGE:19321 ============= Composition/Information on Ingredients ============= Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SODIUM METASILICATE) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: <10% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INGEST:LARGE AMOUNTS MAY CAUSE NAUSEA, VOMITING, CRAMPS & DIARRHEA. EXTREME CASES MAY CAUSE INTERNAL HEMORRHAGE OF INTESTINES. INHAL:MAY IRRITATE UPPER RESPIRATORY TRACT. SKIN CONTACT:CORROSIVE . CAN CAUSE MILD TO SEVERE IRRITATION. EYE CONTACT:CAN CAUSE CHEMICAL BURNS, TEARING, REDNESS & BLURRED VISION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOM. GIVE FLUIDS IMMED, IF VOM OCCURS, GIVE FLUIDS AGAIN. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCON PERS. SEEK IMMED MED ATTN. SKIN:RINSE AREA IMMED W/WATER. IF IRRIT PERSISTS, CO NT MD IMMED. INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN IF BRTHG IS DFCLT. EYES:FLUSH IMMED W/CONSPICUOUS AMT OF WATER FOR A MINIMUM OF 15 MINS, LIFTING UPPER/LOWER LIDS OCCASNLY. GET IMMED MED ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-COMBUSTIBLE. WILL NOT SUPPORT COMBUSTION. USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP FOR REUSE. RINSE AREA W/WATER TO LOCAL SEWER SYSTEM. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERALLY NOT REQUIRED. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV:DENSITY=60#.FT3, (7.188 ) (H2O=1) ================== Physical/Chemical Properties ================== Spec Gravity:SUPP DATA Solubility in Water:15% BY WEIGHT Appearance and Odor:WHITE GRANULAR MIXTURE. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL IS 100% BIODEGRADABLE. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:130 THIN SPREAD FLOOR TILE ADHESIVE CAGE:EO927 CAGE:11761 CAGE:EO927 ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT FUMES, ASPHALT, CUTBACK ASPHALT CAS:8052-42-4 RTECS #:CI9900000 Other REC Limits:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:PETROLEUM OIL, HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM), PETROLEUM DISTILLATES, MINERAL OIL (SEVERE) CAS:64742-52-5 RTECS #:PY8035001 Ingred Name:ALUMINUM SILICATE, BENTONITE, MONTMORILLONITE, CLAY CAS:1302-78-9 RTECS #:CT9450000 ACGIH TLV:10 MG/CUM (DUST) Ingred Name:1,3-BUTADIENE POLYMER, STYRENE-BUTADIENE POLYMER, SBS, SBS (BLOCK POLYMER) CAS:9003-55-8 RTECS #:WL6478000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INGESTION: GASTRIC DISTURBANCES. CHRONIC: PROLONGED/REPEATED CONTACT MAY PRODUCE SKIN IRRITATION & INFLAMMATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. INGESTION: GASTRIC DISTURBANCES. CHRONIC: PROLONGED/REPEATED CONTACT MAY PRODUCE SKIN IRRITATION & INFLAMMATION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS, REMOVE CONTACT LENSES IF WORN. SKIN: WASH EXPOSED AREA W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>200F Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL Fire Fighting Procedures:DON'T ENTER ANY ENCLOSED/CONFINED FIRE SPACE W/OUT PROPER PROTECTIVE EQUIPMENT, WHICH MAY INCLUDE SCBA. Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 212F. DRY PRODUCT CAN BURN. FROTHING MAY OCCUR W/EXTINGUISHING MEDIA. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, SCOOP MATERIAL INTO CONTAINER & REMOVE TO SAFE PLACE TO DRY. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXTREME HEAT & COLD. Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY AS DIRECTED ON LABEL. CLOSE CONTAINER AFTER EACH USE. DON'T REUSE CONTAINER. AVOID SKIN & EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Ventilation:OPEN DOORS & WINDOWS & UTILIZE OTHER MEANS TO ASSURE FRESH AIR ENTRY & EXHAUST. Other Protective Equipment:CLEAN WATER IN WORK AREA FOR FLUSHING EYES & SKIN. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. WASH W/SOAP & WATER AFTER HANDLING. Supplemental Safety and Health PERCENT VOLATILE VOLUME: 25-30/WT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<1 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:DISPERSIBLE Appearance and Odor:BLACK PASTE W/PINE ODOR Percent Volatiles by Volume:SUPP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALIES & OXIDIZING AGENTS. Stability Condition to Avoid:EXTREME HEAT & COLD, TEMP >212F. Hazardous Decomposition Products:FUMES & SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T FLUSH ADHESIVE DOWN DRAINS. NON-PHOTOCHEMICALLY REACTIVE ADHESIVE. UN 1133
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SMOOTHIE CAGE:10054 CAGE:10054 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHA PETROLEUM, HEAVY ALKYLATE C9-C12 BOILING PT 302-428F *92-4* CAS:64741-65-7 Fraction by Wt: 15-60% OSHA PEL:100 PPM TWA Ingred Name:NON-HAZARDOUS FOR INGREDIENTS Fraction by Wt: 40-85% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DISCOMFORT. INGESTION: VOMITING, ASPIRATION HAZARD WHICH CAN RESULT IN CHEMICAL PNEUMONITIS & PULMONARY EDEMA/HEMORRAGE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. USE OXYGEN OR ARTIFICIAL RESPIRATION AS REQUIRED. INGESTION: AVOID ASPIRATION OF LIQUID INTO THE LUNGS CAN RESULT IN CHEMICAL PNEUMONITIS & PULMONARY EDEMA/HEMORRAGE. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:600F Extinguishing Media:DRY CHEMICAL, CO2 OR FOAM Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. FIGHT FIRE FROM A SAFE DISTANCE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL SUCH AS VERMICULITE, SAND, ETC. SWEEP UP & COLLECT IN CONTAINERS TO BE DISPOSED OF AS SOLID WASTE. WASH AREA W/SOAP & WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE REASONABLE CARE FROM CONTAMINATION. KEEP OUT OF REACH OF CHILDREN, ISOLATED FROM FOOD & DRINK. Other Precautions:SPILLS SHOULD BE WIPED OFF COMPLETELY AS THE RESIDUE COULD BE SLIPPERY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED RESPIRATOR, USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. Ventilation:LOCAL EXHAUST/MECHANICAL: RECOMMENDED. USE EXPLOSION PROOF AS REQUIRED TO CONTROL VAPOR CONCENTRATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>375F Vapor Pres:1 Spec Gravity:0.98 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, COLORLESS W/VERY SLIGHT OILY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:HEAT & OPEN FLAME Hazardous Decomposition Products:CO, CO2, LOW MOLECULAR WEIGHT HYDROCARBON & SILICONE DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE APPROVED LANDFILL OR INCINERATION. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AEROSHELL GREASE 14 CAGE:27978 CAGE:27978 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 20-30% Other REC Limits:NONE SPECIFIED Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: 20-30% Other REC Limits:NONE SPECIFIED ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:SOLVENT REFINED, HYDROTREATED LIGHT PARAFFINIC DISTILLATE CAS:64742-55-8 RTECS #:PY8036500 Fraction by Wt: 35-40% Other REC Limits:NONE SPECIFIED Ingred Name:CALCIUM HYDROXYSTEARATE CAS:3159-62-4 Fraction by Wt: 10-12% Other REC Limits:NONE SPECIFIED Ingred Name:OTHER COMPONENTS Fraction by Wt: <2% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INGESTION:NOT EXPECTED TO CAUSE ILL EFFECTS. INHALATION:NO ADVERSE HEALTH EFFECTS EXPECTED. EYE: IRRITATION. SKIN: NOT NORMALLY EXPECTED TO CAUSE ILL EFFECTS. CHRONIC-PROLONGED/REPEATED SKIN CO NTACT MAY CAUSE IRRITATION, DERMATITIS,FOLLICULITIS OIL ACNE. Explanation of Carcinogenicity:THE COMPONENTS OF THIS PRODUCT HAVE NOT SHOWN ANY EVIDENCE OF BEING CARCINOGENIC. Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE SKIN IRRITATION. EYE CONTACT MAY CAUSE EYE IRRITATION. Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN DISORDER SHOULD AVOID PROLONGED CONTACT WHEN HANDLING OR USING THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:590F,310C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER FREE PRODUCT, OR ABSORB WITH DIATOMACEOUS EARTH OR OTHER INERT MATERIAL. STORE IN APPROPRIATE CONTAINER FOR DISPOSAL. KEEP PRODUCT OUT OF SEWERS AND WATERCOURSES. MINIMIZE SKIN CONTACT AND BRE ATHING VAPORS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORAGE NEAR OPEN FLAME OR OTHER SOURCES OF IGNITION,AND STRONG OXIDANTS. KEEP CONTAINERS CLOSED. Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE. DO NOT PRESSURIZE, CUT, WELD OR EXPOSE TO HEAT, FLAME, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED. Ventilation:SUFFICIENT TO MAINTAIN ATMOSPHERE BELOW TLV LIMIT. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CHEMICALLY RESISTANT BOOTS AND APRONS RECOMMENDED. Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT. WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK AREA. Supplemental Safety and Health WASH OR TAKE SHOWER IF GENERAL CONTACT OCCURS. REMOVE GREASE-SOAKED CLOTHING AND LAUNDER BEFORE REUSE. DISCARD CONTAMINATED LEATHER GENERATE D, OBSERVE A TWA/PEL OF 5 MG/M3 FOR MINERAL OIL MIST. ================== Physical/Chemical Properties ================== HCC:V6 Melt/Freeze Pt:M.P/F.P Text:284F,140C Spec Gravity:7.3 Solubility in Water:NEGLIGIBLE Appearance and Odor:TAN, SMOOTH, SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXTREMELY HIGH TEMPERATURES Hazardous Decomposition Products:FUMES,SMOKE, OXIDES OF CARBON, NITRGEN AND SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P136F37010 CAGE:00656 CAGE:00656 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY. INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE U NCONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KAOGUN 30 CAGE:19740 CAGE:19740 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0-15% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: 0-15% Other REC Limits:30 MG/CUM TOTAL DUST OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:PARTICULATES NOT OTHERWISE REGULATED (NUISANCE DUST) Fraction by Wt: >80% OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST; 8990 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE DELAYED LUNG INJRY (SILICOSIS). EYES/SKIN: MAY CAUSE TEMPORARY IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION. NUSIANCE DUST CAUSE NASAL. THROAT/LUNG IRRITATION/DISCOMFORT MAY AGGRAVATE BRONCHIAL. Medical Cond Aggravated by Exposure:NO ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK PLENTY OF WATER. SKIN: WASH W/MILD SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER. IF IRRITATION PLERSISTS, CALL A PHYSICIAN. ================== Accidental Release Measures ================== Spill Release Procedures:FOLLOW ROUTINE HOUSEKEEPING PROCEDURES. COLLECT SPILLED PRODUCT IN CLOSED CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:REMOVAL OF THIS PRODUCT AFTER USE MAY RESULT IN THE GENERATION OF DUST. Other Precautions:REPEATED INHALATION OF RESPIRABLE FREE CRYSTALLINE SILICA DUST MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FULL FACEPIECE RESPIRATOR W/APPROPRIATE FILTER PAD OR CARTRIDGE(S) Ventilation:LOCAL EXHAUST AND MECHANICAL Other Protective Equipment:AS REQUIRED TO MEET APPLICABLE OSHA STANDARDS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.9-3.1 Solubility in Water:INSOLUBLE Appearance and Odor:COARSE AGGREGATE W/FINE POWDERED MATRIX. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTES ARE NOT HAZARDOUS WASTES AS DEFINED BY RCRA (40 CFR 261). COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS. METHOD OF DISPOSAL IS LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPK 0151 HARDENER #AB0151 Kit Part:Y Preparer's Name:KEN DECOSTA CAGE:33564 CAGE:33564 ============= Composition/Information on Ingredients ============= Ingred Name:TRIETHYLENETETRAMINE (LD50 800MG/KG RABBIT, ORAL LD50 4340 MG/KG RAT) CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED ACGIH TLV:1 PPM Ingred Name:REACTIVE POLYAMIDE CAS:68410-23-1 Fraction by Wt: 60-100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: PAIN. SEVERE IRRIT W/CORNEAL INJURY, BLINDNESS, BURNS. SKIN: SEVERE BURNS. ALLERGIC REACTIONS, CORROSIVE. ABSORPTION. INHALATION: RESPIRATORY SENSITIZATION, UPPER RESP TRACT IRRIT. INGEST: GI IR RIT, ULCERATION, MOUTH/THROAT BURNS. Medical Cond Aggravated by Exposure:SKIN & EYE DISORDERS. SKIN OR LUNG ALLERGIES MAY INCREASE. EXPOSURE AGGRAVATES PRE-EXISTING ASTHMA. ======================= First Aid Measures ======================= First Aid:EYE: IRRIGATE W/WATER >30 MIN. GET MED AID ASAP. SKIN: IMMED FLUSH W/PLENTY OF WATER 15 MIN WHILE REMOVING CONTAM CLOTHING & SHOES. CALL DR. WASH CLOTHING BEFORE REUSE. DESTROY CONTAM LEATHER & SHOES WHICH CANT BE DECONTAMINATED. INGEST: DONT INDUCE VOMIT. GIVE LARGE AMOUNT WATER/MILK. TAKE TO DR. DONT GIVE ANYTHING TO UNCONSCIOUS PERSON. INHAL: REMOVE TO FRESH AIR. CALL DR. ===================== Fire Fighting Measures ===================== Flash Point:265F,129C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL FOR SMALL FIRES, FOAM FOR LARGE FIRES Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEANUP AND DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:AVOID SKIN AND EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FRESH AIR MASK IN CONFINED SPACES. Ventilation:LOCAL EXHAUST PREFERRED, MECHANICAL EXHAUST ACCEPTABLE. RESPIRATORS AVAILABLE IF VENTILATION FAILS. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Supplemental Safety and Health MORE INFORMATION ON FILE ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:500F,260C Vapor Pres:<0.01 Vapor Density:5.0 Spec Gravity:0.97 Evaporation Rate & Reference:<0.01 Solubility in Water:20% Appearance and Odor:TRANSLUCENT AMBER, MEDIUM VISCOSITY, SLIGHT AMMONIA ODOR Percent Volatiles by Volume:0.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND CHLORINATED COMPOUNDS Stability Condition to Avoid:NONE Hazardous Decomposition Products:NITROGEN OXIDES, CARBON DIOXIDE, AND CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:NA
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PYRIDINE FREE CHLOROFORM, H7972-6 Preparer's Name:MICHAEL J. SULLIVAN CAGE:JO299 CAGE:47125 CAGE:JO299 ============= Composition/Information on Ingredients ============= Ingred Name:CHLOROFORM (SARA 302/313) (CERCLA) CAS:67-66-3 RTECS #:FS9100000 OSHA PEL:50 PPM, C ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:HEADACHE, NAUSEA, DIZZINESS, DRUNKENNESS. CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E. G., EPINEPHRINE) MA Y BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . Explanation of Carcinogenicity:CHLOROFORM:IARC MONOGRAPHS, SUPP, VOL 7, PG 152, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE (SUPDAT) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMED . INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . EYES:IMMED & CONTINUOUSLY FLUSH W/FLOWING WATER FOR AT LST 15 MINS. SKIN:IMMED & CONTINUOUSLY FLUSH W /FLOWING WATER. NOTE TO MD:OVEREXP TO MANY OF CHLORINATED SOLVS, ESP IF ACCOMPANIED BY ANOXIA, MAY TEMPORARILY INCR CARDIAC IRRITABILITY. MAINTAIN ADEQ OXYGENATION UNTIL RECOVERY. AVOID (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT EQUIP . SLIGHT FIRE HAZARD WHEN EXPOSED TO HIGH HEAT: OTHERWISE PRACTICALLY NON-FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE W/REASONABLE CARE. AVOID BREATHING VAPORS. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY CAUSE FORMATION OF HCL &/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN AREAS OF HIGH CONCENTRATION, WEAR NIOSH/MSHA APPROVED SELF CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST &/OR MECHANICAL (GENERAL). Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLAN OF CARCIN:CARCINOGEN. ANIMAL:LIVER/KIDNEY TUMORS, CNS EFTS. FIRST AID PROC:SYMPTOMINETIC AMINES, SUCH AS EPINEPHRINE, WHICH MAY PRECIPITATE ARRHYTHMIAS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:142F,61C Melt/Freeze Pt:M.P/F.P Text:-82F,-64C Vapor Pres:160 @ 20C Vapor Density:4.13 Spec Gravity:1.49 Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID; ETHEREAL ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAUSTIC SODA ASH & OTHER STRONG BASES (VIOLENT EXOTHERMIC RXN), ALUMINUM & HOT METALS. Hazardous Decomposition Products:HCL, PHOSGENE . ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AVESTA MANUAL METAL ARC WELDING ELECTRODES, -15 CAGE:54649 CAGE:54649 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 2.35% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (CU) (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0-4% OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:IRON (FE) CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MANGANESE (MN) (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1-10% OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST Ingred Name:MOLYBDENUM (MO) CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 1-16% OSHA PEL:10 PPM ACGIH TLV:10 PPM Ingred Name:NICKEL (NI) (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0.1-0.5% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:NIOBIUM (NB) (ALSO CALLED COLUMBIUM) CAS:7440-03-1 RTECS #:QT9900000 Fraction by Wt: 0.5-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM (METAL (K)) CAS:7440-09-7 RTECS #:TS6460000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICON (SI) CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 1-10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SODIUM (NA) (CERCLA) CAS:7440-23-5 RTECS #:VY0686000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 1-10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM FLUORIDE (AS F) CAS:7789-75-5 RTECS #:EW1760000 Fraction by Wt: 1-25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM ALUMINUM FLUORIDE (NA*3ALF*6) CAS:15096-52-3 RTECS #:WA9625000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 1-20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CARBON DIOXIDE (CO2) CAS:124-38-9 RTECS #:FF6400000 OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL Ingred Name:CARBON MONOXIDE (CO) CAS:630-08-0 RTECS #:FG3500000 OSHA PEL:50 PPM ACGIH TLV:25 PPM Ingred Name:NITROGEN TETROXIDE; (NITROGEN DIOXIDE, DI) (CERCLA) CAS:10544-72-6 RTECS #:QX1575000 OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:NITROGEN MONOXIDE; (NITRIC OXIDE) (SARA 302) CAS:10102-43-9 RTECS #:QX0525000 OSHA PEL:25 PPM ACGIH TLV:25 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:NITROGEN DIOXIDE (SARA 302) CAS:10102-44-0 RTECS #:QW9800000 OSHA PEL:C 5 PPM ACGIH TLV:3 PPM/5 STEL EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:HYDROFLUORIC ACID; (HYDROGEN FLUORIDE) (SARA 302/313) (CERCLA) CAS:7664-39-3 RTECS #:MW7875000 OSHA PEL:3 PPM (F) ACGIH TLV:C 3 PPM(F) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:OZONE (SARA 302) CAS:10028-15-6 RTECS #:RS8225000 OSHA PEL:0.1 PPM ACGIH TLV:C 0.1 PPM Ingred Name:PHOSGENE (CARBONYL CHLORIDE) (SARA 302/313) (CERCLA) CAS:75-44-5 RTECS #:SY5600000 OSHA PEL:0.1 PPM ACGIH TLV:0.1 PPM Ingred Name:PHOSPHITE CAS:7803-81-2 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: ELEC ARC WELDING MAY CREATE ONE/MORE OF THE FOLLOWING HLTH HAZ: FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. SHORT-TERM OVEREXP TO WELDING FUMES MAY RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS/DRYNES S/IRRIT OF NOSE, THROAT/EYES. CHRONIC: OVEREXP TO WELDING FUMES CAN LEAD TO SIDEROSIS (IRON PRODS IN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL: IARC MONO ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 257, 1990: GROUP 2B. NTP 7TH ANNUAL RPT ON(SUP DAT) Effects of Overexposure:HLTH HAZ: LUNGS) & BELIEVED BY SOME INDIVIDUALS TO AFFECT PULM FUNC. ARC RAYS CAN INJURE EYES & BURN SKIN. ELEC SHOCK CAN KILL. CARBON MONOXIDE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONS ULT FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS . Medical Cond Aggravated by Exposure:AGGRAVATION OF RESPIRATORY OR ALLERGIC CONDITIONS MAY AFFECT SOME EXPOSED INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE AND CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUE RECOMMENDED BY THE AMERICAN RED CROSS. EYES: FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEE MD . SKIN : FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD . INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WELDING ARC & SPKS CAN IGNITE COMBUSTS & FLAMMS. REFER TO AMERICAN NATIONAL STANDARD Z49.1 FOR FIRE PREVENTION DURING THE USE OF WELDING AND ALLIED PROCEDURES. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS AND THE PRECAUTIONARY LABEL ON THE PRODUCT. Other Precautions:TRAIN EACH WORKER TO KEEP HIS/HER HEAD OUT OF THE FUMES. TRAIN EACH WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS AND TO INSULATE HIS/HER PERSON FROM WORK AND GROUND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR-SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV/PEL. Ventilation:USE ENOUGH VENT, LOC EXHST AT ARC/BOTH, TO KEEP FUMES & GASES BELOW TLV/PEL IN WORKER'S BRTHG ZONE & GEN AREA. Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . ARM PROTECTORS, APRONS, HATS, SHOULDER PROT, & DARK SUBSTANTIAL CLTHG. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR: CONSUMIBLES CONSISTING OF SOLID CORE W/FLUX COATING. EXPLAN OF CARCIN: CARCINS, 1994: ANTIC TO BE CARCIN. HUMAN: LUNGS. HAZ DECOMP PROD: WELDED & PROCESS, PROC, & ELECTRODES USED. CONTACT NEHC FOR MORE SPECIFIC INFORMATION ================== Physical/Chemical Properties ================== Appearance and Odor:CHROMIUM-NICKEL & NICKEL ALLOY COATED ELECTRODES ARE WELDING (SUP DAT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON METAL BEING (SUP DAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STAT E AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEMAND CS - CALIFORNIA Resp. Party Other MSDS Num.:US004666_01 CAGE:0X6X4 Contract Num:SP0450-00-M-D982 CAGE:64184 CAGE:0X6X4 ============= Composition/Information on Ingredients ============= Ingred Name:LAMBDA-CYHALOTHRIN TECHNICAL CAS:91465-08-6 = Wt:9.7 Ingred Name:OTHER INGREDIENTS = Wt:90.3 Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 < Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 >5000 MG.KG Health Hazards Acute and Chronic:IRRITANT (EYE, SKIN, RESPIRATORY PASSAGES, SKIN SENSITIZER). INHALATION (TLV) HARMFUL (ORAL) BASED ON THE AROMATIC PETROLEUM SOLVENT - IRRITANT (SKIN), HARMFUL (CENTRAL NERVOUS SYSTEM DEPRESSION, GAST ROINTESTINAL DISTURBANCE). Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:INGESTION (HYDROCARBON SOLVENT WITHIN MICROCAPSULE): SEVERE GASTROINTESTINAL DISTURBANCE, CNS DEPRESSION (DROWSINESS, DIZZINESS, LOSS OF COORDINATION, FATIGUE); ASPIRATION OF VOMITUS MAY CAUSE LUNG CO NGESTION, LABORED BREATHING, COMA, POSSIBLE DEATH. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.IF REDNESS,ITCHING OR A BURNING SENSATION DEVELOPS,HAVE EYES EXAMINED BY MEDICAL PERSONNEL.SKIN:WASH MATERIAL OFF WITH PLENTY OF SOAP & WATER. IF REDNESS,ITCHING OR BURNING SENSATION DEVELOPS,GET MEDICAL ATTENTION.INHALED:REMOVE VICTIM TO FRESH AIR.IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION. IF BREATHING LABORED,GIVE OXYGEN.CONSULT MEDICAL PERSONNEL.IF CONSCIOUS,WASH MOUTH WITH WATER.IMMEDIATELY CONTACT ZENECA AT 1-800-327-8633.INDUCE VOMITING ONLY UNDER MEDICAL GUIDANCE.IF VOMITING OCCURS,PUT HEAD DOWN BELOW WAIST. IMMEDIATELY TRANSPO RT TO EMERGENCY MEDICAL FACILITY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>100.C, 212.F Autoignition Temp:Autoignition Temp Text:N/DATA Lower Limits:NO DATA Upper Limits:NO DATA Extinguishing Media:WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, HALOGENATED AGENTS. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPRATUS WITH FULL FACEPIECE AND PROTECTIVE CLOTHING. KEEP FIRE EXPOSED CONTAINER COOL WITH WATER SPRAY TO PREVENT RUPTURE FOR EXCESSIVE HEAT. HIGH PRESSURE WATER HOSE MAY SPR EAD PRODUCT INCREASING CONTAMINATION OR FIRE HAZARD. CONTAIN RUN-OFF. Unusual Fire/Explosion Hazard:PRODUCT MAY SUPPORT COMBUSTION AFTER WATER CONTENT BOILED OFF (AS IN A FIRE). HEATING WILL GENERATE TOXIC VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PERSONAL PROTECTIVE CLOTHING & MATERIAL TO ENTER STREAMS,SEWERS OR OTHER WATERWAYS. SPREAD SUITABLE ABSORBENT ON THE SPILL & SHOVEL INTO OPEN DRUM.COVER CONTAMINATED AREA WITH COMMON HOUSEHOLD DETERGENT.USE STIFF BRUSH & WATER WATER,BRUSH AREA THEN LET STAND 2-3 MINUTES,SPREAD ABSORBENT INTO SLURRY THEN SHOVEL INTO DRUM. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS SHOULD BE STORED IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM FLAMMABLE MATERIALS AND SOURCES OF HEAT OR FLAME. EXERCISE DUE CAUTION TO PREVENT DAMAGE TO OR LEAKAGE FROM THE CONTAINER. DO NOT STORE NEAR FEED, FOOD, OR WITHIN THE REACH OF CHILDREN. Other Precautions:EMPTY CONTAINER RETAINS PRODUCT RESIDUE. OBSERVE ALL HAZARD PRECAUTIONS. DO NOTREUSE EMPTY CONTAINER EXCEPT FOR STORAGE OR SHIPMENT OF ORIGINAL PRODUCT. REMOVE ALL PRODUCT RESIDUE FROM CONTAINER & P UNCTURE OR OTHERWISE DESTROY EMPTY CONTAINER AND PUNCTURE OR OTHERWISE DESTROY EMPTY CONTAINER BEFOR E DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF NEEDED, USE MSHA-NIOSH APPROVED RESPIRATOR FOR PESTICIDES. Ventilation:USE VENTILATION ADEQUATE TO MAINTAIN SAFE LEVELS. IF NEEDED, USE LOCAL EXHAUST TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW THE TLV. Other Protective Equipment:THIS PRODUCT IS FIFRA REGULATED. REFER TO PRODUCT LABELING FOR END-USER PERSONAL PROTECTION REQUIREMENTS. WEAR IMPERVIOUS FOOTWEAR, LONG-SLEEVED CLOTHING AND WIDE BRIMMED HAT. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND WASH BEFORE RE-WEARING. WASH SEPARATELY FROM OTHER LAUNDRY. Supplemental Safety and Health AN ADEQUATE SUPPLY OF CLEAN POTABLE WATER SHOULD BE AVAILABLE TO ALLOW THOROUGH FLUSHING OF SKIN AND EYES IN THE EVENT OF CONTACT WITH THIS COMPOUND. ================== Physical/Chemical Properties ================== HCC:T5 Boiling Pt:>100.C, 212.F Vapor Pres:1.5 X 10E-9 @ 20C Vapor Density:NO DATA pH:7.3 Solubility in Water:DISPERSIBLE Appearance and Odor:OFF-WHITE LIQUID; SLIGHT ODOR TYPICAL OF AROMATIC PETROLEUM SOLVENT Percent Volatiles by Volume:NO DATA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES, AMMONIA. TRACE AMOUNTS OF HYDROGEN CYANIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:LD 50 INGESTION RAT, > 5000 MG/KG, MATERIAL IS CLASSIFIED AS "VERY LOW TOXICITY" BY INGESTION. IN HUMANS, INGESTION OF SOLVENT MAY CAUSE SEVERE GASTROINTESTINAL DISTURBANCE, CNS DEPRESSION (DROWSINESS , DIZZINESS, LOSS OF COORDINATION, FATIGUE); ASPIRATION OF VOMITUS MAY CAUSE LUNG CONGESTION, LABORED BREATHING, COMA, POSSIBLE DEATH.LC50 INHALATION RAT, > 4.62 MG/L, THIS MATERIAL IS CLASSIFIED AS " MODERATELY TOXIC" BY INHALATION. AT HIGH CONCENTRATIONS, VAPORS OR AEROSOLS OF THE SOLVENT CAN PRODUCE RESPIRATORY AND CNS DEPRESSION, HEADACHE, DIZZINESS & NAUSEA. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT CONTAMINATE WATERWAYS BY CLEANING OF EQUIPMENT OR BY DISPOSAL OF WASTES. UNTREATED EFFLUENT SHOULD NOT BE DISCHARGED WHERE IT WILL DRAIN INTO WATERWAYS. DISCARDED PRODUCT IS NOT A HAZARDOUS WAS TE UNDER RCRA, 40 CFR 261. =================== MSDS Transport Information =================== Transport Information:ROAD TRANSPORT DOT: NOT REGULATED BY DOT. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 313 SUPPLIER NOTIFICATION: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACTE O F 1986 (EPCRA) AND OF 40 CFR 372: <5% 1,2,4-TRIMETHYLBENZENE (CAS# 95-63-6). Federal Regulatory Information:EPA REGISTRATION NUMBER: 10182-361. TSCA (TOXIC SUBSTANCE CONTROL ACT) REGULATIONS, 40 CFR 710: THIS PRODUCT IS A PESTICIDE AND IS EXEMPT FROM TSCA REGULATION. State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS A TRACE AMOUNT OF CRYSTALLINE SILICA, A COMPOUND WHICH IS FOUND ON CALIFORNIA'S PROPOSITION 65 LIST. WHEN USED ACCORDING TO LABEL DIRECTIONS, EXPOSUREIS BELOW THE LEVEL WHICH REQUIRES A PROPOSITION 65 WARNING OR POSTING. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:BUFFER POWDER PILLOWS, CITRATE TYPE, FOR MANGANESE CAGE:91224 CAGE:91224 CAGE:4T252 CAGE:7Z016 CAGE:NO672 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PHOSPHATE, DIBASIC (SARA III) CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: <55% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CITRIC ACID,MONOHYDRATE CAS:77-92-9 RTECS #:GE7350000 Fraction by Wt: <25% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM SULFATE,ANHYDROUS CAS:7757-82-6 RTECS #:WE1650000 Fraction by Wt: <35% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE IRRITATING TO EYES, SKIN & RESPIRATORY TRACT. MAY CAUSE G/I IRRITATION, VOMITING, LETHERGY, DIARRHEA, FEVER, FLUID LOSS, FALL IN BLOOD PRESSURE AND MAY IMPAIR THE BODY'S ABILITY TO ABSORB CALCI UM. Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE CARCINOGENIC. Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, RESPIRATORY TRACT IRRITATION, VOMITING, LETHERGY, DIARRHEA, FEVER, FLUID LOSS, FALL IN BLOOD PRESSURE. Medical Cond Aggravated by Exposure:NONE REPORTED ======================= First Aid Measures ======================= First Aid:EYES & SKIN:IMMEDIATELY FLUSH EYES W/WATER FOR 15 MINUTES. CALL PHYSICIAN. FLUSH SKIN W/PLENTY OF WATER. INGESTION:GIVE LARGE QUANTITIES OF WATER. CALL PHYSICIAN IMMEDIATELY. INHALATION:REMOVE TO FRES H AIR. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:N/A. Lower Limits:N/A. Upper Limits:N/A. Extinguishing Media:WATER Fire Fighting Procedures:MFR GAVE NO INFORMATION OF MSDS. Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES IN FIRE. CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP POWDER. AVOID BREATHING MATERIAL. DISSOLVE IN WATER. FLUSH DOWN THE DRAIN W/EXCESS WATER. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM LIGHT. Other Precautions:AVOID CONTACT W/EYES & SKIN. DO NOT BREATHE DUST. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MFR GAVE NO INFORMATION OF MSDS. Ventilation:ADEQUATE VENTILATION Other Protective Equipment:EMERGENCY EYEWASH STATION AND SHOWER Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:N/A. Melt/Freeze Pt:M.P/F.P Text:320F,160C Vapor Pres:N/A. Vapor Density:N/A. Spec Gravity:2.3 pH:6.35 Evaporation Rate & Reference:N/A. Solubility in Water:SOLUBLE Appearance and Odor:WHITE CRYSTALLINE POWDER, NO ODOR Corrosion Rate:0.022 AL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MFR GAVE NO INFORMATION OF MSDS. Stability Condition to Avoid:HEAT, FLAMES, EXPOSURE TO MOISTURE Hazardous Decomposition Products:TOXIC SUMES OF PHOSPHORUS, SULFUR, CARBON AND SODIUM OXIDES Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & SYNTHETIC RUBBER COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ICRONIBSI 13 (PWA-996) BRAZE ALLOYS CAGE:UO704 CAGE:UO704 ============= Composition/Information on Ingredients ============= Ingred Name:BORON CAS:7440-42-8 RTECS #:ED7350000 = Wt:2.9 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CHROMIUM CAS:7440-47-3 RTECS #:GB4200000 = Wt:13. OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 = Wt:4. Ingred Name:NICKEL CAS:7440-02-0 RTECS #:QR5950000 = Wt:75.6 OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 = Wt:4.5 ACGIH TLV:15 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:THE ALLOYS IN SOLID FORM ARE GENERALLY NOT CONSIDERED HAZARDOUS. HOWEVER, IF YOUR PROCESS INVOLVES GRINDING, MELTING, WELDING, CUTTING, OR OTHER PROCESSES THAT CAUSE A RELEASE OF DUST OR FUME, THEN HA ZARDOUS LEVELS OF DUST OR FUME OF CONSTITUENTS OF THESE ALLOYS CAN CAUSE ACUTE TOXICITY. TARGET ORGANS: EYE, SKIN AND RESPIRATORY SYSTEM. Explanation of Carcinogenicity:SOME OF THE PRODUCT'S INGREDIENTS ARE FOUND ON THE FEDERAL OSHA Z LIST, NTP, CAL/OSHA OR IARC. CHROMIUM, COBALT-CHROMIUM ALLOYS, & NICKEL HAVE BEEN IDENTIFIED BY IARC &/OR NTP AS POTENTIAL CANCER CAUS ING AGENTS. Effects of Overexposure:USER GENERATED DUST & FUMES MAY ON CONTACT WITH THE SKIN OR EYES PRODUCE MECHANICAL IRRITATION. CHRONIC EXPOSURES COULD CAUSE DERMATITIS (SKIN) OR CONJUNCTIVITIS (EYES). EXCESSIVE INHALATION OF USER G ENERATED FUMES FROM WELDING/BRAZING WITH THESE PRODUCTS MAY, DEPENDING ON THE SPECIFIC FEATURES OF THE PROCESS USED, POSE A LONG-TERM HEALTH HAZARD. Medical Cond Aggravated by Exposure:CAUSING ALLERGIC REACTIONS IN INDIVIDUALS SENSITIVE TO THE METAL(S) CONTAINED IN THESE PRODUCTS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF LARGE AMOUNTS ARE INHALED, REMOVE TO FRESH AIR. SUPPORT RESPIRATION AS NEEDED. SEEK MEDICAL ATTENTION FOR TREATMENT, OBSERVATION AND SUPPORT AS NEEDED. SKIN CONTACT: WASH AFFECTED AREA WITH MILD DETERGENT AND WATER. EYE CONTACT: FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INGESTION: SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Lower Limits:NA Upper Limits:NA Extinguishing Media:DRY CHEMICAL OR SAND. DO NOT USE WATER ON METAL DUST FIRE. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN WHEN FIGHTING METAL DUST FIRES. Unusual Fire/Explosion Hazard:MAY OCCUR WITH CERTAIN METAL DUST FIRES. THIS MATERIAL IS NONCOMBUSTIBLE UNDER NORMAL CIRCUMSTANCES. HOWEVER, FINE POWDERS OR DUSTS (PRODUCED UPON GRINDING, CUTTING, ETC.) OF CERTAIN METALS CAN PRODUC E FIRE & EXPLOSION HAZARDS, UNDER CERTAIN CONDITIONS. DO NOT CREATE DUST CLOUDS. ================== Accidental Release Measures ================== Spill Release Procedures:IN CASE OF A SPILL, CLEAR THE AFFECTED AREA, PROTECT PEOPLE, & RESPOND WITH TRAINED PERSONNEL. FOR EXPOSURE TO PURIFYING RESPIRATOR WITH A HEPA FILTER. SWEEP UP THE SPILLED SOLID & PLACE ALL SPILL RESIDUE IN A DOUBLE PLASTIC BAG & SEAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID GETTING CHEMICAL ON YOU OR IN YOU. WASH HANDS AFTER HANDLING CHEMICALS. DO NOT EAT OR DRINK WHILE HANDLING CHEMICALS. ALL EMPLOYEES WHO HANDLE THIS MATERIAL SHOULD BE TRAINED TO HANDLE IT SAFELY . (SEE BELOW) Other Precautions:ALWAYS USE THIS PRODUCT IN AREAS WHERE ADEQUATE VENTILATION IS PROVIDED. DECONTAMINATE EQUIPMENT USING SOAPY WATER BEFORE MAINTENANCE BEGINS. XOLLECT ALL RINSATES AND DISPOSE OF ACCORDING TO APPLICABL E FEDERAL, STATE, OR LOCAL PROCEDURES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AN APPROPRIATE NIOSH APPROVED RESPIRATOR (IN ACCORDANCE WITH 29 CFR 1910.134) IF AIRBORNE DUST/FUME CONCENTRATIONS EXCEED THE APPLICABLE PEL OR TLV. ALL APPROPRIATE REQUIREMENTS IN 29 CFR 1910.134 SHOULD BE MET. USE AIR-SUPPLIED RESPIRATOR IN CONFINED SPACES. Ventilation:PROVIDE SUFFICIENT GENERAL AND LOCAL EXHAUST VENTILATION TO MAINTAIN AIR CONCENTRATIONS OF FUME OR DUST BELOW THE PEL AND TLV. Other Protective Equipment:EYEWASH FOUNTAINS SHOULD BE READILY AVAILABLE TO AREAS OF USE AND HANDLING. DEPENDING ON ENVEIRONMENT, Work Hygienic Practices:DO NOT TAKE CLOTHING HOME. Supplemental Safety and Health SPILL OR LEAK: USE NORMAL CLEAN-UP PROCEDURES, WET USING SWEEPING TAKING CARE TO AVOID CREATING DUST. VACUUM ONLY WITH HEPA FILTERED EQUIPMENT. DO NOT USE COMPRESSED AIR FOR CLEAN-UP. SOME FINE METAL POWDERS MAY IGNITE OR EXPLODE UNDER SPECIFIC CONDITIONS. TRAINED PERSONNEL USING PRE=PLANNED PROCEDURES SHOULD RESPOND. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:>450.C, 842.F M.P/F.P Text:450-1800 C Spec Gravity:6-9 Solubility in Water:INSOLUBLE Appearance and Odor:METALLIC, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE RESONABLY FORESEEABLE: COPPER IS EXPLOSIVELY INCOMPATIBLE WITH SODIUM OZIDE. COPPER DUST MAY REACT WITH ACETYLENE GAS TO FORM COPPER-ACETYLIDES, WHICH IS SENSITIVE TO SHOCK. Stability Condition to Avoid:OPEN FLAME FOR SOME FINE POWDERS. Hazardous Decomposition Products:METAL (OXIDE) FUME OR DUST. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:AS SHIPPED, THESE ALLOYS HAVE NO KNOWN (UNLESS INGESTED) TOXICOLOGICAL PROPERTIES OTHER THAN CAUSING ALLERGIC REACTIONS IN INDIVIDUALS SENSITIVE TO THE METAL(S) CONTAINED IN THESE PRODUCTS. USER GENER ATED DUST & FUMES MAY ON CONTACT WITH THE SKIN OR EYES PRODUCE MECHANICAL IRRITATION. CHRONIC EXPOSURES COULD CAUSE DERMATITIS (SKIN) OR CONJUNCTIVITIS (EYES). EXCESSIVE INHALATION OF USER GENERATED F UMES FROM WELDING/BRAZING WITH THESE PRODUCTS MAY, DEPENDING ON THE SPECIFIC FEATURES OF THE PROCESS USED, POSE A LONG-TERM HEALTH HAZARD. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CO NCLUDED THAT WELDING FUMES ARE POSSIBL ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL STABILITY: MOST OF THE METALS ELEMENTS ARE NATURALLY PRESENT IN THE SOIL & WATER. INDIVIDUAL METAL'S TRANSPORT IN THE ENVIRONMENT DEPENDS UPON THE EXACT COMPOUND, THE PH, THE SOIL TYPE,& THE SALINITY. ALL WORK PRACTICES SHOULD BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE PRODUCT USER TO DETERMINE AT THE TIME OF DISPOSAL WHETHER A MATERIAL CONTAIN THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE CLASSIFIED AS HAZARDOUS WASTE (40 CFR 261 .20). ALWAYS DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. WHER EVER POSSIBLE TRY TO RECYCLE AND RECLAIM THE METAL =================== MSDS Transport Information =================== Transport Information:THIS ALLOYS ARE NOT CONSIDERED HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE US DEPARTMENT OF TRANSPORTATION AT THE QUANTITY NORMALLY SHIPPED. FOR BULK SHIPMENT OF MORE THAN 1000 LBS SOME METALS MAY B E CONSIDERED HAZARDOUS. ===================== Regulatory Information ===================== SARA Title III Information:SARA 311/312: ACUTE-NO. CHRONIC-YES. FIRE-NO. PRESSURE-NO. REACTIVITY-NO (PURE/SOLI). SARA 313: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS, WHICH ARE SUBJECT TO REPORTING REQUIREMENTS OF SECTION 31 3 OF THE EMERGENCY PLANNING & COMMUNITY RIGHTTO-KNOW ACT OF 1986. CONSUMER MUST REVIEW THEIR SPECIFIC ALLOYS TO DETERMINE THE AMOUNT OF EACH ELEMENT USED: NICKEL, COPPER, SILVER, COBALT, MANGANESE, CH ROMIUM, MOLYBDENUM (TRIOXIDE ONLY), VANADIUM (FUME/DUST ONLY). Federal Regulatory Information:OSHA-COMPLY WITH HAZARD COMMUNICATION STANDARDS 29CFR1910.1200 & 1926.59 & RESPIRATORY PROTECTION STANDARD 29CFR 1910.134 & 1926.103. SOME COMPONENTS OF THIS PRODUCT ARE CONSIDERED TO BE HAZARDOUS AS DEFINED BY OSHA. TSCA-THESE ARE MIXTURE OF VARIOUS METALS COMPONENTS. THE CAS NUMBERS OF ALL INDIVIDUAL CHEMICALS ARE LISTED TSCA CHEMICAL INVENTORY. CERCLA-CHROMIUM & COMPOUNDS, COPPER AND COMPOUNDS,NICKEL & ITS COMPOUNDS, SILVER & ITS COMPOUNDS, VANADIUM (OXIDES & PENTAOXIDE), ZINC & COMPOUNDS. State Regulatory Information:PROPOSITION 65-THIS PRODUCT CONTAINS THE FOLLOWING "CHEMICALS KNOWN TO THE STATE OF CALIFORNIA" TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY: COBALT AND COBALT COMPOUNDS, CHROMIUM VI AND ITS COMPOUNDS , NICKEL AND NICKEL COMPOUNDS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TECTYL 2423 NST BLACK CAGE:IO754 CAGE:IO754 CAGE:72527 ============= Composition/Information on Ingredients ============= Ingred Name:RESIN EMULSION Fraction by Wt: 36-46% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESIN EMULSION Fraction by Wt: 9-19% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 5-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:ZINC PHOSPHATE; (ZINC PHOSPHATE DIHYDRATE) CAS:7779-90-0 RTECS #:TD0590000 Fraction by Wt: 5-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 1.3-11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PROPANOL, 1-PROPOXY-; (PROPYLENE GLYCOL MONOPROPYL ETHER) CAS:1569-01-3 RTECS #:UB9351000 Fraction by Wt: 1-11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CARBON BLACK; (PIGMENT DISPERSION) CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 1-9% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE) (SARA 313) (CERCLA) CAS:85-68-7 RTECS #:TH9990000 Fraction by Wt: 3.2% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BENZOIC ACID, AMMONIUM SALT; (AMMONIUM BENZOATE) (CERCLA) CAS:1863-63-4 RTECS #:DG3378000 Fraction by Wt: 1-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER WITH 2,2,4-TRIMETHYL-1,3-PENTANEDIOL; (TRIME-1,3-PENTANEDIOL, MONOISOBUTYRATE) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 1-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: DMG. THIS MATL (OR COMPONENT) HAS BEEN SHOWN TO CAUSE HARM TO FETUS IN LAB ANIMAL STUDIES. HARM TO (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: FETUS OCCURS ONLY AT EXPOS LEVELS THAT HARM PREGNANT ANIMAL. RELEVANCE OF THESE FINDINGS TO HUMANS IS UNCERTAIN. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: IF CONSCIOUS & ALERT, INDUCE VOMIT BY GIVING SYRUP OF IPECAC OR BY GENTLY PLACING TWO FINGERS (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: AT THE BACK OF THROAT. IF POSS, DO NOT LEAVE INDIVIDUAL UNATTENDED. INHAL: IF SYMPS DEVELOP, MOVE AWAY (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: FROM EXPOS & INTO FRESH AIR. IF SYMPS PERSIST, SEEK MED ATTN. IF BRTHG IS DFCLT, ADMIN OXYGEN. KEEP (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: PERSON WARM & QUIET; SEEK IMMED MED ATTN. RTECS #:9999999ZZ Ingred Name:SPILL PROC: STOP SPILL AT SOURCE. PVNT FROM ENTERING DRAIN, SEWERS, STREAMS OR OTHER BODIES OF WATER. PVNT FROM (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: SPREADING. IF RUNOFF OCCURS, NOTIFY AUTHS AS REQD. PUMP/VACUUM TRANSFER SPILLED PROD TO CLEAN CNTNRS (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: FOR RECOVERY. ABSORB UNRECOVERABLE PROD. TRANSFER CONTAMD ABSORB, SOIL & OTHER MATLS TO CNTNRS FOR (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: DISP. PVNT RUNOFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHS (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: AS REQUIRED, THAT A SPILL HAS OCCURED. RTECS #:9999999ZZ Ingred Name:RESP PROT: (CONSULT YOUR INDUSTRIAL HYGIENIST). ENGINEERING OR ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ Ingred Name:VENT: (FROM KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: EXPOS MAY CAUSE MILD IRRIT. SYMPS MAY INCL STINGING, TEARING & REDNESS. SKIN: EXPOS CAUSES IRRIT. PRLNGD/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS, BURNING, DRYING & CRACKING, SKIN BURNS & SKIN DMG. SKIN ABSORPTION IS POSS & MAYCONTRIBUTE TO SYMPS OF TOX FROM OTHER ROUTES OF EXPOS. INGEST: (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 24-27, 1995:GROUP 2B. Effects of Overexposure:HLTH HAZ: SINGLE DOSE ORAL TOX IS LOW. SWALLOWING SM AMTS DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS; SWALLOWING LARGE AMTS MAY BE HARMFUL W/GI IRRIT (NAUS, VOMIT, DIARR). INHAL: EXPOS TO V AP/MIST IS POSS W/IRRIT (NOSE, THROAT, RESP TRACT). TARGET ORGAN EFTS: OVEREXP TO THIS MATL (OR ITS COMPONENTS) (SUPDAT) Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & LUNG DISORDERS, EG ASTHMA-LIKE CNDTNS; BLOOD ABNORMALITIES, LIVER ABNORMALITIES, ANEMIA, SPLEEN DAMAGE, TESTIS DAMAGE, EYE DAMAGE, KIDNEY DAMAGE, LUNG DAMAGE. ======================= First Aid Measures ======================= First Aid:EYES: IF SYMPS DEVELOP, MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH EYES GENTLY W/WATER WHILE HOLDING LIDS APART. IF SYMPS PERSIST/IF VISUAL DFCLTY, SEEK MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH EX POS AREA W/SOAP & WATER. IF SYMPS PERSIST, SEEK MED ATTN. LAUNDER CLTHG BEFORE REUSE. INGEST: SEEK MED ATTN. IF DROWSY/UNCON, DO NOT GIVE ANYTHING BY MOUTH; PLACE ON LEFT SIDE W/HEAD DOWN. (ING 14) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:150F,66C Lower Limits:1.3% Upper Limits:25.0% Extinguishing Media:ALCOHOL FOAM, WATER FOG. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . REFER TO PERSONAL PROT EQUIP SECTION OF MSDS. COMBUST MAY FORM CARBON DIOXIDE & CARBON MONOXIDE, VARIOUS HYDROCARBS. Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND OR BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAMES & IGNIT SOURCES AT LOCATIONS DISTANT FROM (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL:ABSORB LIQ ON VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL. LG SPILL: ELIM ALL IGNIT SOURCES (FLARES,FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM A REA OF SPILL UNTIL CLEAN-UP COMPLETED. (ING 18) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALL FIVE GALLON PAILS & LARGER METAL CONTAINERS INCLUDING TANK CARS & TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATERIAL IS TRANSFERRED. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN DATA SHEET MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CTL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPS (NEG PRESS TYPE) UNDER SPECIFIED CNDTNS (ING 23) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENT TO MAINTAIN EXPOS BELOW LEVEL OF OVEREXPOSURE (ING 24) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR NORMAL WORK CLOTHING COVERING ARMS AND LEGS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. EFTS OF OVEREXP: HAS BEEN SUGGESTED AS CAUSE OF FOLLOWIN G EFTS IN LAB ANIMALS: BLOOD ABNORMS, LIVER ABNORMS, ANEMIA, SPLEEN DMG, TESTIS DMG, EYE DMG, KIDNEY DMG, LUNG (ING 12) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>97F,>36C Vapor Pres:28.28 @68F Spec Gravity:1.210 pH:9-10 VOC Grams/Liter:1.7 Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER Appearance and Odor:BLACK LIQUID. Percent Volatiles by Volume:57-63 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG MINERAL ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: TECHNOVIT 4000 POWDER Cage: KULZR ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: KULZR ======================================================= Contractor Summary ======================================================= Cage: KULZR ======================================================= Ingredients ======================================================= % Wt: 0-5 ----------------------------- Cas: 14808-60-7 RTECS #: VV7330000 CARC IARC-GROUP 2A; SUSPECTED CARC NTP) *95-3* % Wt: >90 Other REC Limits: 0.05 MG/CUM NIOSH OSHA PEL: 0.1 MG/CUM RESP DUST ACGIH TLV: 0.1 MG/CUM RESP DUST ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: SKIN: MAY CAUSE SENSITIZATION BY CONTACT. Explanation Of Carcinogenicity: SEE INGREDIENTS. Signs And Symptions Of Overexposure: SKIN: MAY CAUSE SENSITIZATION BY CONTACT. First Aid: SKIN: INSTANTLY WASH W/WATER & SOAP & RINSE THOROUGHLY. EYES: RINSE FOR SEVERAL MINS UNDER RUNNING WATER. INGESTION: INITIATE VOMITING & CONSULT A DOCTOR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COLLECT MECHANICALLY. DON'T ALLOW UNDILUTED PRODUCT/LARGE QUANTITIES OF IT TO REACH GROUND WATER, WATER BODIES/SEWAGE SYSTEM. Waste Disposal Methods: MUST NOT BE DISPOSED OF TOGETHER W/HOUSEHOLD GARBAGE. DON'T ALLOW PRODUCT TO REACH SEWAGE SYSTEM. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. NO:31442. PACKAGING CAN BE REUSED/RECYCLED AFTER CL EANING. Handling And Storage Precautions: STORE IN COOL, DRY PLACE IN TIGHTLY CLOSED CONTAINERS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CO2, EXTINGUISHING POWDER/WATER JET/ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures: FIGHT LARGER FIRES W/WATER JET/ALCOHOL RESISTANT FOAM. Unusual Fire/Explosion Hazard: FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING/IN CASE OF FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: NOT REQUIRED Other Protective Equipment: PERSONAL PROTECTIVE EQUIPMENT. Work Hygienic Practices: GENERAL PROTECTIVE & HYGIENIC MEASURES. INSTANTLY REMOVE ANY SOILED & IMPREGNATED GARMENTS. Supplemental Safety and Health: WASH HANDS DURING BREAKS & AT THE END OF THE WORK DAY. ======================================================= Physical/Chemical Properties ======================================================= Solubility in Water: INSOLUBLE Appearance and Odor: WHITE POWDER ODORLESS ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: NONE Hazardous Decomposition Products: IF USED & STORED ACCORDING TO SPECIFICATIONS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TECHNOVIT 4000 POWDER Cage: KULZR Company Name: HERAEUS KULZER GMBH Zipcode: 00000 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: SKIN: MAY CAUSE SENSITIZATION BY CONTACT. SKIN: MAY CAUSE SENSITIZATION BY CONTACT. =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:KVX23P156Q CAGE:14655 CAGE:14655 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MA 3800 + 3802 EPOXY ADHESIVE PREPREG CAGE:5X358 CAGE:5X358 ============= Composition/Information on Ingredients ============= Ingred Name:DGEBA EPOXY RESINS CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DGEBA BROMINATED EPOXY RESIN CAS:40039-93-8 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CARBOXY TERMINATED BUTYL NITRILE CAS:68891-50-9 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CYANOGUANIDINE. CAS:461-58-5 RTECS #:ME9950000 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ANTIMONY TRIOXIDE (SARA III) CAS:1309-64-4 RTECS #:CC5650000 Fraction by Wt: Other REC Limits:N/K OSHA PEL:0.5 MG/M3 (SB) ACGIH TLV:0.5 MG SB/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:DIMETHYLAMINO METHYL =PHENOL. CAS:25338-55-0 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:1-CYANOETHYL 2-ETHYL 4-METHYL IMDAZOLE CAS:23996-25-0 Fraction by Wt: Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POSSIBLE MINOR SKIN IRRITATION RESULTING FROM EXCESSIVE CONTACT WITH ADHESIVE. Explanation of Carcinogenicity:N/A Effects of Overexposure:POSSIBLE ITCHING & REDNESS OF HANDS. Medical Cond Aggravated by Exposure:SENSITIVE SKIN, ALLERGIES. ======================= First Aid Measures ======================= First Aid:INHALATION:N/A, EYES;FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES & GET MEDICAL ATTENTION. SKIN:WASH SKIN WITH SOAP & WATER, REMOVE CONTAMINATED CLOTHING & WASH. INGESTION:NOT A PROBABLE ROUTE OF ENT RY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F (>93C) Lower Limits:NOT DETERMIN Upper Limits:NOT DETERMIN Extinguishing Media:FOAM CO:2, DRY CHEMICAL Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:N/A- FILM ADHESIVE. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT 0F (-18C) FOR LONG SHELF LIFE. Other Precautions:N/K ============= Exposure Controls/Personal Protection ============= Respiratory Protection:N/A - SOLID FILM Ventilation:SUGGESTED MECHANICAL(GENERAL) IS OK. Other Protective Equipment:CLEAN LONG SLEEVE &LONG LEG CLOTHING. Work Hygienic Practices:NORMAL GOOD INDUSTRIAL HOUSE KEEPING. Supplemental Safety and Health N/A:NOT APPLICABLE. PCT VOLT-VOL & PH. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:>140F(>60C) Decomp Temp:Decomp Text:N/K Vapor Pres:N/A-SOLID Spec Gravity:1.2 Evaporation Rate & Reference:N/K Solubility in Water:NEGLIGIBLE Appearance and Odor:CREAM COLORED FILM ON GLASS CARRIER. Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES N/K Stability Condition to Avoid:N/K Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, ALDEHYDES, & OTHER ORGANICS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS . BURY IN AN APPROVED LANDFILL.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:CY-CYP ACTIVATED CARBON CAGE:HO835 CAGE:4U654 CAGE:HO835 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS NON-TOXIC THROUGH INGESTION AND SKIN ABSORPTION. ACTIVATED CARBON IS NOT A PRIMARY SKIN IRRITANT. NO SENSITIZATION EFFECTS ARE KNOWN. THE PHYSICAL NATURE OF THIS PRODUCT MAY IRRITATE T HE RESPIRATORY SYSTEM. THE PHYSICAL NATURE OF THIS PRODUCT MAY PRODUCE EYE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGESTION:CALL MD IMMEDIATELY . INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONTACT A DOCTOR IMMEDIATELY. INHALA TION:THE PERSON SHOULD BE REMOVED FROM THE AREA. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, CO*2, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONTACT WITH STRONG OXIDIZERS MAY RESULT IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:UNUSED PRODUCT SHOULD BE SWEPT UP AND DISCARDED OR REPACKAGED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CAUTION! WET ACTIVATED CARBON REMOVES OXYGEN FROM THE AIR CAUSING A SEVERE HAZARD TO WORKERS IN CONFINED SPACES. Other Precautions:SAMPLING AND WORK PROCEDURES FOR LOW OXYGEN LEVELS SHOULD BE TAKEN WHENEVER WORKERS MAY BE ENTERING CARBON VESSELS, ENCLOSED OR CONFINED SPACES. ALL FEDERAL, STATE AND LOCAL REGULATIONS SHOULD BE OBSE RVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED HIGH EFFECIENCY PARTICULATE FILTER IS RECOMMENDED WHENEVER EXCESSIVE DUST MAY BE GENERATED. Ventilation:LOCAL EXAUST IS RECOMMENDED, SUFFICIENT TO CONTROL DUST. Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:0.3-0.7 Solubility in Water:NOT SOLUBLE Appearance and Odor:ODORLESS BLACK SOLID FLAKE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZERS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CARBON MONOXIDE MAY BE FORMED IN THE EVENT OF A FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . UNUSED CARBON MAY BE DISPOSED OF BY ANY APPROPRIATE MEANS.
1
eyes_protection_mandatory
======================================================= Product ID: LIQUID ROC 300 POLYESTER PUMP, PART A Kit Part: Y Cage: GUNNE Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 79038 Box: UNKNOW Cage: GUNNE ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: CAUSES EYE BURNS. SKIN IRRITANT. CAN HAVE A NARCOTIC EFFECT IF INHALED. CAN CAUSE ALLERGIC SKIN AND RESPIRATORY CONDITION. "STYRENE SICKNESS" CONSISTING OF DROWSINESS, NAUSEA, HEADACHE, FATIGUE AND DI ZZINESS HAS BEEN MENTIONED IN WORKERS EXPOSED AT 200-700 PPM. CRYSTALLINE SILICA IS CONSIDERED BY IARC (EFTS OF OVEREXP) Explanation Of Carcinogenicity: STYRENE:IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 345, 1987:GROUP 2B. ANIMAL:NERVOUS SYSTEM. Signs And Symptions Of Overexposure: HLTH HAZ:TO BE AN ANIMAL CARCINOGEN. THE NATURE AND USE OF THIS PRODUCT SHOULD NOT POSE A CANCER RISK TO HUMANS. Medical Cond Aggravated By Exposure: SKIN & EYE CONDITIONS. First Aid: EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. CALL MD. SKIN:WASH W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. INHAL:MOVE VICTIM TO FRESH AIR. GIVE OXYG &/OR ARTF RESP IF NEEDED . CALL MD. INGEST:GIVE PLENTY OF WATER TO DRINK. DO NOT INDUCE VOMIT. CALL MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. OTHER:REFERRAL TO MD IS REC IF THERE IS ANY QUESTIONS ABOUT THE SERIOUSNESS O F THE INJURY/EXPOSURE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. COVER W/ABSORBENT MATERIAL & PLACE IN SALVAGE CONTAINER FOR PROPER DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: CONSULT W/LOCAL REGULATORY AGENCIES OR CORPORATE PERSONNEL FOR DISPOSAL METHODS THAT COMPLY W/LOCAL, STATE & FEDERAL HEALTH & ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: KEEP IN COOL, DRY PLACE OUT OF DIRECT RAYS OF SUN. STORE <100F. KEEP AWAY FROM IGNIT SOURCES SUCH AS EXCESS HEAT, SPKS & OPEN FLAME. FLAMMABLE. Other Precautions: WARNING! CAUSES EYE BURNS & SKIN IRRIT. CAN HAVE ANESTHETIC EFT IN INHALED. CAN CAUSE ALLERGIC SKIN & RESP RXNS. AVOID CONTACT W/EYES, SKIN & CLTHG. AVOID BREATHING IN VAPOR. AVOID PROLONGED OR REPEAT ED CONTACT W/SKIN. USE W/ADEQUATE VENT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 93.0F,33.9C Lower Limits: 1.1% Upper Limits: 6.1% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). COOL W/WATER SPRAY. Unusual Fire/Explosion Hazard: OSHA CLASS IC - FLAMMABLE LIQUID. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. DECOMPOSITION & COMBUSTION PRODUCTS, MAY BE TOXIC. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR WHEN VAPOR CONCENTRATIONS EXCEED RECOMMENDED EXPOSURE LIMITS. Ventilation: GENERAL - NATURAL OR MECHANICALLY INDUCED FRESH AIR MOVEMENTS THAT MAINTAIN VAPOR CONCS BELOW REC EXPOSURE LIMITS. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: NOTE: USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). APPEARANCE/ODOR: PLASTIC CAULKING TUBE. PART A IS THE LARGE TUBE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >248F,>120C Vapor Pres: SEE ING 3 Vapor Density: SEE ING 3 Spec Gravity: 0.89 Solubility in Water: NIL Appearance and Odor: LIGHT GREY PASTE; STYRENE ODOR.POLYESTER SYS PACKAGED IN DUAL COMPONENT(SUPDAT) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE AT TEMPERATURES Materials To Avoid: STRONG ACIDS, PEROXIDES & OTHER OXIDIZING AGENTS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LIQUID ROC 300 POLYESTER PUMP, PART A Cage: GUNNE Company Name: GUNNEBO FASTENING CORP Street: 180 SOUTH HARTMAN STREET Zipcode: 17405 Label Required IND: Y Date Of Label Review: 12/20/1996 Status Code: C Label Date: 12/20/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. ACUTE:CAUSES EYE BURNS. SKIN IRRITANT. CAN HAVE A NARCOTIC EFFECT IF INHALED. CAN CAUSE ALLERGIC SKIN AND RESPIRATORY CONDITION. "STYRENE SICKNESS" CONSISTING OF DROWSINESS, NAUSEA, HEADACH E, FATIGUE AND DIZZINESS HAS BEEN MENTIONED IN WORKERS EXPOSED AT 200-700 PPM. CHRONIC:CANCER HAZARD. CONTAINS MATERIAL WHICH IS LISTED AS AN ANIMAL NERVOUS SYSTEM CARCINOGEN (FP N). CRYSTALLINE SILIC A IS CONSIDERED BY IARC TO BE AN ANIMAL CARCINOGEN. THE NATURE AND USE OF THIS PRODUCT SHOULD NOT POSE A CANCER RISK TO HUMANS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RUST PREVENTATIVE TM-1822 CAGE:FO810 CAGE:2F853 CAGE:FO810 CAGE:NO710 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 62% Other REC Limits:N/K OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Other REC Limits:N/K OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:ALIPHATIC PETROLEUM DISTILLATES (HYDROTREATED LIGHT NAPHTHENIC DISTILLATE). CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: 15% Other REC Limits:5 MG/M3 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TZ4300000 Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:LONG TERM EXPOSURE (YEARS):VAPOR MAY CAUSE LUNG,LIVER OR KIDNEY DAMAGE. Explanation of Carcinogenicity:ALIPHATIC PETROLEUM DISTILLATES (64742-53-6):SUFF EVID FOR CARC IN ANIM,SUFF EVID FOR CARC IN HUMANS (IARC,1984). Effects of Overexposure:EYES:N/K .SKIN:REDNESS.WILL CAUSE DEFAT.EFTS ARE REVERSIBLE.INGEST:VOMIT.INHAL:DFCLT BREATHING,MAY CAUSE DIZZINESS OR NARCOSIS IN HIGH VAPOR CONCENTRATIONS.LONG TERM EXPOSURE (YEARS):VAPOR MAY CAUSE LUNG,LIVER OR KIDNEY DAMAGE.THE SOLVENTS LISTED HAVE BEEN REPORTED TO AFFECT THE CENTRAL NERVOUS SYSTEM. Medical Cond Aggravated by Exposure:GENERALLY AGGRAVATED BY EXPOSURE:HEART DISEASE,RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES:WASH WITH WATER FOR AT LEAST 15 MINUTES.SKIN:WASH WITH WATER.INGESTION:DO NOT INDUCE VOMITING,GASTRIC LAVAGE.INHALATION:GIVE OXYGEN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F,-40C Lower Limits:12.0% Upper Limits:1.8% Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE. Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT .AEROSOL CANS MAY RUPTURE WHEN HEATED. Unusual Fire/Explosion Hazard:HEATED CANS MAY BURST.HAZARDOUS DECOMPOSITION PRODUCTS:HCL ,PHOSGENE,HALOGEN ACIDS,CARBON DIOXIDE,WATER. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT SWEEPING COMPOUND TO SOAK UP MATERIAL.PUT INTO CONTAINER.DISPOSE AS HAZARDOUS WASTE. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS,OPEN FLAME.STORE AT TEMP <120F,48.89C. Other Precautions:NO SMKNG IN AREA OF USE.DO NOT USE IN GEN VICIN OF ARC WELDING,OPEN FLAMES,HOT SURF.HEAT &/OR UV RADIA MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .USE NIOSH/MSHA APPRVD RESP WHEN SPRAYING MORE THAN ONE HALF CAN CONTINUOUSLY,(SUP DA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .USE SCBA ABOVE TLV LIMIT. Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:LONG SLEEVES,LONG PANTS. Work Hygienic Practices:DO NOT SMOKE WHILE USING.WASH HANDS AFTER USE. Supplemental Safety and Health BP RANGE:-40F,-40C TO UNKNOWN.VP:63 PSIG @ 70F,21.11C.OTHER PREC:MORE THAN ONE CAN CONSECUTIVELY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP Melt/Freeze Pt:M.P/F.P Text:N/A (LIQ) Decomp Temp:Decomp Text:N/K Vapor Pres:SEE SUPP Vapor Density:4.0,AIR=1 Spec Gravity:0.8 (WATER=1) Evaporation Rate & Reference:<3 (BUTYL ACETATE=1) Solubility in Water:NIL Appearance and Odor:BROWN LIQUID WITH SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THE SOLVENTS ARE INCOMPATIBLE WITH STRONG OXIDIZERS.NOT COMPATIBLE WITH ACTIVE METALS. Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:HCL,PHOSGENE .IN FIRE WILL DECOMPOSE TO WATER,CARBON DIOXIDE,HALOGEN ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETYLENE, ETHYNE, ETHINE CAGE:00742 CAGE:00742 CAGE:5H199 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE, ETHYNE, ETHINE CAS:74-86-2 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DO NOT ENTER AREAS WITHIN THE FLAMMABLE RANGE DUE TO THE IMMEDIATE FIRE AND EXPLHAZARD. ACETYLENE IS A SIMPLE ASPHYXIANT, IRRITANT, AND ANESTHETIC. Effects of Overexposure:SYMPTOMS SUCH AS HEADACHES, DIZZINESS, SHORTNESS OF BREATH, & LOSS OF CONSCIOUS-NESS MAY OCCUR IF THE GAS IS PRESENT IN QUANTITIES SUFFICIENT TO DILUTE THE OXY CONCENTRATION IN AIR. SYMPTOMS OF ANOXIAOCCUR ONLY WHEN THE GAS CONCENTRATIONSARE WITH THE FLAMMABLE RANGE AND THE MIXTURE HAS NOT IGNITED. ======================= First Aid Measures ======================= First Aid:FIRST DEGREE & MINOR SECOND DEGREE THERMAL BURNS FROM FIRES SHOULD BE IMMERSEDIN COOL WATER FOR 30 MIN. MAJOR SEC & THIRD DEGREE BURNS SHOULD BE COVERED INTHE CLEANEST MATERIAL AVEIL. SEEK IMMEDI ATE PHYSICIAN AID. PERSONS SUFFERINGFROM LACK OF OXY SHOULD BE MOVED TO AREAS WITH NORMAL ATMOS. CPR SHOULD BE GIVENIF VICTIM IS NOT BREATHING. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:0F/-18C Autoignition Temp:Autoignition Temp Text:581F Lower Limits:100% Upper Limits:2.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, HALON Fire Fighting Procedures:TOP GAS FLOW. USE WATER SPRAY TO KEEP CYL. COOL IF EXPOSED TO FIRE. KEEP PERSONSWAY SINCE CONTAINERS CAN RUPTURE VIOLENTLY. SEE CGA SAFETY BULLETIN SB-4. Unusual Fire/Explosion Hazard:ACETYLENE IS EXTREMELY FLAMMABLE & EXPLOSIVE.IT BURNS WITH INTENSELY HOT FLAME. IGNITES VERY EASILY.VERY WIDE FLAMMABLE LIMITS. POCKETS RATHER THAN DISSIPATES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA TO PREVENT FLAMMABLE MIXTURE FORM FORMING. REMOVE SOURCES OF IGNITION, HEAT, SPARKS,ETC. AVOID ENTERING AREA OF FLAMMABLE ATMOS. CARE-FULLY REMOVE CYLINDERS WITH SLOW LEAKS TO A REMOTE OUTDOOR LOCATION.CONTACT AIR PRODUCTS FOR ASSISTAN ======================Handling and Storage ====================== Handling and Storage Precautions:USE IN WELL VENTILATED AREA.KEEP ACETYLENE CYLINDEUPRIGHT & SECURE.NEVER EXPOSE TO HEAT. SEGREGATE FULL/EMPTY CYL. ALWAYS OPEN/CLOSE VALVES SLOWLY. Other Precautions:AVOID EXPOSURE TO AREAS WHERE SALT OR OTHER CORROSIVE CHEMICALS ARE PRESENT.KEEPACETYLENE CYL. STORAGE AREAS AWAY FROM STORAGE OF OXY & OTHER OXIDIZERS. AVOID HAZARDOUS MIXTURES & SOURCES OF IGNITION .DO NOT REFILL COMPRESSED GAS CYLINDERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OXYGEN-DEFICIENT ATMOSPHERES ARE IN THE FLAMMABLE RANGE. DO NOT ENTER! RESPIRATORS WILL NOT FUNCTION. Ventilation:NATURAL OR MECHANICAL WHERE GAS IS PRESENT. Other Protective Equipment:LEATHER SLEEVES, LEATHER APRON AND OTHER STANDARD PROTECTIVEEQUIPMENT FOR CUTTING AND WELDING. Supplemental Safety and Health MECHANICAL VENTILATION FOR ENCLOSED STORAGE AREAS MUST MEET NATIONAL ELECTRICAL CODE REQUIREMENTS FOR CLASS 1, GROUP A.FORMATION OF EXPLOSIVE COPPER ACETYLIDECAN BE AVOIDED BY USING COPPER ALLOYS PR OVED SUCCESSFUL THROUGH USE IN INDUSTRY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-119F/-84C Vapor Pres:*SEE BELOW Vapor Density:*SEE BELOW Spec Gravity:68F20C1ATM0.906 Solubility in Water:1ATM 1. CUFT/CUFTH20 Appearance and Odor:PURE ACETYLENE IS COLORLESS & ODORLESS. IMPURITIES GENERATE GARLIC-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO OXIDIZERS SUCH AS OXYGEN & HALOGENS. FORMS EXPLOSIVE COMPNDSW/COPPER,BRASS,COPPER SALT,HG/HG SALTS,K,AG/AG SALTS,& HNO3. Stability Condition to Avoid:NEVER UTILIZE FREE GAS OUTSIDE CYL. AVOID MECH. SHOCKS TO CONTAINERS. NEVER EXPOSE CYLINDERS TO SOURCES OF HEAT. Hazardous Decomposition Products:ACETYLENE WILL DECOMPOSE INTO ELEMENTAL CARBON & HYDROGEN UNDER THE ABOVE CONDITIONS IN MATERIALS TO AVOID. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF RESIDUAL GASEOUS ACETYLENE IN CYLINDERS. RETURN TO AIR PRODUCTS INCFOR DISPOSAL.
1
eyes_protection_mandatory
======================================================= Product ID: DA 6960 KRYOLIUM BULLDOG RED Cage: 64557 ======================================================= Contractor Summary ======================================================= Cage: 64557 ======================================================= Ingredients ======================================================= Cas: 74-98-6 RTECS #: TX2275000 Percent by Wt: 15. OSHA PEL: 1800 MG/M3;1000 PPM ACGIH TLV: 1800 MG/M3 ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 Percent by Wt: 11.7 OSHA PEL: 100 PPM OSHA STEL: 150 PPM ACGIH TLV: 434 MG/M3; 100 PPM ACGIH STEL: 651 MG/M3;150 PPM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 67-64-1 RTECS #: AL3150000 Percent by Wt: 17.8 OSHA PEL: 750 PPM OSHA STEL: 1000 PPM ACGIH TLV: 1780 MG/M3;750 PPM ACGIH STEL: 2380 MG/M3;1000 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 100-41-4 RTECS #: DA0700000 Percent by Wt: 2.9 OSHA PEL: 435 MG/M3;100 PPM ACGIH TLV: 434 MG/M3;100 PPM ACGIH STEL: 543 MG/M3;125 PPM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 108-10-1 RTECS #: SA9275000 Percent by Wt: 3.6 OSHA PEL: 410 MG/M3;50 PPM ACGIH TLV: 205 MG/M3;50 PPM ACGIH STEL: 307 MG/M3;75 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 Percent by Wt: .4 OSHA PEL: 15 MG/M3 ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 8032-32-4 RTECS #: OI6180000 Percent by Wt: .6 OSHA PEL: 300 PPM OSHA STEL: 400 PPM ACGIH TLV: 1370 MG/M3;300 PPM ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 2807-30-9 RTECS #: KM2800000 Percent by Wt: 3.1 ------------------------------ Cas: 75-28-5 RTECS #: TI4300000 Percent by Wt: 10. OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM/ 1800 MG/M3 ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: IRRITATION OR RESPIRATORY SYSTEM, EYES AND SKIN, ORGANS EFFECTED: EYE, SKIN IRRITATION, DERMATITIS. Medical Cond Aggravated By Exposure: EXISTING EYE, SKIN OR UPPER RESPIRATORY CONDITION First Aid: EYE: FLUSH W/ WATER FOR 15 MINS. SKIN: WASH WITH SOAP AND WATER. EXCESSIVE INHALATION: REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING - SEEK A PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. REMOVE OPEN FLAMES AND SOURCES OF IGNITION. PICK UP WITH INERT ABSORBANTS. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT PUNCTURE OR INCINERATE. DO NOT REUSE CONTAINER. WRAP CONTAINER AND PLACE IN TRASH COLLECTION. Handling And Storage Precautions: KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME. STORE AT TEMPERATURES BELOW 120F. Other Precautions: USE ONLY AS DIRECTED. INTENTIONAL MISUSE BY DELIBERATLEY CONCENTRATING VAPORS AND INHALING CONTENTS CAN BE HARMFUL OR FATAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TOC Flash Point: =-23.3C, -10.F Lower Limits: 0.7 Extinguishing Media: DRY CHEMICAL, FOAM, CARBON DIOXIDE Fire Fighting Procedures: EXPOSURE TO HEAT MAY CAUSE BURSTING OF AEROSOL CAN. Unusual Fire/Explosion Hazard: TREAT AS CYLINDER OF COMPRESSED GAS. WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CONTAINERS TO PREVENT BURSTING. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A NIOSH APPROVED RESPIRATOR IF NECESSARY Ventilation: MAINTAIN ADEQUATE VENTILATION Other Protective Equipment: LONG SLEEVES, LONG PANTS AND/OR APRON IMPERVIOUS TO THE INGREDIENTS IN THIS PRODUCT. Work Hygienic Practices: WASH HANDS BEFORE EATING OR USING THE WASHROOM SMOKE IN DESIGNATED AREAS ONLY. Supplemental Safety and Health: FLAMMABILITY CLASSIFICATION: 1A. WT/GAL = 6.94 LBS. ======================================================= Physical/Chemical Properties ======================================================= Vapor Pres: 40 PSI Vapor Density: >AIR Evaporation Rate & Reference: FASTER THAN ETHER Solubility in Water: INSOLUBLE Appearance and Odor: RED COLOR; PAINT SOLVENT ODOR Percent Volatiles by Volume: 85.000 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: DO NOT STORE ABOVE 120F. KEEP FROM SPARKS, PILOT LIGHTS OR OPEN FLAME. Materials To Avoid: NONE Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE Hazardous Polymerization Indicator: NO ======================================================= Regulatory Information ======================================================= Sara Title III Information: SECTION 313: XYLENE, ACETONE, ETHYL BENZENE, METHYL ISO-BUTYL KETONE, ETHYLENE GLYCOL MONOPROPYL ETHER ======================================================= Other Information ======================================================= Other Information: HEALTH:1 FIRE:4 REACTIVITY: 1 ======================================================= HAZCOM Label ======================================================= Product ID: DA 6960 KRYOLIUM BULLDOG RED Cage: 64557 Company Name: DRUMMOND AMERICAN CORPORATION Street: 600 CORPORATE WOODS PKWY. Zipcode: 60061 Label Required IND: Y Date Of Label Review: 04/20/2001 Status Code: A Origination Code: G Hazard And Precautions: IRRITATION OR RESPIRATORY SYSTEM, EYES AND SKIN, ORGANS EFFECTED: EYE, SKIN IRRITATION, DERMATITIS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ASBESTOS FILLED SPIRAL WOUND GASKET CAGE:58156 CAGE:4A760 CAGE:58156 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9293 Ingred Name:NATURAL LATEX Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:MINOR EYS/SKIN IRRITATION. INGESTION- IRRITATION OF GI TRACT. INHALATION-IRRITATION OF RESPIRATORY TRACT. CHRONIC: ASBESTOSIS, LUNG CANCER, & MESOTHELIOMA, ALL OF WHICH ARE DISABLING AND FATAL D ISEASES OF THE LUNG. INHALATION AND INGESTION OF ASBESTOS FIBERS MAY CAUSE CANCER OF THE BOWEL. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS ASBESTOS [12001-29-5], AN OSHA REGULATED CARCINOGEN. Effects of Overexposure:INHALATION: FATIGUE AND SHORTNESS OF BREATH THAT GETS WORSE WITH TIME AND EVENTUALLY BECOMES DISABLING. EYES: IRRITATION. SKIN: IRRITATION. INGESTION: MILD STOMACH DISTRESS. DIARRHEA, VOMITING, AND NA USEA. Medical Cond Aggravated by Exposure:ASTHMA, EMPHYSEMA, AND TUBERCULOSIS ARE ALL GENERALLY AGGRAVATED BY EXPOSURE TO ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SEE DOCTOR. EYES: RINSE THOROUGHLY WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEE DOCTOR. INGESTION: DIL UTE WITH WATER. DO NOT INDUCE VOMITING.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NOT REQUIRED Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM THE MATERIAL WITH A HEPA FILTERED VACUUM. THE EQUIPMENT SHALL BE USED & EMPTIED SO AS TO MINIMIZE THE RE-ENTRY OF ASBESTOS INTO THE WORKPLACE. OTHERWISE, WET THE MATERIAL WITH WATER & SURFACTAN T AND THEN SHOVEL OR MOP UP CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:ITEM IS NONFRIABLE & WILL NOT SHED FIBERS IN NORMAL USE AND STORAGE. USED ITEMS SHALL BE WETTED BEFORE, DURING & AFTER DISASSEMBLY. Other Precautions:IF IT IS NECESSARY TO CUT OR IMPACT THE ITEM WHILE INSTALLING IT, WEAR A RESPIRATOR AND PROTECTIVE CLOTHING. USED ITEMS SHALL BE IDENTIFIED AND DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDE RAL REGULATIONS FOR ASBESTOS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED HEPA RESPIRATOR IF REQUIRED. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS OF CONTAMINATES. Ventilation:LOCAL EXHAUST SUFFICIENT TO ENTRAIN ALL PARTICULATE EMISSIONS. HEPA FILTER REQUIRED. NO LEAKS ON PRESSURE SIDE OF FAN. Other Protective Equipment:USE COVERALLS OR DISPOSABLE CLOTHING. Work Hygienic Practices:WET WORK TO THE DEGREE POSSIBLE. WASH HANDS AFTER HANDLING ITEM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:2.5 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT BLUE, NO ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, AND STRONG ALKALIS Stability Condition to Avoid:ACCUMULATIONS OF DUST Hazardous Decomposition Products:ASBESTOS DUST ==================== Disposal Considerations ==================== Waste Disposal Methods:WET THE MATERIAL WITH WATER AND SURFACTANT. PLACE IN 6 MIL THICK POLYETHYLENE PLASTIC BAG. PLACE THESE BAGS INTO ANOTHER POLY BAG OR A SAFE PLACE UNTIL IT CAN BE SHIPPED TO AN APPROVED DISPOSAL SITE. IDENTIFY WITH ASBESTOS CANCER WARNING LABEL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JERIS HAIR TONIC WITHOUT OIL CAGE:ACLUB CAGE:ACLUB ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (MFR CAS # 61-17-5) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 70% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION AND SLIGHT TO MODERATE CNS DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE AND NAUSEA. PRE-EXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. IMPAIRED LIVER FUNC TION FROM PRE-EXISTING DISORDERS ALSO MAY BE AGGRAVATED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. IMPAIRED LIVER FUNCTION FROM PRE-EXISTING DISORDERS ALSO MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . EYES: FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH SKIN WITH WATER. INHAL: MOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFI CULT. GIVE ARTIFICIAL RESPIRATION. ===================== Fire Fighting Measures ===================== Flash Point:78.0F,25.6C Extinguishing Media:USE WATER, "ALCOHOL" FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . FLAMMABLE. Unusual Fire/Explosion Hazard:NONE LISTED. ================== Accidental Release Measures ================== Spill Release Procedures:LG SPILL: EVAC AREA. WEAR PROT CLTHG. SHUT OFF SOURCE OF LEAK. DIKE & CONTAIN. IF VAP CLOUD FORMS, WATER FOG MAY BE USED. CONTAIN RUN-OFF. REMOVE W/VACUUM TRUCK OR PUMP. SOAK UP REST WITH CLAY/SAND. F LUSH AREA W/WATER. STORE IN NON-LEAKINGCNTNR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VENTILATED AREAS. FLAMMABLE LIQUID, KEEP AWAY FROM HEAT. Other Precautions:AVOID EXCESSIVE EXPOSURE. KEEP CONTAINERS IN COOL AREAS. DO NOT PUNCTURE OR CRUSH CONTAINER. DO NOT WELD OR DRILL ON OR NEAR CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE EXPLOSIVE-PROOF VENTILATION. Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:AVOID EXCESSIVE EXPOSURE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:172F,78C Spec Gravity:0.89 Solubility in Water:YES Appearance and Odor:BRIGHT YELLOW LIQUID; FLORAL AND ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE LISTED. Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . PLACE IN NON-LEAK CONTAINER. PLACE CONTAINER IN APPROVED RCRA FACILITY FOR HAZARDOUS WASTE. SEAL TIGHTLY AND LABEL PROP ERLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NPM-101, PESTICIDES MIXTURE #1 FOR METHOD 507 CAGE:0MU35 CAGE:0MU35 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL TERT BUTYL ETHER (MTBE), 2-METHOXY-2-METHYL PROPANE CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: 99.21% EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AMETRYNE CAS:834-12-8 RTECS #:XY9100000 Fraction by Wt: 0.132% Ingred Name:CYCLOATE CAS:1134-23-2 RTECS #:GU7200000 Fraction by Wt: 0.132% Ingred Name:FENAMIPHOS CAS:22224-92-6 RTECS #:TB3675000 Fraction by Wt: 0.132% ACGIH TLV:0.1 MG/CUM (SKIN) Ingred Name:MERPHOS CAS:150-50-5 RTECS #:TG5600000 Fraction by Wt: 0.132% Ingred Name:DISULFOTON CAS:298-04-4 RTECS #:TD9275000 Fraction by Wt: 0.132% ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PROMETON; 2-METHOXY-4,6-BIS ISOPROPYLAMINO!-S-TRIAZINE CAS:1610-18-0 RTECS #:XY4200000 Fraction by Wt: 0.132% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. TOXIC, IRRITANT. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES & SKIN: FLUSH W/WATER. INHALATION: REMOVE TO FRESH AIR, GIVE OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER, WATER SPRAY Fire Fighting Procedures:COMBUSTIBLE LIQUID ================== Accidental Release Measures ================== Spill Release Procedures:LEAKING BOTTLE MAY BE PLACED IN PLASTIC BAG. LIQUID MAY BE ABSORBED ON VERMICULITE OR SAND. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED IN A COOL, DRY PLACE. ============= Exposure Controls/Personal Protection ============= Other Protective Equipment:WEAR OSHA/MSMA APPROVED SAFETY EQUIPMENT INCLUDING CHEMICAL RESISTANT CLOTHING, LABORATORY COAT, RUBBER APRON. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HUMISORB CAGE:84066 CAGE:84066 ============= Composition/Information on Ingredients ============= Ingred Name:BENTONITE (AS NUISANCE DUST OR PARTICULATES NOT OTHERWISE REGULATED) CAS:1302-78-9 RTECS #:CT9450000 Fraction by Wt: 100% Other REC Limits:NONE OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST;8990 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY GENERATE SMALL AMOUNTS OF RESPIRABLE CRYSTALLINE QUARTZ IF PACKAGES ARE TORN AND MATERIAL CRUSHED,CREATING DUST. Effects of Overexposure:INHALATION:COUGH,DYSPNEA,WHEEZ,IMPAIRED PULMONARY FUNCTION;EYES:IRRITATION. Medical Cond Aggravated by Exposure:PERSONS WITH RESPIRATORY ILLNESS. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER;INHALATION:REMOVE TO FRESH AIR,GIVE OXYGEN/CPR IF NEEDED.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM LOOSE MATERIAL FROM TORN BAGS TO AVOID GENERATING AIRBORNE DUST. WEAR RESPIRATOR. DO NOT ADD WATER.PRODUCT WILL BECOME SLIPPERY WHEN MOISTENED. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL PRECAUTIONS FOR NORMAL HANDLING. KEEP CONTAINERS CLOSED. PRODUCT ABSORBS WATER. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST RESPIRATOR FOR EXPOSURE OF CONCERN. Ventilation:NO SPECIAL REQUIREMENTS.(LOCAL EXHAUST,OPTIONAL IF DUSTING IS ANTICIPATED). Other Protective Equipment:NONE. Work Hygienic Practices:DO NOT BREATHE DUST. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.5 Solubility in Water:3% Appearance and Odor:BAGS CONTAINING BENTONITE CLAY. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN APPROVED SANITARY LANDFILL I/A/W ALL APPLICABLE FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DRI-KLEAN CAGE:49310 CAGE:49310 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 96% Other REC Limits:STEL 400 PPM OSHA PEL:300 PPM/400 STEL ACGIH TLV:300 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION, DEFATTING, & DERMATITIS. EYE: IRRITATION, REDNESS, TEARING, & BLURRED VISION. INGESTION: ASPIRATION INTO LUNGS CAN BE FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: IRRITATION, DEFATTING, & DERMATITIS. EYE: IRRITATION, REDNESS, TEARING, & BLURRED VISION. INGESTION: ASPIRATION INTO LUNGS IS FATAL. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:105F Extinguishing Media:CO2, FOAM, WATER SPRAY, & DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM EVEN IF EMPTY BECAUSE PRODUCT OR RESIDUE CAN IGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH W/WATER INTO A RETAINING AREA OR CONTAINER. AVOID EXPOSURE TO SPARKS, HEAT, & OPEN FLAME. FOR SMALL SPILLS: MOP UP. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT, SPARKS, & OPEN FLAMES. USE W/ADEQUATE VENTILATION. AVOID CONTACT W/SKIN. KEEP OUT OF REACH OF CHILDREN. Other Precautions:NEVER USE WELDING OR CUTTING TORCH NEAR OR ON DRUM, EMPTY OR NOT. DON'T GIVE AWAY EMPTY DRUMS TO INDIVIDUALS, USE PROPER DISPOSAL METHODS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF >TLV, A NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. Ventilation:PROVIDE SUFFICIENT MECHANICAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F Vapor Pres:2.0 Vapor Density:4.9 Spec Gravity:0.785 Evaporation Rate & Reference:(ETHER = 1): 70 Solubility in Water:EMULSIFIES Appearance and Odor:COLORLESS THIN LIQUID W/A FAINT WINTER GREEN ODOR. Percent Volatiles by Volume:96% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, & OPEN FLAME Hazardous Decomposition Products:CO ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. DON'T GIVE AWAY EMPTY DRUM TO INDIVIDUAL, USE PROPER DISPOSAL METHODS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CPS294831, ASPHALT EMULSION RS-1 CAGE:0AHD1 CAGE:0AHD1 ============= Composition/Information on Ingredients ============= Ingred Name:ING 5:OF PETRO HYDROCARBONS CALLED MID-DISTILS. TOXICOLOGY DATA DEVEL FOR SIMILAR MID-DISTILS SUPPORT CONCLUSION (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:THAT MATL MAY POSE INCR RISK OF SKIN CANCER FOLLOWING PRLNG/RPTD SKIN CONTACT. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:IF MED ADVICE CANNOT BE OBTAINED, THEN TAKE PERS & PROD CNTNR TO NEAREST MED EMER TREATMENT CTR/HOSPITAL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:APPROP, REMOVE CONTAM SOIL. FOLLOW PRESCRIBED PROCS FOR REPORTING & RESPONDING TO LARGER RELEASES. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CNTNR. REPLACE CAP/BUNG. EMPTIED CNTNR STILL CONTAINS HAZ MATL WHICH MAY IGNITE W/EXPLO VIOLENCE IF (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:HEATED SUFFICIENTLY. CAUTION! DO NOT USE PRESS TO EMPTY DRUM/EXPLO MAY RESULT. RTECS #:9999999ZZ Ingred Name:ASPHALT CAS:8052-42-4 RTECS #:CI9900000 Fraction by Wt: 60% ACGIH TLV:5 MG/M3 FUME Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 38% Ingred Name:NAPHTHA (PETROLEUM), LIGHT STRAIGHT-RUN; (NAPHTHA, LIGHT STRAIGHT RUN) CAS:64741-46-4 RTECS #:QK8000300 Fraction by Wt: 2% Ingred Name:SUPDAT:SKIN CONT W/ASPHALT PROD IS NOT EXPECTED TO PRDCE ANY DELAYED EFTS. WHILE NORM HNDLG OF PROD IS NOT LIKELY(ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:TO CAUSE CANCER IN HUMANS, SKIN CONT & BRTHG OF MISTS/FUMES/VAPS SHLD BE REDUCED TO MIN. PROD CONTAINS MIXT(ING 6) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HAZARDS BASED ON EVALUATION OF SIMILAR MATERIALS. EYE:NOT EXPECTED TO CAUSE PRLNG/SIGNIFICANT IRRIT. SKIN:EXPECTED TO CAUSE NO MORE THAN MINOR IRRIT, BUT PRLNG/FREQUENTLY RPTD CONTACT MAY BE HARMFUL. SHOULD BE PRACTICALLY NON-TOXIC IF IT GETS ON SKIN. INHAL:SUBSTANCE CONSIDERED PRACTICALLY NON-TOXIC (EFT OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:TO INTERNAL ORGANS. INGEST:SYSTEMIC TOX OF SUBSTANCE HAS NOT BEEN DETERMINED. HOWEVER, SHLD BE PRACTICALLY NON-TOX TO INTERNAL ORGANS IF SWALLOWED. IARC CONCLUDED ONLY LTD EVID THAT STEAM-REF INED ASPHALTS WERE CARCIN TO ANIMALS. MICE EXPOSED TO ASPHALTS DILUTED W/HYDROCARBON SOLVS HAD INCR INCIDENCE OF(SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/FRESH WATER FOR @ LST 15 MIN. REMOVE CONTACT LENSES IF WORN. SKIN:REMOVE CONTAM CLTHG & WASH THORO W/SOAP & WATER. DO NOT USE SOLVS/THINNERS TO REMOVE MATLS FROM SKIN. ASPHALT CAN BE REMOV ED W/VEGETABLE OIL/MINERAL OIL. INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . INGEST:GIVE WATER/MILK TO DRINK & CALL FOR MED ADVICE. CONSULT MD BEFORE INDUCING VOMIT. (ING 8) ===================== Fire Fighting Measures ===================== Flash Point:>212F,>100C Extinguishing Media:CO*2, DRY CHEMICAL, FOAM & WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . PROD IS EMULSION CNTNG ASPHALT & PETRO DISTILS DISPERSED IN H*2O. TESTS ON EMULSIONS MAY INDICATE (SUPDAT) Unusual Fire/Explosion Hazard:MATL NORMALLY WILL NOT BURN. HOWEVER, DEHYDRATED RESIDUE WILL BURN. NORMAL COMBUST FORMS CO*2, WATER VAP & MAY PRODUCE SO*X. INCOMPLETE COMBUST CAN PRODUCE CO. ================== Accidental Release Measures ================== Spill Release Procedures:MATL MAY BE TOX TO AQUATIC ORGANISMS & SHLD BE KEPT OUT OF SEWAGE & DRAINAGE SYS & ALL BODIES OF WATER. ELIM ALL OPEN FLAME IN VICIN OF SPILL/RELS VAP. CLEAN UP SM SPILLS USING APPROP TECHNIQUES SUCH AS SORBENT MATLS/PUMPING. WHERE FEASIBLE & (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:READ & OBSERVE ALL PRECS ON PROD LBL. DO NOT USE/STORE NEAR FLAME, SPKS/HOT SURFS. USE ONLY IN WELL VENTED AREA. KEEP CNTNR CLSD. Other Precautions:AVOID CONT W/SKIN/CLTHG. PRLNG/RPTD SKIN CONT CAN BE HARMFUL. MAY EMIT COMBUST HYDROCARBON VAPS. KEEP OUT OF REACH OF CHILDREN. HYDROCARBON SOLV IN PROD MAY ACCUM @ EXPLO LEVELS IN HEADSPACE OF STOR C NTNRS. DO NOT WELD, HEAT/DRILL (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THIS MATERIAL MAY BE INHALATION HAZARD & UNLESS VENTILATION IS ADEQUATE, USE OF NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IS RECOMMENDED. Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS. Other Protective Equipment:MINIMIZE CONTACT BY WEARING PROTECTIVE CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:NO FLASH UP TO 212F WHERE WATER BOILS & TEST IS TERMINATED. DISTILS, HOWEVER, CAN SEPARATE FROM EMULSION, FLOAT TO SURF, VAPORIZE & THEREBY CREATE HAZ. EFTS OF OVEREXP:CERTAIN TYPES OFCANCER. PETRO SOLV CNTND IN PROD MAY INCR POTNTL FOR CANCER FOLLOWING PRLNG & RPTD SKIN CONT. BRIEF/INTERMITTENT(ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:30.0F,-1.1C Vapor Pres:60 @ 100F Spec Gravity:1.01 pH:7-10 Solubility in Water:READILY DISPERSIBLE Appearance and Odor:DARK TO TAN LIQUID. Percent Volatiles by Volume:40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION MAY FORM:CO*2, WATER VAPOR, SO*X, CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAM MATLS IN DISPOSABLE CNTNRS & DISPOSE OF IN A MANNER CONSISTENT W/APPLIC FEDERAL, STATE & LOCAL REGULATIONS. CONTACT LOC ENVIRON/HLTH AUTHORITIES FOR APPRVD DISP OF THIS MATL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RIFLE BORE CLEANER CAGE:KO679 CAGE:KO679 CAGE:74438 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM SOLVENT Fraction by Wt: 60.0% ACGIH TLV:200PPM(PER MFR) Ingred Name:LIGHTWEIGHT OIL Fraction by Wt: 35.0% Ingred Name:CORROSION INHIBITOR Fraction by Wt: 5.0% ===================== Hazards Identification ===================== Effects of Overexposure:SKIN:IRRITATION,DERMATITIS ON PROLNGD CONTCT;EYES/INH:PROLONGD EXPOSR CAUSES IRRIT,HEADACHE,DROWSNSS ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. SKIN:WASH WITH SOAP & WATER. EYES:FLUSH WITH WATER 15 MIN. KEEP WARM AND QUIET. GET MED ATTN IF EYE IRRITATION PERSISTS;ING:DO NOT INDUCE VOMIT.GIVE 2-4 O Z OLIVE/VEGETABLE OIL & 1-2 OZ ACTIVTD CHARCOAL. ===================== Fire Fighting Measures ===================== Flash Point:125F(T.C.C) Lower Limits:0.7 Upper Limits:5.0 Extinguishing Media:DRY CHEM PREFERRED.FOAM & H*2O ALSO APPLICABLE. Fire Fighting Procedures:USE FOAM & H*2O SPARY CAREFULLY TO PREVENT EXCESSIVE FROTHNG Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT OR OPEN FLAMES.CAN REACT W/OXIDIZING MATERIAL COMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTNRS TIGHTLY CLOSED.DO NOT STORE/MIX W/STRONG OXIDANTS.STORE IN COOL WELL-VENTILATED AREA. Other Precautions:STORE AWAY FROM POSSIBLE SOURCES OF IGNITION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE IN NORMAL USE; VAP REMOVING AIR PURIFYNG RESP FOR MIST/SPRAY. Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:WEAR FULL PROTECTIVE CLOTHING. Supplemental Safety and Health MSDS UNDATED:SPEC REFERENCE:MIL-C-372C. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:181-290C Vapor Pres:NEG Vapor Density:4.5 Spec Gravity:0.840 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR,PALE LUBRICATING OIL Percent Volatiles by Volume:64% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS SUCH AS CHLORINE & CONC OXYGEN. Hazardous Decomposition Products:CO IN CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED INCINERATOR OR DISPOSE OF IN APPROVED CHEMICAL DUMP IN ACCORDANCE WITH LOCAL,STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CONCISE COMPOSITE PASTE "B" Kit Part:Y CAGE:76381 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:SILANE TREATED CRYSTALLINE SILICON DIOXIDE; WT % RANGE:70-80% Fraction by Wt: 75.0% ACGIH TLV:5MG/CUM(DUST Ingred Name:MONO & DI METHACRYLATES; WT % RANGE:10-20% Fraction by Wt: 15.0% Ingred Name:INORGANIC PIGMENTS/FILLERS: WT % RANGE 0-5% Fraction by Wt: <5.0% Ingred Name:INHIBITORS; WT % RANGE: 0.0-1.0 Fraction by Wt: <1.0% Ingred Name:BENZOYL PEROXIDE; WT % RANGE: 0.0-0.5 CAS:94-36-0 RTECS #:DM8575000 Fraction by Wt: <0.5% ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE BURNS,IRRITATION,TISSUE DAMAGE. SKIN:SEVERE IRRITATION. INHALATION:MIST AND VAPOR CAUSE RESPIRATORY SYSTEM IRRITATION. Medical Cond Aggravated by Exposure:ANY PREEXISTING SENSITIVITY OR ALLERGY. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH EYES W/LG AMT OF WATER & CONSULT PHYSICIAN;SKIN: WIPE OFF W/CLOTH/TISSUE.WASH WITH SOAP & WATER; INHALATION INGESTION:NOT KNOWN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR. Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE SAFETY EQUIPMENT IF NEEDED.WIPE UP SMALL SPILL & PLACE IN DISPOSAL CONTAINER; FOR LG QTY TRANSFER PASTE TO A SALVAGE TANK & COVER. CLEAN AREA W/SUITABLE SOLVENT & DRY. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:AVOID EYE & SKIN CONTACT.SEE PRODUCT LABEL FOR MORE INFO;CRYSTALLINE SILICON DIOXIDE CAN PRODUCE LUNG DISEASE IF INHALED,HOWEVER,IN THIS FORM EXPOSURE IS UNLIKELY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:NORMAL ROOM VENTILATION. Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KIT CONSISTS OF 5 PARTS (ETCHING LIQUID,PASTE PARTS A & B, AND RESIN PARTS A & B). THIS DATA DESCRIBES PASTE PART B. FOR OTHER PARTS, SEE OTHER PNI'S, SAME NSN. KEY1:N1. ================== Physical/Chemical Properties ================== HCC:C1 Spec Gravity:2.33 Solubility in Water:NEGLIBIBLE Appearance and Odor:TOOT COLORED PASTE,SLIGHT ACRYLATE ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NOT KNOWN Hazardous Decomposition Products:INCOMPLETELY BURNED CARBON PRODUCTS, CO*2, CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:DUE TO SMALL AMOUNTS,DISPOSE OF AS ORDINARY WASTE IN APPROVED LANDFILL.SINCE REGULATIONS VARY,CONSULT APPLICABLE REGULATIONS OR AUTHORITIES BEFORE DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACRYLOID B-72 50% RESIN, 66753 CAGE:GO264 CAGE:GO264 CAGE:77902 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC COPOLYMER Fraction by Wt: 49-51% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESIDUAL MONOMER Fraction by Wt: 0.6% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 49-51% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SPILL PROC: FOR RECOVERY OR DISPOSAL AND SOLID DIKING MATERIAL TO SEPARATE CONTAINERS FOR DISPOSAL. KEEP SPILLS (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: AND CLEANING RUNOFFS OUT OF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. NOTE: SPILLS ON POROUS SURFACES (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: CAN CONTAMINATE GROUNDWATER. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: SOLVENT VAPOR OR MIST CAN CAUSE HEADACHE, DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS & IRRIT OF NOSE, THROAT & LUNGS. SKIN CONTACT: IRRITATING TO SKIN UPON RPTD/PRLNGD CONTACT. LIQUID SUBSTANCE C AN BE ABSORBED THRU INTACT SKIN IN HARMFUL AMOUNTS. EYE CONTACT: SUBSTANCE CAN CAUSE IRRIT & TRANSIENT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CORNEAL INJURY. CHRONIC: TOLUENE APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROP HEALTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HANDLING & EXPOSURE INFO . RPTD OVEREXP TO TOLUENE CAN CAUSE CNS EFTS. EFTS OF OVEREXP ARE BASED ON (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR. GIVE ARTF RESP IF BRTHG HAS STOPPED. SEE MD. EYES: FLUSH EYES W/LARGE AMT OF WATER FOR AT LEAST 15 MIN. SEE MD IF IRRIT PERSISTS. WASH AFFECTED SKIN AREAS W/SOAP & WATER. ING EST: IF SWALLOWED GIVE TWO GLASSES OF WATER TO DRINK. SEE MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. NOTE TO MD: PROD CONTAINS TOLUENE, A PETRO DISTIL HAVING CNS EFTS. CAREFUL (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:44.6F,7.0C Lower Limits:1.2% Upper Limits:7.1% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. MATERIAL CAN FORM EXPLOSIVE VAPOR WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE IGNITION SOURCES. WEAR NIOSH APPROVED RESP (PRESSURE-DEMAND, SCBA OR EQUIVALENT) OR AIR MASK FOR LARGE SPILLS IN CONFINED AREA. DIKE & CONTAIN SPILL W/INERT MATL (EG, S AND, EARTH). TRANSFER LIQUID TO CONTAINERS (ING 4) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE TEMPERATURE: -18C/0F TO 60C/140F. LIMIT STORAGE OF FLAMMABLE MATERIAL TO APPROVED AREAS. GROUND ALL CONTAINERS WHEN TRANSFERRING MATERIAL. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF GOOD VENTILATION IS MAINTAINED. WEAR NIOSH APPROVED RESPIRATOR SUITABLE FOR CONCENTRATIONS AND TYPES OF AIR CONTAMINANTS ENCOUNTERED. Ventilation:EXPLOSION-PROOF LOCAL EXHAUST VENTILATION AT POINT OF CONTAMINANT RELEASE. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health % VOLAT: 50-52 (WT). EFTS OF OVEREXP: INFO ABOUT SIMILAR MATLS & ON TOXICITY PROFILES FOR SOLVENTS USED IN THIS PROD. NOTE: OVEREXP TO TOLUENE HAS CAUSED EMBRYOFETOTOXIC EFTS IN LAB ANIMALS. FIRST AID PROC: GASTRIC LAVAGE MAY BE INDICATED BECAUSE OF RISK OF ASPIRATION POSED BY PETROLEUM DISTILLATES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:230F,110C Melt/Freeze Pt:M.P/F.P Text:-139F,-95C Vapor Pres:22 @ 20C Vapor Density:>1 Spec Gravity:1.0 (H*2O=1) Evaporation Rate & Reference:>1 (BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, VISCOUS LIQUID; SOUR, BURNT ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISCARDED THIS MATERIAL IS A HAZARDOUS WASTE. RCRA #U-220, RQ 2000 LBS (40 CFR 302, SUPERFUND). INCINERATE LIQUID AND CONTAMINATED MIXING MATERIAL AT A PERMITTED FACILITY IN ACCORDANCE WITH LOCAL , STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MT TONER II, EP4230 CAGE:GO339 CAGE:GO339 CAGE:23736 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 1-5% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:PROPENE POLYMERS; (POLYPROPYLENE) CAS:9003-07-4 RTECS #:UD1842000 Fraction by Wt: 1-3% Ingred Name:STYRENE-ACRYLATE COPOLYMER Fraction by Wt: >80% Ingred Name:COPPER OXIDE CAS:1317-38-0 RTECS #:GL7900000 Fraction by Wt: 5-10% OSHA PEL:1 (CU) MG/M3 DUST ACGIH TLV:1 (CU) MG/M3 DUST Ingred Name:ORGANIC PIGMENT Fraction by Wt: 1-5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL ORAT) >5 G/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MINIMAL RESP TRACT IRRIT MAY OCCUR AS W/EXPOS TO LGE AMTS OF ANY NONTOXIC DUST. MAY CAUSE COUGH & RAISE PHLEGM. CHRONIC: NONE. TONER PRESENTS A LOW HAZARD FOR USUAL OCCUP SETTINGS. BASED ON AVA IL DATA, HUMAN EXPOS TO TONER HAS BEEN SHOWN TO CAUSE MINIMAL RESP TRACT IRRIT AS MAY OCCUR W/LGE AMTS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF ANY NONTOXIC DUSTS. RSLTS OF ONE ANIMAL STUDY WHERE RATS INHALED TONER THAT WAS 10X MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER WERE OBSERVED TO HAVE NO LUNG CHANGES AT LOW EXPOS (THE MO ST RELEVANT LEVEL TO POTNTL HUMAN EXPOS). AT HIGHER LEVELS A SLIGHT DEGREE OF LUNG FIBROSIS WAS OBSERVED (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: WASH NOSTRILS & RINSE MOUTH. INGEST: DILUTE STOMACH CONTENTS W/SEVERAL GLASSES OF WATER. EYE: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM & DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID INHALATION OF SMOKE. Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. WHEN DISPERSED IN AIR, IT FORMS EXPLOSIVE MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:TONER, AS A MIXTURE, IS CONSIDERED A NUISANCE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN MINOLTA EQUIPMENT. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT APPLICABLE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE. Supplemental Safety and Health EFTS OF OVEREXP:DUE TO EXCESSIVE AMOUNTS OF DUST RETAINED IN THE LUNGS ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.2 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER; FAINT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC. AVOID BREATHING OF SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE. NO SPECIAL TECHNIQUES BEYOND NORMAL PRACTICE. ENSURE CONFORMITY W/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:ACETYLCHOLINE BROMIDE (1:10,000 SOLUTION),38-2021 Preparer's Name:MICHAEL RESZEJA CAGE:EO227 CAGE:EO227 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLCHOLINE BROMIDE/CHOLINE ACETATE,BROMIDE CAS:66-23-9 RTECS #:FZ9680000 Fraction by Wt: 0.01% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE. ACUTE- EYE:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALE:UNLIKELY. ORAL:EXPECTED TO BE A LOW INGESTION HAZARD AT THIS CO NCENTRATION. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TRANSIENT EYE IRRITATION Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:UNLIKELY. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:FLUSH WITH WATER, THEN WASH SKIN WITH MILD SOAP & WATER. ORAL:IF CONSCIOUS, DRI NK 1-2 GLASSES OF WATER. GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS IF NEEDED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER IF PERMITTED. OTHERWISE, ABSORB SPILL WITH INERT MATERIAL SUCH AS VERMICULITE. PLACE IN A CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE. Other Precautions:DO NOT GET IN EYES. KEEP OUT OF REACH OF CHILDREN. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD/HOUSEHOLD USE. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. IF EXCESSIVE MISTING IS EXPECTED, WORK IN VENTILATION HOOD OR WEAR NIOSH-APPROVED RESPIRATOR. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:14 Vapor Density:0.7 Spec Gravity:1.00 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS WATER SOLUTION - ODORLESS Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ALKALINE MATERIALS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:NONE EXPECTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:52620 TM 185 YELLOW CAGE:SERIC CAGE:SERIC CAGE:SSERI ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOHEXANONE, KETOHEXAMETHYLENE CAS:108-94-1 RTECS #:GW1050000 Other REC Limits:100PPM (SKIN) STEL OSHA PEL:50 PPM ACGIH TLV:100 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIBASIC ESTER Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM *97-4* CAS:64742-94-5 RTECS #:WF3100000 Ingred Name:PIGMENTS Ingred Name:VOLATILE ORGANIC CONTENT: 625 G/L RTECS #:9999999VO Ingred Name:ACETIC ACID, C6-8-BRANCHED ALKYL ESTERS, C3-8-BRANCHED ALKYL ESTERS ACETIC ACID CAS:90438-79-2 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: IRRITATION OF DIGESTIVE TRACT. NERVOUS SYTEM DEPRESSION. ASPIRATION DURING SWALLOWING/VOMITING CAN CAUSE LUNG INFLAMMATION/DAMAGE. SKIN: PROLONGED/REPEATED OVEREXPOSURE MAY CAUSE DERMATITIS /ABSORPTION. EYES: SEVERE IRRITANT/BLURRED VISION. INHALATION: NOSE/RESPIRATORY TRACT IRRITATION. LIVER/KIDNEY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, DIARRHEA, DROWSINESS, DIZZINESS, LOSS OF COORDINATION, FATIGUE, INFLAMMATION, HEADACHES, REDNESS, BURNING, DEFATTING OF SKIN, TEARING, BLURRED VISION. Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISORDERS, ASTHMA-LIKE CONDITIONS, SENSITIZATIN, ALLERGIES. ======================= First Aid Measures ======================= First Aid:INGESTION: DRINK 2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO A WELL VENTILATED AREA. G IVE OXYGEN/CPR IF NECESSARY. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. TREATMENT SHOULD BE DIRECTED AT CONTROL OF SYMPTOMS & CLINICAL CONDITION. ===================== Fire Fighting Measures ===================== Flash Point:>110F Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT. WATER MAY BE UNSUITABLE FOR BURNING LIQUIDS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. WATER MAY BE USED TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM IGNITION SOURCES & HOT SURFACES. CLOSED CONTAINERS MAY RUPTURE/EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:USING NON-SPARKING TOOLS, PLACE LEAKING CONTAINERS IN A WELL VENTILATED AREA. AVOID BREATHING VAPORS. ELIMINATE ALL SOURCES OF HEAT, SPARKS/IGNITION. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED STORAGE AT TEMPERATURES IN EXCESS OF 100F. Other Precautions:DON'T BREATHE VAPORS/SPRAY MISTS. MINIMIZE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH/MSHA APPROVED) DURING & AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST LEVELS ARE BELOW APPLICABLE LIMITS. Ventilation:LOCAL EXHAUST: TO CONTROL EXPOSURE TO MIST/AEROSOLS. GENERAL EXHAUST TO MINIMIZE EXPOSURE TO VAPORS. Other Protective Equipment:IMPERMEABLE APRONS, BOOTS, SAFETY SHOWER, EYE BATH Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, USING TOBACCO PRODUCTS/USING THE WASHROOM. Supplemental Safety and Health TOBACCO & FOOD SHOULD BE CONSUMED IN DESIGNATED AREAS ONLY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:312.8-419F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Appearance and Odor:SOLVENT EVAPORATIVE SCREEN INK ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, OXIDIZERS, ALKALI METAL HYDROXIDES Stability Condition to Avoid:HEAT, SPARKS, ELECTRICAL EQUIPMENT, OPEN FLAMES & OTHER IGNITION SOURCES Hazardous Decomposition Products:CO, CO2, MIXED OXIDES OF NITROGEN, METHYL METHACRYLATE, N-BUTYL METHACRYLATE/HYDROGEN CHLORIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T4500 THEOBROMINE CRYSTALLINE CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:THEOBROMINE CRYSTALLINE CAS:83-67-0 RTECS #:XH2275000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT):1265 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED THROUGH SKIN & MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, ANOREXIA. ======================= First Aid Measures ======================= First Aid:INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. SKIN/EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD. Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:COMBUSTION: CO, CO2, NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN A FURNACE IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENPLATE NI-433M CAGE:EO297 CAGE:EO297 CAGE:02258 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >60% Ingred Name:SODIUM HYPOPHOSPHITE CAS:7681-53-0 RTECS #:WB5950000 Fraction by Wt: <15% Ingred Name:NICKEL SULFATE (2A CARCINOGEN BY IARC & ACGIH) CAS:7786-81-4 RTECS #:QR9350000 Fraction by Wt: <15% OSHA PEL:1 MG NI/M3 ACGIH TLV:0.1 MG NI/M3; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:AMMONIUM HYDROXIDE, AQUA AMMONIA CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <5% Other REC Limits:25 PPM OSHA PEL:35 MG/CUM ACGIH TLV:18 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: MOUTH, THROAT, ESOPHAGUS & STOMACH IRRITATION. SKIN: IRRITATION & NICKEL ITCH. EYES: IRRITATION & DAMAGE. CHRONIC: GENERAL DISCOMFORT, IRRITATION & POSSIBLE SEVERE SENSITIZATION. Explanation of Carcinogenicity:SEE INGREDIENTS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, RESUSCITATE/ADMINISTER OXYGEN IF AVAILABLE. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. IF VOMITING OCCURS SPONTANEOUSLY, KEEP AIRWAY C LEAR. GIVE PLENTY OF WATER & INDUCE VOMITING. SKIN: WASH W/PLENTY OF WATER FOR 15 MINS. REMOVE CONTAMINATED CLOTHING & FOOTWEAR. DISCARD FOOTWEAR IF IT CANNOT BE DECONTAMINATED. SEE SUPP. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER FOG OR SPRAY, CO2, FOAM Fire Fighting Procedures:WEAR NIOSH APPROVED FULL PROTECTIVE CLOTHING & SELF-CONTAINED BREATHING APPARATUS. KEEP CONTAINERS COOL TO PREVENT RUPTURE & RELEASE OF MATERIAL. Unusual Fire/Explosion Hazard:HEATING OF DRIED SALTS TO TEMPERATURES ABOVE 475F MAY RELEASE TOXIC & SPONTANEOUSLY FLAMMABLE PHOSPHINE GAS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT W/SKIN, EYES & CLOTHING. WEAR PROTECTIVE EQUIPMENT. DON'T BREATH MIST OR VAPORS. CONTAIN SPILL & SOAK UP IN SUITABLE ABSORBENT. SHOVEL INTO PLASTIC LINED STEEL CONTAINERS. DILUTE RESIDUA L MATERIAL W/PLENTY OF WATER & NEUTRALIZE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP AWAY FROM ALKALIES & OXIDIZERS. LOOSEN COVER CAUTIOSLY WHEN OPENING. STORE ABOVE FREEZING TEMPERATURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR WHEN AIR CONCENTRATION IS GREATER THAN TLV/PEL. USE CARTRIDGE FILTER FOR ACID MIST. Ventilation:LOCAL EXHAUST: RECOMMENDED. Other Protective Equipment:CHEMICAL RESISTANT COVERALLS, HATS, SHOES OR BOOTS. EYE WASH & SAFETY SHOWER Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health CON'T: EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. HOLDING EYELIDS APART. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F Melt/Freeze Pt:M.P/F.P Text:-4F Spec Gravity:1.258 pH:4.4 Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID W/SLIGHT VINEGAR-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIS & OXIDIZERS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:TOXIC GASES INCLUDING AMMONIA, OXIDES OF SULFUR, NITROGEN & PHOSPHORUS. SPONTANEOUSLY FLAMMABLE PHOSPHINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PC:930G017 DES 420HS C/S (POLYISOCYANATE) PART B Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PENTANE-2,4-DIONE CAS:123-54-6 RTECS #:SA1925000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYL-3-ETHOXYPROPIONATE CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AROMATIC HYDROCARBON SOLVENT NAPHTHA (PETROLEUM) LIGHT AROMATIC CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:AROMATIC SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:TRIMER HDI,TIRMER OF HEXAMETHYLENE DIISOCYANATE <0.2% MONOMERIC HEXAMETHYLENE DIISOCYANATE(CAS#822-06-0) CAS:3779-63-3 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED Ingred Name:N-BUTYL ACETATE (CERCLA) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:AROMATIC SOLVT:EYE/SKIN:MOD IRRIT.INHAL:SLIGHT TOXIC.1-BUTYACETATE:EYE:BURN,TEAR,RED,POSSIBLE TRANS CORN INJURY.SKIN:PROL EXPO DRY,CRACK.INHAL/INGEST:DROWS,DIZZ,FTG,NAU.MEK:EYE:BURN,TEAR,RED,POS SIBLE TRANS CORNEAL CLOUDING.SKIN:PROL EXPO RED,BURN,DRY,CRACK.INHAL:COUGH,CHEST PAINS,THROAT IRRIT,HEAD,DIZZ,ANESTHETIC(SUPP) Effects of Overexposure:ETHYL3-ETHOXYPROPIONATE:EYE:IRRIT,RED,SWELL OF CONJUNC.SKIN:PROL/REP IRIT,DRY,CRACK.INHAL/INGEST:NASAL/RESP IRRIT,CNS EFFECTS.(DIZZ,WEAK,FTG,NAU,HEAD,UNCONSC).TOLUENE:EYE:BURN,TEAR,RED. SKIN:PROL DRY,C RACK,DERM.INHAL:DIZZ,DROWS,FTG,LIV/KID DMG.INGEST:DROWS,DIZZ,NAU.PETRO:EYE:IRRIT.SKIN:DEFAT,DRY.INHAL:IRRI T MUC MEMB Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER FOR 15MINS.GET MED ATTN.SKIN:WASH W/SOAP/WATER.DONT USE SOLVTS.REMOVE CONTAMIN CLOTH.GET MED ATTN.INHAL:REMOVE TO FRESH AIR FROM EXPO.GIVE ART RESP/CARDIOPULM RESUSCITATION(CPR)IF BR EATH DIFFI.GET MED ATTN.INGEST:GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:56.0F,13.3C Autoignition Temp:Autoignition Temp Text:NP Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM. Fire Fighting Procedures:WATERPSRAY MAY BE INEFFECTIVE.COOL FIRE EXPO CNTNR W/WATER.FOG NOZZ PREFER.WEAR NIOSH/MSHA APPROV SCBA & PROTECTIVE CLOTH TO PREVENT CONTACT W/SKIN/EYES. Unusual Fire/Explosion Hazard:VAP MAY ACCUMULATE IN INADEQUATELY VENTI/CONFINED AREAS.VAP MAY FORM EXPLO MIX W/AIR.VAP MAY TRAVEL LONG DISTANCES;FLASHBACK/FLAME TO HNDLG SITE MAY OCCUR(SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:PROTECT FROM IGN.WEAR AIR-SUPPL RESP FOR UNVENTI SPILL.COVER W/ABSORBENT MATL,ADD DECOMO SOLN(5%CONC AMMONIA,2%DETERGT,93%H2O).ALLOW TO RX 10MINS.COLLECT INCNTNR,ADDN ADDN DECOMPO SOLN.KEEP LOOSELY CO VER FOR 48HRS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD.ISOLATE FROM HEAT/ELECTRICAL EQPMT/SPARKS/FLAME.DONT STORE >120F. Other Precautions:EMPTY DR MAY CONTAIN EPXLO VAP.DONT CUT/PUNCTURE/WELD ON/NEAR DRUM.VAP OF PRODUCT ARE HEAVIER THAN AIR & MAY COLLECT IN LOW/CONFINED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAY/APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVEL OF HAZ INGREDS IN EXCESS OF TLV USE ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLIED RESPIRATOR. Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW TLV & PEL. Other Protective Equipment:DURING SPRAY APPLICATION COMPLETE SKIN PROT REQUIRED.AVOID SKIN CONTACT-USE OTHER PROT CLOTH.SAF SHOWER,EYEBATH,WASH FAC Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE. Supplemental Safety and Health FIRE/EXPLO:CLSD CNTNRS MAY EXPLO WHEN EXPO TO EXTREME HEAT.DURING FIRE IRRIT/TOXIC GASES/AEROSOLS FROM DECOMPO/COMBUST PROD MAY BE PRESENT. HEALTH:CNS EFFECTS,REVERSI LIV DMG @HI DOSE.INGEST:DROWS,DIZ Z,NAU.ACETYLACETONE:EYE:BURN,TEAR,RED.SKIN:PORL EXPO DRY,CRACK,DERM.INHAL:DROWS,HEAD,NAU,DIZZ,UNCONSC.INGEST:NAU,VOMIT, ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=79.4C, 175.F Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:>AIR Spec Gravity:1.004 VOC Pounds/Gallon:493 pH:NP Viscosity:NP Evaporation Rate & Reference:UNAVAI Solubility in Water:NP Appearance and Odor:CLEAR LIQUID, SOLVENT ODOR. Percent Volatiles by Volume:43.8 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/WATER,ALCOHOLS,AMINES. Stability Condition to Avoid:NONE RECOGNIZED. Hazardous Decomposition Products:PRODUCTS OF COMBUST HAZ INCLUDES CO,CO2.MAY ALSO INCLUDE OXIDES OF NITROGEN,TRACE OF HCN,ISOCYANATE MONOMER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAINS CHEM(S) SUBJ TO SEC 313 TITLE III SARA/40CFR372.WHEN DISPO MATL ENSURE THAT ITS PKG/STORED/TRANSPO/OHTERWISE MANAGED IAW LOC/STATE/FED REGS.CERCLA RQ:N-BUTYLACETATRE=5000LBS,MEK=5000LBS,TOLUE NE=1000LBS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:J2564, LACQUER THINNER CAGE:5W323 CAGE:5W323 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 3.86% Other REC Limits:200 PPM OSHA PEL:260 MG/CUM ACGIH TLV:262 MG/CUM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYLCYCLOHEXANE CAS:108-87-2 RTECS #:GV6125000 Other REC Limits:400 PPM OSHA PEL:2000 MG/CUM ACGIH TLV:1610 MG/CUM Ingred Name:ETHYL BENZENE CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1-2.6% Other REC Limits:100 PPM OSHA PEL:435 MG/CUM ACGIH TLV:434 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEPTANE CAS:142-82-5 RTECS #:MI7700000 Other REC Limits:400 PPM OSHA PEL:2000 MG/CUM ACGIH TLV:1640 MG/CUM Ingred Name:WEIGHT PER GALLON IN POUNDS: 6.83 LB RTECS #:9999999WG Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 34% Other REC Limits:375 MG/CUM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 19.3% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 8-9.5% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTOXYETHANOL (ETHYLENEGLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 6.6% Other REC Limits:25 PPM (SKIN) OSHA PEL:50 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. SKIN: IRRITATION, MAY BE TOXIC VIA ABSORPTION. INHALATION: IRRITATION OF THE NOSE & THROAT, NERVOUS SYSTEM DEPRESSION. INGESTION: IRRITATION OF THE DIGESTIVE TRACT, ASPIRATIONHAZARD, CNS DEPRESSION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: STINGING, TEARING, REDNESS, SWELLING. SKIN: REDNESS, BURNING, DRYING, CRACKING. INHALATION: NAUSEA, VOMITING, HEADACHE, DROWSINESS, DIZZINESS, INCOORDINATION, FATIGUE. INGESTION: BLINDNESS, CONV ULSIONS, COMA, DEATH. TOLUENE: CHANGES IN DNA OF CELL. Medical Cond Aggravated by Exposure:SKIN, LUNG, ASTHMA, BLOOD, KIDNEY, LIVER, HEART DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: MOVE TO FRESH AIR. FLUSH W/WATER FOR 20 MINS. SKIN: FLUSH W/SOAP & WATER. DRESS DAMAGED SKIN. INHALATION: MOVE TO FRESH AIR. IF BREATHING DIFFICULT OR STOPPED, GIVE OXYGEN OR CPR. INGESTION: GIV E SYRUP OF IPECAC TO INDUCE VOMITING. PUT PERSON ON LEFT SIDE W/HEAD DOWN. NOTE TO PHYSICIAN: EPINEPHRINE & SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIA ARRHYTHMIA. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:0F Lower Limits:1% Upper Limits:36% Extinguishing Media:DRY CHEMICAL, CO2, HALON, POLAR OR ALCOHOL FOAM, WATER SPRAY Fire Fighting Procedures:EXTREMELY FLAMMABLE LIQUID & VAPOR. VAPOR MAY CAUSE FLASH FIRE. WEAR FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:VAPORS TRAVEL LONG DISTANCES IN LOW AREAS TO IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP AWAY IGNITION SOURCES. ISOLATE AREA. STOP SPILL IF W/OUT RISK. PREVENT FROM ENTERING SEWERS, STORM DRAINS, NATURAL WATERWAYS. DIKE & RECOVER. ABSORB. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT & IGNITION SOURCES. GROUND ALL EQUIPMENT. Other Precautions:DON'T PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND CONTAINERS, MAY EXPLODE. EMPTY CONTAINERS RETAIN RESIDUE, ARE DANGEROUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF LEVELS EXCEED LIMITS, USE AIR SUPPLIED RESPIRATOR. Ventilation:EXHAUST SYSTEMS MAY BE REQUIRED TO KEEP LEVELS BELOW LIMITS. INSURE ELECTRICAL SYSTEMS ARE SAFE FOR EXPLOSIVE AREAS. Other Protective Equipment:IMPERVIOUS CLOTHING. EYE WASH & SHOWER IN AREA. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DON'T WEAR CONTAMINATED CLOTHING OR SHOES. Supplemental Safety and Health CONT'D MATERIAL TO AVOID: ISOCYANATES, OXIDIZING AGENTS, ORGANOMETALLIC CONTAMINANTS, STRONG REDUCING AGENTS. DELIBERATE INHALATION MAY BE HARMFUL OR FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 133-340F Vapor Pres: 75.4 Vapor Density:3 Spec Gravity:0.820 Evaporation Rate & Reference:(N BU AC = 1): 3.2 Solubility in Water:APPRECIABLE Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, AMINES, ANHYDRIDES, ACETALDEHYDE, ALUMINUM, BASES, CHLORINE, ETHYLENE OXIDE, HYDROGEN PEROXIDE (SEE SUPP) Stability Condition to Avoid:IGNITION SOURCES (HEAT, SPARKS, FLAMES, STATIC ELECTRICITY, PILOT LIGHTS, ELECTRICAL EQUIPMENT). Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1-COAT, TT-P-2756, 13670 P/C 03Y144 Kit Part:Y Preparer's Name:NORM GAUL CAGE:5M511 CAGE:33461 CAGE:5M511 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 13 MM HG @ 68F) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM;STEL 200 PPM ACGIH TLV:150 PPM;STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL 3-ETHOXYPROPIONATE (VAPOR PRESSURE 0.7 MM HG @ 68F) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 10% Other REC Limits:50 PPM; STEL 100 PPM Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2 MM HG @ 68F) (NIOSH LIMITS: 350 MG/M3 - 8 HR TWA; 1800 MG/M3 - 15 MIN SAMPLE) CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:C8&10 AROMATIC HYDROCARBON (VAPOR PRESSURE 3 MM HG @ 68F) CAS:64742-95-6 Fraction by Wt: <1% Other REC Limits:MFR PEL: 100 PPM Ingred Name:DISPERSION AGENT (VAPOR PRESSURE 0 MM HG) Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:ANTI-FLOAT AGENT CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MP/F3 ACGIH TLV:10 MP/F3 Ingred Name:METHYL N-PROPYL KETONE (VAPOR PRESSURE 27.8 MM HG @ 68F) CAS:107-87-9 RTECS #:SA7875000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM;STEL 250 PPM ACGIH TLV:200 PPM;STEL 250 PPM Ingred Name:ANTI MAR AGENT (VAPOR PRESSURE 0 MM HG) Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENE (SARA III) (VAPOR PRESSURE 21 MM HG @ 100F) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 0.08% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) (VAPOR PRESSURE 7.1 MM HG @ 68F) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.04% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 125 PPM ACGIH TLV:100 PPM;STEL 125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) (VAPOR PRESSURE 22 MM HG @ 68F) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 1.66% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:DIBUTYLTIN DILAURATE (VAPOR PRESSURE 0.2 MM HG @ 320F) CAS:77-58-7 RTECS #:WH7000000 Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED ACGIH TLV:0.1 MG/M3 Ingred Name:2-4 PENTANEDIONE (VAPOR PRESSURE 6.9 MM HG @ 68F) CAS:123-54-6 RTECS #:SA1925000 Fraction by Wt: <1% Other REC Limits:UNION CARBIDE:20 PPM Ingred Name:VOC: 255 G/L RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: RESP TRACT IRRIT & ACUTE NERVOUS SYSTEM DEPRESSION (HEADACHE,DIZZINESS,STAGGERING,CONFUSION,UNCONSCIOUSNESS,COMA). SKIN: IRRIT (SWELLING,REDNESS,RASH). ABSORPTION:IRRIT,DRYING,DEFAT. EYE:IRRIT (TEARING,REDNESS,SWELLING W/STING).INGEST:IRRIT, CORROSIVE IN GI TRACT. VOMIT MAY CAUSE ASPIRATION--CHEM PNEUMONITIS. Effects of Overexposure:ACUTE:EYES, NOSE, THROAT IRRIT. INHAL:HEADACHE, DIFFICULT BREATHING, UNCONSCIOUSNESS. CHRONIC:PROLONGED CONTACT WILL CAUSE DRYING & CRACKING OF SKIN, DUE TO DEFATTING ACTION. SKIN SENSITIZATION, ASTHM A OR OTHER ALLERGIC RESPONSES MAY DEVELOP. HARMFUL IF SWALLOWED/ABSORBED THROUGH SKIN. MAY CAUSE LIVER & KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMEDIATE OR DELAYED BY SEVERAL HOURS). GET MEDICAL AID. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH SOAP & WATER. EYES: FLUSH WITH LUKEWARM WATER (LOW PRESSURE) 15 MIN, LIFTING EYELIDS. GET MEDICAL AID. INGESTION: DO NOT INDUCE VOMITING. NOTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:0.60 Upper Limits:11.40 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG, WATER SPRAY Fire Fighting Procedures:WEAR FULL FIRE FIGHTING EQUIP W/SCBA & FULL PROTECTIVE CLOTHING. USE WATER TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP, AUTO IGNITION, OR EXPLOSION. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDGS IN COMPLY W/OSHA 1910.106,IN VENTD AREA,IN CLOSED CONTAINER.DON'T STORE NEAR HIGH TEMP/IGNIT SOURCES.PREVENT PROLONGED BREATHING VAPOR. Other Precautions:KEEP CONTAINERS TIGHT & UPRIGHT (PREVENT LEAK). PROLONGED OVEREXPOSURE MAY CAUSE ALLERGIC REACTION. AVOID SKIN & EYE CONTACT. DON'T INGEST. DON'T HANDLE TILL MFR PRECAUTIONS READ/UNDERSTOOD.SMOKE IN S MOKING AREAS ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR RECOMMENDED FOR ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED) OBEY OSHA REGS FOR RSPRTR USE. PROVIDE VENT TO KEEP BELOW OSHA LIMITS. IF MAINTAIN BELOW PEL/TLV, OTHER OSHA/NIO SH APPROVED RSPRTR MAY BE USED. Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP VAPOR CONCENTRATIONS BELOW TLVS. REMOVE ALL IGNITION SOURCES. Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:213 TO 401F Vapor Density:> AIR Spec Gravity:1.33373 Viscosity:* Evaporation Rate & Reference:0.87 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:28.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED WITH CARE (RESIDUE IS FLAMMABLE). DO NOT INCINERATE CLOSED CO NTAINERS. EPA HZD CODE: D001, F003, F005.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METADI AEROSOL SPRAY, 40-6269 Preparer's Name:THOMAS R. DERAM CAGE:09410 CAGE:09410 ============= Composition/Information on Ingredients ============= Ingred Name:HEXYLENE GLYCOL CAS:107-41-5 RTECS #:SA0810000 Fraction by Wt: <10% OSHA PEL:C 25 PPM ACGIH TLV:C 25 PPM; 9192 Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 10-30% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:FLUORO CHLORO CARBON PROPELLANT(CONSISTING OF INGREDIENTS 4 & 5 AT A 50/50 MIXTURE) Fraction by Wt: >60% Other REC Limits:1000 PPM (MFR) Ingred Name:P-11 CAS:1175-69-4 Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:DIAMOND ABRASIVE/VARIOUS GRADES Fraction by Wt: 5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DEFATTING WITH PROLONGED CONTACT, SEE EFFECTS OF OVEREXPOSURE Effects of Overexposure:EYES/SKIN:MILD IRRITATION. INHAL:DROW,DIZZ,NASAL AND RESP IRRIT.INJEST:NAUSEA, VOMIT,DIARRHEA,ABDOM IRRIT. Medical Cond Aggravated by Exposure:OVER EXPOSURE MAY AGGRAVATE ASTHMATIC CONDITIONS ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHAL: MOVE TO FRESH AIR. SUPPORT BREATHING(GIVE O*2 ARTF/RESP) . EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MIN. INJEST: DILUTE WITH WATER, IN DUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:COMBUSTIBLE Extinguishing Media:WATER, CARBON DIOXIDE, FOAM Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIP. Unusual Fire/Explosion Hazard:CONTR CONTAINS LIQUEFIED COMPRESSED GAS UNDER PRESSURE,PLUS MINOR AMOUNT OF FLAM SOLVENT.THERMAL DECOMP OF PROD WILL INCLUDE CHLORIDES,FLORIDES&PHOSGENE ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, ABSORB LIQUID ON SUITABLE INERT ABSORBING MATERIAL AND DISPOSE IN SUITABLE WASTE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRODUCT CONTAINS LIQUEFIED GAS UNDER PRESSURE. AVOID TEMPS ABOVE 125F. Other Precautions:NO NOT SPRAY NEAR EYES. NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT &/OR UV RADIATION MAY CAUSE FORMATION OF CHLORIDES,FLUORIDES OR PHOSGE NE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IN PRESENCE OF HIGH VAPOR CONCENTATION. Ventilation:LOCAL EXHAST TO MAINTAIN EXPOSURE BELOW TLV IN INGRED SECTION Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:GOOD PERSONAL HYGIENE TO BE FOLLOWED AT ALL TIMES Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-6F,-21C Melt/Freeze Pt:M.P/F.P Text:90% Vapor Pres:1900 @ 70F Vapor Density:3 Spec Gravity:> 1 Evaporation Rate & Reference:>1(BUTYL ACETATE=1) Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:PLEASANT ODOR, VARIOUS COLORS ACCORDING TO DIAMOND GRADE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVIOD CONTACT WITH STRONG MINERAL ACIDS STRONG OXIDIZING AGENTS, RUBBER AND SOME PLASTICS. Stability Condition to Avoid:AVOID OPEN FLAMES OR HIGH TEMPERATURES ABOVE 125F IN STORAGE CANS Hazardous Decomposition Products:HIGH TEMP (FLAME) DECOMP OF PROPELLANT ONLY MAY FORM HYDROCHLORIC AND HYDROFLUORIC ACIDS, POSSIBLY PHOSGENE ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH WASTE MATERIAL WITHOUT PROPELLENT DOWN DRAIN.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:606516 GASPAK POUCH Preparer's Name:DALE M. OREN CAGE:06531 CAGE:05545 CAGE:06531 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN 1% CRYSTALLINE SILICA CAS:61790-53-2 RTECS #:HL8600000 Fraction by Wt: 57% Other REC Limits:10 MG/CUM OSHA PEL:20 MPPCF ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 2% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYE: IRRITATION. INHALATION: IRRITATION & PNEUMONOCONIOSIS. * NATURAL DIATOMACEOUS EARTH PRESENTS A MODERATE RISK FROM INHALATION OF PAARTICULATE. OTHERWISE IT IS NONTOXIC AND RELATIVELY HARMLESS . PNEUMONOCONIOSIS IS A POSSIBLE OCCUPATIONAL HAZARD FROM EXCESSIVE INHALATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYE: IRRITATION. INHALATION: IRRITATION & PNEUMONOCONIOSIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY Unusual Fire/Explosion Hazard:ANY ORGANIC POWDER CAN BE POTENTIALLY EXPLOSIVE IF DISTRIBUTED IN AIR IN CERTAIN CONCENTRATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:USE VACUUM OR WET SWEEPING TO AVOID CREATING DUST CONDITIONS WHEN PICKING UP SPILLS. PLACE IN CLOSED CONTAINER FOR DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:PROVIDE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:AS REQUIRED Supplemental Safety and Health MSDS RECEIVED FROM FOCAL POINT F (AIR FORCE). AIR FORCE IDENTIFIED THE NSN. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:PLASTIC BAG W/SACHET FILLED W/MIXTURE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID & ALKALI CARBONATE. Stability Condition to Avoid:HIGH TEMPERATURE ==================== Disposal Considerations ==================== Waste Disposal Methods:POWDER SHOULD BE LANDIFILLED & ACTIVATED PACKAGES SHOULD BE AUTOCLAVED IF EXPOSED TO MICROORGANISMS & DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:8270 SOLVENT CLEANER Preparer's Name:JOHN SCOTT CAGE:CALGN CAGE:CALGN ============= Composition/Information on Ingredients ============= Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SUSPECTED ANIMAL CARCINOGEN BY NTP & IARC - GROUP 2B) *95-2* CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: 8-10% Other REC Limits:50 PPM OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PETROLEUM DISTILLATE Fraction by Wt: 50-60% OSHA PEL:500 PPM Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY ACGIH, SUSP ANIM CARC BY IARC; NTP - IARC GROUP 2B) *95-2* CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 30-40% OSHA PEL:500 PPM ACGIH TLV:174 MG/CUM (A2) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 8850 MG/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITANT. INHALATION: WILL IRRITATE NASAL & RESPIRATORY PASSAGES. OVEREXPOSURE MAY CAUSE LIVER ABNORMALITIES, KIDNEY, LUNG/BRAIN DAMAGE. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, SKIN DRYNESS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/EYES FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN/CPR AS NECESSARY. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIANS: DON'T GIVE STIMULANTS. EPINEPHRINE/EPHEDRINE MAY ADVERSLY AFFECT THE HEART W/FATAL RESULTS. ===================== Fire Fighting Measures ===================== Flash Point:174F Extinguishing Media:FOAM, CO2 Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS W/A FULL FACE SHIELD OPERATED IN PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VAPORS ARE >AIR & MAY TRAVEL ALONG THE GROUND/BE MOVED BY VENTILATION & IGNITED BY IGNITION SOURCES AT LOCATIONS DISTANT FROM HANDLING POINT. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WILL EVAPORATE. LARGE: MAY BE ABSORBED W/AN ABSORBENT MATERIAL & DRUMMED. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT. KEEP CONTAINER CLOSED AT ALL TIMES. MOVE W/BUNGS IN PLACE. WEAR ADEQUATE EQUIPMENT WHEN TRANSFERRING CHEMICAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION ISN'T ADEQUATE, USE SELF CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST TO MAINTAIN TLVS. Other Protective Equipment:RUBBER BOOTS, APRON, NIOSH APPROVED CLOTHING/EQUIPMENT, SAFETY SHOWER, EYE WASH Supplemental Safety and Health ORAL LD50 INFORMATION IS FOR: TETRACHOLOROETHYLENE. FIRE HAZARD CONT'D: NEVER USE WELDING/CUTTING TORCH IN/NEAR DRUM EVENT EMPTY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:103.6F Vapor Density:>1 Spec Gravity:0.94 Evaporation Rate & Reference:(N-BU ACETATE=1): >1 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR WATER-WHITE W/CHLORINATED SOLVENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT, PILOT LIGHTS & OTHER IGNITION SOURCES Hazardous Decomposition Products:CO2, CO, PHOSGENE, VARIOUS HYDRO CARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:DESTROY BY LIQUID INCINERATOR W/OFF-GAS SCRUBBER. CONTAMINATED ABSORBENT MAY BE DEPOSITED IN LANDFILL IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. UN/NA1693.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLYURETHANE FLOOR ENAMEL TILE RED, A33 R 8 CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ING 4: HARMFUL OR FATAL. PROTECT AGAINST DUST WHICH MAY BE GENERATED BY SANDING OR ABRADING DRIED FILM. RTECS #:9999999ZZ Ingred Name:HYDROTREATED LIGHT PETROLEUM DISTILLATE. VP: 2.0. CAS:64742-47-8 Fraction by Wt: 5% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:MINERAL SPIRITS. VP: 0.5. CAS:64742-88-7 Fraction by Wt: 35-40% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:CHROMIUM (III) OXIDE (2:3) CAS:1308-38-9 RTECS #:GB6475000 Fraction by Wt: 0-5% OSHA PEL:0.5 MG/M3 (CR) ACGIH TLV:0.5 MG/M3 (CR) Ingred Name:SUPP DATA: SANDING/ABRADING OF DRIED FILM. INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING CONTENTS CAN BE (ING 5) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IN CONFINED AREA VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC. OVEREXPOSURE MAY RESULT IN LIGHTHEADEDNESS AND STAGGERING GAIT. IRRITANT TO SKIN AND UPPER RESPIRATORY SYSTEM. CHRONIC: REPORTS HAV E ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH W ITH LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:102F,39C Lower Limits:0.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.WATER SPRAY MAY BE INEFT.IF WATER USED,FOG NOZZ PREF.WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD.ISOLATE FROM HEAT,ELEC EQUIP,SPARKS,& OPEN FLAME.CLSD CNTNRS MAY EXPLO WHEN EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS REQS (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE COMBUST.KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROC. KEEP CNTNRS CLSD WHEN NOT IN USE. Other Precautions:TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LBLG.DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.COATING CONTAINS MATLS CLASSIFIED AS NUISANCE PARTICULATES, FOR EXAMPLE TITANIUM DIOXIDE, CALCIUM CARBONATE ETC.SEE ACGIH (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR NIOSH/MSHA APPROVED RESPIRATORY DEVICE FOR PROTECTION AGAINST MATERIALS IN INGREDIENTS SECTION. Ventilation:LOC EXHST PREFERABLE. GENERAL EXHST ACCEPTABLE IF EXPOS TO MATLS IN ING SEC IS MAINTAINED BELOW APPLIC EXPOS LIMITS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:USE ONLY WITH ADEQ VENT. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC: PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ: SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE IMMED APPAREN T. OBTAIN MED ATTN. OTHER PREC: TLV LIST, PREFACE & APPENDIX D) WHICH MAY BE PRESENT AT HAZ LEVS ONLY DURING (ING 4) ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:SEE ING Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:61 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISP OF I/A/W FED, ST,& LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALL WOOD CASED PENCIL PRODUCTS, DARK GRAY CAGE:73781 CAGE:73781 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS; (WOOD CASED PENCIL) OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PENCIL PRODUCTS BEARING THE PMA CERTIFICATION MARK (SEAL) ARE CERTIFIED IN A PROGRAM OF TOXICOLOGIC EVALUATION BY MEDICAL EXPERT SUBJECT TO REVIEW BY THE PROGRAMS TOXICOLOGICAL REVIEW BD. TO CONTAIN N O MATERIALS IN SUFFICIENT QUANTITIES TOOFFER AN ACUTE OR CHRONIC HEALTH HAZARD TO HUMANS. NO ACUTE OR (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CHRONIC HEALTH LABELING IS REQUIRED UNDER, PROVISION OF FEDERAL LAW, THE FEDERAL HAZARDOUS SUBSTANCE ACT, OR UNDER ASTM STANDARD D 4236. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSIS TANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point:365F,185C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PENCIL PRODUCTS STORED IN BULK ARE SUBJECT TO IGNITION BY FIRE AND MAY, IN CASE OF FIRE, RELEASE TOXIC AND OTHER IRRITATING GASES. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NOT APPLICABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NOT APPLICABLE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID STICK FORM----CEDAR FRAGRANCE, DK GREY ================= Stability and Reactivity Data ================= NOT APPLICABLE. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
======================================================= Product ID: AMMONIUM HYDROXIDE SOLUTIONS, LC11080 Cage: EO318 ======================================================= Contractor Summary ======================================================= Cage: EO318 Cage: 0MX47 ======================================================= Ingredients ======================================================= Cas: 1336-21-6 RTECS #: BQ9625000 % Wt: 4.2-50 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: BALANCE OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ BURNS. GET MED AID AT ONCE. INGEST: GIVE ----------------------------- ALKALI. DO NOT INDUCE VOMIT. GET MED AID AT ONCE. ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENT 1 Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: AMMONIUM HYDROXIDE IS CORR IRRITANT TO SKIN, EYE, RESP TRACT & MUC MEMBS. CAN CAUSE SEV BURNS, EYE & LUNG INJURY AT HIGH SOLN CONCS. ACUTE: MILD EXPOS MAY CAUSE IRRIT OF NOSE (COUGHING, SNEEZING), RED NESS & ITCHING OF SKIN, REDNESS & IRRITOF EYES. EXPOS AT HIGHER CONCS MAY CAUSE RESP DISTRESS, PULM (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: EDEMA, SHOCK, CONVULSIONS, CYANOSIS, CNS DEPRESS; CHEM BURNS TO EYES & SKIN MAY OCCUR RESULTING IN CORROSIVE DMG INCLUDING ULCERATION & TEMPORARY BLINDNESS. INGEST MAY RSLT IN NAUS, VOMIT, G I IRRIT, EXCESSIVE SALIVATION; IN SEVERE CASES PERFORATION, CNS DEPRESS, SHOCK, CONVULSIONS & PULM EDEMA CAN (SUPDAT) Medical Cond Aggravated By Exposure: SKIN AND RESPIRATORY DISEASE AGGRAVATED BY EXPOSURE. First Aid: INHAL: MOVE VICTIM TO FRESH AIR IMMED, GIVE ARTF RESP IF NECESSARY. GET MED AID AT ONCE. SKIN: REMOVE CONTAM CLTHG, WASH W/SOAP & WATER. FLUSH W/LARGE QTYS OF WATER (15-20 MIN) UNTIL CHEM IS GONE. COV ER BURNS W/DRY STERILE DRESSING (SECURE, NOT TIGHT). GET MED AID AT ONCE. EYES: IMMED FLUSH W/LARGE AMTS OF WATER (AT LEAST 15-20 MIN) LIFTING UPPER/LOWER LIDS OCCASIONALLY UNTIL CHEMICAL IS ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NEUT TO PH 7 W/DILUTE ACID OR SUITABLE AGENT. ABSORB W/INERT ABSORB (SAND, DIATOMACEOUS EARTH), SCOOP INTO GLASS/PLASTIC CNTNR FOR LATER DISPOSAL. VENT AREA, WASH DOWN W/WATER IF NECESSARY. AVOID BRTH G GAS, WEAR PROT CLTHG/NIOSH APPRVD RESP EQUIP. Neutralizing Agent: NEUTRALIZE TO PH 7 WITH A DILUTE ACID OR SUITABLE AGENT. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: STORE CAPPED IN GLASS OR PLASTIC CONTAINER. PROTECT FROM HEAT AND INCOMPATIBLE SUBSTANCES. VENTILATE AREA. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONFLAM (SUPDAT) Lower Limits: 16% (SUPDAT) Upper Limits: 25% Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NGELIG FIRE & EXPLOSION HAZ. ALTHOUGH NOT A FLAM LIQ (DOT), AMMONIA GAS EVOLVED IS FLAMM, IS EYE, SKIN & RESP IRRITANT. MOVE CNTNRS IF POSS, COOL WITH (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: NOT REQUIRED FOR LAB USE WHEN WORKING UNDER APPROVED HOOD. >300PPM - NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. Ventilation: PROVIDE LOCAL EXHAUST VENTILATION TO MEET PERMISSABLE EXPOSURE LIMITS (PEL) FOR AMMONIA GAS. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. Supplemental Safety and Health: BP: (NH*3 VAPOR RELEASE). PH: ALKALINE. FL PT: (AS AQUA AMMONIA). LEL: (FOR EVOLVED AMMONIA GAS) EXPLO HAZ: WATER. AVOID BRTHG CORR VAPS. MATLS TO AVOID: W/STRONG OXIDIZERS, MOST METALS & THEIR ALLOYS . EFTS OF OVEREXP: OCCUR. CHRONIC: BRONCHITIS, DERMATITIS, CONJUNCTIVITIS CAN OCCUR. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: SUPDAT M.P/F.P Text: <32F,<0C Vapor Density: >AIR Spec Gravity: <1.0 PH: SUPDAT Evaporation Rate & Reference: 1 (WATER) Solubility in Water: COMPLETELY SOLUBLE Appearance and Odor: CLEAR, COLORLESS LIQUID; PUNGENT TO FAINT AMMONIA ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEATING EVOLVES AMMONIA GAS (NH*3). Materials To Avoid: REACTS EXOTHERMICALLY W/ACIDS, REACTS W/HYPOCHLORITES, HALOGENS, SODIUM HYDROXIDE & GALVANIZED SURFS. REACTS (SUPDAT) Hazardous Decomposition Products: AMMONIA GAS IS RELEASED WHICH MAY DECOMPOSE ABOVE 842F TO HYDROGEN AND NITROGEN GASES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: AMMONIUM HYDROXIDE SOLUTIONS, LC11080 Cage: EO318 Assigned IND: Y Company Name: LABCHEM INC Street: 200 WILLIAM PITT WAY Zipcode: 15238 Label Required IND: Y Date Of Label Review: 11/09/1998 Status Code: C Label Date: 11/09/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: MILD EXPOSURE MAY CAUSE IRRITATION OF NOSE (COUGHING, SNEEZING), REDNESS AND ITCHING OF SKIN, REDNESS AND IRRITATION OF EYES. EXPOSURE AT HIGHER CONCENTRATIONS MAY CAUSE RESPIRATORY DISTRESS, P ULMONARY EDEMA, SHOCK, CONVULSIONS, CYANOSIS, CNS DEPRESSION. CHEMICAL BURNS TO EYES AND SKIN MAY OCCUR RESULTING IN CORROSIVE DAMAGE INCLUDING ULCERATION AND TEMPORARY BLINDNESS. INGESTION MAY RESULT IN NAUSEA, VOMITING, GASTRIC IRRITATION, EXCESSIVE SALIVATION; IN SEVERE CASESPERFORATION, CNS DEPRESSION, SHOCK, CONVULSIONS AND PULMONARY EDEMA CAN OCCUR. CHRONIC: BRONCHITIS, DERMATITIS, CONJUNCTI VITIS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:UM900 SERIES Preparer's Name:FRANK PETERS CAGE:21546 CAGE:21546 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:ABRASIVE CAN SCRATCH EYES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE TECHNIQUES & MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:MATERIAL CAN SPATTER >212F. POLYMER FILM CAN BURN. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP PROPERLY W/PAPER TOWELS & A WET SPONGE. PUT PAPER TOWELS IN TRASH & RINSE OUT SPONGE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER SEALED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRATOR THAT IS NIOSH APPROVED FOR SPRAYS & MISTS. Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): RECOMMENDED WHEN SPRAYING. Other Protective Equipment:NONE Work Hygienic Practices:GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Density:<1 Spec Gravity:1-1.3 pH:6.5-9 Evaporation Rate & Reference:(BUTYL ACETATE=1): <1 Solubility in Water:INSOLUBLE Appearance and Odor:OPAQUE COLORED LATEX PAINT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPS >212F ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ETHYL KETONE CAGE:0YFV5 CAGE:0YFV5 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV:PEL: 200 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. SKIN: MODERATE IRRITATION, DEFATTING, DERMATITIS. INHALATION: NASAL AND RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS, DEATH. INGESTION: GASTROINTESTINAL IRRITATION. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:EYES: REDNESS, TEARING, BLURRED VISION. INHALATION: DIZZINESS, WEAKNESS, FATIGUE, HEADACHE, UNCONSCIOUSNESS. INGESTION: NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, RESPIRATORY TRACT, LIVER, OR KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHALATION: MOVE TO FR ESH AIR. IF NOT BREATHING, GIVE CPR. IFBREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. KEEP PERSON WARM. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:23.0F,-5.0C Lower Limits:2.0 Extinguishing Media:ALCOHOL FOAM OR CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR & MAY TRAVEL ALONG THE GROUND & IGNITE BY PILOT LIGHTS OR OTHER SOURCES OF IGNITION AT LOCATIONS DISTANT FROM MATERIAL HANDLING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL AND TRANSFER TO HOOD Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID AND/OR SOLID) ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT IS EXCEEDED, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIR ATORS (NEGATIVE PRESSURE TYPE). Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLVS. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER, IMPERVIOUS WORK CLOTHING AND APRON AS REQUIRED TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health FLAMMABLE LIQUID. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175F,79C Vapor Pres:70 MM Vapor Density:2.5 AIR=1 Spec Gravity:0.805-0.807 Evaporation Rate & Reference:5.70 (N-BUTYL ACETATE=1) Appearance and Odor:LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT WORK. DISPOSE OF REMAINING MATERIAL IN ACCORDANCE WITH APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1325, KRYLON ALL-PURPOSE SILICONE SPRAY CAGE:09800 CAGE:26290 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 10-30% Ingred Name:METHYLCYCLOHEXANE CAS:108-87-2 RTECS #:GV6125000 Fraction by Wt: 5-10% OSHA PEL:500 PPM ACGIH TLV:400 PPM; 9495 Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-10% OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEXANE (N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 10-30% OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CYCLOHEXANE (SARA 313) (CERCLA) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 1-5% OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-HEPTANE CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: 10-30% OSHA PEL:500 PPM ACGIH TLV:400 PPM/500STEL;9495 Ingred Name:V M & P NAPHTHA CAS:64742-89-8 Fraction by Wt: 30-50% Ingred Name:HEXANE ISOMERS Fraction by Wt: 10-30% Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10-30% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAUSES IRRITATION. SKIN:CAUSES IRRITATION. NOT EXPECTED TO BE HARMFUL BY ABSORPTION. INHALED:MAY BE HARMFUL. LIQUID OR VAPOR MAY CAUSE RESPIRATORY IRRITATION. INGESTION:NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. IF SWALLOWED, MAY CAUSE IRRITATION OR BURNS OF MUCOUS MEMBRANE, ESOPHAGUS, G/I TRACT. Explanation of Carcinogenicity:AS OIF THE DATE OF THIS MSDS, NONE OF THE INGREDIENTS HAVE BEEN LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:IRRITATION. SKIN:IRRITATION. INHALED:IRRITATION OF RESPIRATORY TRACT. INGESTION:G/I BURNS, IRRITATION. Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION ON MSDS. ======================= First Aid Measures ======================= First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. A ID OR RESTORE BREATHING AS NEEDED. INGESTED:DILUTE BY DRINKING LARGE QUANTITIES OF WATER. IMMEDIATELY CONTACT POISON CONTROL CENTER OR HOSPITAL EMERGENCY ROOM FOR TREATMENT DIRECTIONS. ===================== Fire Fighting Measures ===================== Flash Point:>-4F,>-20C Lower Limits:1.2 Upper Limits:9.5 Extinguishing Media:USE FOG, FOAM, CARBON DIOXIDE OR DRY CHEMICAL. WATER MAY BE INEFFECTIVE, USE IT TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:VERY FLAMMABLE LIQUID. VAPORS ARE HEAVIER THAN AIR & CAN TRAVEL ALONG SURFACES TO IGNITION SOURCES & FLASH BACK. Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. DO NOT INCINERATE CONTAINER. AVOID HEAT. KEEP CONTAINER <120F. DO NOT PUNCTURE. AVOID ALL IGNIOION SOURCES. VAPOR MAY IGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP ABSORBENT MATERIAL AND REMOVE TO CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 120F. DO NOT PLACE ON REAIATOR, STOVE OR IN DIRECT SUNLIGHT. Other Precautions:HANDLE I/A/W GOOD INDUSTRIAL HYGIENE & SAFETY PRACTICE. AVOID UNNECESSARY EXPOSURE. REMOVE MATERIAL FROM EYES,SKIN,CLOTHING. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE AIR CONTAMINATION CAN EXCEED ACCEPTABLE CRITERIA, USE NIOSH/MSHA APPROVED RESPIRATORY EQUIPMENT. SELECT RESPIRATORS BASED ON FORM & CONCNTRATION OF AIR CONTAMINATION I/A/W OSHA 29 CFR 1910.134 O R OTHER STANDARDS OR GUIDELINES. Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & FLOW TO KEEP CONTAMINANT CONCENTRATION LEVELS BELOW ACCEPTABLE CRITERIA. Other Protective Equipment:MFR GAVE NO INFORMATION ON MSDS. Work Hygienic Practices:MFR:? HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICES. MINIMIZE CONTACT & WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V3 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>-48F,>-44C Melt/Freeze Pt:M.P/F.P Text:<32F,<0C Vapor Pres:50 PSI Vapor Density:>1 Spec Gravity:0.65 +/-0.02 pH:NEUT Evaporation Rate & Reference:>1(BUTYL ACETATE=1) Solubility in Water:SLIGHT Appearance and Odor:LIQUID & LIQUIFIED GAS, HYDROCARBON SOLVENT ODOR. Percent Volatiles by Volume:92-94 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS OR BASES. Stability Condition to Avoid:MFR GAVE NO INFORMATION ON MSDS. Hazardous Decomposition Products:OXIDES OF CARBON. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE/PROVINCIAL, AND FEDERAL REQUIREMENTS. EMPTY CONTAINER:MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE CONTAINER TO BURST VIOLENTLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FRENCH ULTRAMARINE BLUE Preparer's Name:WOODHALL STOPFORD CAGE:72925 CAGE:72925 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM PIGMENT Ingred Name:CADMIUM SUSPECTED HUMAN CARCINOGEN (ACGIH,IARC, & NTP) INTENDED CHANGE (IC) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: 0.05% Other REC Limits:A2 CARCINOGEN OSHA PEL:0.05 MG/CUM (CD) ACGIH TLV:0.01 MG/CUM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM Ingred Name:HEXACHLOROBENZENE CAS:118-74-1 RTECS #:DA2975000 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC, ACGIH) INTENDED CHANGE (IC) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 1.00% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: MAY BE HARMFUL IF SWALLOWED. CRONIC: EXPOSURE MAY CAUSE DAMAGE TO THE HEART/LUNGS. EXPOSURE MAY CAUSE DAMAGE TOTHE CHEST. EXPOSURE MAY CAUSE HARM TO THE DEVELOPING FETUS. LUNG DISEASE. KID NEY DISEASE. PREGNANCY. HEART DISEASE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:INGESTION: GET PROMPT MEDICAL ATTENTION. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL SPILL PROCEDURES REQUIRED. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH-CERTIFIED MASK FOR DUSTS Ventilation:LOCALLY EXHAUSTING HOOD Work Hygienic Practices:DON'T SPRAY APPLY. WASH HANDS IMMEDIATELY AFTER USE. WHEN USING DON'T EAT, DRINK/SMOKE. AVOID USING IF PREGNANT. Supplemental Safety and Health ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATAE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: TANDEM-R FERRITIN Kit Part: Y Cage: FO596 Box: 269006 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: FO596 Assigned Ind: Y Box: 269006 ======================================================= Contractor Summary ======================================================= Cage: 63493 Box: 269006 Cage: FO596 Box: 269006 ======================================================= Ingredients ======================================================= Cas: 26628-22-8 RTECS #: VY8050000 % Wt: 0.1 Other REC Limits: 0.1 PPM ACGIH TLV: C 0.29 MG/CUM EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Explanation Of Carcinogenicity: NONE First Aid: EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH DRAINS W/COPIOUS AMOUNTS OF WATER TO PREVENT AZIDE ACCUMULATION. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. REFRIGERATE, UNLESS OTHERWISE SPECIFIED IN KIT INSERT. Other Precautions: AZIDE REACTS W/MANY HEAVY METALS SUCH AS LEAD, COPPER, MERCURY, SILVER & GOLD TO FORM EXPLOSIVE COMPOUNDS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: DRY CHEMICAL Unusual Fire/Explosion Hazard: CONTACT W/COPPER/LEAD DRAIN PIPES MAY RESULT IN THE FORMATION OF POTENTIALLY EXPLOSIVE AZIDE DEPOSITS. ======================================================= Control Measures ======================================================= Other Protective Equipment: LAB COAT Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.85 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: ACIDS, HEAVY METALS; LEAD, COPPER, BROMINE, CARBON DISULFIDE, CHROMYCHLORIDE, DIBROMO MALONITRILE, DIMETHYL SULFATE Hazardous Decomposition Products: SODIUM & OXIDES OF NITROGEN Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: TANDEM-R FERRITIN Cage: FO596 Assigned IND: Y Company Name: HYBRITECH INCORPORATED Street: 11095 TORREYANA ROAD PO Box: 269006 Zipcode: 92126 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: N/K N/K =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HARD HAT PRIMERS AND TOPCOATS, 2190 CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:SUPDAT:KIDNEY, LUNG, SPLEEN & EYE DMG AS WELL AS ANEMIA. AFFECTS IN HUMANS HAVE SHOWN LIVER & CARD ABNORM. (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:ETHYLENE GLYCOL BUTYL ETHER MAY BE HARMFUL IF ABSORBED THROUGH SKIN & HAS BEEN SHOWN TO CAUSE BLOOD ABNORM (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:IN LAB ANIMALS. RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:XYLENE; (XYLOL) (SARA 313) (CERCLA). VP:9.5 @ 20C. LEL:1.2%. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 15-25% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22 @ 20C. LEL:1.2%. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10-25% OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM & P NAPHTHA. VP:2 @ 20C. LEL:0.9%. CAS:64742-89-8 Fraction by Wt: 0-5% OSHA PEL:300 PPM (MFR) ACGIH TLV:300 PPM (MFR) Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL BUTYL ETHER). VP:0.9 @ 20C. LEL:1.1%. CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 0-5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). VP:70 @ 20C. LEL:2.0%. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 0-3% OSHA PEL:200 PPM ACGIH TLV:200 PPM/300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HYDROCARBON PROPELLANT (PROPANE/ISOBUTANE); (PROPELLANT) (PROPANE, BUTANE, ISOBUTANE). VP:85 PSIG. LEL:1.8% CAS:68476-86-8 Fraction by Wt: 25% OSHA PEL:1000 PPM (MFR) ACGIH TLV:1000 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:HARMFUL IF INHALED. MAY AFFECT BRAIN & NERV SYS CAUSING DIZZ, HDCH/NAUS. RPTD OVEREXP MAY PROGRESSIVELY LEAD TO STAGG GAIT, CONFUSION, UNCON/COMA. CAUSES NOSE & THROAT IRRIT. SKIN OR EYE:C AUSES EYE & SKIN IRRIT WHICH CAN LEAD TO DERM W/RPTD OVEREXP. INGEST:MAY CAUSE GI IRRIT, NAUS, VOMIT & (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:DIARR. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON THE CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTR ACTED FROM DHHS (NIOSH) PUB NO. 90-118). TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZS. SEEK (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE, RESTORE BREATHING & NOTIFY PHYS. EYE:FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. NOTIFY PHYS. SKIN:WASH AFFECTED AREA WITH SOAP & WATER, REMOVE CONTAMI NATED CLOTHING AND WASH BEFORE REUSE. INGEST:DO NOT INDUCE VOMITING. KEEP PERSON WARM, QUIET & GET MED ATTN. ASPIRATION OF THIS MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<0F,<-18C Lower Limits:SEE INGS Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR FOAM). Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO. IF WATER IS USED, FOG (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT PUNCTURE OR INCINERATE CONTAINERS. Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR (TC23C) TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY AND ORGANIC VAPORS DURING SPRAY APPLICATION. IN CONFINED AREAS:USE NIOSH APPROVED SUPPLIED-AIR RESPIRATORS OR HOODS (TC19C). Ventilation:PROVIDE GENERAL DILUTION/LOC EXHAUST VENT IN VOLUME & PATTERN TO KEEP TLV OF HAZ INGREDS BELOW ACCEPTABLE LIMITS. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC:NOZZ ARE PREF. EFTS OF OVEREXP:CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . CHRONIC:RPTS HAVE SHOWN RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. OVEREXP TO TOLUENE & XYLOL IN LAB ANIMALS HAS SHOWN LIVER ABNORM, (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:SLOWER ETHER Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY OPEN FLAME-CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAY SILV 35 CAGE:27911 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER (SARA III) CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 35.0% OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 26.0% OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 21.0% OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CADMIUM CAS:86627-71-6 RTECS #:EY9800000 Fraction by Wt: 18.0% ===================== Hazards Identification ===================== Effects of Overexposure:WHEN BRAZING IN CONFINED AREAS,DIZZINESS AND NAUSEA ======================= First Aid Measures ======================= First Aid:CONSULT PHYSICIAN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRATOR WHEN IN CONFINED AREAS Ventilation:LOCAL EXHAUST IS PREFERRED Other Protective Equipment:RESPIRATOR MASK Supplemental Safety and Health ITEM IS GRADE VIII OF FEDERAL SPECIFICATION QQ-B-654 ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:9.18 Appearance and Odor:COPPER COLORED AND ODORLESS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:23990 BP616-500 TRIETHYLAMINE 99.7% CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:TRIETHYLAMINE CAS:121-44-8 RTECS #:YE0175000 Fraction by Wt: 100% Other REC Limits:10 PPM OSHA PEL:100 MG/CUM ACGIH TLV:41 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 460 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: SEVERE IRRITATION/BURNS. MAY BE ABSORBED. LACRYMATOR. INGESTION: HARMFUL. MAY CAUSE SEVERE GI TRACT IRRITATION W/POSSIBLE BURNS. INHALATION: RESPIRATORY TRACT IRRITATION W/BURNING PAIN TO N OSE/THROAT. PULMONARY EDEMA. PROLONGED/REPEATED EXPOSURE MAY CAUSE DAMAGE TO KIDNEYS & LUNGS. DERMATITIS/ULCERATIONS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, SENSITIZATION TO LIGHT, HALO VISION, NAUSEA, VOMITING, COUGHING, WHEEZING, SHORTNESS OF BREATH ======================= First Aid Measures ======================= First Aid:EYES: DON'T ALLOW TO RUB/KEEP EYES CLOSED. FLUSH CONTINUOUSLY W/WATER. IRRIGATE EXCESSIVELY FOR 30 MINS. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: IF CONSCIOUS & ALERT, GIVE 2-4 CUP FULS OF MILK/WATER. NEVER GIVE ANYTHINGBY MOUTH IF UNCONSCIOUS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:12.2F Lower Limits:1.2 Upper Limits:8 Extinguishing Media:DRY CHEMICAL, CO2/ALCOHOL-RESISTANT FOAM. DON'T USE WATER. Fire Fighting Procedures:WEAR SCBA IN PRESSURE DEMAND, MSHA/NIOSH APPROVED & FULL PROTECTIVE GEAR. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:VAPORS TRAVEL TO IGNITION SOURCES & FLASHBACK/CAUSE FLASH FIRE. FIRE MAY SPREAD BY USE OF WATER. VAPORS MIXED W/AIR CAN EXPLODE WHEN IGNITED. AUTOIGNITION:446F. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL; DRY SAND/EARTH. PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE ALL SOURCES OF IGNITION. ISOLATE AREA & DENY ENTRY. PROVIDE VENTILATION. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM HEAT/SPARKS/FLAME. STORE IN A COOL, DRY PLACE AWAY FROM STRONG ACIDS. KEEP CONTAINERS TIGHTLY CLOSED. USE W/ADEQUATE VENTILATION. Other Precautions:GROUND & BOND CONTAINERS WHEN TRANSFERRING MATRERIAL. DON'T GET IN EYES, ON SKIN/ON CLOTHING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE. DON'T INGEST/INHALE. DON'T PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL /GRIND/EXPOSED TO IGNITION SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MEETING OSHA'S 29 CFR 1910.134 & ANSI Z88.2 REQUIREMENTS WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Ventilation:PROCESS ENCLOSURES/LOCAL EXHAUST TO CONTROL AIRBORNE LEVELS <RECOMMENDED EXPOSURE LIMITS. USE ONLY IN CHEMICAL FUME HOOD Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. DISCARD CONTAMINATED SHOES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:192.02F Melt/Freeze Pt:M.P/F.P Text:-174.5 Vapor Pres:54 Vapor Density:3.5 Spec Gravity:0.728 Evaporation Rate & Reference:(BUTYL ACETATE =1): 5.6 Appearance and Odor:CLEAR, COLORLESS LIQUID W/AMMONIA-LIKE/FISHY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZING AGENTS Stability Condition to Avoid:EXCESS HEAT & OTHER IGNITION SOURCES Hazardous Decomposition Products:NITROGEN OXIDES, CO, CO2, NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1401 ANTI SEIZE CAGE:OFC18 CAGE:0FC18 CAGE:OFC18 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHOL SPIRITS; (ISOPARAFINNIC HYDROCARBON) CAS:64742-48-9 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COPPER; (COPPER COMPOUND) (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 13% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC: INHALATION: HIGH CONCENTRATIONS ARE IRRITATING TO THE EYES AND UPPER RESPIRATORY TRACT. MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC AND MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFEC TS. SKIN: FREQUENT OR PROLONGED CONTACTMAY IRRITATE AND CAUSE DERMATITIS. LOW ORDER OF TOXICITY. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: INGESTION: SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION OR FROM VOMITING MAY CAUSE BRONCHIOPNEUMONIA OR PULMONARY EDEMA. MINIMAL TOXICITY. EYES: CAN CAU SE SEVERE IRRITATION, REDNESS, TEARING AND BLURRED VISION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. IF BREATHING IS STOPPED GIVE ARTIFICIAL RESPIRATION. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: DILUTE WITH WATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTIO N. EYES: FLUSH EYES WITH WATER LIFTING UPPER AND LOWER LIDS. GET MEDICAL ATTENTION. SKIN: WASH EXPOSED SKIN AREAS WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:76.0F,24.4C Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE EQUIPMENT . USE EQUIP OR SHIELDING REQD TO PROTECT PERSONNEL AGAINST BURSTING, RUPTURING OR VENTING CNTNRS. Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE SPRAY PER CPSC FLAME EXTENSION TEST. AT ELEVATED TEMPERATURES (ABOVE 120F) CONTAINERS MAY VENT, RUPTURE OR BURST. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP AREA BY MOPPING OR WITH ABSORBENT MATERIALS AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. CONTACT FEDERAL, STATE OR LOCAL AUTHORITIES FOR APPROVED DISPOSAL PROCEDURES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AEROSOL PRODS PRESENT LIMITED HAZ DURING STOR/USE IF LABEL PRECS ARE FOLLOWED. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. Other Precautions:PRESSURIZED CONTAINERS MUST NOT BE EXPOSED TO TEMPS ABOVE 120F AND SPRAY SHOULD NOT BE DIRECTED TOWARD FACE OR EYES, OPEN FLAME OR OTHER IGNIT SOURCE. PLEASE READ & FOLLOW DIRECTIONS ON PROD LABEL. TH EY ARE BEST GUIDE TO USING PROD (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL CONDITIONS NO RESPIRATORY PROTECTION IS REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL VENTILATION NORMALLY ADEQUATE. USE EXPLOSION PROOF EQUIPMENT IN CONFINED AREAS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LONG SLEEVES SHOULD BE WORN. Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREA. WASH HANDS BEFORE EATING. DO NOT STORE AT TEMPERATURES ABOVE 120F. Supplemental Safety and Health OTHER PRECS: IN MOST EFFECTIVE WAY & THEY ALSO GIVE THE NECESSARY SAFETY PRECS TO PROTECT HEALTH. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:140F,60C Vapor Pres:45 @ 75F Spec Gravity:0.973 @ 75F Solubility in Water:NEGLIGIBLE Appearance and Odor:GREY VISCOUS LIQUID; MILD SOLVENT ODOR. Percent Volatiles by Volume:67% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:DO NOT EXPOSE TO TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN USED PROPERLY AEROSOL PRODUCTS DO NOT GENERATE HAZARDOUS WASTE. EMPTY DE-PRESSURIZED CONTAINERS SHOULD BE RECYCLED. CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES FOR APPROVED PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9734 ENDURANCE OIL STAIN CAGE:EO698 CAGE:01PD6 CAGE:EO698 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE (PETROLEUM), (C10-C15 SATURATED HYDROCARBONS 97%, C10 AROMATICS 3%) (SUSP ANIMAL CARCINOGEN BY IARC)*98-3* CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 60-70% Other REC Limits:200 PPM EXXON Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *98-3* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 1-5% Other REC Limits:0.05 MG/CUM (NIOSH) OSHA PEL:10 MG/CUM %RESP SIO2 ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:YELLOW OXIDE, YELLOW IRON OXIDE*98-3* CAS:51274-00-1 Fraction by Wt: 1-5% Ingred Name:FATTY ACIDS, TALL-OIL, POLYMER W/GLYCEROL, PENTAERYTHRITOL & PHTHALIC ANHYDRIDE *98-3* CAS:66070-62-0 Fraction by Wt: 20-30% Ingred Name:VOLATILE ORGANIC CONTENT: 7.3 LBS/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT IRRITANT. CNS DEPRESSION. SKIN: MAY CAUSE IRRITATION/DERMATITIS. EYES: SEVERE IRRITANT/BLURRED VISION. INGESTION: LARGE AMOUNTS CAN CAUSE LUNG INFLAMMATION & DAMAGE DUE T O ASPIRATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. (SEE SUPP) Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, FATIGUE, DROWSINESS, DIZZINESS, LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, COUGHING, DEFATTING, BLURRED VISION, TEARING, REDNESS, INFLAMMATION Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, RESPIRATORY & LUNG DISORDERS, ASTHMA-LIKE CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NEEDED. SKIN: WASH OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:105F Lower Limits:0.7 Extinguishing Media:DRY CHEMICAL/FOAM Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT/FIRE. VAPORS CAN FORM EXPLOSIVE MIXTURES IN AIR AT ELEVATED TEMPS. EMITS TOXIC GASES UNDER FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. MAY BE COLLECTED W/NONCOMBUSTIBLE ABSORBENT MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 100F. KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE. USE W/ADEQUATE VENTILATION. Other Precautions:GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN, EYES & BREATHING OF VAPORS. EMPTY CONTAINERS MA Y CONTAIN HAZARDOUS RESIDUES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY NIOSH/MSHA APPROVED RESPIRATORS IAW/OSHA STANDARD 29 CFR 1910.134. AVOID CONDITIONS WHICH RESULT IN FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING PAINTED SURFACES. Ventilation:DILUTION/LOCAL EXHAUST TO PREVENT BUILDUP OF VAPORS. Other Protective Equipment:EYE WASH, SAFETY SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:310-400F Percent Volatiles by Volume:78.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS, BASES, AMINES Stability Condition to Avoid:EXTREME HEAT/FIRE/OPEN FLAME, SPARKS, ELEVATED TEMPERATURES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. UN1263 COMBUSTIBLE LIQUID.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIX 170C RFT CAGE:19740 CAGE:19740 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <5% OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:PARTICULATES NOT OTHERWISE REGULATED (NUISANCE DUST) Fraction by Wt: 100% OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST; 8990 ===================== Hazards Identification ===================== Effects of Overexposure:REPEATED INHALATION OF RESP. FREE CRYSTALLINE SILICA MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). ======================= First Aid Measures ======================= First Aid:TERMINATE EXPOSURE. ======================Handling and Storage ====================== Handling and Storage Precautions:REMOVAL OF THIS PRODUCT AFTER USE MAY RESULT IN THE GENERATION OF DUST. Other Precautions:REPEATED INHALATION OF RESPIRABLE FREE CRYSTALLINE SILICA DUST MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FULL FACEPIECE RESPIRATOR W/APPROPRIATE FILTER PAD OR CARTRIDGE(S) Ventilation:LOCAL EXHAUST AND MECHANICAL Other Protective Equipment:AS REQUIRED TO MEET APPLICABLE OSHA STANDARDS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.8 Solubility in Water:INSOLUBLE Appearance and Odor:COARSE AGGREGATE W/FINE POWDERED MATRIX. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:ROUTINE HOUSEKEEPING
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A54RS50 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA) LD50 (ORAL RAT): 5628 MG/KG CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM/250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: THOSE OF ACUTE INHALATION AND INGESTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: EFTS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, INCL EXCITEMENT, FOLLOWEDBY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT, LIVER & KIDNEY DAMAGE, ADVERSE CNS EFTS INCLUDING HDCH, CONVULSIONS, & PO SS DEATH. MAY CAUSE VISUAL IMPAIRMENT &POSS PERM BLINDNESS, & EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.00% Upper Limits:31.00% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CONTRS CAN BUILD-UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERS PROT EQUIP AS INDICATED. SCOOP UP W/NON-SPARKING TOOL, THEN PLACE INTO SUITABLE CONTR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE SOURCES OF IGNIT. ABSORB SPILL USING ABSORB,NON-COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS RETAIN PROD RESIDUE (LIQUID, &/OR VAPOR), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM IN COMPATIBLE SUBSTANCES. FLAMMABLES-AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ: MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASH POINT. MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSI UM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 MMHG Vapor Density:1.1 Spec Gravity:0.791 Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: WASTE NUMBER U154 (IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MANNITOL, M1120, M1128, MA165, MA170; CODE M3410 Preparer's Name:E. BRULL CAGE:63415 CAGE:63415 CAGE:TO829 ============= Composition/Information on Ingredients ============= Ingred Name:MANNITOL. (C6H1406) CAS:69-65-8 RTECS #:OP2060000 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL TOXICITY (LD50): 13500 MG/KG (RAT). Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SLIGHTLY DANGEROUS TO DANGEROUS IN CASE OF INGESTION. VERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE OF SKIN OR EYE CONTACT (IRRITANT), AND INHALATION. CHRONIC: THERE IS NO KNOWN EFFECT FROM CHRON IC EXPOSURE TO THIS PRODUCT. CARCINOGENIC EFFECTS, MUTAGENIC EFFECTS AND TERATOGENIC EFFECTS: NOT AVAILABLE. TOXICITY OF PRODUCT TO REPRODUCTIVE SYSTEM: NOT AVAILABLE. Medical Cond Aggravated by Exposure:REPEATED OR PROLONGED EXPOSURE IS NOT KNOWN TO AGGRAVATE MEDICAL CONDITION. ======================= First Aid Measures ======================= First Aid:EYE CONT: IMMED FLUSH EYES W/RUNNING WATER FOR AT LEAST 15 MINS, KEEPING EYELIDS OPEN. COLD WATER MAY BE USED. SKIN CONT: IF CHEM GOT ONTO CLOTHED PORTION OF BODY, REMOVE CONTAM CLTHG AS QUICKLY AS PO SS, PROT YOUR OWN HANDS & BODY. PLACE VICTIM UNDER DELUGE SHOWER. IF CHEM TOUCHES EXPOS SKIN, THOROUGHLY WASH CONTAM SKIN W/RUNNING WATER & NON-ABRASIVE SOAP. BE PARTICULARLY CAREFUL TO CLEAN FOLDS, C REVICES, CREASES, & GROIN. COLD WATER MAY BE USED. COVER IRRIT SKIN W/EMOLIENT. IF IRRIT PERSISTS, SEEK MED ATTN. WASH CONTM CLTHG BEFORE REUSING. SERIOUS SKIN CONT: NO ADDNL INFO. INHAL: ALLOW VICTI M TO REST IN WELL VENT (OTHER INFO). ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE. Autoignition Temp:=460.C, 860.F Lower Limits:NOT AVAILABL Upper Limits:NOT AVAILABL Extinguishing Media:SMALL FIRE: USE DRY CHEMICALS, CO2, WATER SPRAY, OR FOAM. LARGE FIRE: USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER JET. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . PRODUCTS OF COMBUSTION: CARBON OXIDES (CO, CO2). FLAMMABILITY OF THE PRODUCT: COMBUSTIBLE. Unusual Fire/Explosion Hazard:NO SPECIFIC INFORMATION IS AVAILABLE IN DATABASE REGARDING FLAMMABILITY OR RISKS OF EXPLOSION OF PRODUCT IN PRESENCE OF VARIOUS MATERIALS. RISKS OF EXPLOSION OF PRODUCT IN PRESENCE OF MECHANICAL IMPAC T OR STATIC DISCHARGE: NOT AVAILABLE. SPECIAL REMARKS ON FIRE & EXPLOSION HAZARDS: NO ADDITIONAL REMARKS. ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL: USE APPROP TOOLS TO PUT SPILLED SOLID IN A CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY SPREADING WATER ON CONTAM SURFACE & DISPOSE OF ACCORD TO LOCAL & REGIONAL AUTHORITY REQ. LRG SPILL:DATABASE CONTAINS NO ADDNL INFO IN CASE OF A SPILL &/OR LEAK OF PROD. USE A SHOVEL TO PUT MATL IN CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY SPREADING WATER ON CONTAM SURF & ALLOW (WASTE DISP). ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & SOURCES OF IGNITION. DO NOT BREATH DUST. KEEP CONTAINER DRY, IN COOL PLACE, TIGHTLY CLOSED. GROUND ALL EQUIPMENT CONTAINING MATERIAL. KEEP IN A COOL, WELL-VENTILATED PLACE. COMB UST MATERIALS SHOULD BE STORED AWAY FROM EXTREME HEAT & AWAY FROM STRONG OXIDIZING AGENTS. Other Precautions:EMPTY CONTAINERS POSE A FIRE RISK. EVAPORATE RESIDE UNDER A FUME HOOD. GROUND ALL EQUIPMENT CONTAINING MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN . Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOS LIMITS. (SUPP SFTY & HLTH). FACESHIELD . Other Protective Equipment:EYEWASH & DELUGE SHOWER METING ANSI DESIGN CRITERIA . LAB COAT. Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health VENTILATION: IF USER OPERATIONS GENERATE DUST, FUME OR MIST, USE VENTILATION TO KEEP EXPOS TO AIRBORNE CONTAMS BELOW EXPOS LIMIT. EXPOSURE LIMITS: NOT AVAILABLE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES. Melt/Freeze Pt:=166.C, 330.8F Vapor Pres:NOT AVAILABLE. Vapor Density:NOT AVAIL. Spec Gravity:1.52 (WATER=1). pH:NOT AVAILABLE. Solubility in Water:SOLUBLE IN COLD WATER. Appearance and Odor:SOLID. COLOR, ODOR, TASTE, CRITICAL TEMPERATURE, VOLATILITY: NOT AVAILABLE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO SPECIFIC INFORMATION IS AVAILABLE IN DATABASE REGARDING REACTIVITY OF MATERIAL IN PRESENCE OF VARIOUS OTHER MATERIALS. SPECIAL REMARKS ON REACTIVITY: NO ADDITIONAL REMARK. Stability Condition to Avoid:INSTABILITY TEMPERATURE: NOT AVAIL. CONDITIONS OF INSTABILITY: NO ADDITIONAL REMARK. CORROSIVITY: NON-CORROSIVE IN PRESENCE OF GLASS. SPECIAL REMARKS CORROSIVITY: NO ADDTL REMARK. =================== Toxicological Information=================== Toxicological Information:TOXICITY TO ANIMALS: ACUTE ORAL TOXICITY (LD50): 13500 MG/KG (RAT). SPECIAL REMARKS ON TOXICITY TO ANIMALS, CHRONIC EFFECTS ON HUMANS, AND OTHER TOXIC EFFECTS ON HUMANS: NO ADDITIONAL REMARKS. TOXIC OLOGICAL DATA ON INGREDIENTS: NOT APPLICABLE. TOXICITY OF THE PRODUCT TO THE REPRODUCTIVE SYSTEM: NOT AVAILABLE.CARCINOGENIC EFFECTS: NOT AVAILABLE. MUTAGENIC EFFECTS: NOT AVAILABLE. TERATOGENIC EFF ECTS: NOT AVAILABLE. PHYSICAL/CHEMICAL: ODOR THRESHOLD, WATER/OIL DIST. COEFF., IONICITY: NOT AVAILABLE. DISPERSION PROPERTIES: SEE SOLUBILITY IN WATER. ===================== Ecological Information ===================== Ecological:ECOTOXICITY, BOD5 AND COD: NOT AVAILABLE. PRODUCTS OF BIODEGRADATION: CARBON OXIDES (CO, CO2). TOXICITY OF PRODUCTS OF BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE MORE TOXIC. SPECIAL REMARKS ON PR ODUCTS OF BIODEGRADATION: NO ADDITIONAL REMARK. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/APPLICABLE FEDERA, STATE AND LOCAL REGULATIONS . RECYCLE TO PROCESS, IF POSS. CONSULT LOCAL OR REGIONAL AUTH. SPILL/RELEASE: TO EVACUATE THRU SANITARY SYSTEM. SUGGESTED PROT CLOTHES MAY NOT BE SUFFICIEN T. CONSULT A SPECIALIST BEFORE HANDLING PRODUCT. =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: NOT A DOT CONTROLLED MATERIAL (UNITED STATES). IDENTIFICATION: NOT APPLICABLE (PIN AND PG). SPECIAL PROVISIONS FOR TRANSPORT: NOT APPLICABLE. D.O.T. ===================== Regulatory Information ===================== Federal Regulatory Information:THE FOLLOWING PRODUCT IS LISTED ON TSCA: MANNITOL. OTHER REGULATIONS: OUR DATABASE CONTAINS NO SPECIAL CONSIDERATIONS ON THE PRODUCT. OTHER CLASSIFICATION: NOT CONTROLLED UNDER WHMIS (CANADA). NOT CO NTROLLED UNDER DSCL (EUROPE). State Regulatory Information:CALIFORNIA PROPOSITION 65 WARNINGS: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER. CHEMICAL INGREDIENT REQUIRING THIS WARNING: NONE. WARNING: THIS PRODUCT CON TAINS A CHEMICAL KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CHEMICAL REQUIRING THIS WARNING: NONE. OTHER SPECIAL CONSIDERATIONS: NO ADDITIONAL REMARK. REFERENCES: NOT AVAILABLE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SAVIN TONER PAK-BLACK, PART NO:4120-36 Preparer's Name:KRISTINA SAGE CAGE:54762 CAGE:54762 CAGE:29382 CAGE:4M009 CAGE:0NU41 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED HEAVY NAPHTHA CAS:64742-48-9 Fraction by Wt: 89% Other REC Limits:NONE RECOMMENDED Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:ACRYLIC POLYMER CAS:25608-63-7 Fraction by Wt: 3% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYETHYLENE (WAX) CAS:9002-88-4 RTECS #:TQ3325000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50: >5000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OF HIGH CONCENTRATIONS (>1000 PPM) MAY CAUSE RESPIRATORY IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION. CONTACT MAY CAUSE SKIN AND EYE IRRITATION. CHRONIC: HEALTH STUDIES HAVE SHO WN THAT MANY PETROLEUM PRODUCTS POSE POTENTIAL HUMAN HEALTH RISKS WHICH VARY FROM PERSON TO PERSON. Explanation of Carcinogenicity:CARBON BLACK IS LISTED BY IARC AS UNCLASSIFIABLE AS TO CARCINOGNEICITY. Effects of Overexposure:INHALATION: COUGHING, WHEEZING, SHORTNESS OF BREATH, HEADACHE, NAUSEA. EYES: REDNESS, BLURRED VISION, TEARING. SKIN: REDNESS, RASH, ITCHING. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSC ITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: RINSE MOUTH & DRINK LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION IF SYMPTOMS DEVELOP. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:106F,41C Lower Limits:0.7 Upper Limits:6.5 Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE CONFINED OR ENCLOSED AREAS. KEEP PRODUCT OUT OF SEWERS AND WATERWAYS. CONTAIN SPILL. ABSORB WITH INERT MATERIAL AND PLACE IN A CONTAINER FOR LATER DISPOSAL . Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM STRONG OXIDIZING AGENTS AND SOURCES OF IGNITION. KEEP CONTAINERS CLOSED WHEN MATERIAL IS NOT IN USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. EMPTY CONTAINERS MAY CONTAIN RESIDUE AND CAN BE DANGEROUS IF WELDED, CUT, DRILLED OR OTHERWISE HEATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health USED WITH SAVIN COPIER MODELS: 7450, 7350, 7300, AND 7230. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:322F,161C Vapor Pres:<10 MM HG Vapor Density:>5 (AIR=1) Spec Gravity:0.78 (WATER=1) Evaporation Rate & Reference:0.3 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK LIQUID, FAINT PETROLEUM HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:AVOID CONTACT WITH STRONG OXIDIZING AGENTS. AVOID SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:50649 DE-VO-KO WONDER-SPEED,HIGH HIDE BASE CAGE:EO559 CAGE:EO559 CAGE:6R552 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM SILICATE ANHYDROUS *93-1* CAS:22708-90-3 Fraction by Wt: 1-10% ACGIH TLV:30 MPPCF Ingred Name:ALUMINUM SILICATE *93-1* CAS:1335-30-4 Fraction by Wt: <5% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:WEIGHT PER GALLON IN POUNDS:10.64-11.22 RTECS #:9999999WG Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 45-55% Ingred Name:POLYVINYL ACETATE ACRYLIC RESIN Fraction by Wt: 10-15% Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 5-20% OSHA PEL:15 MG/CUM (DUST) ACGIH TLV:10 MG/CUM (DUST) Ingred Name:CLAY (KAOLIN) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:DIATOMACEOUS EARTH, FLUX-CALCINED, NATURAL, SILICA*93-1* CAS:68855-54-9 Fraction by Wt: <5% OSHA PEL:1.7 MPPCF ACGIH TLV:0.80 MG/CUM Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: <5% Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AMMONIUM HYDROXIDE, AQUA AMMONIA CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <5% Other REC Limits:25 PPM OSHA PEL:35 MG/CUM ACGIH TLV:25 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT IRRITATION, HEADACHE & DIZZINESS. SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:INHALATION: DUST DISEASE OF THE LUNGS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: REMOVE W/SOAP & WATER. INGESTION: DRINK 1 TO 2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. TREAT SYMPTOMATICALLY . OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED CLASS B EXTINGUISHER Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:WATER SHOULD BE USED TO COOL CLOSED CONTAINERS & PREVENT PRESSURE BUILD-UP, AUTOIGNITION, OR EXPLOSION WHEN EXPOSED TO FIRE OR EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:WASH W/WATER. CONTAIN SPILLED MATERIAL & REMOVE W/INERT ABSORBENT. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 110F & KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE. DON'T REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR OR OPEN AREAS W/UNRESTRICTED VENTILATION & DURING SANDING OR GRINDING OPERATIONS, USE NIOSH/MSHA APPROVED MECHANICAL FILTER RESPIRATOR. RESTRICTED VENTILATION AREAS, WEAR NIOSH/MSHA APPROVED C HEMICAL/MECHANICAL FILTERS. SEE SUPP. Ventilation:GENERAL DILUTION OR LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP AIR CONTAMINANT CONCENTRATION BELOW APPLICABLE TLV LIMITS Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM. Supplemental Safety and Health RESPIRATORY PROTECTION (CONT'D): CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR SUPPLY RESPIRATORS OR HOODS. USE NIOSH/MSHA APPROVED RESPIRATORS WHEN FLAME CUTTING, WELDING, BRAZING & SANDING MATERIAL CO ATED W/PRODUCT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212-387F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:68-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN, & OXIDES OF METALS IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INTERTUF EPOXY XD BASE CAGE:50411 CAGE:50411 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC PETROLEUM DISTILLATES). VP:3.0 @ 20C CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 10% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE). VP:2.14 @ 20C CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 6% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.1 @ 20C CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHOSPHORIC ACID, ZINC SALT (2:3); (ZINC PHOSPHATE) CAS:7779-90-0 RTECS #:TD0590000 Fraction by Wt: 7% OSHA PEL:10 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 2% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:OTHER PREC:BRAZE/WELD WITHOUT NIOSH APPRVD MECH FILTER RESP/APPROP & ADEQ VENT. ALL ELEC EQUIP & INSTALLATIONS (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:SHOULD BE MADE & GROUNDED I/A/W NATIONAL ELEC CODE. WORKMEN ARE REQD TO USE ONLY NON-FERROUS TOOLS & WEAR (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:NON-SPARKING SHOES IN AREAS WHERE EXPLO HAZ EXIST. IF WORKMEN ARE EXPOS TO SPRAY APPLIC/ABRASIVE BLAST (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CLEANING, ENGINEERING & ADMINISTRATIVE CONTROLS MUST BE USED TO MAINTAIN EXPOS LEVEL BELOW OSHA REQD (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:LEVEL/USE NIOSH APPRVD MECH FILTER RESP/PROT. THIS PROD CONTAINS CRYSTALLINE SILICA WHICH CAN CAUSE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:ADVERSE HLTH EFTS WHEN RESPIRED. REC USE OF PROD IS NOT EXPECTED TO CREATE SUCH EXPOSURE RISK. SANDING (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:OF DRIED COATING IS NOT REC. IF SANDING OF DRIED COATING IS PERFORMED, ENGINEERING & ADMINISTRATIVE (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:CONTROLS MUST BE USED TO MAINTAIN EXPOSURE LEVEL BELOW APPLIC PEL, OR APPROP NIOSH APPRVD RESP MUST USED (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:FOR PROTECTION. RTECS #:9999999ZZ Ingred Name:RESP PROT:PARTICULATES, GAS & VAPOR. IN CONFINED AREAS, USE NIOSH APPRVD AIR-LINE RESPIRATORS AND HOOD. RTECS #:9999999ZZ Ingred Name:VENT:AND LOWER EXPLO LEVEL (LEL) BELOW STATED LIMIT & TO REMOVE DECOMP PRODS DURING WELDING & FLAME CUTTING OF (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:SURFACES COATED WITH THIS PRODUCT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT/ACUTE NERV SYS CAUSING HDCH, DIZZ/NAUS. EYE & SKIN:PRIMARY IRRIT. INHAL OF SOLV VAP MAY CAUSE NOSE & THROAT IRRIT & DIZZ , NAUS, HDCH & SLEEPINESS. DIRECT EYE /SKIN CON T MAY CAUSE MOD TO SEV IRRIT & SKIN SENSIT. SOLV CAN BE ABSORBED INTO BODY THROUGH SKIN. OVEREXP OR (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, (SUPDAT) Effects of Overexposure:HLTH HAZ:INTENTIONAL INHAL OF VAP MAY CAUSE HEART ABNORM. PRLNGD/RPTD OVEREXP MAY CAUSE ANEMIA, PERM BRAIN & NERV SYS DMG, LIVER, KIDNEY & EYE DMG. Medical Cond Aggravated by Exposure:CRYSTALLINE SILICA MAY AGGRAVATE EXISTING RESPIRATORY CONDITIONS. SMOKING AGGRAVATES THE EFFECTS OF OVEREXPOSURE. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE FROM EXPOSURE. KEEP WARM & QUIET. NOTIFY PHYS. EYES:FLUSH IMMEDIATELY W/LG AMTS OF WATER FOR @ LST 15 MINUTES. TAKE TO PHYSICIAN FOR MEDICAL TREATMENT.SKIN:WASH AFFECTED AREAS W/LG AMTS OF WATER. REMOVE CONTAMINATED CLOTHING. ===================== Fire Fighting Measures ===================== Flash Point:102F,39C Lower Limits:0.7-1.0% Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, SPKS, ELEC EQUIP, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. IN ABSENCE OF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, & ELECTRICAL, STATIC/FRICTION SPARKS). AVOID BRTHG VAPORS, WEAR APPRVD (NIOSH) RESP, & VENTILATE AREA. REMOVE W/INERT ABSORB SUCH AS SAND, KITTY L ITTER, ETC, AND USE NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SECURE CLOSURES & KEEP CNTNRS UPRIGHT TO PVNT LEAKAGE. STORE LG QTYS ONLY IN BUILDING DESIGNED TO COMPLY W/OSHA 1910.106. DO NOT STORE >120F. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT GET IN EYES/ON SKIN. AVOID BRTHG VAPS/SPRAY MIST. DO NOT STORE/USE NEAR HEAT, SPKS/OPEN FLAME. CNTNRS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQ IN EXCESS O F FEW INCHES. DO NOT FLAME CUT, (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR/OPEN AREAS W/UNRESTRICTED VENT, USE NIOSH APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLIC. IN RESTRICTED VENT AREAS, USE NIOSH APPRVD MECH FILTERRESPS DESIGNED TO REMOVE (ING 15) Ventilation:PROVIDE GEN DILUTION/LOC EXHAUST VENT IN VOL & PATTERN TO KEEP THRESHOLD LIM VALUES (TLV) BELOW STATED OSHA LIMS(ING 16) Other Protective Equipment:AS NEEDED-USE BODY PROT, SUCH AS RUBBER APRON, ETC. ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:BEFORE SMOKING/EATING, WASH HANDS THOROUGHLY. Supplemental Safety and Health EXPLO HAZ:ELECTRICITY, WATER SPRAY (FOG NOZZLE IS PREFERRED) MAY BE USED TO COOL CONTAINERS. AVOID EXPOSURE TO DECOMPOSITION. REFER TO D.O.T. P 5800.3 (1984 EMERERGENCY RESPONSE BOOK, GUIDBOOK FOR HAZ MATLS' INCIDENT" GUIDE NO. 26, ID NO. 1263). EXPLAN OF CARCIN:1994:ANTICIPATED TO BE CARCINOGEN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>210F,>99C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.51 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:MAY PRDCE HAZ FUMES WHEN HEATED TO DECOMP AS IN WELDING. FUMES MAY PRDCE CARBON DIOXIDE & CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A SAFE MANNER IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS THAT APPLY TO INCINERATION OR SECURE LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MARKING CHALK-RED CAGE:0NML2 CAGE:0NML2 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL; (SILICON DIOXIDE (AMORPHOUS)) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: <1% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 10-20% OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBER/CC, A1 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <2% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:CARBONIC ACID, CALCIUM SALT; (CALCIUM CARBONATE) CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: >50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IRON (III) OXIDE; (PIGMENT RED 101) (IRON OXIDE RED) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <20% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG(FE)/M3 FUME, B2 Ingred Name:ARSENIC (SARA 313) (CERCLA) (<100 PPM) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CADMIUM (SARA 313) (CERCLA) (<5 PPM) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: <0.1% OSHA PEL:0.2 MG/M3 DUST; Z-2 ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:MERCURY (SARA 313) (CERCLA) (<1 PPM) CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: <0.1% OSHA PEL:C, 0.1 MG/M3; Z-2 ACGIH TLV:S, 0.025 MG/M3; A4 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SARA 313) (CERCLA)(<400 PPM) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <0.1% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:LEAD (SARA 313) (CERCLA) (<100 PPM) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3 DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SUPDAT: MONO ON EVAL OF CARCIN RISK OF CHEM TO MAN, VOL 49, PG 257, 1990:GROUP 2B. NTP 7TH ANNUAL RPT ON (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: CARCINS, 1994:ANTIC TO BE CARCIN. HUMAN:LUNGS, NASAL CAVITIES. SILICA, CRYSTALLINE-QUARTZ:IARC MONO, (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL PRT ON CARCINS, 1994:ANTIC TO BE CARCINOGEN. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:LEAD APPEARS ON NAVY LIST OF OCCUP CHEM REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ACUTE:IRRIT MAY RSLT FROM PRL NGD/RPTD EXPOS BY INHAL/BY EYE CONT. PRLNGD INHAL OF IRON OXIDE DUST MAY RSLT IN CNDTN OF LUNG KNOWN (EFTS OF OVEREXP) Explanation of Carcinogenicity:ARSENIC:IARC MONO, SUPP. VOL 7, PG 100, 1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE CARCIN. (SUPDAT) Effects of Overexposure:HLTH HAZ:AS SIDEROSIS. PRLNGD INHAL OF SILICON DIOXIDE MAY RSLT IN SILICOSIS. THERE IS SOME EVID THAT THIS MATL MAY BE CARCINOGENIC. CALCIUM CARBONATE CONTAINS CRYSTALLINE SILICA AT LEVELS BETWEEN 0.0 1%-2%. THERE IS SOME EVIDENCE THAT THISMATERIAL MAY BE CARCINOGENIC. LIMIT EXPOSURE TO THE LOWEST LIMIT POSSIBLE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER FOR @ LEAST 15 MINS. CALL PHYS IF IRRIT CONTINUES. SKIN:WASH IMMED W/SOAP & PLENTY OF WATER. INHAL:REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BRTHG. CALL PHYS. INGEST:CALL PHYS IMME D. ===================== Fire Fighting Measures ===================== Flash Point:NONE-FLAMMABLE Extinguishing Media:NONE. USE WATER TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE USED TO WASH SPILLS AWAY FROM EXPOSURES. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID BREATHING VAPORS OR DUST. Unusual Fire/Explosion Hazard:CALCIUM OXIDE, CARBON DIOXIDE, TOXIC OXIDES OF CARBON. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SCOOP MATERIAL INTO APPROP CNTNR FOR RECLAMATION/DISP. IF EXCESSIVE DUST IS GENERATED, USE APPROP NIOSH/MSHA APPRVD RESPIRATORY EQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND EYES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL VENT TO KEEP DUST LEVS BELOW REC EXPOS LIM. IF EXPOS LIM ARE EXCEEDED, NIOSH/MSHA APPRVD DUST RESP SHOULD BE WORN. Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH THORO AFTER HNDLG, WASH CONTAMD CLTHG BEFORE REUSE. FOLLOW GOOD HOUSEKEEPING PROCEDURES. Supplemental Safety and Health PH:8.6-8.8 (SATURATED SOLUTION). EXPLAN OF CARCIN:CODE OF FED REGS, VOL 29, PG 1910.1018, 1987:OSHA CANCER HAZ. ANIMAL:LUNG & LYMPHATIC CANCER. CADMIUM:IARC MONO, SUPP, VOL 7, PG 139, 1987:GROUP 2A. N TP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN. HUMAN:LUNG, PROSTATE, RENAL SYS EFTS. NICKEL CMDPS:IARC (ING 11) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:>1500F,>816 Spec Gravity:3.2 (H*2O=1) pH:SUPDAT Solubility in Water:NEGLIGIBLE Appearance and Odor:RED POWDER, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES (W/CALCIUM CARBONATE):ACIDS, ALUMINUM, FLUORINE, MAGNESIUM, ALUM OR AMMONIUM SALTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC OXIDES OF CARBON AND CALCIUM OXIDE UPON THERMAL DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLACK DEVELOPER FOR DC-1605, 1656, 1685, 1855, 2155 CAGE:65678 CAGE:65678 ============= Composition/Information on Ingredients ============= Ingred Name:IRON (III) OXIDE; (IRON OXIDE) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 67% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3 FUME (FE) Ingred Name:ZINC OXIDE (SARA 313) (CERCLA) CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 18% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:COPPER OXIDE CAS:1317-38-0 RTECS #:GL7900000 Fraction by Wt: 10% OSHA PEL:1 MG CU/M3 ACGIH TLV:1 MG CU/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE IN NORMAL HANDLING AND USE. MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL TR EATMENT. INGEST: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER AND SEEK MEDICAL TREATMENT. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF PRODUCT BECOMES INVOLVED IN A FIRE, USE CARBON DIOXIDE EXTINGUISHER. WATER, FOAM OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE UNDER NORMAL STORAGE AND USE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP WITH A VACUUM CLEANER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CLOSE CAP TIGHTLY AND STORE IN A COOL, DRY AND DARK PLACE. Other Precautions:AVOID COMBUSTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED UNDER NORMAL USE. Other Protective Equipment:NONE REQUIRED UNDER NORMAL USE. Work Hygienic Practices:AVOID INHALATION, INGESTION, SKIN OR EYE CONTACT. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:1.91 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:FINE BLACK POWDER; PRACTICALLY ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE IN NORMAL HANDLING AND USE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEVRAN, DV229C BASE Kit Part:Y Preparer's Name:H KLINE CAGE:0Y2E4 CAGE:55849 CAGE:0Y2E4 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE). LD50 (ORAL, RAT): 10 G/KG CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <30% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:IRON OXIDE; (IRON OXIDE (RED)) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <10% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5MG(FE)/M3FUME,B2;95 Ingred Name:ALUMINO-SILICATE CAS:37244-96-5 Fraction by Wt: <15% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 6.6 @ 68F. LD50 (ORAL, RAT): 3.9 G/KG CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1.03% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ALCOHOL; (BUTYL ALCOHOL) (SARA 313) (CERCLA). VP: 4.3 @ 68F. LD50 (ORAL, RAT): 4.2 G/KG CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 2.83% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY 2-PROPANOL ACETATE). VP: 2.1 @ 68F. LD50 (ORAL, RAT): 12 G/KG CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 12.77% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METHYL N-AMYL KETONE. VP: 2.1 @ 68F. LD50 (ORAL, RAT): 12 G/KG CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 4.43% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9495 Ingred Name:P-CHLOROBENZOTRIFLUORIDE. VP: 5.3 @ 68F. LD50 (ORAL, RAT): 2.7 G/KG CAS:98-56-6 RTECS #:XS9145000 Fraction by Wt: 20.97% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACRYLIC RESIN. VP: 3.38 @ 68F CAS:29354-73-2 Fraction by Wt: <10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACRYLIC RESIN. VP: 3.7 @ 68F CAS:29354-73-2 Fraction by Wt: <20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BISPHENOL A EPOXY RESIN; (EPOXY RESIN (SARA)). LD50 (ORAL, RAT): 20 G/KG CAS:25036-25-3 Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC CONTENT MIXED: 384 G/L. MIXED THINNED: 420 G/L RTECS #:9999999VO Ingred Name:SUPDAT: CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: OCCURS, NOTIFY LOCAL AUTHORITIES. RTECS #:9999999ZZ Ingred Name:RESP PROT: TO CHEM HAZ. "IN CONFINED/RESTRICTED VENT AREAS USE AIR-LINE RESP/HOODS. REFER TO 29 CFR, OSHA PARTS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: 1910.134 & 1915 FOR COATING OPERATIONS; PART 1910.146 CONFINED SPACES; ANSI Z68.2, PRACTICES FOR RESP PROT. RTECS #:9999999ZZ Ingred Name:VENT: TO KEEP AIR CONTAMINANT CONC BELOW TLV LIMS. REMOVE WELDING/FLAME CUTTING DECOMP PRODS; FOLLOW CURRENT (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: ANSI 249.1 "SAFETY IN WELDING & CUTTING. "REFER TO 29 CFR PARTS 1910 & 1915, FOR COATING OPERATIONS: (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: PART 1910.146, CONFINED SPACES. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: SHOE COVERINGS TO PREVENT SKIN CONTACT. USE EXPLOSION AND SPARK-PROOF EQUIPMENT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAP/SPRAY MIST/SPATTERED MATL CAN BE HARMFUL. IRRIT TO EYES, SKIN, & IF INHALED, TO NOSE & THROAT. EXCESSIVE/PRLNG INHAL CAN CAUSE HDCH, NAUS/DIZZ. RPTD & PRLNG OCCUP OVEREXP TO SOLV IS ASSOCD W/PERM BRAIN & NERVOUS SYS DMG &/DEATH. OVER-EXP (PRLNG/RPTD USE) CAN AGGRAVATE/ACCENTUATE ANY OF THESE EFTS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: SKIN: IRRIT. SENSIT/ALLERGIC RXN, SUCH AS RASH/HIVES. CAN BE ABSORBED THRU SKIN. CAN CAUSE DEFAT & DRYING OF SKIN. INHAL: IRRIT. LUNG INJURY. CNS DMG. CHEM PNEUMONIA. XYLENE/TOLUENE MAY CAUS E IRREGULAR HEART BEAT. HIGH VAP CONCS MAY CAUSE KIDNEY &/LIVER DMG. EYES: SEV IRRIT. INGEST: HARMFUL IF (SUPDAT) Medical Cond Aggravated by Exposure:KIDNEYS, LIVER, SKIN, EYES, RESPIRATORY, ALLERGIES, LUNGS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE NORM BRTHG. TREAT SYMPTOMATICALLY, SEE MD. SKIN: WASH THOROUGHLY W/SOAP & H*2O. REMOVE CONTAMD CLTHG. CONSULT MD IF IRRIT PERSISTS. EYES: FLUSH IMMED W/PLENTLY OF H *2O FOR AT LEAST 15 MIN & GET MED ATTN.INGEST: DRINK 1 OR 2 GLASSES OF H*2O TO DILUTE. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. DO NOT INDUCE VOMIT (UNLESS METHANOL LISTED IN SECTION (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:103F,39C Lower Limits:0.90% Upper Limits:13.10% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CNTNRS TO PVNT PRESS BUILD-UP/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT AND PRESSURE BUILDUP. MAY PRODUCE A FLOATING FIRE HAZARD. KEEP AWAY FROM HEAT AND OPEN FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. AVOID BRTHG VAP. VENT AREA. USE ABSORB, INERT, CLEANUP MATLS. (DO NOT USE SAWDUST.) REMOVE ABSORB MATL W/NON-SPARKING TOOLS. PLACE IN SEPARATE CNTNRS. KEEP OUT OF SEWERS & WATERWAYS. IF ENTRY IS THREATENED/ (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID PROLONGED STORAGE TEMPERATURES ABOVE 100F. Other Precautions:USE CAUTION WHEN POURING. AVOID BREATHING SANDING DUST. DO NOT WELD OR FLAME CUT ON EMPTY CONTAINER. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES WHICH CANNOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH CERTIFIED RESP DESIGNED TO REMOVE A COMBINATION OF PARTICULATES (DUST/SPRAY MIST) & VAP. WHEN BRUSHING, ROLLING/SPREADING SELECT APPROP RESP PROT FOR CNDTNS. FOR SPECIFIC CNDTNS, REFER TO C URRENT "NIOSH POCKET GUIDE (ING 15) Ventilation:IMPLEMENT ADMINISTRATIVE & ENGINEERING CONTROLS TO REDUCE EXPOS. PROVIDE SUFFICIENT VENT IN VOL & PATTERN (ING 17) Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . DEPENDENT UPON APPLICATN METH WEAR RESISTANT COVERALLS, & (ING 20) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE USE. Supplemental Safety and Health EVAP RATE: LOW: 0.34 HIGH: 0.90 (BU AC =1). EFTS OF OVEREXP: SWALLOWED. ASPIRATION INTO LUNGS CAN DMG LUNGS & CAUSE CHEM PNEUMONIA. LIVER DMG. TARGET ORGANS: KIDNEY, LIVER, BLOOD, LUNGS, HEART, SKIN, EYES, STOMACH, INTESTINES, SPLEEN, CNS,FETAL DEFECTS. FIRST AID PROC: 2). CONTACT PHYSICIAN OR POISON CONTROL (ING 13) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>244F,>118C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:1.28-1.40 Evaporation Rate & Reference:SUPDAT Appearance and Odor:LIQUID; SOLVENT ODOR. Percent Volatiles by Volume:51.3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. Stability Condition to Avoid:HEAT, OPEN FLAMES, ARC OR SPARKS. AMINES UNDER UNCONTROLLED CONDITIONS. Hazardous Decomposition Products:BY FIRE, BURNING OR WELDING: CO, CO*2, IRON OXIDE FUMES, CHLORINE, ALDEHYDES, FLUOROCARBON GASES. TOXIC GASES OF FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN SEPARATE, APPROPRIATE, CLOSED CONTAINER IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN TESTED BY TOXICITY CHARACTERISTIC LEACHING PROCEDUR E (TCLP). EPA WASTE NO: D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:W12,W13 "RADIUS INDICATOR FLUID" CAGE:HO257 CAGE:38589 CAGE:HO257 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: >95% OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:EYES: POSS IRRIT. SKIN:POSS SLIGHT IRRIT. INHAL: POSS NASAL, RESPIRATORY IRRIT FROM (SEE OTHR PRECAU ======================= First Aid Measures ======================= First Aid:SKIN: WASH EXPOS AREA W/SOAP & H*20. REMOVE CONTAM CLOTHES & CLEAN BEFORE RE-USE. EYES: FLUSH W/LRG AMTS H*20 AT LEAST 15 MIN,LIFTING LIDS.GET MED ATTN. INGEST:GIVE 2 GLASSES H*20,INDUCE VOMIT IMMED B Y STICKING FINGER DOWN THROAT. (SEE OTHR PRECAU) ===================== Fire Fighting Measures ===================== Flash Point:241F,116C (CC) Lower Limits:3.2 Extinguishing Media:WATER FOG,CO*2,OR DRY CHEMICAL Fire Fighting Procedures:H*20/FOAM MAY CAUSE FROTHING WHICH CAN BE (SEE SUPP DATA) Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY),PROD (EVEN RESIDUE) CAN IGNITE EXPLOSIVELY ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL: ABSORB LIQ ON ABSORMENT MATL,TRANSFER TO HOOD. LRG SPILL: ELIM ALL IGNIT SOURCES. STOP SPILL AT SOURCE,DIKE AREA OF SPILL TO PREVENT SPREAD,PUMP LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE TAK EN UP ON ABSORBENT MATL & SHOVELLED INTO CONTAINER ======================Handling and Storage ====================== Handling and Storage Precautions:CNTNRS OF MATL POSS HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES,ALL HAZARD PRECAUTNS GIVEN FOR THIS PROD MUST BE OBSERVED. Other Precautions:EFFECTS OF OVEREXP: EXCESSIVE INHAL OF VAPS. INGEST: POSS GI IRRIT,NAUSEA,VOMITING,DIARRHA. EMER FIRST AID PROC: CALL A PHYS. INHAL: REMOVE TO FRESH AIR. KEEP PERSON WARM,QUIET,GET MED ATTN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD AIR SUPPLIED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:SUFFICIENT MECHANICAL- GENERAL &/OR LOCAL EXHAUST Other Protective Equipment:TO PREVENT RPTD/PRLNG SKIN CONT,WEAR IMPERVIOUS CLOTHES,BOOT Supplemental Safety and Health SPECL FIRE FIGHT PROC: VIOLENT & POSS ENDANGER THE LIFE OF THE FIREFIGHTER,ESPECIALLY IF SPRAY INTO CNTNRS OF HOT,BURNING LIQ. USE SCBA W/FULL FACEPIECE OPERATED IN A POSITIVE PRESSURE MODE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:387F (197C) Vapor Pres:0.1 Vapor Density:2.6 Spec Gravity:1.115 Evaporation Rate & Reference:<1.00 (BU AC) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CO*2 & CO,ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:SM SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW ENOUGH TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT WORK. DISPOSE OF REMAINING MATL. LRG SPILL: DESTROY BY LIQ INC INERATION. WASTE DISPOAL MUST BE IAW FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:O-M-232 METHANOL,METHYL ALCOHOL CAGE:DO973 CAGE:82925 CAGE:DO973 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 99.9% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:WEAKNESS,HEADACHE,NAUSEA,VOMITING,ABDOMINAL PAIN,DIMNESS OF VISION,NARCOSIS,COMA,RESPIRATORY FAILURE ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG DIFF GIVE OXYGEN, EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP & WATER. RTY CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT IS CLEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATT ===================== Fire Fighting Measures ===================== Flash Point:54F,12C OC Lower Limits:6.0 Upper Limits:36.5 Extinguishing Media:DRY CHENICAL,ALCOHOL FOAM,WATER SPRAY INEFFECTIVE Fire Fighting Procedures:USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT BUILDS UP PRESSURE IN CLOSED DRUMS.COOL WITH WATER.AVOID SPARKS.BULK VESSELS GROUND ================== Accidental Release Measures ================== Spill Release Procedures:USE WATER SPRAY TO DISPERSE VAPORS AND TO PROTECT MEN ATTEMPTING TO STOP A LEAK.REMOVE SOURCES OF IGNITION.VENTILATE AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS IN WELL VENTILATED PLACE.LARG VOLUME STORAGE REMOTE FROM INHABITED BUILDINGS OR STRUCTURES. Other Precautions:KEEP AWAY FROM ALL SOURCES OF IGNITION.WEAR CHEMICAL & GET DOC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF CONTAINED BREATHING APPARATUS,OR BUREAU OF MINES CARTRIDGE Ventilation:MECHANICAL AS NEEDED,SPARKPROOF FANS. Other Protective Equipment:FACE SHIELD,CHEMICAL Supplemental Safety and Health THIS COMMODITY IS GRADE "A" IN FEDERAL SPECIFICATION OM 232 ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:147F,64C Vapor Pres:92 Vapor Density:1.1 Spec Gravity:0.8 Evaporation Rate & Reference:2.0,BUTYL ACETATE Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS LIQUID,SLIGHT ALCOHOL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,SOURCES OF IGNITION. Stability Condition to Avoid:KEEP AWAY FROM OPEN FLAME,HEAT & SPARKS.OPEN CONTAINER. Hazardous Decomposition Products:BURNING MAY PRODUCE IRRITATING VAPOR OR CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL MAY BE INCINERATED I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-H-46170B;HYDRAULIC FLUID Preparer's Name:P.A.PARKER CAGE:0DH22 CAGE:0DHB8 CAGE:0DH22 ============= Composition/Information on Ingredients ============= Ingred Name:SYNTHETIC HYDROCARBONS(DIESTER) Ingred Name:OTHER COMPONENTS (TYPE NOT SPECIFIED) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE HEADACHE,DIZZINESS,NAUSEA AND VOMITING.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATITIS POSSIBLE. Explanation of Carcinogenicity:DATA PER MSDS Effects of Overexposure:SEE HEALTH HAZARDS DATA. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:450F,232C Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT BUILDS UP PRESSURE IN CLOSED CONTAINERS.FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;REMOVE ALL IGNITION SOURCES;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NOT REQUIRED;USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS/MIST AS REQUIRED IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>600F,>316C Spec Gravity:<1.0 Evaporation Rate & Reference:<1.0(N-BUTYL ACETATE = 1) Solubility in Water:NEGLIGIBLE Appearance and Odor:RED CLEAR LIQUID;MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER UNIDENTIFIED COMPONENTS (TOXIC IN NATURE.). ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GENETRON (FC)-134A Preparer's Name:MSDS # GTRN-0011 CAGE:0B7T5 CAGE:0B7T5 CAGE:0PK95 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,1,2-TETRAFLUOROETHANE CAS:811-97-2 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 INHAL RAT IS >500,000PPM/4 HRS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE IRRITATION.SKIN:MAY CAUSE IRRITATION.LIQUID CAUSES DEFATTING.INGEST:UNLIKELY ROUTE OF EXPOSURE DUE TO PHYSICAL STATE,HOWEVER TISSUE MAY FREEZING MAY OCCUR.INHAL:THIS ITEM IS A SI MPLE ASPHYXIANT. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:LOSS OF COORDINATION,INCREASED PULSE RATE,DEEPER RESPIRATION.HIGHER LEVELS MAY CAUSE CARDIAC ARRYTHMIAS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.WARM FROSTBITTEN AREA WITH LUKEWARM WATER;CALL PHYSICIAN.EYES:FLUSH FROSTBITTEN AREA WITH LUKEWARM WATER;CALL PHYSICIAN.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.DO NOT GIVE EPINEPHRINE(ADRENALIN).INGEST:DO NOT INDUCE VOMITING UNLESS DIRECTED BY PHYSICIAN.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:>750C Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:THIS MATERIAL MAY BECOME FLAMMABLE WHEN MIXED WITH AIR UNDER HIGH PRESSURE IN THE PRESENCE OF A STRONG IGNITION SOURCE.AVOID REACTIVE METALS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.REMOVE IGNITION SOURCES;SHUT OFF LEAK;PROVIDE VENTILATION.TEST AREA FOR SUFFICIENT OXYGEN BEFORE REENTERING(ESP. LOW-LYING AREAS). Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID SKIN AND EYE CONTACT.AVOID SUNLIGHT.DO NOT STORE IN SUBGROUND LOCATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS,DEPENDING ON THE AIRBORN CONCENTRA TION. Ventilation:USE GENERAL DILUTION VENTILATION FOR STORAGE AREAS;LOCAL VENTILATION FOR FILLING OPERATIONS. Other Protective Equipment:IMPERVIOUS SHOES/CLOTH WHERE LEAKAGE IS PROBABLE & SHOULD BE THERMALLY INSULTAED TO PREVENT FREEZING.NO CONTACT LENSES. Work Hygienic Practices:EYEWASH STATIONS,SAFETY SHOWERS.TEST FOR ADEQUATE OXYGEN BEFORE ENTERING CONFINED SPACES. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-15F,-26C Melt/Freeze Pt:M.P/F.P Text:214F,101C Decomp Temp:Decomp Text:482F,250C Vapor Pres:85.8 Vapor Density:3.5 Spec Gravity:<1.22 Evaporation Rate & Reference:>1 COMPARED TO CCL*4 Solubility in Water:NEGLIGIBLE Appearance and Odor:GAS AT RT.CLEAR COLORLESS LIQUID AND VAPOR,FAINT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO FRESHLY ABRADED AL SURFACES MAY CAUSE STRONG EXOTHERMIC REACTION.AVOID ACTIVE METALS (NA,K,CA,POWDERED AL,MG,ZN). Stability Condition to Avoid:DO NOT MIX WITH OXYGEN OR AIR ABOVE ATMOSPHERIC PRESSURE.AVOID IGNITION SOURCES. Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS, POSSIBLY CARBONYL HALIDES, PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:082391, TRAFFIC SPOTTER CAGE:97257 CAGE:97257 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-;(2-BUTOXYETHANOL); (EGBE); (ETHYLENE GLYCOL MONOBUTYL ETHER) CAS:111-76-2 RTECS #:KJ8575000 OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATE TO SEVERE IRRITATION AND POSSIBLE TISSUE DAMAGE TO EYES DEPENDING ON EXPOSURE. NAUSEA, VOMITING AND DIARRHEA MAY OCCUR UPON INGESTION. PROLONGED SKIN CONTACT MAY CAUSE MODERATE IRRITATION, DE FATTING AND DERMATITIS. OVEREXOPUSRE OF2-BUTOXYETHANOL MAY CAUSE KIDNEY, LIVER & RED BLOOD CELL (EFT OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:INJURY. MAY PENETRATE SKIN. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON THE CNS, THE HEMATOPOIETIC TISSUES, THE BLOOD, THE KIDNEYS & LIVER, ASSOCIATED WITH THE ADMINIS TRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR. CALL MD IF SYMPTOMS PERSIST. INGEST:GIVE LARGE QUANTITIES OF WATER THEN SEVERAL GLASSES OF MILK. INDUCE VOMITING, GET MD IMMEDIATELY. EYE:FLUSH IMMEDIATELY WTIH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES LIFTING EYELIDS OCCASIONALLY. SKIN:REMOVE CONTAMINATED CLOTHING AND WASH WITH PLENTY OF SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:AS REQUIRED BY SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN LARGE SPILLS AND PUMP TO RECOVER, SMALL SPILLS CAN BE MOPPED UP. FLUSH CONTAMINATED AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ONLY WITHOUT ADEQUATE VENTILATION. NIOSH/MSHA APPROVED RESPIRATORS APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:EQUIVALENT TO OUTDOORS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:1.04 Solubility in Water:COMPLETE Appearance and Odor:OPACIFIED YELLOW LIQUID WITH CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZERS. Stability Condition to Avoid:EXTREME TEMPERATURES. Hazardous Decomposition Products:CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WAX, FLOOR, WATER EMULSION Preparer's Name:REGULATORY AFFAIRS DEPT. CAGE:28745 CAGE:28745 ============= Composition/Information on Ingredients ============= Ingred Name:NONHAZARDOUS INGREDIENTS Fraction by Wt: NA Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE KNOWN Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:NA ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP WITH MOP OR WET VAC AND WASH AWAY WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:FREEZING OF PRODUCT MAY RUPTURE CONTAINER AND DAMAGE PRODUCT QUALITY. PRODUCT SHELF LIFE IS BEST RETAINED BY STROEAGE AT 45-100F TEMPERATURES. Other Precautions:NA ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:MECHANICAL VENTILATION IS SUGGESTED. Other Protective Equipment:NA Work Hygienic Practices:DO NOT TAKE INTERNALLY. WASH CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:213F,101C Melt/Freeze Pt:M.P/F.P Text:30.0F,-1.1C Vapor Pres:21.4 MM Vapor Density:0.6 Spec Gravity:1.00 pH:9.0 Evaporation Rate & Reference:<1 (DIETHYL ETHER = 1) Solubility in Water:APPRECIABLE Appearance and Odor:OFF WHITE EMULSION: NON-OBJECTIONABLE ODOR Percent Volatiles by Volume:83.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN TO HILLYARD INDUSTRIES, INC. Hazardous Decomposition Products:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:WASH SMALL QUANTITIES DOWN SEWER W/LARGE AMT OF WATER. KEEP SPILLS/CLEANING RUNOFFS OUT OF MUNICIPAL SEWERS/OPEN BODIES OF WATER. LARGE SPILLS: PICK UP RUNOFFS W/WET VAC/ABSORBENT. LANDFILL/INCINERATE SOLID; LIQ PER LOCAL, STATE, FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM TRIPOLYPHOSPHATE Resp. Party Other MSDS Num.:7758-29-4 CAGE:MO680 CAGE:MO680 Contract Num:SP0450-00-M-D758 CAGE:75656 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM TRIPOLYPHOSPHATE CAS:7758-29-4 RTECS #:YK4570000 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): >2000MG/KG Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS MILDLY IRRITATING TO THE EYES. SKIN IRRITATION FROM CONTINUOUS CONTACT HAS BEEN REPORTED DURING MANUFACTURING WHEN PROTECTIVE MEASURES FOR CONTACT OR PERSONAL HYGIENE PROCEDURES ARE NOT FOL LOWED. HUMAN INDUSTRIAL EXPERIENCE HAS SHOWN NO SIGNIFICANT INHALATION HAZARD OR SKIN IRRITATION WHEN EXPOSURES ARE PROPERLY CONTROLLED. CHRONIC: CHRONIC EXPOSURE TO VERY HIGH LEVELS OF THIS PRODUCT P RODUCES KIDNEY DAMAGE AND IMPAIRED BONE DEVELOPMENT IN LABORATORY ANIMALS. HOWEVER, PRODUCT IS LISTED BY THE UNITED STATES FOOD AND DRUG ADMINISTRATION AS A GENERALLY RECOGNIZED AS SAFE (GRAS) FOOD AD DITIVE. Explanation of Carcinogenicity:ACGIH: NOT LISTED. Effects of Overexposure:PRODUCT IS MILDLY IRRITATING TO THE EYES AND NON-IRRITATING TO THE SKIN. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION OCCURS & PERSISTS, OBTAIN MEDICAL ATTENTION. SKIN: WASH WITH PLENTY OF SOAP & WATER. GET MEDICAL ATTENTION IF IRRITATION OCCURS & PERSISTS . INGESTION: DRINK 1 TO 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON IF DISCOMFORT PERSISTS, OBTAIN MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF BREATHING DIFFIC ULTY OR DISCOMFORT OCCURS & PERSISTS, OBTAIN MEDICAL ATTENTION. NOTES TO MD: THIS PRODUCT CAUSES MILD EYE IRRITATION & IS NON-IRRITATING TO SKIN. TREATMENT IS CONTROLLED REMOVAL OF EXPOSURE WITH SYMPT OMATIC & SUPPORTIVE CARE. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:NON-COMBUSTIBLE. Fire Fighting Procedures:NOT APPLICABLE. Unusual Fire/Explosion Hazard:NONE. SENSITIVITY TO STATIC DISCHARGE: NONE. SENSITIVITY TO IMPACT: NONE. ================== Accidental Release Measures ================== Spill Release Procedures:MATERIAL SHOULD BE SWEPT UP FOR SALVAGE OR DISPOSAL. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:ANIMAL STUDIES AND MANUFACTURING EXPERIENCE INDICATE THAT EXPOSURE TO THE PRODUCT MAY RESULT IN EYE AND SKIN IRRITATION UNDER NORMAL CONDITIONS OF USE. IN THE EVENT OF CONTACT, IMMEDIATELY FLUSH EYES WITH WATER; WASH SKIN WITH SOAP AND WATER. Other Precautions:THE PRODUCT SHOULD BE STORED IN A CLEAN DRY AREA TO MAINTAIN PRODUCT QUALITY AND TO PREVENT POSSIBLE CONTAMINATION BY OTHER CHEMICALS. COMMENTS: VENTILATION: CONTROL MEASURES SUCH AS LOCAL EXHAUST VE NTILATION MAY BE REQUIRED WHERE EXCESSIVE AIRBORNE DUST LOADING MAY BE PRESENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED RESPIRATORY PROTECTION ID RELEASE OF THE PRODUCT INTO THE WORK AREA IS EXPECTED. Ventilation:CONTROL MEASURES SUCH AS LOCAL EXHAUST VENTILATION MAY BE REQUIRED WHERE EXCESSIVE AIRBORNE DUST LOADING MAY BE PRESENT. EXPECTED. Other Protective Equipment:USE LONG SLEEVED WORK SHIRT TO REDUCE EXPOSED SKIN AREA. Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY. Supplemental Safety and Health PREVENTION OF EYE & SKIN CONTACT MAY BE REQUIRED UNDER NORMAL USE CONDITIONS. HOWEVER, SEVERE AGITATION OR DISPERSION INTO THE WORK ENVIRONMENT MAY REQUIRE ENCLOSURE OF THE PROCESS & LOCAL EXHAUST VE NTILATION AT THE SOURCE TO PREVENT RELEASE INTO THE AIR. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:>1000.C, 1832.F Melt/Freeze Pt:=622.C, ######F Vapor Pres:NON-VOLITILE Vapor Density:N/VOLITILE Spec Gravity:0.5 - 1.2 G/ML pH:10@25C Evaporation Rate & Reference:NON-VOLITILE (BUAC=1) Solubility in Water:13 Appearance and Odor:WHITE GRANULES OR POWDER; NO ODOR Percent Volatiles by Volume:NON-VOLITILE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:EYE EFFECTS: MILDLY IRRITATING (RABBIT) [FMC 186-917].SKIN EFFECTS: NON-IRRITATING (RABBIT) [FMC 188-1047]. DERMAL LD50: NO DATA AVAILABLE FOR THE PRODUCT. ORAL LD50: >2000 MG/KG (RAT) [FMC STUDY 197- 2169]. INHALATION LC50: 0.39 MG/L (RAT)(4 HR) (MAXIMUM ATTAINABLE DUST CONCENTRATION) [FMC STUDY 188-1011]. ACUTE EFFECTS FROM OVEREXPOSURE: PRODUCT IS MILDLY IRRITATING TO EYES & NONIRRITATING TO SKI N. CHRONIC EFFECTS: CHRONIC EXPOSURE TO VERY HIGH LEVELS OF PRODUCT PRODUCES KIDNEY DAMAGE & IMPAIRED BONE DEVELOPMENT IN LABORATORY ANIMALS. HOWEVER, PRODUCT IS LISTED BY US FDA AS A GENERALLY RECOGN IZED AS SAFE (GRAS) FOOD ADDITIVE. ===================== Ecological Information ===================== Ecological:ECOTOXICOLOGICAL INFORMATION: 96 HR LC50 >100 MG/L, NON-TOXIC (RAINBOW TROUT, INLAND SILVERSIDES AND MYSID SHRIMP). [FMC STUDY 189-1081], 1082 & 1083]48 HR EC50 > 100 MG/L, NON-TOXIC (DAPHNIA MAGNA) [ FMC 189-1084]. CHEMICAL FATE INFORMATION: INORGANIC COMPOUNDS IN CONTACT WITH THE SOIL, SUB-SURFACE OR SURFACE WATERS MAY BE TAKEN UP BY PLANTS AND UTILIZED AS ESSENTIAL NUTRIENTS. PHOSPHATES MAY ALSO FORM PRECIPITATES, USUALLY IN THE FORM OF CALCIUM OR MAGNESIUM. THE RESULTANT COMPOUNDS ARE INSOLUBLE IN WATER AND BECOME PART OF THE SOIL OR SEDIMENT. THE TERM BIODEGRADABILITY, AS SUCH, IS NOT APPL ICABLE TO INORDGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT DOES NOT PRESENT A DANGER OR HAZARD FOR DISPOSAL. EXCEPT FOR FOOD APPLICATIONS, SALVAGE AND RETURN TO CONTAINER. PROCESS OR RECYCLE FOR OTHER USES. MAY BE DISPOSED OF IN LANDFILLS ACCORDI NG TO LOCAL, STATE OR FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:US DOT (DEPARTMENT OF TRANSPORTATION): PROPER SHIPPING NME: NOT REGULATED. UN/NA NUMBER: NONE. PLACARDS: NOT REQUIRED. LABEL: NOT REQUIRED. OTHER SHIPPING INFORMATION: DOT MARKING: NOT APPLICABLE. HAZ ARDOUS SUBSTANCE/RQ: NOT LISTED. 49 STCC NUMBER: NOT APPLICABLE. SPECIAL SHIPPING NOTES: IMDG: NOT REGULATED. IATA: NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311 HAZARD CATEGORY (40 CFR 370): NOT APPLICABLE. SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): NOT APPLICABLE. SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): NOT APPLICABLE.SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NOT LISTED. Federal Regulatory Information:CERCLA REGULATORY (40 CFR 302.4): LISTED. CERCLA: SODIUM TRIPOLYPHOSPHATE (STPP) - 5000 LBS. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZIRCONIUM OXIDE, Z83500 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ZIRCONIUM OXIDE. PEL & TLV:5 MG/M3;10 MG/M3 STEL, (ZR). CAS:1314-23-4 RTECS #:ZH8800000 Fraction by Wt: 100% OSHA PEL:SEE INGREDIENT NAME ACGIH TLV:SEE INGREDIENT NAME Ingred Name:OTHER PROT EQUIP:EMPLOYER SHOULD PROVIDE EYE WASH FOUNTAIN W/IN IMMED WORK AREA FOR EMERGENCY USE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:SINGLE INTRATRACHEAL INSTILLATION TO RATS PRDCD FIBROGENIC & PROLIFERATIVE CHANGES & SCLEROSIS IN LUNG TISS. SKIN:APPLICATN TO ABRADED SKIN MAY CAUSE ALLERGIC GRANULOMA FORM IN PREVIOUSLY EXPOSED PERS. INGEST:GI ABSORP IS POOR & THEREFORE ORAL TOX IS LOW. CHRONIC:INHAL:ONE STUDY REPORTED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:PULM GRANULOMAS IN RABBITS EXPOSED TO ZIRCONIUM CMPDS. SKIN:RPTD/PRLNG CONT TO ABRADED SKIN MAY CAUSE ALLERGIC GRANULOMA, CHARACT BY RED-BROWN, FIRM, SHINY, ERYTHEMATOUS, NONTENDER PAPULES WH ICH GENERALLY DISAPPEAR SPONT, BUT SLOWLY, PERSISTING FOR MTHS/YRS. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & @ REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG AMTS OF H*2O UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MINS). GET MD IMMED. EYE:WASH IMMED W/LG AMTS OF H*2O/NORM SALINE, OCCAS LIFTING (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINGUISH USING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS-DEMAND/POS PRESS SCBA & FULL PROT EQUIP . NO ACUTE HAZ. MOVE CNTNR FROM FIRE AREA IF POSS. AVOID BRTHG VAP/DUST; KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:OCCUP SPILL:FOR LG SPILLS, SWEEP UP W/MINIMUM OF DUSTING & PLACE INTO SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. RESIDUE SHOULD BE CLEANED UP USING HIGH-EFFICIENCY PARTICULATE F ILTER VACUUM. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER. Other Precautions:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS WHEN STORING THIS SUBSTANCE. FOR ASSISTANCE, CONTACT DISTRICT DIRECTORS OF ENVIRONMENTAL PROTECTION AGENCY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR BASED ON CONTAMINATION LEVEL FOUND IN WORKPLACE & ON SPECIFIC OPERATION. REFER TO ORIGINAL MSDS FOR SPECIFIC SELECTIONS . Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM TO MEET PEL. Other Protective Equipment:APPROP PROT (IMPERVIOUS) CLTHG & EQUIP. WHERE THERE IS ANY POSS THAT EMPLOYEE'S EYES MAY BE EXPOS TO SUBSTANCE, (ING 2) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR:MONOCLINIC CRYSTALS. FIRST AID PROC:UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MINS). GET MD IMMED. INGEST:TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED. IF VOMIT OCCURS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIR. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:9032F,5000C Melt/Freeze Pt:M.P/F.P Text:4919F,2715C Spec Gravity:5.6-6.2 Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS, TASTELESS, WHITE TO YELLOW-BROWN, HEAVY AMORPHOUS POWDER OR(SUPP DATA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO DATA AVAILABLE. Stability Condition to Avoid:PREVENT DISPERSION OF DUST IN AIR. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC &/OR HAZARDOUS GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT DISTRICT DIRECTORS OF ENVIRONMENTAL PROTECTION AGENCY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COIN CELL POLY-CARBONMONOFLURIDE (BR) LITHIUM BATTERY Preparer's Name:DOD, HMIS, DSCR-VBA CAGE:99998 CAGE:99998 CAGE:1HJ92 ============= Composition/Information on Ingredients ============= Ingred Name:CATHODE: POLY-CARBONMONOFLUORIDE, (CF)N Ingred Name:ANODE: LITHIUM, (LI) Ingred Name:ELECTROLYTE, LI SALT: LITHIUM TETRAFLUOROBORATE, (LIBF4) Ingred Name:ELECTROLYTE, SOLVENT: Y-BUTYROLACTONE, (Y-BL) Ingred Name:ELECTROLYTE, SOLVENT: 1,2 DIMETHOXYETHANE, (DME) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS BATTERY IS A SEALED ARTICLE EXEMPT FROM THE REQUIREMENTS OF THE HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. A MSDS IS NOT REQUIRED. UNDER NORMAL CONDITIONS OF USE THIS BATTERY DOES NOT RELEA SE MORE THAN VERY SMALL QUANTITIES, E.G. MINUTE OR TRACE AMOUNTS OF A HAZARDOUS CHEMICAL, AND DOES NOT POSE A PHYSICAL HAZARD OR HEALTH RISK TO EMPLOYEES. Effects of Overexposure:NONE. ======================= First Aid Measures ======================= First Aid:NONE REQUIRED. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:REMOVE BATTERIES FROM AREA OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:IF ONE OF THESE BATTERIES SHOULD LEAK ELECTROLYTE, WASH THE AREA WITH COPIOUS AMOUNTS OF WATER. IF CONTACTED BY ANY OF LEAKED ELECTROLYTE, WASH AREA WITH COPIOUS AMOUNTS OF WATER AND IF IRRITATION OR ADVERSE SYMPTOMS DEVELOP OR PERSISTS, GET MEDICAL ATTENTION. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT ALLOW CELLS OR BATTERIES TO SHORT CIRCUIT. STORE IN ORIGINAL CONTAINERS. DO NOT PUNCTURE, INCINERATE, EXPOSE TO FIRE OR TEMPERATURES ABOVE 185F. DO NOT CHARGE. DO NOT CUT OPEN. ============= Exposure Controls/Personal Protection ============= Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:NO SPECIAL WORK HYGENIC PRACTICES NEEDED. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:Z6 Appearance and Odor:A SEALED COIN CELL BATTERY. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ITEM IS A SEALED BATTERY CELL. Stability Condition to Avoid:SEALED CELL. AVOID EXPOSURE ABOVE 350F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE OR EXPOSE BATTERIES TO FIRE. DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL RGULATIONS. =================== MSDS Transport Information =================== Transport Information:LETTER TO DICK TRAYLOR FROM CHARLES P. MONAHAN, OF TRN TECHNICAL, INC DATED JAN 1, 1998 : THIS BATTERY UNDER NORMAL CONDITIONS OF USE DOES NOT RELEASE MORE THAN SMALL QUANTITIES E.G. MINUTE OR TRACE A MOUNTS OF A HAZARDOUS CHEMICAL, AND DOES NOT POSE A PHYSICAL HAZARD OR HEALTH RISK TO EMPLOYEES. FROM WEB SITE: ALL PANASONIC BR LITHIUM BATTERIES ARE UNREGULATED FOR TRUCK, RAIL, OCEAN, AND AIR TRANS PORTATION BECAUSE THEY MEET THE REQUIREMENTS OF 49 CFR 173.185 (B). THE ONLY REQUIREMENTS FOR TRANSPORTING THESE BATTERIES ARE THEY MUST BE SECURELY PACKAGED TO PREVENT THE POSSIBILITY OF SHORT-CIRCUI TING.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:DERUSTO RPE SPRAY GRADE, 885 GLOSS BLUE (52559) CAGE:90300 CAGE:90300 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 25-30% OSHA PEL:1000 PPM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15-20% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 10-15% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:KEROSENE (PETROLEUM), HYDROCARBON; (PETROLEUM DISTILLATES) CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 5-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 1-5% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 3-15% OSHA PEL:200 PPM ACGIH TLV:S, 50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC COMPOUND LESS WATER LESS EXEMPT SOLVENT:540-623 G/L. RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND MATERIAL:540-623 (GRAMS/LITER) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:MAY IRRIT EYES, SKIN, NOSE & RESP TRACT. HARMFUL IF INHALED. HARMFUL/FATAL IF SWALLOWED. IF INGESTED, THIS PROD MAY CAUSE VOMIT, DIARR & DEPRESSED RESP. ASPIR OF MATL INTO LUNGS DUE TO VOMIT MAY CAUSE CHEM PNEUM WHICH CAN BE FATAL. INHAL MAY AFFECT BRAIN/NERV SYS CAUSING HDCH, DIZZ/NAUS. (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:CHRONIC:TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . RPTS HAVE ASSOC PERM BRAIN & NERV SYS DMG W/PRLNGD & RPTD OCCUP OVEREXP TO SOLVS. PRLNGD/RPTD CONT W/SKIN CAN CAUSE DEFAT(SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN IMMEDIATELY. SKIN:WASH IMMEDIATELY WITH SOAP AND WATER. INHALATION:REMOVE TO FRESH AIR. CONTACT A PHYSICIAN IMMEDIAT ELY. INGESTION:DO NOT INDUCE VOMITING. IMMEDIATELY CONTACT A PHYSICIAN OR REGIONAL POISON CONTROL CENTER FOR ADDITIONAL TREATMENT. ===================== Fire Fighting Measures ===================== Flash Point:AEROSOL Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:CNTNRS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ELIM SOURCE OF IGNIT, HEAT, ELEC EQUIP, SPKS & OPEN FLAMES. DO NOT PUT IN CONT W/OXIDIZING/CAUSTIC MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL AREA. USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL AND PLACE INTO CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM CAUSTICS AND OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:KEEP CONTAINERS FROM EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE 120F. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF 8-HOUR EXPOSURE LIMIT OR VALUE IS EXCEEDED FOR ANY COMPONENT, USE AN APPROVED NIOSH/OSHA/MSHA RESPIRATOR. CONSULT YOUR SAFETY EQUIPMENT SUPPLIER AND THE OSHA REGULATION, 29 CFR 1910.134 FOR RESPIRA TOR REQUIREMENTS. Ventilation:PROVIDE SUFFICIENT MECH VENT (LOC/GEN EXHST) TO MAINTAIN EXPOS BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL COLLECT (SUPDAT) Other Protective Equipment:PROVIDE EYEWASH AND SOLVENT IMPERVIOUS APRON IF BODY CONTACT OCCURS. BARRIER CREAMS MAY BE USED. Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health SPEC GRAV:0.66-1.04 (H*2O=1). EFTS OF OVEREXP:WHICH MAY LEAD TO DERMATITIS. OVEREXPOSURE OR MISUSE OF TOLUENE CAN CAUSE LIVER, KIDNEY AND BRAIN DAMAGE, AS WELL AS CARDIAC ABNORMALITIES. VENT:IN LOW AR EAS. CHECK ALL LOW AREAS (BASEMENTS, SUMPS, ETC.) FOR VAPOR BEFORE ENTERING. ================== Physical/Chemical Properties ================== Vapor Density:>1 Spec Gravity:SUPP DATA Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID, VARIOUS COLORS; GASOLINE-LIKE ODOR. Percent Volatiles by Volume:85-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND CAUSTICS. Stability Condition to Avoid:EXCESSIVE HEAT AND FREEZING. Hazardous Decomposition Products:NORMAL COMBUSTION PRODUCTS, I.E. CO*X, NO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL STANDARDS. USE ALL MATERIAL BEFORE DISPOSAL. IF UNABLE TO USE ENTIRE CONTENTS OF CAN, RELIEVE PRESSURE IN CONTAINER UNTIL IT EQUALS EXTERNAL PRESSURE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:893 RECOAT SEALER CAGE:ACMEA CAGE:ACMEA ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 88% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:WEIGHT PER GALLON IN POUNDS: 6.79 RTECS #:9999999WG Ingred Name:VOL ORGANIC CMPD: 5.96 LBS/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY SYSTEM. CNS DEPRESSION. PROLONGED SOLVENT MAY CAUSE ADVERSE EFFECTS TO LIVER/URINARY/REPRODUCTIVE. PERMANENT BRAIN & CNS DAMAGE. EXTREME OVEREXPOSURE MAY CAUSE UNCO NSCIOUSNESS & POSSIBLY DEATH. ALCOHOLS & ACETATES CAN BE ABSORBED THROUGH THE SKIN. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: HEADACHE/DIZZINESS/NAUSEA/COORDINATION LOSS/UNCONSCIOUSNESS/DEATH. SKIN/EYES: REDNESS/ITCH/BURNING SENSATION. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF PROBLEMS REMAIN OR OCCUR DURING USE, IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH W/PLENTY OF WATER FOR 1 5 MINUTES. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:45F Lower Limits:0.7% Upper Limits:12.7% Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP, POSSIBLE AUTOIGNITION, OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA. REMVOE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME. DURING USE & UNTIL ALL VAPORS ARE GONE; KEEP ARE VENTILATED. DON'T SMOKE. Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS. TURN OFF STOVES/ELECTRIC TOOLS/APPLIANCES & OTHER IGNITION SOURCES. CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING PROCEDURES. KEEP CONTAINER CLOSED W HEN NOT IN USE. DON'T TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW TLV BY VENTILATION, USE A FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED FILM, USE A NIOSH/MSHA DUST/MI ST RESPIRATOR. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE TO MATERIALS IS MAINTAINED BELOW APPLICABLE LIMITS. Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE LABELING. KEEP OUF OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. MAY CONTAIN M ATERIAL CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAAZARDOUS LEVELS ONLY DURING ABRADING/SANDING FILM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:178-425F Vapor Density:>1 Spec Gravity:0.82-1.5 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:55-92 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/PILOT LIGHTS & OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CO2, CO & OXIDES OF METALS IN THE INGREDIENTS SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS AS DEFINED UNDER THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINER. DISPOSE OF IAW FED/STATE/LOCAL REGS.
1
eyes_protection_mandatory
======================================================= Product ID: GEAR OILS 68, 100, 150, 220, 280, 320, 460 Cage: 5R396 Box: 2197 Resp. Party Other MSDS No.: LUBC0180 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 5R396 Box: 2197 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Skin: YES Effects of Exposure: THE PRODUCT, AS WITH MANY PETROLEUM PRODUCTS, MAY CAUSE MINOR SKIN, EYE, AND LUNG IRRITATION, BUT GOOD HYGIENIC PRACTICES CAN MINIMIZE THESE EFFECTS. NORMAL USE OF THIS PRODUCT DOES NOT RESULT IN GENE RATION OF AN OIL MIST. HOWEVER, IF AN OIL MIST IS GENERATED, OVEREXPOSURE CAN CAUSE MINOR AND REVERSIBLE IRRITATION TO THE EYES, SKIN, AND ESPECIALLY THE LUNGS. PROPER PERSONAL PROTECTIVE EQUIPMENT AN D SUFFICIENT VENTILATION CAN PROVIDE ADEQUATE PROTECTION. Explanation Of Carcinogenicity: NONE OF THE COMPONENTS PRESENT IN THIS MATERIAL AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC, NTP, OSHA OR ACGIH AS A CARCINOGEN. Signs And Symptions Of Overexposure: THE PRODUCT, AS WITH MANY PETROLEUM PRODUCTS, MAY CAUSE MINOR SKIN, EYE, AND LUNG IRRITATION, BUT GOOD HYGIENIC PRACTICES CAN MINIMIZE THESE EFFECTS. NORMAL USE OF THIS PRODUCT DOES NOT RESULT IN GENE RATION OF AN OIL MIST. HOWEVER, IF AN OIL MIST IS GENERATED, OVEREXPOSURE CAN CAUSE MINOR AND REVERSIBLE IRRITATION TO THE EYES, SKIN, AND ESPECIALLY THE LUNGS. PROPER PERSONAL PROTECTIVE EQUIPMENT AN D SUFFICIENT VENTILATION CAN PROVIDE ADEQUATE PROTECTION. Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. SKIN: WASH SKIN THOROUGHLY W/SOAP & WATER. IF IRRITATION DEVEL OPS/PERSISTS, CONSULT A PHYSICIAN. EYE: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINS. CALL A PHYSICIAN. INGESTION: MATERIAL POSES AN ASPIRATION HAZARD. IF SWALLOWED, DO NOT INDUCE VO MITING. IMMEDIATELY GIVE 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN FOREWARD TO REDUCE THE RISK OF ASPI RATION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. REMOVE SOURCE OF HEAT, SPARKS, AND FLAME. DIKE SPILL. PREVENT MATERIAL FROM ENTERING SEWERS, WATERWAYS, OR LOW AREAS. RECOVER FREE LIQUID FOR REUSE OR RECLAMATION. SOAK UP WITH SAWDUST, SAND, OIL DRY OR OTHER ABSORBENT MATERIAL. Waste Disposal Methods: TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL, AND LOCAL REGULATIONS. RECOVER NONUSABLE FREE LIQUID AND DISPOSE OF IN APPROVED AND PER MITTED INCINERATIOR. DO NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTEM. Handling And Storage Precautions: CLOSE CONTAINER AFTER EACH USE. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, GRIND, OR DRILL ON OR NEAR FULL OR EMPTY CONTAINER. EMPTY CONTAINER RETAINS RESIDUE & MAY EXPLODE IN HEAT OF FIRE. STORE IA W NFPA RECOMMENDATIONS. STORE IN COOL DRY WELL-VENTILATED AREA. Other Precautions: EMPTY DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED, AND PROMTLY SHIPPED TO THE SUPPLIER OR A DRUM RECONDITIONER. ALL OTHER CONTAINERS SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER. ST ORE AWAY FROM OXIDIZERS, HEAT, SPARKS, FLAME. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: COC Flash Point: =210.C, 410.F Flash Point Text: MIN F/P BY WT Extinguishing Media: WATER SPRAY, FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures: WATER OR FOAM MAY CAUSE FROTHING. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. WATER MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES. Unusual Fire/Explosion Hazard: PRODUCTS OF COMBUSTION MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE, AND OTHER TOXIC MATERIALS. DO NOT ENTER ENCLOSED OR CONFINED SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECT ION. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NORMALLY REQUIRED EXCEPT IN EMERGENCIES OR WHEN CONDITIONS CAUSE EXCESSIVE AIRBORNE LEVELS OF MIST OR VAPORS. SELECT APPROPRIATE NIOSH-APPROVED RESPIRATORY PROTECTIVE EQUIPMENT WHEN EXPOSED TO SP RAY OR MISTS. PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED BY ADEQUATELY TRAINED PERSONNEL AND BASED ON THE CONTAMINANT(S), THE DEGREE OF POTENTIAL EXPOSURE Ventilation: NORMAL SHOP VENTILATION. Other Protective Equipment: COVERALLS WITH LONG SLEEVES IF SPLASHING IS PROBABLE. Work Hygienic Practices: AVOID BREATHING VAPORS OR MIST. AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WASH THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING PRIOR TO REUSE. Supplemental Safety and Health: NOTE TO PHYSICIAN: ACTIVATED CHARCOAL MIXTURE MAY BE ADMINISTERED. TO PREPARE ACTIVATED CHARCOAL MIXTURE, SUSPEND 50 GRAMS ACTIVATED CHARCOAL IN 400 ML WATER AND MIX THOROUGHLY. ADMINISTER 5 ML/KG, OR 350 ML FOR AN AVERAGE ADULT. ======================================================= Physical/Chemical Properties ======================================================= HCC: V6 B.P. Text: NOT AVAILABLE Vapor Pres: NIL Vapor Density: >1 Spec Gravity: 0.87 - 0.90 @60F (16C) Evaporation Rate & Reference: NIL Solubility in Water: INSOLUBLE Appearance and Odor: COLORLESS, AMBER TO BROWN (LIGHT) LIQUID;PETROLEUM (MILD), PUNGENT(SLIGHT) ODOR Percent Volatiles by Volume: NIL ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, SPARKS, AND FLAMES. Materials To Avoid: INCOMPATIBLE OR CAN REACT WITH OXIDIZERS. Hazardous Decomposition Products: HAZARDOUS GASES OR VAPORS INCLUDING OXIDES OF CARBON , NITROGEN, SULFUR, & PHOSPHORUS. ODOROUS & TOXIC FUMES MAY FORM IF STORED AT TEMP >113F FOR EXTENDED PERIODS OF TIME OR IF HEAT SOURCES >250F USED. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: MOUSE SKIN PAINTING STUDIES HAVE SHOWN THAT HIGHLY REFINED PETROLEUM LUBE OILS SIMILAR TO INGREDIENTS IN THIS PRODUCT HAVE NOT CAUSED SKIN TUMORS. ======================================================= Ecological Information ======================================================= Ecological: NO SPECIFIC DATA AVAILABLE ON THIS PRODUCT. ======================================================= ======================================================= Transport Information: NOT RESTRICTED ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: MATERIAL COVERED UNDER CERCLA PETROLEUM EXCLUSION. MATERIAL AND/OR CONTENTS LISTED IN TSCA INVENTORY. DOES NOT MEET HAZARDOUS WASTE CHARACTERISTS UNDER RCRA. State Regulatory Information: MATERIAL MAY CONTAIN INGREDIENTS KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTVE HARM. READ & FOLLOW LABEL DIRECTIONS. NOT SUBJECT TO PENNSYLVANIA WORKER & COMMUNITY RIGHT TO KNOW ACT. ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 156294 Product ID: GEAR OILS 68, 100, 150, 220, 280, 320, 460 Review Date: 03/16/2001 Multiple KIT Number: 0 Unit Of Issue: CY Type Of Container: CYLINDER ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: GEAR OILS 68, 100, 150, 220, 280, 320, 460 Cage: 5R396 Company Name: CONOCO INC Street: 5 GREENWAY PLAZA E PO Box: 2197 Zipcode: 77252 Label Required IND: Y Date Of Label Review: 03/16/2001 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: THE PRODUCT, AS WITH MANY PETROLEUM PRODUCTS, MAY CAUSE MINOR SKIN, EYE, AND LUNG IRRITATION, BUT GOOD HYGIENIC PRACTICES CAN MINIMIZE THESE EFFECTS. NORMAL USE OF THIS PRODUCT DOES NOT RESULT IN GENE RATION OF AN OIL MIST. HOWEVER, IF AN OIL MIST IS GENERATED, OVEREXPOSURE CAN CAUSE MINOR AND REVERSIBLE IRRITATION TO THE EYES, SKIN, AND ESPECIALLY THE LUNGS. PROPER PERSONAL PROTECTIVE EQUIPMENT AN D SUFFICIENT VENTILATION CAN PROVIDE ADEQUATE PROTECTION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DAVISON BLUE INDICATING SILICA GEL Preparer's Name:J.H.CONVEY,MGR.ENVIR.CTRL CAGE:16210 CAGE:00334 CAGE:16210 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL - CONSIDERED A NUISANCE DUST CAS:63231-67-4 RTECS #:VV7322000 Other REC Limits:NONE SPECIFIED OSHA PEL:20 MPPCF ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:COBALT CHLORIDE CAS:7646-79-9 RTECS #:GF9800000 Other REC Limits:NON SPECIFIED OSHA PEL:0.1 MG CO/CUM ACGIH TLV:0.1 MG CO/CUM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 RAT(ESTIMATED) >31,600 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:COBALT CHLORIDE IS GENERALLY RECOGNIZED AS SAFE AS A TRACE MINERAL ADDED TO ANIMAL FEED. SILICA GEL IS A SYNTHETIC AMORPHOUS SILICA NOT TO BE CONFUSED W/CRYSTALLINE SILICA. EPIDEMIOLOGICAL STUDIES IND ICATE A LOW POTENTIAL FOR HEALTH EFFECTS. IT IS CONSIDERED A NUISANCE DUST & ACTS AS A DESICCANT TO HUMAN TISSUE. Explanation of Carcinogenicity:THIS PRODUCT AND ITS COMPONENETS ARE NOT LISTED ON THE IARC, NTP OR OSHA CARCINOGENS LISTS. Effects of Overexposure:DRYING ACTION PF PRODUCT CAN CAUSE IRRITATION OF THE MUCOUS MEMBRANES OF THE NOSE & THROAT & IRRITATION OF THE SKIN. COBALT CHLORIDE CAN CAUSE DERMATITIS AND IRRITATION OF NASAL PASSAGE AND LUNGS. Medical Cond Aggravated by Exposure:DAVISON KNOWS OF NO MEDICAL CONDITIONS ABNORMALLY AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:IF ANY IRRITATION PERSISTS OR SEVERE, GET MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. OCCASIONALLY LIFTING LIDS. SKIN:WASH W/SOAP & WATER. INHALED:REMOVE TO FRESH AIR. INGESTED:MATERIAL WILL PASS THROUGH BODY NORMALLY. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:MFR GAVE NO INFORMATION OF MSDS. Fire Fighting Procedures:NON-FLAMMABLE. MFR GAVE NO INFORMATION OF MSDS. Unusual Fire/Explosion Hazard:NON-FLAMMABLE. MFR GAVE NO INFORMATION OF MSDS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP OR VACUUM UP. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY SEALED TO PROTECT QUALITY. Other Precautions:WHEN POURING INTO A CONTAINER OF FLAMMABLE LIQUID, GROUND BOTH CONTAINERS ELECTRICALLY TO PREVENT A STATIC ELECTRIC SPARK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUSTY CONDITION PREVAIL, WEAR A PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR. Ventilation:MFR GAVE NO INFORMATION OF MSDS. Other Protective Equipment:FOR MANUAL HANDLING:WEAR LONG SLEEVES AND Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NOT KNOWN TO HAVE ANY ADVERSE EFFECTS ON THE AQUATIC ENVIRONMENT. THE SILICA BASE IS INSOLUBLE AND NONTOXIC. COBALT CHLORIDE MAY LEACH AWAY IF CONTACTED WITH WATER. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Spec Gravity:2.1 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR BLUE GRANULES, NO ODOR. PH OF 5% SLURRY; 6.5 TO 7.5 Corrosion Rate:UNKNOWNN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MFR GAVE NO INFORMATION OF MSDS. Stability Condition to Avoid:MFR GAVE NO INFORMATION OF MSDS. Hazardous Decomposition Products:MFR GAVE NO INFORMATION OF MSDS. Conditions to Avoid Polymerization:MFR GAVE NO INFORMATION OF MSDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED LANDFILL I/A/W FEDERAL, STATE & LOCAL REGULATIONS. COVER PROMPTLY TO AVOID BLOWING OF DUST.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:007 PENETRATING STAINS CAGE:DALWO CAGE:DALWO ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS-ALIPHATIC HYDROCARBONS Fraction by Wt: 80% OSHA PEL:500 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL & RESPIRATORY IRRITATION. ANEMIA, KIDNEY DAMAGE. NOTICE: REPORTS HAVE ASSOCIATED PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE W/REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS. INTENTIONAL MI SUSE BY DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, PALE, NAUSEA, DIZZY, WEAK, REDNESS, TEARING, BLURRED VISION, VOMITING, DIARRHEA. SENSITIZATION. Medical Cond Aggravated by Exposure:RESPIRATORY ALLERGIES & SKIN SENSITIZATION MAY BECOME WORSE UPON EXPOSURE TO THE PRODUCT/ITS INGREDIENTS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED. EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: THOROUGHLY WASH EXPOSED AREA W/SOAP & WATER. INGESTION: DONT INDUCE VOMITING, KEEP WARM & QUIET. OBT AIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F Lower Limits:1.02 Extinguishing Media:FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR SCBA W/A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND/OTHER POSITIVE PRESSURE MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:VAPORS ARE > THAN AIR & MAY TRAVEL ALONG THE GROUND TO OTHER IGNITION SOURCES. AUTO-IGNITION TEMP 473F. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT. STOP AT SOURCE, DIKE AREA, PUMP LIQUID TO SALVAGE TANK. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VENTILATED AREA. AVOID STORAGE AT FLASH POINT OF 100F TEMP NEAR FIRE/OPEN FLAME. Other Precautions:KEEP CLOSURE TIGHT & CONTAINER UPRIGHT TO PREVENT LEAKAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED CHEMICAL/MECHANICAL FILTERS. Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): RECOMMENDED. EXPLOSION PROOF. Other Protective Equipment:WEAR CHEMICAL RESISTANT BOOTS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING/USING THE WASHROOM. Supplemental Safety and Health FIRE & EXPLOSION CONT'D: NEVER USE WELDING/CUTTING TORCH NEAR CONTAINER EVEN EMPTY BECAUSE PRODUCT EVEN RESIDUE CAN IGNITE EXPLOSIVELY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F Vapor Pres:2 Vapor Density:4.9 Spec Gravity:0.89 Solubility in Water:INSOLUBLE Appearance and Odor:COLOR LIQUID W/PETROLEUM NAPTHA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES. Hazardous Decomposition Products:CO, HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. DESTROY BY LIQUID INCINERATION IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: AZ-1411 CA MIDTONE BASE AZ-COTE ALL TOPCOATS & PRIMERS Cage: OADX8 ======================================================= Contractor Summary ======================================================= Cage: OADX8 ======================================================= Ingredients ======================================================= Cas: 64741-41-9 % low Wt: 25. % high Wt: 50. ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Effects of Exposure: MAY BE IRRITATING TO THE EYES & RESPIRATORY TRACT. MAY CAUSE NERVOUS SYSTEM EFFECTS & DEATH. ANESTHETIC. LOW ORAL & DERMAL TOXICITY. INGESTION: MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING INGESTION /VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY & POSSIBLY DEATH. CHRONIC EXPOSURE MAY CAUSE DAMAGE TO THE CNS, RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, LIVER, GI TRACT, SPLEEN, KIDNEYS & BLOOD. REP EATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. Signs And Symptions Of Overexposure: IRRITATION, HEADACHE, DIZZINESS, DROWSINESS, UNCONSCIOUSNESS, VOMITING. First Aid: INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. TREAT SYMPTOMATICALLY. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WIPE OFF W/TOWEL. WASH W/SOAP & WATER. INGESTION: REMOVE STOMACH CONTENTS BY GASTRIC SUCTION/INDUCE VOMITING ONLY AS DIRECTED BY A MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION, FLAMES, HOT SURFACES, ELECTRICAL, STATIC/FRICTIONAL SPARKS. AVOID BREATHING VAPORS. VENTILATE AREA. USE NON-SPARKING TOOLS. REMOVE W/INERT ABSORBENT. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: DON'T STORE NEAR HEAT, SPARKS/FLAME. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point: =38.9C, 102.F Extinguishing Media: CO2, DRY CHEMICAL, FIRE FOAM Fire Fighting Procedures: WATER IS UNSUITABLE, BUT MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard: KEEP AWAY FROM HEAT, SPARKS & FLAME. ======================================================= Control Measures ======================================================= Respiratory Protection: IN CONFINED AREAS OF POOR VENTILATION, USE CHEMICAL CARTRIDGE RESPIRATOR/SELF CONTAINED BREATHING APPARATUS. Ventilation: GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP TLV & LEL OF MOST INGREDIENTS BELOW ACCEPTABLE LIMIT. Other Protective Equipment: NONE Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 311-380F Vapor Density: >1 Evaporation Rate & Reference: SLOWER THAN ETHER Percent Volatiles by Volume: 53.87-63.82 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, SPARKS, FLAMES, HOT SURFACES, ELECTRICAL, STATIC/FRICTIONAL SPARKS Hazardous Decomposition Products: FIRE, BURNING & WELDING MAY GENERATE CO. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: FIRE, BURNING, WELDING. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: AZ-1411 CA MIDTONE BASE AZ-COTE ALL TOPCOATS & PRIMERS Cage: OADX8 Assigned IND: Y Company Name: DIAMOND VOGEL PAINT Street: 1020 ALBANY PLACE SOUTH Zipcode: 51041 Label Required IND: Y Date Of Label Review: 09/14/1999 Status Code: A Origination Code: G =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:117 6262 KODAK READY PRO DENTAL TWIN PACK, PART DEVELOPER CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 3% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD FOR RECOMMENDED HANDLING. EYES: CAUSES IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING OR CHEST TIGHTNESS. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. SKIN-IMMEDIATELY REMO VE CONTAMINATED CLOTHES/SHOES & WASH WITH SOAP & PLENTY OF WATER. IF SKIN IRRITATION DEVELOPS, GET MEDICAL ATTENTION. NGESTED-DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE TYPE OF HAND CLEANER & REGULAR CLEANING OF WORK SURFACES WILLHELP MINIMIZE SKIN REACTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MMHG Vapor Density:0.6 AIR=1 Spec Gravity:1.08 pH:10.1 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, ODORLESS. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE WITH COMMON MATERIALS AND CONTAMINATS WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
1
eyes_protection_mandatory