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===================== Product Identification ===================== Product ID:TRX-200 (BULK & TUBES), 1018B Preparer's Name:LINDA SUE SHEPHERD CAGE:0AV13 CAGE:0AV13 CAGE:0ZUM2 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM DISTILLATE; (PETROLEUM OIL MIXTURE) CAS:8002-05-9 RTECS #:SE7449000 OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE VOMITING, NAUSEA OR DIARRHEA. INHALATION: NOT EXPECTED TO BE A PROBLEM. MASSIVE EXPOSURE TO FUMES MAY CAUSE HEADACHES, DIZZINESS, AND/OR DROWSINESS. SK IN: MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER USING EYECUP OR FOUNTAIN FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF DISCOMFORT PERSISTS. INGESTION: DO NOT INDUCE VOMITING. GIVE 3-4 GLASSES OF WATER. GET MEDICAL ATTENT ION. INHALATION: REMOVE TO FRESH AIR. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Extinguishing Media:DRY CHEMICAL (PREFERRED), CARBON DIOXIDE, FOAM, WATER. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMPTY CONTAINERS MAY RETAIN PRODUCT RESIDUE INCLUDING FLAMMABLE OR EXPLOSIVE VAPORS. DO NOT CUT, DRILL, GRIND OR WELD ON OR NEAR, PART FULL OR EMPTY DRUM. ================== Accidental Release Measures ================== Spill Release Procedures:STOP FLOW, DIKE SPILL. ELIMINATE ALL IGNITION SOURCES. ABSORB ON INERT MATERIAL AND SCRAPE UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED EXPOSURE TO MIST AND VAPORS. AVOID FLAMES, SPARKS AND HOT SURFACES. KEEP CONTAINERS CLOSED. SHELF LIFE IN ONE YEAR. Other Precautions:EMPTY CONTAINERS MAY CONTAIN EXPLOSIVE GAS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED IN EXCESS TO NORMAL VENTILATION. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . OIL RESISTANT APRON. Work Hygienic Practices:DO NOT WORK IN OIL SOAKED CLOTHING. WASH HANDS WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING. Supplemental Safety and Health VP: <0.01 @ 20C. ================== Physical/Chemical Properties ================== Vapor Pres:SUPDAT Solubility in Water:NEGLIGIBLE Appearance and Odor:RED GEL; OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHLORINE OR OXYGEN. Stability Condition to Avoid:AVOID OXIDIZING ATMOSPHERES. Hazardous Decomposition Products:THERMAL - UNIDENTIFIED ORGANICS OXIDATION - OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SF99 SOLVENT KAMPEL BLEND 3293 CAGE:2L263 CAGE:2L263 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: >9% Other REC Limits:375 MG/CUM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: >9% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: >9% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:METHYL ISOAMYL KETONE, MIAK, 5-METHYL-2-HEXANONE CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: >9% Other REC Limits:50 PPM OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: ANESTHETIC. INHALATION: RESPIRATORY TRACT IRRITATION & NERVOUS SYSTEM DEPRESSION. EYES/SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: ANESTHETIC. INHALATION: RESPIRATORY TRACT IRRITATION & NERVOUS SYSTEM DEPRESSION. EYES/SKIN: IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH W/PLENTY OF WATER FOR 15 MIN. INHALATION: REMOVE TO FRESH AIR, IF BREATHING IS DIFFICULT GIVE OXYGEN. IF BREATHING STOPS GIVE ARTIFICIAL RESPIRATION. INGESTION: CALL PHYSICIAN IMMEDIA TELY. DON'T INDUCE VOMITING. HAVE PATIENT LIE DOWN & KEEP WARM. VOMITING MAY LEAD TO ASPIRATION INTO LUNGS WHICH MAY BE FATAL. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:28F Upper Limits:1.7% Extinguishing Media:NFPA CLASS B EXTINGUISHER (CO2 OR FOAM) FOR CLASS 1 B LIQUID FIRES. Fire Fighting Procedures:WATER SPRAY CAN PROTECT FIRE FIGHTERS & COOL CLOSED CONTAINERS. USE FOG NOZZLES IF WATER IS USED. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL-MOP W/ABSORBENT MATERIAL & TRANSFER TO HOOD. LARGE-STOP SPILL, DIKE AREA TO PREVENT SPREAD. PUMP LIQUID TO SALAVAGE TANK & ABSORB REMAINDER & SHOVEL INTO CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. STORE LARGE AMOUNTS IN STRUCTURES MADE FOR OSHA CLASS 1 B LIQUIDS. Other Precautions:AVOID FREE FALL OF LIQUID. GROUND CONTAINERS WHEN POURING. DON'T FLAME CUT SAW, BRAZE, OR WELD. EMPTY CONTAINER HAZARDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/OSHA APPROVED AIR PACK Ventilation:LOCAL EXHAUST Supplemental Safety and Health BOILING RANGE: 172-297F ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP Vapor Pres:31.0 Vapor Density:3.0 Spec Gravity:0.836 Evaporation Rate & Reference:(ETHER=1) 5.8 Appearance and Odor:CLEAR WATER-WHITE, KETONE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS SUCH AS PERMANGANATE Stability Condition to Avoid:HEAT, SPARKS, NON-EXPLOSION PROOF ELECTRIC EQUIPMENT & OPEN FLAME. Hazardous Decomposition Products:C0 & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL-EVAPORATE UNTIL ALL VAPORS ARE GONE. LARGE-RECYCLE OR INCINERATE. DISPOSE OF IN ACCORDANCE W/LOCAL, FEDERAL & STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COPOLYMER OF 2-CHLORO-1, 3-BUTADIENE AND (SUP DAT) Preparer's Name:F M LOGULLO CAGE:0ERJ7 CAGE:0ERJ7 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:2-CHLORO-1,3-BUTADIENE POLYMERS AND COPOLYMERS; (COPOLYMER OF 2-CHLORO-1,3-BUTADIENE AND 2-ETHYLHEXYL METHACRYLATE) CAS:31454-65-6 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METHACRYLIC ACID, 2-ETHYLHEXYL ESTER; (2-ETHYLHEXYL METHACRYLATE) CAS:688-84-6 RTECS #:OZ4630000 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 1% OSHA PEL:20 MPPCF Z-3 ACGIH TLV:2 MG/M3 RDUST Ingred Name:RESP PROT: USE NIOSH/MSHA APPRVD POS PRESS AIR SUPP RESP IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: EXPOS LEVELS ARE NOT KNOWN/ANY OTHER CIRCUMSTANCES WHERE AIR PURIFYING RESPS MAY NOT PROVIDE ADEQUATE PROTECTION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 20000 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INGEST: ONE TYPE OF NEOPRENE WAS TESTED FOR ORAL TOXICITY IN RATS. LD-50 IS IN EXCESS OF 20000 MG/KG WHICH IS LOW TOXICITY. OTHER TYPES OF NEOPRENE ARE PREDICTED TO HAVE SAME LOW TOXICITY. SKIN : RESIDUAL 2-ETHYLHEXYL METHACRYLATE MAY CAUSE SKIN IRRIT & SENSIT IN SOME INDIVIDUALS. AVOID PRLNG/ (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: RPTD CONT W/SKIN. EYES: MECH IRRIT ONLY. INHAL: AVOID BRTHG DUST FROM FREE TALC LEFT IN BAG. TALC IS DUST WHICH MAY CAUSE SORE THROAT & PAINS IN LUNGS & CHEST. AT PROCESSING TEMPS > 200C, FU MES IRRIT TO EYES, NOSE, & THROAT MAY BE PRODUCED. THIS EXPOS MAY RSLT IN REDDENING, TEARING, & ITCH OF EYES (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: NO SPECIFIC INTERVENTION INDICATED AS CMPD IS NOT LIKELY TO BE HAZ BY INHAL. CONSULT MD IF NEC. SKIN: FLUSH W/WATER AFTER CONT. WASH CONTAM CLTHG BEFORE REUSE. EYES: IMMED FLUSH W/PLENTY OF WAT ER FOR AT LEAST 15 MIN. CALL MD. INGEST: NO SPECIFIC INTERVENTION IS INDICATED AS COMPOUND IS NOT LIKELY TO BE HAZARDOUS BY INGESTION. CONSULT MD IF NECESSARY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>500F,>260C Extinguishing Media:USE WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:COMPLETE COMBUST GIVES HYDROGEN CHLORIDE, CARBON DIOXIDE, SULFUR OXIDE & WATER. INCOMPLETE COMBUST GIVES IN ADDN CARBON MONOXIDE, ORG ACIDS, (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY PRECAUTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. RECOVER UNDAMAGED AND MINIMALLY CONTAMINATED MA TERIAL FOR REUSE OR RECLAMATION. SHOVEL/SWEEP UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE. KEEP CONTAINER TIGHTLY CLOSED. USE ONLY WITH ADEQUATE VENTILATION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGE W/DUST/MIST CANISTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS LIM. PROT PROVIDED BY AIR PURIFYING RESPS IS LIMITED. (ING 4) Ventilation:LOCAL VENTILATION SHOULD BE USED OVER PROCESSING EQUIPMENT. Other Protective Equipment:IF POTENTIAL CONT W/HOT/MOLTEN MATL, WEAR HEAT RESIST CLTHG & FOOTWEAR. ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health TRADE NAME/PART #: 2-ETHYLHEXYL METHACRYLATE. EXPLO HAZ: ALDEHYDES, & ALCOHOLS. EFTS OF OVEREXP: & SORENESS IN NOSE & THROAT, TOGETHER W/COUGHING. CHRONIC: NONE KNOWN. WASTE DISP METH: COMBUST PRODS. TREATMENT, STOR, TRANSPORTATION, & DISPMUST BE I/A/W APPLIC FED, STATE, & LOC REGS. ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE Appearance and Odor:PALE CREAM CHIPS, WITH MILD CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:TEMPERATURES ABOVE 200C. Hazardous Decomposition Products:HAZARDOUS GASES/VAPORS PRODUCED ARE CARBON MONOXIDE, HYDROGEN CHLORIDE, AND ORGANIC ACIDS, ALDEHYDES, ALCOHOLS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREFERRED OPTIONS FOR DISP ARE (1) RECYCLING, (2) INCIN W/ENERGY RECOVERY, & (3) LANDFILL. HIGH FUEL VALUE OF THIS PROD MAKES OPTION 2 VERY DESIRABLE FOR MATL THAT CANNOT BE RECYCLED, BUT INCIN MUST B E CAPABLE OF SCRUBBING OUT ACIDIC (SUP DAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:H-251, THINNER CAGE:11931 CAGE:11931 ============= Composition/Information on Ingredients ============= Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 50% OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9192 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 25% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 25% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION TO SKIN, EYES, AND RESPIRATORY SYSTEM WHEN OVEREXPOSED. Effects of Overexposure:IRRITATION TO SKIN, EYES, AND RESPIRATORY SYSTEM WHEN OVEREXPOSED. Medical Cond Aggravated by Exposure:PULMONARY DISORDERS ======================= First Aid Measures ======================= First Aid:INHALATION: FRESH AIR AND TREATMENT FOR EFFECT OF SOLVENTS-CONTACT PHYSICIAN. EYES: FLUSH 10 MINUTES WITH CLEAN COOL WATER-CONSULT EYE PHYSICIAN. SKIN: WASH WITH MILD SOAP AND CLEAN WATER. INGESTION: DO NOT INDUCE VOMITING-CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:48F,8.8C Autoignition Temp:Autoignition Temp Text:997F Lower Limits:1.2 Upper Limits:7.1 Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRE IN CONFINED AREA. Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND. ELIMINATE ALL IGNITION SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AREA TO CONTAIN MATERIAL, PUMP INTO PROPER WASTE CONTAINER. CLEAN AREA WITH OIL ABSORBENCY MATERIAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT EXPOSE TO TEMPERATURE IN EXCESS OF 120F. Other Precautions:KEEP AWAY FROM SOURCES OF IGNITION OR OPEN FLAME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA SELF CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL (GENERAL): 60 FT./MIN. VENTILATION LOCAL: 20 FT./MIN. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING, RUBBER BOOTS Work Hygienic Practices:AFTER USE, WASH SKIN WITH MILD SOAP AND WATER. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:200F,93C Vapor Pres:25 Vapor Density:3.2 Spec Gravity:0.92 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR COLORLESS LIQUID, PLEASANT SWEET ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURE Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, HYDROCARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS FOR FLAMMABLE ORGANIC SOLVENTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TYPES 793/795 DRY SILVER PAPER CAGE:1LF36 CAGE:39711 CAGE:1LF36 ============= Composition/Information on Ingredients ============= Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 Fraction by Wt: 80-90% % Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:POLYVINYL BUTYRAL RESIN CAS:63148-65-2 RTECS #:TR4955000 Fraction by Wt: 2-5% % Other REC Limits:NONE RECOMMENDED Ingred Name:BEHENIC ACID CAS:112-85-6 Fraction by Wt: 1-3% % Other REC Limits:NONE RECOMMENDED Ingred Name:CELLULOSE ACETATE (RESIN) CAS:9004-35-7 Fraction by Wt: 2-5% % Other REC Limits:NONE RECOMMENDED Ingred Name:SILVER BEHENATE (SARA III) CAS:2489-05-6 Fraction by Wt: <1.0% % Other REC Limits:NONE RECOMMENDED OSHA PEL:0.01 MG/M3 (AG) ACGIH TLV:0.01 MG/M3 (AG) Ingred Name:2,2'-METHYLENE-BIS-6-(TERT BUTYL)-P-CRESOL CAS:119-47-1 RTECS #:PA3500000 Fraction by Wt: 1-3% % Other REC Limits:NONE RECOMMENDED Ingred Name:MERCURIC BROMIDE (SARA III) CAS:7789-47-1 RTECS #:OV7415000 Fraction by Wt: <0.1% % Other REC Limits:NONE RECOMMENDED OSHA PEL:S, C, 0.1 MG/M3 ACGIH TLV:S, 0.1 MG/M3 Ingred Name:SILVER BROMIDE (SARA III) CAS:7785-23-1 Fraction by Wt: <0.1% % Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO ADVERSE HEALTH EFFECTS, BECAUSE NO EXPOSURE IS EXPECTED. Explanation of Carcinogenicity:2,2'-METHYLENEBIS (6-TERT-BUTYL-P-CRESOL) FED TO RATS AT 50 MG/KG/DAY FOR 10 MONTHS CAUSES PHYSICAL CHANGE IN THE TESTES Effects of Overexposure:NONE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:NO NEED FOR FIRST AID IS ANTICIPATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Neutralizing Agent:NONE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM SOURCES OF IGNITION. Other Precautions:MAINTAIN REGULAR CLEANING OF IMAGING EQUIPMENT BY AN AUTHORIZED SERVICE TECHNICIAN TO AVOID DUST BUILDUP. AVOID SKIN AND EYE CONTACT OR INHALATION OF PAPER DUST THAT MAY COLLECT INSIDE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:USE IN A WELL-VENTILATED AREA. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:SLIGHT Appearance and Odor:WHITE COATED PAPER, SLIGHT ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:AVOID EXPOSURE TO LIGHT, ELEVATED TEMPERATURES, AND HUMID CONDITIONS. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, HYDROCARBONS, AND TRACES OF MERCURY OXIDES AND HYDROGEN BROMIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER = D009. MANUFACTURER RECOMMENDS RECLAMATION OF SILVER AND MERCURY AT PERMITTED SITE.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:METALCLAD SPEEDALLOY ACTIVATOR PART B Kit Part:Y Preparer's Name:F. LAUMAN CAGE:00933 CAGE:00933 ============= Composition/Information on Ingredients ============= Ingred Name:POLYMERCAPTAN. VP:0.01 Fraction by Wt: 40% Ingred Name:SILICA CAS:7631-86-9 Fraction by Wt: 54% OSHA PEL:0.1 MG/M3 (MFR) ACGIH TLV:0.1 MG/M3 (MFR) Ingred Name:SILICA DERIVATIVES; (COLLOIDAL SILICA) CAS:67762-90-7 Fraction by Wt: 2% OSHA PEL:20 MPPCF (MFR) ACGIH TLV:5 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAN CAUSE IRRITATION. MAY CAUSE CHEMICAL BURN IN EYES. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DERMATITIS. INHAL:CAN CAUSE RESPIRATORY IRRITATION. INGEST:SLIGHTLY TOXIC.IARC MONOGRAPHS CONCLUDE THERE IS LIMITED EVIDENCE OF CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MINS LIFTING EYELIDS OCCASNLY. GET MD PROMPTLY. SKIN:WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG PROMPLY. WASH CLTHG BEFORE REUSE. INGEST:DO NOT INDU CE VOM! KEEP PERS WARM, QUIET & GET MD.ASPIR OF MATL INTO LUNGS DUE TO VOM CAN CAUSE CHEM PNEUMONITIS WHICH CAN BE FATAL. INHAL:MOVE AFFECTED PERS TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM & WATER FOG. USE WATER FOR COOLING MATERIAL STORED IN VICINITY OF FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL/LARGE SPILL: SCRAPE UP/SOAK UP W/ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:EXPOSURE TO AIR WILL CAUSE SKINNING & RENDER MATERIAL UNFIT FOR USE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV OF PROD IS EXCEEDED, A NIOSH/MSHA APPRVD AIR SUPPLY RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RESPS UNDER SPECIFIED CNDTNS. (SEE YOUR S FTY EQUIP SUPPLIER.) (SUPP DATA) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:EYE WASH & SAFETY SHOWER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. RESP PROT:ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TOREDUCE EXPOSURE. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:1.63 Evaporation Rate & Reference:0 (N-BUTYL ACETATE=1) Appearance and Odor:CREAM COLOR PASTE; DISAGREEABLE ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZERS & ACIDS. Stability Condition to Avoid:KEEP AWAY FROM HEAT & OPEN FLAME. Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE & DIOXIDE; OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL/LARGE SPILL: INCINERATE OR LANDFILL IN ACCORDANCE W/ALL FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DIESEL FUEL ANTI-GEL M22-16 CAGE:77628 CAGE:77628 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETROLEUM DISTILLATE CAS:8002-05-9 Fraction by Wt: >50% ACGIH TLV:300 PPM Ingred Name:AROMATIC PETROLEUM DISTILLATE CAS:64742-95-6 Fraction by Wt: 15-30% ACGIH TLV:100 PPM Ingred Name:AROMATIC HYDROCARBON SOLVENT CAS:64742-94-5 Fraction by Wt: 15-30% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE:IRRITANT.SKIN:DEFATTING,DRYNESS,DERMATITIS.INHALATION:E XCESSIVE INHALATION CAN CAUSE DIZZINESS,STUPOR.INGESTION:HARMFUL IF SWALLOWED.IF ASPIRATED INTO LUNGS,CAN CAUSE LUNG IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE CONTACT:FLUSH EYE WITH WATER FOR 15 MIN.SKIN CONTACT:WASH WITH SOAP AND WATER.INHALATION:MOVE TO FRESH AIR.INGESTION:DO NOT INDUCE VOMITING.DRINK WATER.CONSULT PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:120F Extinguishing Media:FOAM,CO2,DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED,POSITIVE PRESSURE BREATHING APPARATUS AND PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH RAGS.OBSERVING HEALTH HAZARDS,REMOVE IGNITION SOURCES,VENTILATE AREA.CONFINE SPILL AND TRANSFER TO WASTE DRUM. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT TEMPERATURES BELOW 120F,AWAY FROM IGNITION SOURCES AND OXIDIZING AGENTS. Other Precautions:KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED WEAR NIOSH APPROVED RESPIRATOR. Ventilation:GENERAL Other Protective Equipment:NEOPRENE APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:320F Spec Gravity:0.8 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR AMBER LIQUID Percent Volatiles by Volume:>70% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Hazardous Decomposition Products:FIRE:NORMAL PRODUCTS OF COMBUSTION;CARBON DIOXIDE,CARBON MONOXIDE,SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE GOVERNMENT LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MEDIUM DRY AQUEOUS RECORDER INK, 61102BEMA Preparer's Name:GEORGE SARKISIAN CAGE:17405 CAGE:17405 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM, (4-(P-(DIMETHYLAMINO)-ALPHA-(P-(ETHYL(M-SULFOBENZYL) AMINO PHENYL) BENZYLIDE NE)-2,5-CYCLOHEXADIEN-1-YLIDENE)ETHYL(M-SULFOBENZYL)-,HYDROXIDE,INN ER SALT,SODIUM SALT;(C.I. ACID VIOLET 49, DYE) CAS:1694-09-3 RTECS #:BQ1140000 Fraction by Wt: 0.5-1.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER % (WT): 98.5 - 99.5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >98.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): >5 GM/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN: CAN CAUSE IRRITATION AND SKIN STAINING. EYES: CONTACT MAY CAUSE IRRITATION. INHALATION: INHALATION OF VAPORS MAY RESULT IN RESPIRATORY IRRITATION. INGESTION: MAY RESULT IN GASTRIC DISTURB ANCE. CHRONIC: NONE EXPECTED BASED ON EMPLOYEE HISTORY OF EXPOSURE. Explanation of Carcinogenicity:C. I. ACID VIOLET 49: IARC MONOGRAPHS, SUPP VOL 7, PG 56, 1987: GROUP 2B. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES MINIMUM. IF IRRITATION PERSISTS, GET PROMPT MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH SKIN THOROUGHLY WITH SOAP AND WATER. INHAL: REM OVE PERSON TO FRESH AIR. AID BREATHING IF NECESSARY AND GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP SPILLS WITH TOWELS OR CLOTHS. REMOVE STAINS WITH SOAPY WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENTS. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR, IF VAPORS OR MIST ARE GENERATED. Ventilation:MECHANICAL (GENERAL) VENTILATION IS SATISFACTORY. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VAPOR DENSITY: DUE TO H*2O ONLY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:DUE TO H*20 ONLY Vapor Density:SUPDAT Spec Gravity:1.038-1.055 (H*20=1) pH:4.0-8.0 Evaporation Rate & Reference:DUE TO H*2O ONLY Solubility in Water:COMPLETE Appearance and Odor:BLACK, RED, BLUE, GREEN, ORANGE, PURPLE; SLIGHT CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ACROLEIN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH EXISTING FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AROCLOR 1242 MIX, 32109 CAGE:0JL17 CAGE:0JL17 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYL (ARCOLOR 1242); (AROCHLOR 1242) CAS:53469-21-9 RTECS #:TQ1356000 Fraction by Wt: 0.1% OSHA PEL:1 MG/M3, S ACGIH TLV:1 MG/M3, S EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXANE CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 99.9% OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITANT, CONVULSIONS, UNCONSCIOUSNESS. CHRONIC: DERMATITIS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:DRYNESS AND ITCHING; MILD DEPRESSION, CONVULSIONS, UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: REMOVE CONT LENSES IF PRESENT. HOLD LIDS OPEN & IRRIGATE W/LG VOL OF WATER FOR @ LST 15 MIN. SEEK MED TRTMT. SKIN: IMMED WASH W/SOAP & WATER. CONTINUE RINSING W/LG VOL OF WATER FOR 15 MIN. INHAL : REMOVE TO FRESH AIR. RESTORE &/OR SUPPORT BRTHG. HAVE TRAINED PERSON ADMINISTER OXYGEN IF NEEDED. SEEK MED TRTMT. INGEST: DRINK LG QTY OF WATER. DO NOT INDUCE VOMIT. CONT POIS CTL CTR. ===================== Fire Fighting Measures ===================== Flash Point:-9F,-23C Lower Limits:1.2% Upper Limits:7.7% Extinguishing Media:DRY CHEMICAL, CO2, HALON, ALCOHOLS, FOAM, WATER SPRAY AS APPROPRIATE FOR SURROUNDING FIRE AND MATERIALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . KEEP FIRE-EXPOSED CONTAINERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:MAY FORM EXPLOSIVE VAPOR/AIR MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. ABSORB SMALL SPILLS ON PAPER, VERMICULITE, OR OTHER ABSORBENT. COLLECT AND STORE IN CLOSED CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE WITH UTMOST CARE. AVOID ALL CONTACT AND INHALATION. STORE IN AN EXPLOSION PROOF REFRIGERATOR @ 4C. KEEP IN A TIGHTLY CLSD CONTR @ ALL TIMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. Ventilation:USE IN AN AREA PROVIDED WITH GENERAL AND LOCAL EXHAUST VENTILATION MEETING OSHA REQUIREMENTS. Other Protective Equipment:PROTECTIVE CLOTHING MEETING LAB SAFETY REQUIREMENTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:>151F,>66C Vapor Pres:124@20C Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS/HYDROCARBON ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS LIKE LIQUID CHLORINE AND CONCENTRATED OXYGEN. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE AT AN APPROVED FACILITY I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEGREASER SOLVENT CAGE:0JVH6 CAGE:0JVH6 ============= Composition/Information on Ingredients ============= Ingred Name:ORANGE OIL, TERPENES (NON-HAZARDOUS) CAS:68647-72-3 Other REC Limits:NONE RECOMMENDED Ingred Name:PARAFFINIC OILS (NON-HAZARDOUS) CAS:64771-72-8 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRIT, TEARING, REDNESS. SKIN: DEFATTING, DRYNESS, DERMATITIS. INHAL: RESPIRATORY TRACT IRRIT, NAUSEA, DIZZY, HEADACHE. INGEST: ACUTE ORAL TOXICITY, NAUSEA, VOMIT, GI IRRIT, ASPIRATION INTO LUNGS . ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP AND WATER. INHAL: GET FRESH AIR. INGEST: DONT INDUCE VOMIT. PRODUCT CONTAINS HYDROCARBONS. IN ALL CASES, GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:144F,62C Autoignition Temp:Autoignition Temp Text:410F Lower Limits:1.3 Upper Limits:8.9 Extinguishing Media:CO2, FOAM, DRY CHEMICAL, CLASS B FOR FIRE PROCEDURES. Fire Fighting Procedures:COMBUSTIBLE LIQUID, CAN FORM COMBUSTIBLE MIXTURES AT OR ABOVE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:LAND SPILL: REMOVE IGNITS, CONTAIN SPILL, RECOVER FREE PRODUCTS, ABSORB W/SUITABLE CHEMICAL ABSORBENT FOR DISPOSAL. WATER SPILL: REMOVE FROM WATER BY SKIMMING, OR USE SUITABLE ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE TEMPERATURE AMBIENT KEEP AWAY FROM HEAT AND IGNITS. KEEP PRODUCT CONTAINER CLOSED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL DILUTION VENTILATION RECOMMENDED IN CONFINED AREAS, HEATED >AMBIENT TEMPERATURES OR IS AGITATED. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:380 TO 430F Vapor Pres:<1 @ 20C Vapor Density:>1 AIR=1 Spec Gravity:0.76 VOC Pounds/Gallon:756 pH:NA Evaporation Rate & Reference:3.2 N BUAC = 100 Solubility in Water:NON-MISCIBLE Appearance and Odor:COLORLESS LIQUID, W/CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR BURY IN APPROVED LANDFILL IN ACCORDANCE W/STATE, FEDERAL AND LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: 84-9802-0072-3 00-51111-43913-5, DISKETTE (SUPDAT) Cage: EO130 ======================================================= Contractor Summary ======================================================= Cage: 06XS2 Box: UNKNOW Cage: EO130 ======================================================= Ingredients ======================================================= Cas: 67-63-0 RTECS #: NT8050000 % Wt: 100 OSHA PEL: 400 PPM ACGIH TLV: 400 PPM; 500 STEL ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: MOD EYE IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELLING, PAIN, TEARING & HAZY VISION. SKIN: MILD SKIN IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELLING & ITCHING. INHAL: CNS DEPRESS: SIGNS/SYMPS CAN I NCL HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS & (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: UNCON. IRRIT (UPPER RESPIRATORY): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGHING & SNEEZING. INGEST: IRRIT OF GI TISSUES: SIGNS/SYMPS CAN INCL PAIN, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS & BLOOD IN FECES. CNS DEPRESS: SIGNS/SYMPS CAN INCL HEADACHE, DIZZINESS, DROWSINESS, MUSC WEAKNESS, INCOORD, SLOWED RXN TIME, FATIGUE, BLURRED VISION, SLURRED SPEECH, GIDDINE SS, TREMORS & CONVULSIONS. ASPIR PNEUM: SIGNS/SYMPS CAN INCLUDE COUGH, DFCLTY BRTHG, WHEEZING, COUGHING UP BLOOD & PNEUM WHICH CAN BE FATAL. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMED FLUSH EYES W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMED MED ATTN. SKIN: FLUSH SKIN W/LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MED ATTN. INHAL: IF SIGNS/SYMPS OCCU R, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPS CONTINUE, CALL MD. INGEST: IF SWALLOWED, CALL MD IMMED. ONLY INDUCE VOMITING AT INSTRUCTION OF MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING PHYSICAL & HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION & PERSONAL PROTECTIVE EQUIPMENT. IN USA CALL 612-733-1110 OR 612-733-6100 FOR 24-HR SP ILL ASSISTANCE. EXTINGUISH ALL IGNITION SOURCES. COVER W/ABSORBENT MATL. COLLECT SPILLED MATL. CLEAN UP RESIDUE. PLACE IN APPRVD METAL CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGS (FP N). INCINERATE IN AN INDUSTRIAL OR COMMERCIAL FACILITY. DISPOSE OF WASTE PRODUCT IN A FACILITY PERMITTED TO ACCEPT CHEMICAL WASTE. MATL TO BE DIS POSED HAS A US EPA HAZ NUMBER D001 (IGNITABLE). Handling And Storage Precautions: FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF IGNITION. Other Precautions: AVOID EYE CONTACT. AVOID SKIN CONTACT. DO NOT INGEST. KEEP OUT OF THE REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 53.0F,11.7C Lower Limits: 2.00% Upper Limits: 12.00% Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID BREATHING OF VAPORS.USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: USE IN A WELL-VENTILATED AREA. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: HEAD CLEANING KIT (FLUIDS AND PACKETS). ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 130F,54C Vapor Pres: 33 Vapor Density: 5.0 Spec Gravity: 0.600 (H*2O=1) VOC Grams/Liter: 785 Evaporation Rate & Reference: 0.80 (H*2O=1) Solubility in Water: 100 G/100 CC Appearance and Odor: CLEAR LIQUID; ALCOHOL ODOR. Percent Volatiles by Volume: 100 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 84-9802-0072-3 00-51111-43913-5, DISKETTE (SUPDAT) Cage: EO130 Assigned IND: Y Company Name: IMATION ENTERPRISES CORPORATION Street: 1 IMATION PLACE Zipcode: 55128-1110 Label Required IND: Y Date Of Label Review: 01/13/1997 Status Code: C Label Date: 01/13/1997 Origination Code: G Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: EYES: MODERATE EYE IRRITATION WITH REDNESS, SWELLING, PAIN, TEARING AND HAZY VISION. SKIN: MILD SKIN IRRITATION WITH REDNESS, SWELLING AND ITCHING. INHALATION: CNS DEPRESSI ON WITH HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS AND UNCONSCIOUSNESS. IRRITATION. INGESTION: IRRITATION OF GI TISSUE, CNS DEPRESSION, ASPIRATION PNEUMONITIS. CHRONIC: NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ECONOMISER CAGE:ALLXS CAGE:023L7 CAGE:ALLXS ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM OXIDE; (FUSED ALUMINUM OXIDE) (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 48-92% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICON CARBIDE CAS:409-21-2 RTECS #:VW0450000 Fraction by Wt: 48-92% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:FLUORIDE; (FLUORIDES (AS F)) CAS:16984-48-8 RTECS #:LU6290000 Fraction by Wt: 8-24% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SULFUR CAS:7704-34-9 RTECS #:WS4250000 Fraction by Wt: 1-8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IRON OXIDE (RED) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 2-10% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5MG(FE)/M3FUME, B2 Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: 0-1% OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MATERIALS GENERATED WHEN A WHEEL IS USED HAVE NOT BEEN IDENTIFIED BUT ARE CONSIDERED NUISANCE DUST BY FEDERAL OSHA. ACUTE: INHALATION: COUGHING, SHORTNESS OF BREATH. SKIN: SOME MAY EXPERIENCE SKIN IRR ITATION. EYES: DUSTS MAY IRRITATE. CHRONIC: MAY AFFECT BREATHING CAPACITY. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. ARTIFICIAL RESPIRATION AS NEEDED. OBTAIN MEDICAL ASSISTANCE. SKIN: WASH WITH SOAP AND WATER. OBTAIN MEDICAL ASSISTANCE. EYES: WASH WITH LARGE AMOUNTS OF WATER FOR AT L EAST 15 MINUTES. OBTAIN FIRST AID AND/OR MEDICAL ASSISTANCE IF NEEDED. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:PRODUCT IS NON-FLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE WHEELS IN A FLAT POSITION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL. SEE OSHA 29 CFR 1910.94. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WHEEL GUARD; SEE OSHA 29 CFR 1910.25. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:2-3 Solubility in Water:INSOLUBLE Appearance and Odor:BROWN TO BLACK SOLID, WITH TYPICAL RUBBER ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHAFOAM 220 ANTI-STATIC PLANK POLYETHYLENE CAGE:96717 CAGE:96717 ============= Composition/Information on Ingredients ============= Ingred Name:WAX/POLYETHYLENE FOAM CAS:8002-74-2 RTECS #:RV0350000 Fraction by Wt: 84- 100% Other REC Limits:NONE SPECIFIED Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 0 - 3% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:DICHLOROTETRAFLUOROETHANE (SARA III) CAS:76-14-2 RTECS #:KI1101000 Fraction by Wt: 0 - 11% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ozone Depleting Chemical:1 Ingred Name:ETHOXYLATED ALKYL AMINE/ANTI-STATIC ADDITIVE CAS:61791-44-4 Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYE:SOLID/DUST MAY CAUSE IRRITATION/CORNEAL INJURY.SKIN:NON-IRRITATING.MECHANICAL INJURY ONLY.INHALATION:DUST/VAPORS MAY CAUSE IRRITATION OF UPPER RESPIRATORY TRACT.INGESTION:MAY CAUSE CHOKING.C HRONIC-NONE Effects of Overexposure:DUST MAY CAUSE EYE IRRITATION/CORNEAL INJURY. MECHANICAL INJURY OF SKIN ONLY.DUST/VAPORS (AT HIGH TEMPERATURES) MAY CAUSE IRRITATION OF UPPER RESPIRATORY TRACT. INGESTION MAY CAUSE CHOKING. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.CONSULT A PHYSICIAN.EYES:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 5 MINUTES HOLDING EYELIDS OPEN.MECHANICAL EFFECTS ONLY.SKIN/INGESTION:NO ADVERSE EFFECTS ANTICIPATED.N OTE TO PHYSICIAN:NO SPECIFIC ANTIDOTE.SUPPORTIVE CARE.TREATMENT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE. COOL FIRE EXPOSED CONTAINERS WITH H2O Unusual Fire/Explosion Hazard:DENSE SMOKE ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP AND HANDLE AS ANY OTHER INERT MATERIAL. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN A COOL AREA AWAY FROM EXCESSIVE HEAT,FLAME/SOURCES OF IGNITION. Other Precautions:LARGE QUANTITIES OF THIS PRODUCT CAN CAUSE CORROSION OF HEATERS AND EVENTUALLY CREATE HOLES IN THE COMBUSTION CHAMBER LEADING TO THE RELEASE OF COMBUSTION GASES AND CARBON MONOXIDE. THIS PRODUCT IS CO MBUSTIBLE AND CAN BURN RAPIDLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATORY PROTECTION SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION. LOCAL EXHAUST VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS SUCH AS HOT-WIRE CUTTING. Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, WORK CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.02 - 0.06 Solubility in Water:INSOLUBLE Appearance and Odor:CELLULAR SOLID PLASTIC FOAM WITH NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:FIRE AND TEMPERATURES ABOVE 625F(329C) Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER TOXIC SUBSTANCES ==================== Disposal Considerations ==================== Waste Disposal Methods:REUSE OR BURY IN AN APPROVED LANDFILL. DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2242 HARD HAT FLUORESCENT TOPCOAT CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (IARC CARC- GROUP 3) *95-4* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 10% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 5% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:BUTANE, N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 10% Other REC Limits:800 PPM OSHA PEL:800 PPM ACGIH TLV:1900 MG/CUM Ingred Name:PROPANE (DIMETHYLMETHANE)*95-4* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 25% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:HEXANE, N-HEXANE CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 15% Other REC Limits:50 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:176 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY AFFECT THE BRAIN/NERVOUS SYSTEM. CAUSES NOSE & THROAT IRRITATION. SKIN: IRRITATION, DERMATITIS. EYES: IRRITATION. INGESTION: GI IRRITATION. SOLVENTS MAY CAUSE PERMANENT BRAIN/ NERVOUS SYSTEM DAMAGE. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:DIZZINESS, HEADACHE, NAUSEA, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA, IRRITATION, VOMITING, DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR, RESTORE BREATHING. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. KEEP WARM & QUIET. ASPIRA TION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<-25F Extinguishing Media:CO2, DRY CHEMICAL/FOAM Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. WATER SPRAY MAY BE INEFFECTIVE. USE WATER TO COOL CLOSED CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES, VENTILATE AREA & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. PROTECT FROM FREEZING. DON'T PUNCTURE/INCINERATE CONTAINERS. Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR TO REMOVE SOLID AIRBORNE OVERSPRAY PARTICLES & ORGANIC VAPORS DURING SPRAYING. CONFINED AREAS: NIOSH APPROVED SUPPLIED AIR RESPIRATORS/HOODS. Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN VOLUME & PATTERN TO KEEP TLVS < ACCEPTABLE LIMITS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health HEALTH HAZARDS CONT'D: OVEREXPOSURE TO TOLUENE, EFFECTS IN HUMANS HAVE INCLUDED LIVER & CARDIAC ABNORMALITIES. OVEREXPOSURE TO HEXANE IN HIGH VAPOR CONCENTRATIONS (1000-1500 PPM) OVER A PERIOD OF SEVE RAL MONTHS MAY CAUSE PERIPHERAL POLYNEUROPATHY WHICH HAS THE POTENTIAL OF BECOMING IRREVERSIBLE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:31-396F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:85-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAMES, HOT SURFACES, IGNITION SOURCES, FREEZING. Hazardous Decomposition Products:OPEN FLAME: CO, CO2, UNIDENTIFIABLE ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GALLIUM(III) OXIDE 99.9+%, 21506-6 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:GALLIUM OXIDE; (GALLIUM(III) OXIDE) CAS:12024-21-4 RTECS #:LW9650000 Fraction by Wt: 99.9%+ OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE AND SKIN IRRITATION. TO THE BEST OF MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IMMED FLUSH WITH COPIOUS AMOUNTS OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. IF NOT BR EATHING GIVE ARTF RESP. IF BREATHING ISDIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPRORPIATE FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL BAG AND HOLD FOR WASTE DISP. AVOID RAISING DUST. VENT AREA & WASH SPILL SITE AFTER MAT L PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHAL. AVOID CONT W/EYES, SKIN & CLTHG. AVOID PRLNGD/RPTD EXPOS. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:5.880 Appearance and Odor:WHITE CRYSTALLINE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL AND HAZARDOUS WASTES. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIROMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL, A452SK 1 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 OSHA PEL:200 PPM, S ACGIH TLV:200PPM/250STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, CYANURIC (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE PROTECTION (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHRONIC INHALATION & INGESTION MAY CAUSE EFFECTS SIMILAR TO THOSE OF ACUTE INHALATION & INGESTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: SYMPS MAY BE DELAYED. METABOLISM OF MEOH CAN BE PREVENTED BY ADMIN OF ETOH BY QUALIFIED MED PERS. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:OTHER PREC: AWAY FROM INCOMPATIBLE SUBSTANCES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 5628 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: KIDNEYS, CNS, LIVER, CARDIOVASCULAR SYS, EYES. ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMF UL AMTS. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT, RESP FAILURE, VASCULAR COLLAPSE & DMG, KIDNEY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT, LIVER & KIDNEY DMG. MAY CAUSE ADVERSE CNS EFTS INCL HDCH, CONVLS, & POSS DEATH. MAY CAUSE VISUAL IMPAIRMENT & POSS PERM BLINDNESS. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. CHRONIC: PRLNG/RPTD SKIN CONT CAN CAUSE DERM. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB EYES/KEEP EYES CLSD. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAS T 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 6) ===================== Fire Fighting Measures ===================== Flash Point:52.0F,11.1C Lower Limits:6.0% Upper Limits:36.0% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CONTRS CAN BUILD UP PRESS IF EXPOSED TO HEAT &/FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRIT & HIGHLY TOX GASES MAY BE (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP WITH A NON-SPARKING TOOL, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE THE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING AN ABSORBENT, NON-CO MBUSTIBLE MATERIAL SUCH AS EARTH, SAND. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID AND/OR VAPOR), AND CAN BE DANGEROUS. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS & OPEN FLAMES. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. KEEP AWAY FROM SOURCES OF IGNIT. STORE IN CO OL, DRY, WELL-VENTILATED AREA (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1010.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ: GENERATED BY THERMAL DECOMP/COMBUST. FLAMM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIXS AT TEMPS ABOVE FLASH POINT. MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSIUM & MA GNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, BERYLLIUM (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:147F,64C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:29 Vapor Density:1.1 Spec Gravity:0.8 (H*2O=1) pH:NEUT Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ALCOHOL-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
======================================================= Product ID: BERYLLIUM Cage: 0YZE5 Box: 30188 ======================================================= Contractor Summary ======================================================= Cage: 0YZE5 Box: 30180 ======================================================= Ingredients ======================================================= Cas: 7440-41-7 RTECS #: DS1750000 % Wt: 0.1 OSHA PEL: 0.002 MG/M3, Z-2 ACGIH TLV: .002 MG/M3, A2 ----------------------------- Cas: 7697-37-2 RTECS #: QU5775000 % Wt: 2 OSHA PEL: 2 PPM ACGIH TLV: 2 PPM/4 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE:INHALATION:MAY CAUSE MILD IRRITATION OF RESPIRATORY TRACT. AS A SUSPECTED CANCER HAZARD IN HUMANS BECAUSE OF BERYLLIUM COMPONENT INHALATION IS PRIMARY ROUTE OF EXPOSURE. INGESTION:SYMPTOMS ARE E XPECTED TO BE LESS SEVERE THAN EXPOSURETO HIGHER CONCENTRATIONS OF ACID (HYDROCHLORIC OR NITRIC) (EFTS OF OVEREXP) Explanation Of Carcinogenicity: BERYLLIUM:IARC MONO, SUPP, VOL 7, PG 127, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE CARCIN.(SUPDAT) Signs And Symptions Of Overexposure: HLTH HAZ:WHERE SYMP MAY INCL BURNING SENSATION, VOMITING & DIARRHEA. SKIN:SYMP ARE EXPECTED TO BE LESS SEVERE THAN EXPOSURE TO HIGHER CONC OF ACID (HYDROCHLORIC OR NITRIC) WHERE SYMP MAY INCL IRRITATI ON, REDNESS, PAIN & BURNS. CHRONIC:SUSPECTED CARCIN PROPERTIES IN HUMANS DUE TO INHALATION OF BERYLLIUM COMPOUNDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: CALL A PHYSICIAN. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). INGEST:DO NOT INDUCE VOMITING, IF CONSCIOUS GIVE WATER, MILK. EYES/SKIN:FLUSH WITH PLENTY OF WATER FOR @ LEA ST 15 MINUTES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE SOURCE OF IGNITION IF HYDROGEN IS A HAZARD. PROVIDE OPTIMUM VENTILATION. FLUSH TO HOLDING AREA OF NEUTRALIZATION. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS FOR ACID WASTE. EPA HAZARDOUS WASTE #P015. Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: LOCAL EXHAUST. Other Protective Equipment: LAB COAT/APRON; VENT HOOD. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: EXPLAN OF CARCIN:HUMAN:LUNG FIBROSIS. EYE PROT:FULL LENGTH FACESHIELD (FP N). ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Spec Gravity: 1 (H*2O=1) Evaporation Rate & Reference: NOT KNOWN Solubility in Water: COMPLETE Appearance and Odor: CLEAR, COLORESS, ODORLESS SOLUTION. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: METALS, HYDROXIDES, CARBONATES, CYANIDES. Materials To Avoid: STRONG REDUCING AGENTS. Hazardous Decomposition Products: NO, NO*2, GAS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: BERYLLIUM Cage: 0YZE5 Company Name: HIGH-PURITY STANDARDS INC Street: 2040 SAVAGE RD PO Box: 30180 Zipcode: 29417 Label Required IND: Y Date Of Label Review: 10/16/1995 Status Code: C Label Date: 10/16/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:INHALATION:MAY CAUSE MILD IRRITATION OF RESPIRATORY TRACT. AS A SUSPECTED CANCER HAZARD IN HUMANS BECAUSE OF BERYLLIUM COMPONENT INHALATION IS PRIMARY ROUTE OF EXPOSURE. INGESTION:SYMPTOMS ARE E XPECTED TO BE LESS SEVERE THAN EXPOSURETO HIGHER CONCENTRATIONS OF ACID (HYDROCHLORIC OR NITRIC) WHERE SYMPTOMS MAY INCLUDE BURNING SENSATION, VOMITING AND DIARRHEA. SKIN:MAY INCLUDE IRRITATION, REDNE SS, PAIN AND BURNS. CHRONIC:CANCER HAZARD. CONTAINS BERYLLIUM WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WT-230 CLT-100 CAGE:3V338 CAGE:3V338 ============= Composition/Information on Ingredients ============= Ingred Name:MORPHOLINE CAS:110-91-8 RTECS #:QD6475000 Fraction by Wt: 10% Other REC Limits:20 PPM OSHA PEL:S,20 PPM/30 STEL ACGIH TLV:S, 20 PPM; 9192 Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 8% Other REC Limits:5 MG/CUM (DUST) Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 3% Other REC Limits:2MG/M3 CEILING NIOSH OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN/INGESTION: CORROSIVE, HIGHLY IRRITATING & TISSUE DAMAGE/DESTRUCTION. INHALATION: CORROSIVE, HIGHLY IRRITATING TO RESPIRATORY TRACT & MUCOUS MEMBRANES, TISSUE DAMAGE/DESTRUCTION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN/INGESTION: CORROSIVE, HIGHLY IRRITATING, & TISSUE DAMAGE/DESTRUCTION. INHALATION: CORROSIVE, HIGHLY IRRITATING TO RESPIRATORY TRACT & MUCOUS MEMBRANE, TISSUE DAMAGE/DESTRUCTION. REPEATED TIS SUE DAMAGE MAY RESULT IN ACCUMULATION OF SCAR TISSUE. Medical Cond Aggravated by Exposure:ANY TISSUE IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE W/WATER FOR 15 MIN. SKIN: WASH OFF & RINSE THOROUGHLY W/WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. DRINK A SOLUTION OF VINEGAR & WATER FOLLOWED BY CLEAR W ATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NON-COMBUSTIBLE ================== Accidental Release Measures ================== Spill Release Procedures:DON'T DRAIN INTO SEWERS OR SURFACE WATERS. SOAK UP IN ABSORBENT MATERIAL & SEAL IN PROPERLY LABELLED NON-LEAKING CONTAINERS FOR PROPER HAZARDOUS WASTE DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN ORIGINAL SHIPPING CONTAINERS. KEEP CONTAINERS SEALED WHEN NOT IN USE. PROTECT FROM FREEZING. KEEP OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:AS REQUIRED Other Protective Equipment:RUBBER BOOTS & APRON, EYEWASH STATION & SAFETY SHOWERS. Work Hygienic Practices:DON'T EAT OR DRINK IN WORK AREAS. WASH HANDS BEFORE USING RESTROOM FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.12 Evaporation Rate & Reference:(WATER = 1): 1 Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID W/MORPHOLINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING & REDUCING AGENTS, ALUMINUM, & ACIDS. Stability Condition to Avoid:FREEZING, EXTREME HEAT Hazardous Decomposition Products:SULFUR OXIDES, NITROGEN, HYDROGEN GAS, & SULFUR DIOXIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AUTHORIZED HAZARDOUS WASTE DISPOSAL IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMMONIUM SULFATE Preparer's Name:MICHAEL RASZEJA CAGE:6V042 CAGE:6V042 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM SULFATE (SOLUTION) (SARA 313) CAS:7783-20-2 RTECS #:BS4500000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 3000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:LOW HAZARD AT TEMPERATURE BELOW 100C. ESSENTIALLY NON-TOXIC. EXCERCISE APPROPIATE PROCEDURES TO MIMIZE POTENTIAL HAZARD. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:CAUSES SNEEZING-MILD NOSEBLEED TO SENITIZED PERSONS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGESTION-IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF WATER TO DRINK & CALL PHYSCIAN. INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. SKIN-FLUSH THOROUGHLY WITH WATER, THEN WASH WITH MILD SOAP & WATER. EYES-FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE ANY SUITABLE FOR EXTINGUISHING SUPPORT FIRE. Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR A NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONCOMBUSTIBLE. MELTS & DECOMPOSES WITH EMISSION OF A MIXTURE OF AMMONIA & SULFUR TRIOXIDE AT ABOUT 455F. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. SWEEP UP SPILL AND PLACE IN A SUITABLE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER HANDLING. Other Precautions:AVOID CONTACT WITH SKIN, EYES AND CLOTHING. REMOVE AND WASH CONTAMINATED CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING. IF DUSTY CONDITION EXIST WORK IN VENTILATED HOOD OR WEAR A NIOSH APPROVED DUST MASK. Ventilation:LOCAL EXHAUST-YES. MECHANICAL-IF DUSTY. STATION, VENTILATION HOOD. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOSUHOLD USE. KEEP OUT OF REACH OF CHLIDREN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NA Decomp Temp:Decomp Text:536F,280C Vapor Pres:SOILD Vapor Density:4.6 Spec Gravity:1.769 Evaporation Rate & Reference:NA Solubility in Water:70.6 GRAMS/100ML Appearance and Odor:BROWNISH-GRAY TO WHITE CRYSTAL; ODORLESS. Percent Volatiles by Volume:NA Corrosion Rate:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS (POTASSIUM CHLORATE, POTASSIUM NITRATE, POTASSIUM NITRILE). Stability Condition to Avoid:EXCESSIVE TEMPERATURES AND HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO LOCAL, STATE AND FEDERAL LAWS. THESE DISPOSAL GUIDELINES ARE INTENDED FOR THE DISPOSAL OF CATALOG-SIZE QUANTITIES ONLY. DISSOLVE IN WATER AND FLUSHTO SEWER WITH COPIOUS AMOUNTS OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:169 3894 FLEXICOLOR STABILIZER & REPLENISHER, WORKING SOLN Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 95-100% Other REC Limits:NONE RECOMMENDED Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 96 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ORGANO SILICONE Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:NONIONIC SURFACTANT (NEW JERSEY TRADE SECRET: 80100185-5062P) Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHAL:FORMALDEHYDE DETECTABLE BY SOME @<1PPM.MILD SENSORY IRRIT OF EYE/NOSE/THROAT @2-5PPM,UNPLEASANT @5-10PPM,INTOLERABLE @HI CONCEN CAUSING SEVERE BURN SENS OF NOSE/THROAT W/COUGH.RESP SEN IN SOME.E YE:SEVERE BURNS.VAP IRRIT,TEARING.SKIN:IRRIT,ALLERGIC SKIN RX.INGEST:FATAL,BLINDNESS.CAN'T BE NONPOIS.BURNS(SIGNS/SYMPT) Explanation of Carcinogenicity:CONTAINS FORMALDEHYDE [50-00-0] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN FRM PART A. Effects of Overexposure:HEALTH HAZ:MOUTH,ESOPHAGUS,STOMACH.RETINAL/KIDNEY DMG MAY OCCUR.IMMED SEVERE ABD PAIN,W/VOMIT,NAU,DIARR,DIZZ,UNCONSC,COMA,ANURIA,CONVULS,DEATH. HI CONCEN INHAL OF FORMALDEHYDE:CHEST CONSTRICTION,HEADA CHE,BRONCHOPNEUMONIA,DYSPHAGIA,EDEMA,SPASMS OF LARYNX/DYSPNEA. Medical Cond Aggravated by Exposure:EXPOSURE TO FORMALDEHYDE AMY CAUSE RESP SENSITIZATION IN SOME INDIVIDUALS OR AGGRAVATE PRE-EXISTING ASTHMATIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.SYMPTOMS OCCUR GET MED ATTN. EYES:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS.GET MED ATTN. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS WHILE REMOVING CONTAMIN CLOTH/SHOES.IRRIT/ALLERGIC SKIN REACTION DEVELOPS GET MED ATTN. INGEST:DRINK 1-2 GLASSES OF WAER.SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE,NON-COMBUST Lower Limits:NA Upper Limits:NA Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB W/VERMICULITE OR O Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY FROM INCOMPATIBLE MATERIALS. USE ONLY WITH ADEQUATE VENTILATION. Other Precautions:WASH THOROUGHLY AFTER HANDLING. DO NOT BREATH VAPOR. DO NOT GET IN EYES, ON SKIN, ON CLOTHES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A FULL FACEPEICE WITH CARTIDGES OR CANISTERS SPECIFICALLY APPROVED BY NIOSH FOR PROTECTION AGAINST FORMALDEHYDE OR A TYPE C SUPPLIED AIR RESPIRATOR OR AN APPROPRIATE NIOSH APPROVED RESPIRATOR FOR ORGA NIC VAPORS SHOULD BE WORN IF NEEDED. Ventilation:LOCAL EXHAUST VENTILATION OR AN ENCLOSED HANDLING SYSTEM MAY BE NEEDED TO CONTROL AIR CONTAMINANTS. Other Protective Equipment:USE CHEMICAL PROTECTIVE CLOTHING MADE MATERIAL IMPERVIOUS TO FORMALDEHYDE AND THE USE OF OTHER PROTECTIVE CLOTHING. Work Hygienic Practices:THE ROUTINE USE OF A NON-ALKALINE (ACID) TYPE OF SKIN CLEANER & REGULAR CLEANING OF WORKING SURFACE. Supplemental Safety and Health MSDS IS FOR WORKING SOLUTION. SEE PNI B FOR PART B; PNI A FOR PART A. KIT CONSISTS OF PART A, 1-6 OUNCE BOTTLE OF FORMALDEHYDE SOLUTION; PART B 1-1 OUNCE BOTTLE OF NON-HAZARDOUS LIQUID-WHICH WHEN MIXE D WITH WATER MAKE 5 GALLONS WORKING SOLUTION. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:18 @20C Vapor Density:0.6 Spec Gravity:1.00 pH:7.2 Evaporation Rate & Reference:NP Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, FORMALDEHYDE ODOR. Percent Volatiles by Volume:100 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE W/COMMON MATLS & CONTAMINANTS W/WHICH THE MATL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE (NON-COMBUSTIBLE). ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER OR CONTACT A LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE MAY BE SUBJECT TO LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FLYTEK FLY BAIT CAGE:51112 CAGE:8C885 CAGE:51112 ============= Composition/Information on Ingredients ============= Ingred Name:METHOMYL (LANNATE)(SARA III) CAS:16752-77-5 RTECS #:AK2975000 Other REC Limits:NONE SPECIFIED OSHA PEL:2.5 MG/M3 ACGIH TLV:2.5 MG/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SUCROSE CAS:57-50-1 RTECS #:WN6500000 Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9192 Ingred Name:9-TRICOSENE,(Z)- CAS:27519-02-4 RTECS #:YD0807000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) = 3,000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE OF THE LISTED INGREDIENTS IS A CARCINOGEN ACCORDING TO NTP, IARC, OSHA. Effects of Overexposure:SEE HEALTH HAZARDS SECTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:PRODUCT IS A CHOLINESTERASE INHIBITOR.ATROPINE IS ANTIDOTAL.IN CASE OF TOXIC SIGNS,I.V.ADMINISTRATION TO EFFECT MAY BE PREFERABLE.IF SWALLOWED,CALL A PHYSICIAN IMMEDIATELY.IF CONSCIOUS,DRINK 1 OR 2 GL ASSES OF WATER & INDUCE VOMITING.IF ON SKIN,WASH WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING & CLEAN BEFORE REUSE.IF IN EYES,IMMEDIATELY FLUSH WITH GENTLY FLOWING WATER & CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL FOR SURROUNDING FIRE.WATER MAY INCREASE CONTAMINATION HAZARD. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH-APPROVED POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. MOVE PEOPLE UPWIND FROM FIRE/SMOKE. Unusual Fire/Explosion Hazard:WILL IGNITE IF EXPOSED TO INTENSE HEAT/OPEN FLAME. BURNING PRODUCES TOXIC FUMES AND CARBON MONOXIDE FROM INCOMPLETE COMBUSTION.FIRE/HEAT MAY RUPTURE CONTAINER. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL AMOUNTS MAY BE SWEPT UP AND SPREAD IN PLANNED USE AREAS AS DIRECTED ON LABEL OR PLACED IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,VENTILATED AREA.MAY BE HARMFUL IF SWALLOWED,INHALED,OR ABSORBED THROUGH SKIN.KEEP AWAY FROM FOODSTUFFS,CHILDREN & ANIMALS. Other Precautions:DO NOT CONTAMINATE FEED OR FOODSTUFFS.DO NOT BREATHE FUMES OR VAPORS.DO NOT GET ON SKIN OR IN EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PROLONGED EXPOSURE IS EXPECTED OR IN EXCESSIVE AIRBORNE EXPOSURES, WEAR AN MSHA/NIOSH APPROVED PESTICIDE RESPIRATOR (ORGANIC VAPOR CARTRIDGE PLUS DUST PREFILTER) IN COMPLIANCE WITH CFR 29-1910,34. Ventilation:MECHANICAL (GENERAL) Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER RECOMMENDED. INDUSTRIAL-TYPE WORK CLOTHING. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T5 Spec Gravity:>1 Solubility in Water:SOLUBLE Appearance and Odor:SOLID YELLOW GRANULES WITH CHARACTERISTIC SULFUROUS ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS AND REACTIVE METALS. Stability Condition to Avoid:HIGH TEMPERATURES AND FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:PESTICIDE THAT CANNOT BE USED ACCORDING TO LABEL SHOULD BE DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CALCIUM CHLORIDE FLAKE, 77-80% Preparer's Name:ALICE MARTINO CAGE:2R467 CAGE:2R467 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CHLORIDE CAS:10043-52-4 RTECS #:EV9800000 Fraction by Wt: 90-92% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Fraction by Wt: 1-2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM CHLORIDE CAS:7447-40-7 RTECS #:TS8050000 Fraction by Wt: 2-3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM CHLORIDE; (POTASSIUM CHLORIDE TRACE MINERAL SALTS) CAS:7447-40-7 RTECS #:TS8050000 Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF THE MD IN RESPONSE TO RXNS OF THE PATIENT. RTECS #:9999999ZZ Ingred Name:SPILL PORC:SPILLED PROD, CREATING A SLIPPING HAZ. AVOID BY THOROUGHLY H*2O RINSING SURFS. LRG SPILL:WEAR (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:APPROP, IMPERVIOUS SAFETY APPAREL DURING CLEAN-UP: SEE OTHER PREC SECTION. IF POSS, RECOVER QUICKLY INTO (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:SUITABLE DRY, SEALABLE CNTNRS FOR REUSE. AVOID ENTRY OF LRG AMT OF PROD INTO SEWERS, NATURAL WATERS, & (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:DRINKING WATER SCOURCES. MINIMIZE CONTACT WITH VEGETATION, ANIMALS AND FISH LIFE. RTECS #:9999999ZZ Ingred Name:VENT:10 MG/CUM. THERE IS NOT OSHA PEL OR ACGIH TLV FOR CALCIUM CHLORIDE. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CNTCT W/CALCIUM CLORIDE. EMPTY CNTNRS USUALLY CONTAIN A RESIDUE. ALL PRECS ARE TO BE OBSERVED. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:PROFESSIONALLY RECONDITION FOR REUSE/PROPERLY DISPOSE OF "EMPTY" CNTNRS. FOLLOW NORMAL GOOD HOUSEKEEPING (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:PRACTICES TO AVOID SKIN/EYE CNTCT, AVOID BRTHG DUST, & NOT SMOKING/EATING IN AREA. SKIN PROT:FOR BRIEF (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:CNTCT, NO PRECS OTHER THAN CLEAN BODY-COVERING CLTHG SHOULD BE NEEDED. PROT CLTHG IMPERVIOUS TO THIS MATL(ING 16) RTECS #:9999999ZZ IMPERVIOUS TO THIS MATL. IF SKIN COMES IN CONTACT W/CALCIUM (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:CHLORIDE/W/CONTAMINATED CLOTHING, WASH SKIN AREA WITH SOAP AND WATER; LAUNDER CLOTHING BEFORE REUSE. (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:IT IS GENERALLY RECOGNIZED THAT CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF AN EYE INJURY. RTECS #:9999999ZZ Ingred Name:MATLS TO AVOID:CHLORIDE WHICH IS CORROSIVE, IRRITATING AND REACTIVE. REACTS W/WATER-REACTIVE MATERIALS SUCH AS SODIUM. RTECS #:9999999ZZ Ingred Name:EYE PROT:AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAUSES MOD TO SEV IRRIT W/CORNEAL INJURY, WHICH MAY BE SLOW TO HEAL. WHEN DISSOLVING, THE HEAT PRDCED MAY CAUSE MORE INTENSE EFTS AS WELL AS THERMAL BURNS. SKIN:SHORT, SINGLE EXPOS NOT LIKELY TOCAUSE SIGNIFICANT SKIN IRRIT. PRLNG/RPTD EXPOS MAY CAUSE IRRIT, EVEN A BURN. MAY CAUSE MORE SEVERE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:RESPONSE IF SKIN IS DAMP &/ABRADED (SCRATCHED/CUT)/IF MATL IS CONFINED TO SKIN. WHEN DISSOLVING, HEAT GENERATED MAY CAUSE MORE INTENSE EFTS AS WELL AS THERMAL BURNS. INGEST:SINGLE DOSE TOX IS LOW. SMALL AMTS SWALLOWED INCIDENTAL TO NORM HNDLG NOT LIKELY TO CAUSE INJURY. LRG AMTS MAY CAUSE INJURY. (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IRRIGATE W/FLOWING H*2O IMMEDIATELY & CONTINUOUSLY FOR AT LEAST 15 MIN. CONSULT MED PERS. SKIN:WASH OFF IN FLOWING H*2O/SHOWER. INGEST:SEEK MED ATTN. DO NOT INDUCE VOMIT UNLESS DIRECTED TO DO SO BY MED PERS. (NEVER GIVE ANYTHING BY MOUTH/ATTEMPT TO INDUCE VOMIT IN AN UNCON PERS.) INHAL:REMOVE TO FRESH AIR IF EFTS OCCUR. CONSULT A MD. NOTE TO MD:IF BURN IS PRESENT, TREAT AS ANY THERMAL(SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROPRIATE TO SOURCE OF FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:LOSSES INCIDENTAL TO CORRECT APPLICATN OF THIS PROD IN ITS INTENDED USES ARE NOT EXPECTED TO BE HARMFUL TO THE ENVIRONMENT. SMALL QTIES MAY BE FLUSHED AWAY W/PLENTY OF H*20. WALKING SURF MAY REMAIN WE T LONGER DUE TO MOISTURE BEING HELD BY (ING 7) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY AREA; KEEP CNTNR CLSD. WHEN EXPOSED TO THE ATM, CALCIUM CHLORIDE WILL PICKUP H*2O, FORM A SOLN OR CAKE THE EXPOSED SURFACE OF THE MATL. Other Precautions:IF DISSOLVING CALCIUM CHLORIDE TO MAKE A SOLN:ALWAYS USE COOL H*2O (<80F,27C); HEAT WILL BE GENERATED WHEN CALCIUM CHLORIDE DISSOLVES. ALWAYS ADD CALCIUM CHALORIDE TO H*20 WHILE STIRRING. LEATHER CLTH G & SHOES WILL BE DMGD BY (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN DUSTY ATMOSPHERES USE A NIOSH APPROVED DUST RESPIRATOR. Ventilation:GENERAL &/LOC EXHST VENT TO CONTROL AIRBORNE LEVELS BELOW THE EXPOS GUIDELINES. MFRS EXPOS GUIDELINE IS (ING 11) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH AFTER HNDLG & BEFORE EATING, DRINKING/SMOKING. TO AVOID SECONDARY EXPOS, SHOWER & WASH GARMENTS AFTER HNDLG. Supplemental Safety and Health SOL IN H*2O:VERY SOLUBLE. CALCIUM CHLORIDE IS HYDROSCOPIC (ABSORBS MOISTURE FROM ENVIRONMENT). EFTS OF OVEREXP:INGEST MAY CAUSE IRRIT OF THE MOUTH, THROAT & GI TRACT. INHAL:DUST MAY CAUSE IRRIT TO UPP ER RESP TRACT. VAPS ARE UNLIKELY DUE TOPHYSICAL PROPERTIES. FIRST AID PROC:BURN AFTER DECONTAMINATION. (ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:347F,175C Vapor Pres:1.0 @ 20C Spec Gravity:1.85 Solubility in Water:SUPDAT Appearance and Odor:FLAKE, WHITE TO OFF-WHITE SOLID FLAKE; ODOR: NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WILL CORRODE MOST METALS; ATTACKS ALUMINUM, ITS ALLOYS & YELLOW BRASS. REACTS W/SULFURIC ACID TO FORM HYDROGEN (ING 20) Stability Condition to Avoid:DECOMPOSES AT 349F. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL LAWS, REGULATIONS AND PROCEDURES. PRODUCT AS SOLD IS NOT A RCRA LISTED OR CHARACTERISTIC HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2-101200-1, 30903861 FIREX CARTRIDGE Preparer's Name:JOEL GEVING CAGE:54181 CAGE:54181 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD AZIDE CAS:13424-46-9 RTECS #:OF8650000 Fraction by Wt: <1% Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 Fraction by Wt: <1% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:POTASSIUM PERCHLORATE CAS:7778-74-7 RTECS #:SC9700000 Fraction by Wt: <1% Ingred Name:GRAPHITE CAS:7782-42-5 RTECS #:MD9659600 Fraction by Wt: <0.1% Other REC Limits:2.5MG/CUM ACGIH TLV:2 MG/CUM RESP IC Ingred Name:1,1-DIFLUOROETHENE, TETRAFLUOROETHENE, 1,1,2,3,3,3-HEXAFLUORO-1-PROPANE POLYMER CAS:25190-89-0 Fraction by Wt: <0.1% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IF PRODUCT SEAL RUPTURES, MAY CAUSE IRRITATION. INHALATION: RESPIRATORY IRRITANT. INGESTION: POISONOUS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION Medical Cond Aggravated by Exposure:PRE-EXISTING PULMONARY DISEASES SUCH AS EMPHYSEMA, ASTHMA. ======================= First Aid Measures ======================= First Aid:EYES: IF EXPOSED TO FRAGMENTATION, BANDAGE EYES. IGNITION BYPRODUCTS, REMOVE CONTACT LENSES IMMEDIATELY, FLUSH W/WATER FOR 15 MINS. SKIN: WASH OFF ANY RESIDUE W/SOAP & WATER. INHALATION: REMOVE TO FRE SH AIR. GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: USE SUPPORTIVE CARE. TREATMENT SHOULD BE BASED ON JUDGEMENT OF PHYSICIAN & REACTIONS OF THE PATIENT. ===================== Fire Fighting Measures ===================== Extinguishing Media:PERMANENTLY-INSTALLED: AUTOMATIC WATER SPRINKLER/DELUGE SYSTEM IS RECOMMENDED. Fire Fighting Procedures:DON'T ATTEMPT TO MANUALLY FIGHT FIRES. IMMEDIATELY EVACUATE AREA, USING AS MUCH PROTECTIVE COVER AS POSSIBLE & ACTIVATE DELUGE & ALARM SYSTEMS. Unusual Fire/Explosion Hazard:SENSITIVE TO SHOCK/IMPACT/FRICTION/STATIC DISCHARGE/HIGH PRESSURE/TEMP. MAY DEFLAGRATE/DETONATE IF EXPOSED RELEASING TOXIC FUMES/HEAT/SHOCK WAVES & FRAGMENTS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: IF SEAL RUPTURES, BARRICADE AREA, ELIMINATE IGNITION SOURCES. USE A SOFT BRISTLE BRUSH & A CONDUCTIVE RUBBER PAN/RUBBER SHOVEL TO CLEAN UP. USE CONDUCTIVE CONTAINERS & GROUND ALL CONTAINERS WHE N TRANSFERRING MATERIAL. (SEE SUPP) ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN APPROVED STORAGE MAGAZINES ONLY. STORAGE & HANDLING MUST CONFORM TO APPROPRIATE QUANTITY/DISTANCE REQUIREMENTS, BARRICADING/GROUNDING/LIMITS. Other Precautions:KEEP PRODUCT COOL & DRY IN STORAGE. HANDLING & USE OF EXPLOSIVES & RELATED DANGEROUS MATERIALS MUST BE LIMITED TO PERSONNEL AUTHORIZED/TRAINED IN THIS AREA. REFER TO ON INSTRUCTIONS TO HANDLING, STORA GE, USE & DISPOSAL OF EXPLOSIVES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSED TO PARTICULATE MATTER. USE A NIOSH/MSHA APPROVED RESPIRATOR FOR PROTECTION AGAINST TOXIC GASEOUS IGNITION BYPRODUCTS. Ventilation:GENERAL MECHANICAL: MODERATE FLOW FOR PARTICULATE/IGNITION BYPRODUCT REMOVAL. EXPLOSION PROOF EQUIPMENT IS REQUIRED. Other Protective Equipment:100% COTTON UNDERWEAR & FLAME-RESISTANT, FULL-BODY COVERALLS, CONDUCTIVE SHOES, SAFETY SHOWER/EYEWASH/LAUNDRY FACILITIES Supplemental Safety and Health SPILL CONT': LARGE: SOIL-REMOVE ALL CONTAMINATED SOIL, DISPOSE OF AS HAZARDOUS WASTE. WATER: FLUSH W/COPIOUS AMOUNTS OF WATER. COLLECT TO DISPOSE OF AS HAZARDOUS WASTE. ================== Physical/Chemical Properties ================== Spec Gravity:>1 Solubility in Water:<0.1% Appearance and Odor:METALLIC ORDNANCE HARDWARE; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OTHER HAZARDOUS MATERIALS Stability Condition to Avoid:SHOCK, IMPACT, FRICTION, ELECTROSTATIC DISCHARGE, HIGH PRESSURE, HIGH TEMPS, OPEN FLAME, CHEMICAL/PHYSICAL CONTAMINATION Hazardous Decomposition Products:LEAD, ZIRCONIUM & FLUORINE COMPOUNDS, HYDROGEN FLUORIDE GAS, POTASSIUM CHLORIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:EXPLOSIVES/DANGEROUS MATERIAL SHOULD BE DESTROYED BY OPEN BURNING/OPEN DETONATION IN AN APPROVED INCINERATOR. BY CHEMICAL TREATMENT/DESTRUCTION. CONTAMINATED PROPERTY MUST NOT BE BURIED. DISPOSE OF IA W/LOCAL, STATE & FEDERAL REGULATIONS. D003/D008.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARDROX 9D6/D495A Preparer's Name:SHEREE L.KINZEL CAGE:23373 CAGE:23373 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 87.0% Other REC Limits:NONE SPECIFIED OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:OTHER COMPONENTS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE HEADACHE,DIZZINESS,NAUSEA AND VOMITING. REDNESS/TEAR OR BURNS OF EYES/SKIN POSSIBLE.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATI TIS. Explanation of Carcinogenicity:DATA PER MSDS Effects of Overexposure:MAY CAUSE IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;MAY CAUSE HEADACHE,DIZZINESS,NAUSEA,VOMITING OR GI TRACT DISTURBANCES POSSIBLE.BURNS OR REDNESS OF EYES/CRACKING OR DRYNESS OF SKIN. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CO*2 AND WATER FOG Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE DUE TO EXTREME HEAT.TOXIC VAPORS OF PHOSGENEN ARE EXPECTED ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;REMOVE ALL IGNITION SOURCES. CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY FROM NAKED FLAMES. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:165F,74C Vapor Pres:110 Vapor Density:4.5 Spec Gravity:1.3 Evaporation Rate & Reference:6.0 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE POWDER SUSPENDED IN COLORLESS LIQUID,CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES,ALKALI METALS. Stability Condition to Avoid:HIGH TEMPERATURES ,SPARKS AND NAKED FLAMES. Hazardous Decomposition Products:HYDROGEN CHLORIDE ;VERY SMALL AMOUNT OF PHOSGENE AND CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IODINE MONOCHLORIDE, 98% 20822-1 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE CHLORIDE (IODINE MONOCHLORIDE, 98%) CAS:7790-99-0 RTECS #:NN1650000 Fraction by Wt: 98% . RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INGESTED, INHALED OR ABSORBED THROUGH SKIN. MATL IS EXTREMELY DESTRUCTIVE TO TISS OF MUC MEMB & UPPER RESP TRACT, EYES & SKIN. INHAL MAY BE FATAL AS RESULT OF SPASM, INFLAMM & EDEMA O F LARYNX & BRONCHI, CHEM PNEUMONITIS & PULMONARY EDEMA. WARNING:ATTACKS SKIN, FORMING DARK, PAINFUL (SEE SUPP DATA) Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/FINGERS. SKIN:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR 15 MINUTES WHILE REMOVING CONTAM CLTHG/SHOES. WASH CONTAM CLTHG BEFORE REUSE. DISCARD CONTAM SHOES. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP), CALL MD. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL POWDER. DO NOT USE WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPRVD SCBA, PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPELTE. Neutralizing Agent:SEE WASTE DISPOSAL METHOD. ======================Handling and Storage ====================== Handling and Storage Precautions:REFRIGERATE. HANDLE/STORE UNDER NITROGEN. KEEP TIGHTLY CLOSED. AVOID PRLNGD/RPTD EXPOSURE. DO NOT GET IN EYES, ON SKIN OR CLTHG. Other Precautions:LIGHT SENSITIVE. AIR & MOISTURE SENSITIVE. CORROSIVE. IODINE MONOCHLORIDE EXPLODES ON CNTCT W/POTASSIUM WHILE A MIXTURE W/SODIUM EXPLODES ONLY ON IMPACT. ALUMINUM FOIL IGNITES ONLY AFTER PRLNGD CNTCT. ON MIXING W/PHOSPHOROUS (SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN CHEMICAL FUME HOOD. Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. FACESHIELD (8-INCH MINIMUM). Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health HLTH HAZ:PATCHES. EFTIVE COUNTERMEASURE.IMMED WASH W/20% HYDROCHLORIC ACID, FOLLOW BY FLUSHING FOR AT LEAST 15 MIN W/WATER. WASTE DISP METH:GENERATE HEAT & FUMES WHICH CAN BE CONTROLLED BY RATE OF ADD ITION. OBSERVE ALL FED, STATE & LOCAL LAWS. OTHER PREC:TRICHLORIDE, AN INTENSELY EXOTHERMIC REACTION OCCURS. (INGRED-02) ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:207F,97C Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= STRONG BASES. Stability Condition to Avoid:AIR AND MOISTURE SENSITIVE, MAY DISCOLOR ON EXPOSURE TO LIGHT. Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, HYDROGEN IODIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL QTYS:SLOWLY ADD TO LG STIRRED EXCESS OF WATER. ADJUST PH TO NEUTRAL, SEPARATE ANY INSOLUBLE SOLIDS/LIQS & PACKAGE FOR HAZ WASTE DISP. FLUSH AQUEOUS SOLN DOWN DRAIN W/PLENTY OF WATER. HYDROLYSIS/ NEUTRALIZATION REACTIONS MAY (SEE SUPP DATA)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5255 HIGH PERFORMANCE ACRYLIC COATING CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 5% Ingred Name:DIETHYLENE GLYCOL METHYL ETHER, 2-(2-METHOXYETHOXY) ETHANOL METHYL CARBITOL CAS:111-77-3 RTECS #:KL6125000 Fraction by Wt: 0.3% Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF NOSE, THROAT & LUNGS. SKIN/EYES: PRIMARY IRRITANT. INGESTION: GI IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, VOMITING, DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH AFFECTED AREA W/SOAP & WATER. INGESTION: DILUTE STOMACH CONTENTS W/TWO GLASSES OF WATER & INDU CE VOMITING BY EITHER GIVING IPECAC SYRUP/BY PLACING TWO FINGERS AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>200F Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILD-UP OF STEAM. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILD-UP OF STEAM. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP LIQUID W/ABSORBENT & SHOVEL INTO WASTE CONTAINER. WASH AREA W/WATER & FLUSH TO SEWER SERVICED BY WASTE WATER TREATMENT FACILITY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLICATION. Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP TLV BELOW ACCEPTABLE LIMITS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:302-385F Vapor Density:>1 pH:8-9.2 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:60-70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXTREME HEAT, OPEN FLAME, FREEZING. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5102, SOLID COLORS AUTOMOTIVE TOUCH-UP CAGE:9P972 CAGE:86142 CAGE:9P972 ============= Composition/Information on Ingredients ============= Ingred Name:ING 4: USED TO EFFECTIVELY MINIMIZE EMPLOYEE EXPOSURE: LOC EXHST VENT, ENCLOSED SYS DESIGN, PROCESS ISOLATION (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: & REMOTE CONTROL IN COMBINATION W/APPROP USE OF PERSONAL PROTECTIVE EQUIPMENT & PRUDENT WORK PRACTICES. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: THESE TECHNIQUES MAY NOT NECESSARILY ADDRESS ALL ISSUES PERTAINING TO YOUR OPERATIONS. WE, THEREFORE, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: RECOMMEND THAT YOU CONSULT WITH EXPERTS OF YOUR CHOICE TO DETERMINE WHETHER OR NOT YOUR PROGRAMS ARE ADEQUATE. RTECS #:9999999ZZ Ingred Name:2-PENTANONE, 4-METHYL; (METHYL ISOBUTYL KETONE) (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 30-50% OSHA PEL:50 PPM;75 STEL ACGIH TLV:50 PPM;75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CYCLOHEXANONE (SARA III) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: 5-10% OSHA PEL:25 PPM, S ACGIH TLV:25 PPM, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENE (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10-30% OSHA PEL:100 PPM;150 STEL ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA: BELOW ACCEPTABLE CRITERIA. ENGINEERING CONTROLS: THE FOLLOWING EXPOSURE CONTROL TECHNIQUES MAY BE (ING 5) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN ABSORP/INGEST: NOT EXPECTED TO BE HARMFUL UNDER NORMAL CONDITIONS OF USE. IF ACCIDENTALLY SWALLOWED, BURNS OR IRRIT TO MUC MEMBS, ESOPHAGUS OR GI TRACT CAN RESULT. INHAL:MAY BE HARMFUL IF INHALED. LIQ/VAP MAY CAUSE IRRIT OF NOSE, THROAT & LUNGS. SKIN: MAY CAUSE IRRIT ON PROLONGED OR (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: REPEATED CNTCT. EYES: CAUSES IRRIT. INGRED 1: CAN CAUSE CNS DEPRESS. SIGNS & SMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT, UNCON & EVEN ASPHY. INGRED 2 & 3: CAN CAUSE LIVER & KIDNEY DMG. CAN CAUSE CNS DEPRESS. SIGNS & SYMPS MAY INCLUDE HDCH, DIZZ, NAUS, VOMIT, UNCON & EVEN ASPHY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN ABSORP:IMMED FLUSH EYE/SKIN W/PLENTY OF WATER FOR @ LST 15 MIN. INGEST: DILUTE BY DRINKING LRG QTYS OF WATER. IMMED CNTCT POIS CTL CTR/HOSPITAL EMERGENCY ROOM FOR ANY OTHER ADDITIONAL TREATMENT D IRECTIONS. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. SKIN:FLUSH WITH WATER. EYE:IMMED FLUSH W/ PLENTY OF WATER FOR @ LST 15 MIN. EYELIDS SHOULD BE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:65.3F,18.5C Extinguishing Media:USE DRY CHEMICAL, "ALCOHOL" FOAM OR CO2. WATER MAY BE INEFTIVE, BUT SHOULD BE USED TO COOL FIRE-EXPOSED CNTNRS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:KEEP LIQ & VAP AWAY FROM HEAT, SPARKS, FLAME & OTHER IGNIT SOURCES INCL, BUT NOT LIMITED TO, PILOT LIGHTS, HEATERS, CIGARETTES, ELECTIC MOTORS AND (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL, DRY PLACE. AVOID PROLONGD OR REPEATED CONTACT WITH EYES, SKIN OR CLTHG. AVOID BREATHING VAPOR. Other Precautions:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNECESSARY EXPOSURE AND REMOVAL OF THE MATERIAL FROM EYES, SKIN AND CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE AIR CONTAMS CAN EXCEED ACCEPTABLE CRITERIA, USE NIOSH/MSHA APPROVED RESP PROT EQUIP. RESPS SHOULD BE SELECTED BASED ON THE FORM AND CONC OF CONTAMS IN AIR IN ACCORD W/OSHA 29 CFR 1910.134 OR OTH ER APPLICABLE STDS OR GUIDELINES. Ventilation:IF AIRBORNE CONTAMS ARE GENERATED WHEN MATL IS HEATED/ HANDLED, SUFFICIENT VENT IN VOL & AIR FLOW PATTERNS (SUPP DATA) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health % VOL: 58.3-79.0 (WT). EXPLO HAZS: STATIC DISCHARGE. VAP IS HVR/AIR & MAY SETTLE IN LOW PLACES OR TRAVEL OUTWARD TO A SOURCE OF IGNIT AND FLASHBACK. FIRST AID PROC: HELD APART DURING IRRIGATION TO INS URE WATER CNTCT W/ENTIR SURF OF EYES & LIDS. CALL MD. VENT: SHOULD BE PROVIDED TO KEEP AIR CONTAM CONC LEVELS (ING 4) ================== Physical/Chemical Properties ================== HCC:F3 Spec Gravity:0.88-1.27 Solubility in Water:SLIGHT Appearance and Odor:COLORED LIQUID, SOLVENT ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVER FREE LIQUID. ABSORB RESIDUE AND DISPOSE OF ACCORDING TO LOCAL, STATE/PROVINCIAL, AND FEDERAL REQUIREMENTS. EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEA RBY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHYLENE GLYCOL MONOMETHYL ETHER, NC9476220 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:2-METHOXYETHANOL; (ETHYLENE GLYCOL MONOMETHYL ETHER). LD50:(ORAL,RAT) 2370 MG/KG. NIOSH: 0.1 PPM TWA; 0.3 MG/M3 TWA 200 PPM IDLH (NOT APPLICABLE BECAUSE OF NIOSH REL). EINECS/ELINCS: 203-713-7. CAS:109-86-4 RTECS #:KL5775000 > Wt:98. OSHA PEL:80 MG/M3;25 PPM ACGIH TLV:16 MG/M3;5 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT & TOXICOLOGICAL INFO. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MODERATE IRRITATION. MAY CAUSE TRANSIENT CORNEAL INJURY. SKIN: MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. IF ABSORBED, CAUSES SYMPTOMS SIMILAR TO THOSE OF INGESTION. INGEST ION: CAUSES DIGESTIVE TRACT IRRITATION. MAY CAUSE LIVER AND KIDNEY DAMAGE. EXPOSURE MAY CAUSE ANEMIA AND BLOOD ABNORMALITIES. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. INHALATION: MAY CAUSE RESPIRA TORY TRACT IRRITATION. MAY CAUSE LIVER AND KIDNEY DAMAGE. MAY CAUSE DYSPNEA (DIFFICULT BREATHING FROM SHORTNESS OF BREATH. CHRONIC: MAY CAUSE BONE MARROW ABNORMALITIES WITH DAMAGE TO BLOOD FORMING TIS SUES. MAY CAUSE ANEMIA(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. Effects of Overexposure:HLTH HAZS: AND OTHER BLOOD CELL ABNORMALITIES. MAY CAUSE REPRODUCTIVE AND FETAL EFFECTS. NOTE: ETHYLENE GLYCOL MONOMETHYL ETHER APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION . TARGET ORGANS: BLOOD, KIDNEYS, CENTRAL NERVOUS SYST EM, LIVER, BONE MARROW, REPRODUCTIVE SYSTEM. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN:GET MED AID IMMED. IMMED FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CON TAM CLTHG & SHOES. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERS. GET MED AID IMMED. INDUCE VOMIT BY GIVING 1 TSP OF SYRUP OF IPECAC. INHAL:REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID. NOTES TO MD:TREAT SYMPTOMATICALLY & SUPPORTIVELY. ANTIDOTE:NO SPECIFIC ANTI DOTE EXISTS. ===================== Fire Fighting Measures ===================== Flash Point:=41.7C, 107.F Autoignition Temp:=285.C, 545.F Lower Limits:1.8% Upper Limits:14% Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:WARNING! FLAMMABLE LIQUID. VAPORS MAY FORM AN EXPLOSIVE MIXTURE WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. NFPA RATING: HEALTH - 2; FLAMMABILITY - 2; REACTIVITY - 0. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR A NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS AND APPROPRIATE PERSONAL PROTECTION. USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. A BSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE ALL SOURCES OF IGNITION. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNIT. DO NOT STORE IN DIRECT SUNLIGHT. STORE IN TIGHTLY CLSD CNTNR. STORE IN COOL, DRY, WELL-VENTED AREA AWAY FROM INCOMPAT SUBSTANCES. DO NOT EXPOSE TO AIR. DO NOT GET ON S KIN OR IN EYES. DO NOT INGEST OR INHALE. AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. Other Precautions:USE W/ADEQ VENT. GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. USE SPK-PROOF TOOLS & EXPLO PROOF EQUIP. EMPTY CNTNRS RETAIN PROD RESIDUE, (LIQ &/OR VAP), & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CNTNRS TO HEAT, SPKS/OPEN FLAME S. IN CASE (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health OTHER PREC:OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LBL WHERE POSS). -- PHYSICAL & CHEM PROPERTIES: MOLECULAR FORMULA: C3H8O2. MOLECULAR WT: N/P. -- OTHER INFO:OEL-AUSTRALIA, UNITED KINGDOM:TWA 5 PPM (16 MG/M3); SKIN OEL-BELGIUM, DENMARK, FRANCE, JAPAN, THE NETHERLANDS:TWA 5 PPM (ECOLOGICAL INFO) ================== Physical/Chemical Properties ================== Boiling Pt:=124.2C, 255.6F Melt/Freeze Pt:=-85.C, -121.F Decomp Temp:Decomp Text:NOT AVAILABLE Vapor Pres:9.7 MM HG @ 25C Vapor Density:2.6(AIR=1) Spec Gravity:0.966 @ 20C pH:NOT AVAILABLE Viscosity:NOT AVAILABLE Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS LIQUID; PLEASANT ODOR - WEAK ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND ALKALIES. SUBSTANCE CAN REACT WITH AIR TO FORM EXPLOSIVE PEROXIDES. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS HEAT. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information=================== Toxicological Information:CAS # 109-86-4: RTECS # KL5775000: LD50/LC50: LC50:(INHAL,MOUSE) 1480 PPM/7H; LC50:(INHAL,RAT) 1500 PPM/7H; LD50:(ORAL,MOUSE) 2560 MG/KG; LD50:(ORAL,RABBIT) 890 MG/KG; LD50:(SKIN,RABBIT) 1280 MG/KG. E PIDEMIOLOGY:NO INFO AVAIL. TERATOGENICITY:EFTS ON NEWBORN:BEHAVIORAL, INHAL-RAT TCLO=25 PPM/7H; BIOCHEM & METABOLIC, ORAL-RAT TDLO=175 MG/KG; GROWTH STATISTICS, INHAL-RAT TCLO=100 PPM/6H. EMBRYO/FETUS :DEATH, ORAL-MONKEY TDLO=930 MG/KG; FETOTOXICITY, ORAL-RAT TDLO=350 MG/KG. SPECIFIC DEVEL ABNORMS: CARDIOVASCULAR, ORAL-RAT TDLO=175 MG/KG; CNS & UROGENITAL, INTRAPERITONEAL(IPR)-RAT TDLO=190 MG/KG; M USCULOSKELETAL, (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:ECOTOXICITY:NO INFO AVAIL. ENVIRON FATE:NO INFO REPORTED. PHYSICAL/CHEM:NO INFO AVAIL. OTHER:NONE. -- TOX INFO:IPR-RAT TDLO=330 MG/KG. REPRO EFTS:FERTILITY:ABORTION, ORAL-MONKEY TDLO=930 MG/KG; FEMALE INDEX, INHAL-RAT TCLO=100 PPM/6H; LITTER SIZE, INHAL-MOUSE TCLO=50 PPM/6H. PATERNAL EFTS:SPERMATOGENESIS, ORAL-RAT TDLO=250 M/KG; TESTES/SPERM DUCT/EPIDIDYMIS, ORAL-RAT TDLO=100 MG/KG. NEUROTOXICITY/ MUTAGENICITY:NO INFO AVAIL. OTHER STUDIES:PLEASE REFER TO RTECS KL5775000 FOR ADDNL INFO. -- SUPP DATA:(16 MG/M3); SKIN OEL-FINLAND:TWA 25 PPM (80 MG/M3); STEL 40 PPM (12 MG/M3); SKIN OEL-GERMANY:TWA 5 PPM (15 MG/M3); (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA: D-SERIES MAXIMUM CONCENTRATION OF CONTAMANTS; D-SERIES CHRONIC TOXICITY REFERENCE LEVELS; F-SERIES; P-SERIES; & U-SER IES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:U.S. DOT:SHIPPING NAME:ETHYLENE GLYCOL MONOMETHYL ETHER; HAZ CLASS:3; UN #:UN1188; PACKING GRP:III. IATA; RID/ADR/IMO:SHIPPING NAME:NO INFO AVAIL. CANADA TDG:SHIPPING NAME:ETHYLENE GLYCOL MONOMETHYL E THER; HAZ CLASS:3; UN #:UN1188; PACKINGGRP:III; ADDNL INFO:FL PT:39C (102.2F). -- ECOLOGICAL INFO:SKIN OEL-HUNGARY:TWA 15 MG/M3; STEL 30 MG/M3; SKIN OEL-THE PHILIPPINES, TURKEY:TWA 25 PPM (80 MG/M3);SKIN OEL-POLAND:TWA 50 MG/M3; OEL-RUSSIA:TWA 5 PPM; OEL-SWEDEN:TWA 5 PPM (16 MG/M3); STEL 10 PPM (30 MG/M3); SKIN OEL-SWITZERLAND:TWA 5 PPM (15 MG/M3); STEL 10 PPM (30 MG/M3; SKIN JAN 9 OEL IN BULGARI A, COLOMBIA, JORDAN, (SARA TITLE III) ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ):NONE OF CHEMS IN THIS MATL HAVE RQ. SECTION 302 (TPQ):NONE OF CHEMS IN THIS PROD HAVE TPQ. SARA CODES: CAS # 109-86-4:ACUTE, CHRONIC, FLAMM. SECTION 313:THIS MATL CONTAINS 2-METHOXYET HANOL (CAS # 109-86-4, 98%), WHICH IS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. -- TRANSPORT INFO:KOREA, NEW ZEALAND, SINGAPORE, VIETNAM: CHECK ACGIH TLV. Federal Regulatory Information:TSCA:CAS # 109-86-4 IS LISTED ON TSCA INVENTORY. HLTH & SFTY REPORTING LIST:NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. CHEM TEST RULES:NONE OF CHEMS IN THIS PROD ARE UNDER CHEM TEST RULE. SECTIO N 12B:NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE:NONE OF CHEMS IN THIS MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT:THIS MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS; C LASS 1/CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT:NONE OF CHEMS IN THIS PROD ARE LISTED AS HAZ SUBSTAN CES; PRIORITY/TOX POLLUTANTS UNDER CWA. OSHA:NONE OF CHEMS IN THIS PROD ARE CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/ (STATE REGULATORY INFO) State Regulatory Information:CAS # 109-86-4 CAN BE FOUND ON FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. FOLLOWING STATEMENT(S) IS(ARE) MAKE IN ORDER TO COMPLY W/CA LIFORNIA SAFE DRINKING WATER ACT: WARNING:THIS PROD CONTAINS 2-METHOXYETHANOL, CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS/OTHER REPRO HARM. CALIFORNIA NO SIGNIFICANT RISK LEVEL:NONE OF C HEMS IN THIS PROD ARE LISTED. -- FED REGULATORY:INTERNATIONAL REGS:EUROPEAN LABELING I/A/W EC DIRECT IVES:HAZ SYMBOLS: T F. RISK PHRASES: R 10 - FLAMM. R 20/21/22 - HARMFUL BY INHAL, IN CONT W/SKIN & IF SWALLOWED. R 60 - MAY (OTHER INFO) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPEEDY-STRIP CAGE:22969 CAGE:22969 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 68% Other REC Limits:A2 CARCINOGEN OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 10% Other REC Limits:200 PPM OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE DIZZINESS, UNCONSCIOUSNESS, LIVER & KIDNEY DAMAGE. EYES: PAIN & IRRITATION. SKIN: IRRITATION & DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DIZZINESS, UNCONSCIOUSNESS, LIVER/KIDNEY DAMAGE. EYES: PAIN & IRRITATION. SKIN: IRRITATION & DERMATIITS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/HAND SOAP & WATER, APPLY MILD SKIN CREAM. CONTACT PHYSICIAN. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. GET MED ATT. INHALATION: MOVE TO FRESH AIR, GIVE OXYGEN IF NEEDED. IF UNCONSCIOUS, G IVE ARTIFICIAL RESPIRATION. NEVER GIVE FLUIDS/INDUCE VOMITING IF PATIENT IS UNCONSCIOUS/HAVING CONVULSIONS. GET MED ATT. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS/AIR SUPPLIED RESPIRATOR. EVACUATE THE AREA. MOVE UPWIND. DIKE AREA TO CONTAIN SPILL. ABSORB W/ABSORBENT MATERIALS SUCH AS SAW DUST/VERMICULITE & SHOVEL INTO APP ROPRIATE DISPOSAL CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE AT NORMAL ROOM TEMPERATURE. VAPORS ARE HEAVIER THAN AIR & WILL COLLECT IN LOW AREAS. Other Precautions:A SPILL/LEAK MAY CONTAMINATE UNDER GROUND WATER SUPPLY. DON'T TRANSFER INTO UN-MARKED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF VENTILATION IS INADEQUATE. Ventilation:PROVIDE LOCAL EXHAUST/MECHANICAL VENTILATION TO PROVIDE ADEQUATE FRESH AIR & FOR ENCLOSED AREAS. Other Protective Equipment:RUBBER APRON & BOOTS, EYE WASH STATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:104F Vapor Pres:349 Vapor Density:>AIR Spec Gravity:1.32 Evaporation Rate & Reference:(BU AC = 1): 0.71 Solubility in Water:SOLUBLE Appearance and Odor:VISCOUS LIQUID. ORGANIC SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DON'T MIX W/LIQUID OXYGEN/STRONG OXIDANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T FLUSH INTO SEWER. CONTAMINATED ABSORBENT MATERIAL MUST BE DISPOSED OF IN AN APPROVED HAZARDOUS WASTE FACILITY IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHROMIUM 1000 UG/ML (0.1% W/V) Preparer's Name:SUSAN C TYMINST CAGE:0EK28 CAGE:0EK28 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM DICHROMATE CAS:7789-09-5 RTECS #:HX7650000 Fraction by Wt: 0-1% OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:NITRIC ACID, HYDROGEN NITRATE CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 0-5% OSHA PEL:5 MG/CUM ACGIH TLV:5.2 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 1870 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES: IRRITATION & BURNS. SKIN: BURNS. INHALATION: IRRITATION TO NOSE & THROAT, COUGHING, DIFFICULT BREATHING. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:EYES: IRRITATION & BURNS. SKIN: BURNS. INHALATION: IRRITATION TO NOSE & THROAT, COUGHING, DIFFICULT BREATHING. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE EXTINGUISHING MEDIA. Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE IN POSITIVE PRESSURE MODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. STOP LEAK SAFELY. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP W/SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH SPILL AREA W/ WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION PROOF AREA. AVOID INHALATION OF VAPORS & CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST: REQUIRED, VENT HOOD Other Protective Equipment:LAB COAT, APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1 Solubility in Water:COMPLETE Appearance and Odor:PALE YELLOW, CLEAR SOLUTION W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANIC MATERIALS, STRONG REDUCING AGENTS Hazardous Decomposition Products:OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. D002 (CORROSIVE WASTE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILVER NITRATE SOLUTIONS & CONCENTRATE 40170, SS72 1 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:WATER LD50 (ORAL MOUSE): 50 MG/KG CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILVER (I) NITRATE (1:1) (SARA 313) (CERCLA) LD50 (ORAL MOUSE): 50 MG/KG CAS:7761-88-8 RTECS #:VW4725000 Fraction by Wt: 15.0% OSHA PEL:0.01 MG(AG)/M3 ACGIH TLV:0.01 MG(AG)/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE/SKIN: CAUSES IRRIT. INGEST: CAUSES GI IRRIT W/NAUS, VOMIT & DIARR. INHAL: CAUSES RESP TRACT IRRIT. CHRONIC: MAY CAUSE METHEMOGLOBINEMIA, WHICH IS CHARACTERIZED BY CHOCOLATE-BROWN COLORED BL OOD, HDCH, WEAK, DIZZ, BREATH SHORTNESS, CYANOSIS, RAPID HEART RATE, UNCON & POSS DEATH. (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CHRONIC INHAL/INGEST OF SILVER NITRATE MAY CAUSE "ARGYRIA", WHICH IS CHARACTERIZED BY BLUE-GRAY PIGMENTATION OF SKIN & MUC MEMBS. THE CNDTN DEVELOPS SLOWLY, USUALLY AFTER 2-25 YRS OF EXPOS. CHRONIC SKIN CONT MAY CAUSE LOC ARGYRIA, A PERM DISCOLORATION OF SKIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST:IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED AID. INHAL: REMOVE FROM EXPOS (SUP DAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT, AS INDICATED IN "CONTROL MEASURES" SECTION. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND EYES. AVOID INGESTION AND INHALATION. USE WITH ADEQUATE VENTILATION. Other Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1010.134. ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MATLS TO AVOID: & NITRIC ACID, ETHYLENE HYDROPEROXIDE, HYDROGEN PEROXIDE, MAGNESIUM ARSENIC, & CUPROUS ACETYLIDE. FIRST AID PROC: TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, G IVE OXYGEN. GET MED AID IF COUGH/OTHER SYMPS APPEAR. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ================== Physical/Chemical Properties ================== Vapor Pres:14 @ 20C Vapor Density:0.7 Spec Gravity:1.0-1.1 Evaporation Rate & Reference:1 (ETHER=1) Solubility in Water:COMPLETELY SOLUBLE Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SILVER NITRATE IS INCOMPATIBLE W/ACETYLENE, AMMONIUM HYDROXIDE, AZIRIDINE, CALCIUM CARBIDE, ETHANOL, ETHANOL (SUP DAT) Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:NITROGEN OXIDES, SILVER OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND, LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:229H9502, DEVRAN 229 ACRYLIC EPOXY GLOSS (SUPP DATA) Kit Part:Y CAGE:1HK86 CAGE:1HK86 ============= Composition/Information on Ingredients ============= Ingred Name:ING 17:LG QTYS IN BLDGS TO COMPLY W/OSHA 1910.106. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:BOTTLES/OTHER UNLABELED CNTNRS. DO NOT REUSE EMPTY CNTNRS. IF THIS MATL IS PART OF 2 COMPONENT PROD, THEN(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:MIXT OF BASE & CONVERTER PORTIONS WILL HAVE HAZARDS OF BOTH COMPONENTS. RTECS #:9999999ZZ Ingred Name:SUPDAT:FILTER DESIGNED TO REMOVE DECOMP PARTICULATES & VAPS. WHEN USED IN CONFINED AREAS, USE NIOSH APPRVD AIR (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:SUPPLY RESPS/HOODS. USE NIOSH APPRVD CHEM RESP WHEN FLAME CUTTING, WELDING, BRAZING & SANDING MATL COATED W/PROD. RTECS #:9999999ZZ Ingred Name:VENT:MIXING, APPLICATN & CURING AREAS & TO REMOVE SANDING DUSTS OF DRIED COATINGS & DECOMP PRODS DURING WELDING (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:& FLAME CUTTING ON SURFS COATED W/THIS PROD. VAPS MAY SPREAD LONG DISTS. PVNT BUILD-UP BY REMOVING HEAVY (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:SOLVENT VAPORS FROM LOWER LEVELS OF THE WORK AREA. ELIMINATE ALL IGNITION SOURCES. RTECS #:9999999ZZ Ingred Name:ACETIC ACID, HEXYL ESTER; (HEXYL ACETATE.) VP:1. MFR CAS # 88230-35-7 CAS:142-92-7 RTECS #:AT0875000 Fraction by Wt: 15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA). VP:13. LD50:(ORAL,RAT) 15 GM/KG. CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 20% OSHA PEL:150 PPM ACGIH TLV:150 PPM;200 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ALCOHOL; (N-BUTYL ALCOHOL) (SARA 313) (CERCLA). VP:4.2. LD50:(ORAL,RAT) 2.5 GM/KG. CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 5% OSHA PEL:100 PPM ACGIH TLV:50 PPM, S, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER;(PROPYLENE GLYCOL MONOMETHYLETHER ACETATE). VP:2.7. LD50:(ORAL,RAT)8.5 GM/KG. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA). VP:6. LD50:(ORAL,RAT) >5 GM/KG. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANE, 1-CHLORO-2, 3-EPOXY-; (EPICHLOROHYDRIN) (SARA 302/313) (CERCLA) CAS:106-89-8 RTECS #:TX4900000 OSHA PEL:5 PPM, S ACGIH TLV:2 PPM, S EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:EXPLO HAZ:BEYOND CLSD DOORS. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. NEVER USE A (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:WELDING/CUTTING TORCH ON/NEAR CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE MAY IGNITE. DURING EMER CNDTNS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ASSISTANCE. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:REPRO HARM/CANCER. NOTE:TOLUENE APPEARS ON NAV LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:IMMED. DO NOT INDUCE VOMIT. ASPIR OF MATL CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. RTECS #:9999999ZZ Ingred Name:OTHER PREC:OF VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE >120F/NEAR FIRE/OPEN FLAME. STORE (ING 18) RTECS #:9999999ZZ Ingred Name:ACRYLIC RESIN Fraction by Wt: 25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EPOXY RESIN CAS:25068-38-6 RTECS #:KC2100000 Fraction by Wt: 10% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT; HDCH, NAUS, DIZZ, WEAK & FATG. EXTREME EXPOS CAN RSLT IN UNCON & EVEN RESP ARREST. SKIN/EYE CONT:CAUSE IRRIT. MAY BE HARMFUL IF ABSORBED THRU SKIN. INGEST:CAN CAUSE ST OM &/OR INTEST IRRIT, NAUS, VOMIT & DIARR. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS (EFTS OF OVEREXP) Explanation of Carcinogenicity:EPICHLOROHYDRIN:IARC MONOGRAPHS, SUPP, VOL 7 PG 202, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO (SUPDAT) Effects of Overexposure:HLTH HAZ:W/PERM BRAIN & NERV SYS DMG. PRLNG/RPTD BRTHG OF SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF YRS MAY CAUSE DUST DISEASE OF THE LUNGS. NOTICE:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENT S MAY BE HARMFUL/FATAL. WARNING:THIS PROD CNTNS CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS, OTHER (ING 14) Medical Cond Aggravated by Exposure:NONE, WHEN USED I/A/W SAFE HANDLING & USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHAL:IF YOU EXPER DFCLTY IN BRTHG, LEAVE AREA TO OBTAIN FRESH AIR. IF CONTINUED DFCLTY IS EXPER, SUMMON MED ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING APPRVD CPR TECHNIQUES & SUMMON HELP IMMED.EYES:FLUSH IMMED W/LG AMTS OF WATER FOR AT LST 15 MINS. GET MED ATTN. SKIN:WASH AFFECTED AREAS W/SOAP & WATER. REMOVE SOILED CLTHG. GET MED ASSISTANCE IF IRRIT PERSISTS. INGEST:CONSULT MD (ING 16) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:80.0F,26.7C Lower Limits:1% Extinguishing Media:IN CASE OF FIRE USE CO*2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ PREF. IF EXPOS TO(SUPDAT) Unusual Fire/Explosion Hazard:FLAMM LIQ-CLASS IC. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & FLAME. VAPS MAY CAUSE FLASH FIRE, IGNIT EXPLO & SPREAD LONG DISTS & (ING 11) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT (FLAMES, HOT SURFS & ELEC, STATIC/FRICTIONAL SPKS). PVNT BRTHG OF VAPS. VENT AREA. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZ CAUT INFO IN OTHER SECTIONS OF THIS MSDS. CONTAI N SPILLED MATL & REMOVE W/INERT ABSORB & (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPS, SPRAY MIST/SANDING DUST. DO NOT GET ON SKIN/IN EYES. KEEP AWAY FROM HEAT, SPKS & FLAMES. DO NOT SMOKE. OBSERVE ALL APPLIC PRECS. Other Precautions:EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT INCL HEATERS, FANS & OTHER NON-EXPLO-PROOF ELEC EQUIP, DURING USE & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE EXPLOSIVELY & SPREAD LONG DISTS & B EYOND CLSD DOORS. PVNT BUILD-UP (ING 17) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS & DURING SANDING/GRINDING OPERATIONS, USE NIOSH APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST. WHEN USED IN RESTRICTED VENT AREAS, WEAR NIOSH APPRVD (SUPDAT) Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP AIR CONC BELOW CURRENT APPLIC SFTY & HLTH STDS IN (ING 23) Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . SOLV IMPERMEABLE CLTHG & BOOTS TO PREVENT SKIN CONTACT ARE REC. Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:COATING - NEUTRAL TINT BASE. FIRE FIGHT PROC:FIRE/EXTREME HEAT, WATER SHOULD BE USED TO COOL CLSD CNTNRS & PVNT PRESS BUILD UP/POSS AUTO-IGNIT. EXPLAN OF CARCIN:BE CARCIN. HUM AN:RESP CANCER. SPILL PROC:NON-SPKING TOOLS. STORE IN CLSD CNTNR UNTIL PROPERLY DISP OF. RESP PROT:CHEM/MECH (ING 21) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>244F,>118C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.99 VOC Pounds/Gallon:563 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:63.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KAPTON POLYMIDE FILM TYPE CR CAGE:0ERJ7 CAGE:0ERJ7 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:INERT POLYIMIDE FILM RTECS #:9999999ZZ Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETAMIDE, N,N - DIMETHYL -; (DIMETHYL ACETAMIDE (RESIDUAL IN FILM)) CAS:127-19-5 RTECS #:AB7700000 Fraction by Wt: <1% OSHA PEL:S, 10 PPM ACGIH TLV:S, 10 PPM; 9495 Ingred Name:POLYIMIDE POLYMER (AS NUISANCE DUST) CAS:25038-81-7 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM OXIDE (2:3); (ALUMINA) (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: <35% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:FIRST AID PROC: DUPONT CAUTION BULLETIN NO. H-50102. RTECS #:9999999ZZ Ingred Name:VENT: "KAPTON" ARE INVOLVED, NORM AIR CIRCULATION MAY BE ALL THAT IS NEEDED IN CASE OF OVERHEATING. WHETHER/NOT (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: EXISTING VENT IS ADEQUATE AT HIGHER TEMP WILL DEPEND ON COMBINED FACTORS OF FILM QTY, TEMP & EXPOSURE TIME. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BEFORE USING "KAPTON" POLYIMIDE FILMS, READ BULLETIN ON SAFE HNDLG & USE. INHAL: NOT A PROBABLE ROUTE OF EXPOS FOR FILM. EXPOS TO ALUMINA/CARBON BLACK ENCAPSULATED IN POLYMER IS NOT LIKELY. FOR THE PO LYMER FROM WHICH THE FILM IS MADE, DUPONT RECS TREATING POLYMER DUST AS A NUISANCE PARTICULATE. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: SKIN: NO IRRITATION IS EXPECTED FROM HANDLING FILM. LESS THAN 1 PPM DIMETHYL ACETAMIDE WAS EXTRACTED FROM FILM BY DISTILLED WATER AT 40 DEG C FOR 4 HOURS. EYE & INGESTION: NOT A PROBABLE ROU TE OF EXPOSURE FOR FILM. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMED . INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . SKIN: WASH W/SOAP & H*2O AFTER HNDLG. IF SKIN IRRIT DEVELOPS, CONSULT A MD. EYE: FLUSH W/H*2O FOR A T LEAST 15 MINS. CONSULT A MD IF IRRIT PERSISTS. ADDITIONAL INFO: MED USE: CAUTION: DO NOT USE IN MED APPLICATIONS INVOLVING PERM IMPLANTATION IN HUMAN BODY. FOR OTHER MED APPLICATIONS SEE (ING 5) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FLAMM PROPERTIES: NOT A FIRE/EXPLOSION HAZ. FLAMMABILITY CHARACT OF POLYIMIDE FILM IS RPTD AS "SELF-ENTINGUISHING". "KAPTON" CHARS BUT DOES NOT BURN IN (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SAFEGUARDS (PERSONNEL): NOTE: REVIEW FIRE FIGHTING MEASURES & HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING W/CLEAN-UP. USE NIOSH APPRVD APPROPRIATE PERSONAL PROT EQUIPMENT DURING CLEAN-UP. ACCIDENT AL RELEASE MEASURES: PICK UP TO PVNT SLIPPING HAZ. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM FLAMMABLE MATERIALS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORS ARE NOT NEEDED FOR NORMAL USE. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:SAFE HNDLG OF "KAPTON" POLYIMIDE FILMS AT HIGH TEMPS (ABOVE 200 DEG C) REQS ADEQ VENT IF SMALL QTIES OF (ING 6) Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . SPECIAL PROTECTIVE CLOTHING IS NOT NEEDED FOR NORMAL USE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ: AIR. "KAPTON" WILL BURN IN AN ATM OF 100% OXYGEN. MAJOR OFF-GASES ARE CARBON DIOXIDE & CARBON MONOXIDE. PROCESSING OF "KAPTON" POLYIMIDE FILMS CAN CAUSE GENERATION OF STATIC CHARGE. PRECAUT IONS FOR STATIC CHARGES SHOULD ALSO BE TAKEN WHEN REMOVING PLASTIC FILMS USED AS PROT PACKAGING FOR "KAPTON". ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:NONE Spec Gravity:>1.4 Solubility in Water:INSOLUBLE Appearance and Odor:LIGHT AMBER TRANSPARENT FILM; NO ODOR. Percent Volatiles by Volume:1 MAX ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AT TEMPERATURES ABOVE 400 DEG C, THE MAJOR OFF GASES ARE CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATE IN COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SNOFLO CAGE:BASFC CAGE:BASFC CAGE:0PK40 ============= Composition/Information on Ingredients ============= Ingred Name:PROPRIETARY INGREDIENTS Fraction by Wt: 4% Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 85-95% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM PHOSPHATE, DIBASIC *92-4* CAS:7758-11-4 Fraction by Wt: 2% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 0.7% Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL, 2,2-OXYBISETHANOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: 0-10% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INGESTION: ABDOMINAL DISTRESS, CNS DEPRESSION, POSSIBLY RESPIRATORY &/OR KIDNEY FAILURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: LIVER & KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:SKIN, RESPIRATORY DISORDERS, OR IMPAIRED FUNCTION OF THE LIVER/KIDNEYS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: DILUTE W/WATER & INDUCE VOMITING. NEVER GIVE FLUIDS OR INDUCE VOMITING IF VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS. INHALATION : REMOVE TO FRESH AIR. AID IN BREATHING, IF NECESSARY. NOTE: ADMINISTRATION OF ETHANOL MAY COUNTERACT THE EFFECTS OF ETHYLENE GLYCOL (METABOLIC ACIDOSIS & RENAL DAMAGE). OBTAIN MED ATTN IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:250F Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2 OR DRY CHEMICAL EXTINGUISHING MEDIA. Fire Fighting Procedures:FIRE FIGHERS SHOULD USE A SELF CONTAINED BREATHING APPARATUS & TURNOUT GEAR. Unusual Fire/Explosion Hazard:VAPORS FROM HEATED (ABOVE FLASHPOINT) OF PRODUCT MAY TRAVEL TO A SOURCE OF IGNITION & FLASH BACK. AUTOIGNITION: 775F ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN, SOLIDIFY & PLACE IN A SUITABLE CONTAINER FOR DISPOSAL IN A LICENSED FACILITY. COVER SPILLS W/SOME INERT ABSORBENT MATERIAL. SWEEP UP & PLACE IN A WASTE DISPOSAL CONTAINER. FLUSH AREA W/WATER. ======================Handling and Storage ====================== Other Precautions:AVOID BREATHING VAPORS OR FUMES OF HEATED PRODUCT OR BURNING PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VAPORS OR MISTS ARE GENERATED, USE A NIOSH/MSHA APPROVED ORGANIC VAPOR/MIST RESPIRATOR. Ventilation:LOCAL EXHAUST Other Protective Equipment:COVERALLS, APRON, BOOTS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:330F Vapor Pres:18 Spec Gravity:1.135 Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID W/GLYCOL ODOR. Percent Volatiles by Volume:9-11 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL IS A CERCLA HAZARDOUS SUBSTANCE. RQ= 1LB. INCINERATE OR BURY IN A RCRA LICENSED FACILITY. DON'T DISCHARGE INTO WATERWAYS OR SEWER SYSTEMS. DISPOSE CONTAINERS IN A LICENSED FACILITY. CRUSH OR OTHER TO PREVENT UNAUTHORIZED REUSE.
1
eyes_protection_mandatory
======================================================= Product ID: LUBE-A-TUBE KS-S COMPOUND, 303850 Cage: TO179 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: TO179 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EFFECTS OF OVEREXPOSURE : NO KNOWN EFFECTS. Signs And Symptions Of Overexposure: NO KNOWN EFFECTS. First Aid: EYES: FLUSH WITH WATER. IF IRRITAION OCCURS & PERSISTS, SEEK MEDICAL AID. INGESTION: CONTACT A PHYSICIAN IMMEDIATELY (FP N). INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A PHYSICIAN IMM EDIATELY (FP N). SKIN CONTACT: FLUSH WITH COPIOUS AMOUNTS OF WATER. CONTACT A PHYSICIAN (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: RECOVER FREE PRODUCT OR WASH WITH WATER. Waste Disposal Methods: DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: PROTECT FROM FREEZING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point: >204.4C, 400.F Lower Limits: UNKNOWN Upper Limits: UNKNOWN Extinguishing Media: CARBON DIOXIDE, FOAM OR DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N). TREAT AS AN OIL FIRE. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN (FP N). NOT NORMALLY REQUIRED (MFR). Ventilation: NOT NORMALLY REQUIRED. (MFR). Other Protective Equipment: NONE. Supplemental Safety and Health: FLASH POINT: >400F - >204C (FOR ANHYDROUS MATERIAL). PH= 9.0-9.8 (10% SOLUTION). ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 0.96 - 1.00 PH: 9.0 - 9.8 Solubility in Water: EMULSIFIES. Appearance and Odor: LIGHT YELLOW GREASE - MILD FATTY ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: NONE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= Toxicological Information: THRESHOLD LIMIT VALUE NOT ESTABLISHED. ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= Transport Information: D.O.T. PROPER SHIPPING NAME: NOT REGULATED. ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: /NFPA RATINGS: HEALTH=0; FLAMMABILITY=0; REACTIVITY=0. THIS MSDS SUPERSEDES: MAY 20, 1993. ======================================================= HAZCOM Label ======================================================= Product ID: LUBE-A-TUBE KS-S COMPOUND, 303850 Cage: TO179 Assigned IND: Y Company Name: RICHARDS APEX INCORPORATED Street: 4202-24 MAIN ST Zipcode: 19127-1698 Label Required IND: Y Date Of Label Review: 12/02/2000 Status Code: A Origination Code: F Skin Protection IND: NO Signal Word: NONE Respiratory Protection IND: NO Health Hazard: None Contact Hazard: None Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: EFFECTS OF OVEREXPOSURE - NO KNOWN EFFECTS. =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:GLEITMO 700 MOLYBDENUM DISULPHIDE PASTE W/SYNTHETIC OIL Preparer's Name:RUDOLF GRUBER CAGE:GO583 CAGE:10873 CAGE:GO583 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDENUM DISULFIDE CAS:1317-33-5 RTECS #:QA4697000 OSHA PEL:15 MG/CUM AS (MO) ACGIH TLV:10 MG/CUM AS (MO) Ingred Name:SYNTHETIC OIL ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(LAB ANIMAL): >10ML/KG BASE OIL Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:GLEITMO 700 IS BELIEVED TO BE NON-HAZARDOUS WHEN USED PROPERLY. Explanation of Carcinogenicity:NONE Effects of Overexposure:GLEITMO 700 IS BELIEVED TO BE NON-HAZARDOUS WHEN USED PROPERLY. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:392F Extinguishing Media:WATERSPRAY, DRY CHEMICAL, FOAM, CO2 Fire Fighting Procedures:USE SCBA. ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT ENTRY INTO SEWERS & WATERWAYS. AVOID CONTACT W/EYES & SKIN. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLEAN, DRY PLACE. NO SPECIAL HANDLING IS REQUIRED. Other Precautions:AVOID CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, NO RESPIRATORY PROTECTION IS REQUIRED. Other Protective Equipment:NO SPECIAL PROTECTIVE MEASURES ARE NECESSARY. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:BLACK GREASE; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:TEMPS >572F. Hazardous Decomposition Products:THERMAL: CO, CO2, SULFUR DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T DUMP INTO SEWERS, ON THE GROUND/INTO ANY BODY OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METERPAK #215 CAGE:LO289 CAGE:0SL71 CAGE:LO289 ============= Composition/Information on Ingredients ============= Ingred Name:NA Fraction by Wt: NA Other REC Limits:NA OSHA PEL:NA ACGIH TLV:NA ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT SOLD IN WATER SOLUBLE POUCHES & DIRECT CONTACT W/POWDER UNLIKELY DURING NORMAL USE. HOWEVER UNDER UPSET CONDITIONS, INHALATION OF DUST MAY CAUSE ALLERGIC REACTIONS IN SUSCEPTIBLE PEOPLE. ENZYM ES MAY CAUSE EYE IRRITATION ON CONTACT.MAY PRODUCE RESPIRATORY ALLERGIES (ASTHMA) & SKIN IRRITATION IN EXPOSED WORKERS. Effects of Overexposure:ALLERGIC TYPE REACTIONS, IRRITATION TO SKIN. Medical Cond Aggravated by Exposure:ALLERGIES ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY W/WATER & SEEK MEDICAL ATTN. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHES & WASH BEFORE REUSE. INHALATION: IF ALLERGIC RESPONSE IS EXHIBITED, SEEK MEDICAL A TTN. ===================== Fire Fighting Measures ===================== Flash Point:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:NO SPECIAL REQUIREMENTS Fire Fighting Procedures:NO SPECIAL REQUIREMENTS Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:POWDERS SHOULD BE VACUUMED OR MOISTENED W/WATER & REMOVED. COLLECTED WASTE WATER SHOULD BE RETURNED TO SYSTEM OR SEALED IN CONTAINERS TO PREVENT DUST GENERATION. ======================Handling and Storage ====================== Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING. AVOID GENERATION OF DUST OR AEROSOL. AVOID EXPOSURE OF ENZYME PRODUCT TO CONDITIONS OF HIGH TEMPERATURE & HUMIDITY WHICH* Other Precautions:*MAY REDUCE PRODUCT ACTIVITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED, HOWEVER UNDER UNUSUAL/UPSET CONDITIONS, RESPIRATORY EQUIPMENT MUST BE SELECTED & USED IN ACCORDANCE WITH OSHA/NIOSH GUIDELINES. Ventilation:LOCAL EXHAUST: SHOULD BE SUFFICIENT TO PREVENT DUST RELEASE. Other Protective Equipment:SUFFICIENT TO PREVENT DIRECT SKIN CONTACT. Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING. AVOID GENERATION OF DUST. WASH HANDS THOROUGHLY AFTER HANDLING. Supplemental Safety and Health DUSTING LIKELY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:NA Evaporation Rate & Reference:NA Solubility in Water:APPRECIABLE Appearance and Odor:GREEN POWDER, TYPICAL ENZYME ODOR, PACKAGED IN WATER SOLUBLE POUCHES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NK Stability Condition to Avoid:ENZYME ACTIVITY MAY BE AFFECTED BY EXPOSURE TO HIGH TEMPERATURES & MOISTURE. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL THE ABSORBED MATERIAL IN CLOSED CONTAINERS IN ACCORDANCE W/FEDERAL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:86 PROCLEAN SURFACE CLEANER CAGE:ACMEA CAGE:ACMEA ============= Composition/Information on Ingredients ============= Ingred Name:ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM), HYDROTREATED HEAVY, NON AROMATIC HEAVY NAPHTHA) ISOPAR G *93-3* CAS:64742-48-9 Fraction by Wt: 95% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; PETROLEUM DISTILLATE, HYDROTREATED ,(MINERAL SPIRITS) CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 5% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:WEIGHT PER GALLON IN POUNDS: 6.20 RTECS #:9999999WG Ingred Name:VOL ORGANIC CMPD: 6.20 LBS/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY SYSTEM. CNS DEPRESSION. CHRONIC EXPOSURE MAY CAUSE ADVERSE EFFECTS TO LIVER/URINARY/BLOOD FORMING/REPRODUCTIVE/CARDIOVASCULAR SYSTEMS/PERMANENT BRAIN/CNS DAMAGE. EX TREME ACUTE EXPOSURE MAY CAUSE UNCONSCIOUSNESS & POSSIBBLY DEATH. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: HEADACHE/DIZZINESS/NAUSEA/COORDINATION LOSS/UNCONSCIOUSNESS/DEATH. SKIN/EYES: REDNESS/ITCH/BURNING SENSATION. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF PROBLEMS REMAIN OR OCCUR DURING USE, IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH W/PLENTY OF WATER FOR 1 5 MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:44F Lower Limits:0.7% Upper Limits:36.5% Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP, POSSIBLE AUTOIGNITION, OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA. REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME. DURING USE & UNTIL ALL VAPORS ARE GONE; KEEP ARE VENTILATED. DON'T SMOKE. Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS. TURN OFF STOVES/ELECTRIC TOOLS/APPLIANCES & OTHER IGNITION SOURCES. CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING PROCEDURES. KEEP CONTAINER CLOSED W HEN NOT IN USE. DON'T TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW TLV BY VENTILATION, USE A FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED FILM, USE A NIOSH/MSHA DUST/MI ST RESPIRATOR. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE TO MATERIALS IS MAINTAINED BELOW APPLICABLE LIMITS. Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. KEEP OUF OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:132-395F Vapor Density:>1 Spec Gravity:0.75-0.84 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/PILOT LIGHTS & OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS AS DEFINED UNDER THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINER. DISPOSE OF IAW FED/STATE/LOCAL REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5173, BUFFERED OXIDE ETCH CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ING 11: IF PAIN IS NOT COMPLETELY RELIEVED, ADTNL TREATMENT IS INDICATED. HYAMINE 1622 IS TRADE NAME FOR (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:TETRACAINE BENZETHONIUM CHLORIDE, MERCK INDEX MONOGRAPH 1078, QUATERNARY AMMONIUM CMPD SOLD BY ROHM HAAS,(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:PHILADELPHIA. SEPHIRAN CHLORIDE IS TRADE NAME FOR BENZALKONIUM CHLORIDE, MERCK INDEX MONOGRAPH 1059, ALSO(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: A QUATERNARY AMMONIUM COMPOUND, SOLD BY WINTHROP LABORATORIES, N.Y.C. RTECS #:9999999ZZ Ingred Name:OTHER PREC: SHD NEVER BE TRASNFERRED TO GLASS CNTNRS.MATL SHD REMAIN IN ORIGINAL POLYETHYLENE CNTNR. UNLINED (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: STEEL TANKS IN HYDROFLUORIC SERVICE ARE SUBJECT TO INDISCRIMINATION HYDROGEN BLISTERING & SHD ROUTINELY (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: BE INSPECTED AND REPAIRED. RTECS #:9999999ZZ Ingred Name:AMMONIUM FLUORIDE (SARA III) CAS:12125-01-8 RTECS #:BQ6300000 Fraction by Wt: 2-20% OSHA PEL:2.5 (F) MG/M3 ACGIH TLV:2.5 (F) MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:HYDROFLUORIC ACID (SARA III) CAS:7664-39-3 RTECS #:MW7875000 Fraction by Wt: 0-1% OSHA PEL:3 PPM/6 PPM STEL (F) ACGIH TLV:3 PPM STEL, C (F) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SUPP DATA: TRADE NAME FOR TETRACAINE HYDROCHLORIDE, MERCK INDEX MONOGRAPH 8904, SOLD BY WINTHROP LABORATORIES, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: N.Y.C. SKIN: REMOVE VICTIM FROM CONTAM AREA & IMMED PLACE HIM UNDER SAFETY SHOWER/WASH HIM W/H*2O HOSE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: WHICHEVER, IS AVAIL. REMOVE CONTAM CLTHG. KEEP WASHING W/LRG AMTS OF H*2O FOR MIN OF 15-20 MIN. HAVE (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: SOMEONE MAKE ARANGEMENTS FOR MED ATTN WHILE YOU CONTINUE FLUSHING AFFECTED AREAS W/H*2O. IF AVAIL, AFTER(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: THOROUGH WASHING, BURNED AREA SHD BE IMMERSED IN SOLN OF 0.2% ICED AQUEOUS HYAMINE 1622 OR 0.13% ICED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: AQUEOUS ZEPHIRAN CHLORIDE. IF IMMERSION IS NOT PRACTICAL, TOWELS SHD BE SOAKED W/ONE OF ABOVE SOLNS & (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:USED AS COMPRESSES FOR BURNED AREA.IDEALLY COMPRESSES SHD BE CHANGED EVERY 2 MIN.AN ALTERNATIVE TREATMENT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: IS FOR PHYS TO INJECT STERILE 10% AQUEOUS CALCIUM GLUCONATE SOLN SUBCUTANEOUSLY BENEATH, AROUND,& IN (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:BURNED AREA. INITIALLY USE NO MORE THAN 0.5 CC PER SQUARE CENTIMETER & DO NOT DISTORT APPEARANCE OF SKIN.(ING 12) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50: (INHAL-RAT-1H): 1276 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VAPS MAY BE IRRITATING TO SKIN, EYES, AND MUCOUS MEMBRANES. INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, OR LUNG INFLAMMATION. LIQUID AND VA POR CAUSE SEVERE BURNS WHICH MAY NOT BEIMMEDIATELY PAINFUL OR VISIBLE. SUBSTANCE IS READILY ABSORBED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: THROUGH SKIN, PENETRATING SKIN TO ATTACK UNDERLYING TISSUES AND BONE. INGESTION MAY CAUSE SEVERE BURNS TO MOUTH, THROAT, AND STOMACH. MAY HAVE ADVERSE EFFECT ON KIDNEY FUNCTION AND MAY BE FA TAL. CHRONIC: CHRONIC EFFECTS OF EXPOSURE MAY INCLUDE HYPOCALCEMIA, BONE AND JOINT CHANGES. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:CALL PHYS.INGEST:DO NOT INDUCE VOMIT;IF CONSCIOUS, GIVE H2O, MILK/MILK OF MAGNESIA.INHAL: REMOVE TO FRESH AIR.IF NOT BRTHG,GIVE ARTF RESP.IF BRTHG IS DFCLT,GIVE O2.EYES: IRRIGATE EYES FOR AT LEAST 15 MIN W/COPIOUS QTYS OF H2O,KEEPING EYELIDS APART & AWAY FROM EYEBALLS DURING IRRIGATION.GET COMPETENT MED ATTN IMMED, PREFERABLY AN EYE SPECIALIST.IF PHYS IF NOT IMMED AVAIL, APPLY 1-2 (SUPP DATA) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:PRODUCES TOXIC GASES OF HYDROGEN FLUORIDE, AMMONIA, NITROGEN OXIDES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.STOP LEAK IF YOU CAN DO SO W/OUT RISK.VENT AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATL INTO CLEAN, DRY CNTNR & C OVER; REMOVE FROM AREA. FLUSH SPILL W/WATER. Neutralizing Agent:J.T. BAKER NEUTRASOL R "LOW NAT" ACID NEUTRALIZER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD.STORE IN CORR-PROOF AREA. ISOLATE FROM INCOMPATIBLE MATLS.KEEP CNTNRS OUT OF SUN & AWAY FROM HEAT. PROTECT FROM FREEZING. Other Precautions:POISON! DANGER! USE W/ADEQ VENT. MAY BE FATAL IF SWALLOWED. REACTS VIOLENTLY W/H2O, LIBERATING EXCESSIVE HEAT. DO NOT GET IN EYES, ON SKIN/CLTHG. DO NOT BRTH VAP. HYDROFLUORIC ACID IS INCOMPAT W/ GLAS S/ALL SILICON-BEARING MATLS & (ING 16) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP PROT REQD IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 20 PPM A NIOSH/MSHA APPROVED CHEMICAL CARTRIDGE RESP WITH ACID/ORGANIC CARTRIDGE AND DUST/MIST FILTER IS RECOM. ABOVE LEVE L, A NIOSH/MSHA APPRVD SCBA IS RECOM. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT. EMERGENCY EYEWASH & DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATLS TO AVOID: OXIDES OF SILICON, ESP. GLASS, OXIDES OF NITROGEN. FIRST AID PROC: DROPS OF 0.5% PONTOCAINE HYDROCHLORIDE SOLN FOLLOWED BY SECOND IRRIGATION FOR AT LEAST 15 MIN.USE NONE OF SOLNS DESCR IBED FOR SKIN TREATMENT. USE NO OILS/GREASES UNLESS INSTRUCTED TO DO SO BY PHYS. PONTOCAINE HYDROCHLORIDE IS (ING 3) ================== Physical/Chemical Properties ================== HCC:C1 Melt/Freeze Pt:M.P/F.P Text:64.4F,18.0C Spec Gravity:1.1 (H2O=1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS SOLUTION. Percent Volatiles by Volume:80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES,ORG MATLS, MOST COMMON METALS, RUB, LEATHER, FLUORINE, STRONG BASES, CARBONATES, SULFIDES, CYANIDES,(SUPP DATA) Stability Condition to Avoid:COLD, LIGHT, HEAT. Hazardous Decomposition Products:HYDROGEN FLUORIDE, AMMONIA, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: OTR PREMIUM PLUS 4, 44-20-2 Cage: XNDEX Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: XNDEX ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE CONTACT: EYE IRRITANT. BASED ON DATA FROM COMPONENTS OR SIMILAR MATERIALS. SKIN CONTACT: SKIN IRRITANT. BASED ON DATA FROM COMPONENTS OR SIMILAR MATERIALS. PROLONGED OR REPEATED SKIN CONTACT MAY C AUSE DERMATITIS. SYMPTOMS MAY INCLUDE REDNESS, EDEMA, DRYING, DEFATTING AND CRACKING OF SKIN. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: INHALATION: EXPOSURE TO VAPORS AT ELEVATED TEMPERATURES MAY CAUSE RESPIRATORY IRRITATION. INGESTION: SWALLOWING THE MATERIAL MAY CAUSE IRRITATION OF THE GASTROINTESTINAL LINING, NAUSEA, VOMI TING, DIARRHEA AND ABDOMINAL PAIN. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH IMMED W/WATER FOR AT LEAST 15 MIN. GET IMMED MED ATTN. SKIN: WASH IMMED W/SOAP & WATER. REMOVE CONTAMD CLTHG. GET MED ATTN IF IRRIT PERSISTS. LAUNDER CONTAMD CLTHG BEFORE REUSE & DISCARD S HOES & OTHER LEATHER ARTICLES SATURATEDW/MATL. INHAL: REMOVE EXPOS PERSON TO FRESH AIR. IF ADVERSE EFTS ARE OBSERVED SEEK MED ATTN. INGEST: DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE 2 GLASSES (SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: PERSONAL PROTECTIVE EQUIPMENT MUST BE WORN. VENT AREA IF SPILLED IN CONFINED SPACE OR OTHER POORLY VENTD AREAS. PREVENT ENTRY INTO SEWERS & WATERWAYS. PICK UP FREE LIQUID FOR RECYCLE &/OR DISPOSAL. RE SIDUAL LIQUID CAN BE ABSORBED ON INERT MATERIAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL TO ENSURE CONFORMITY TO LOCAL, STATE AND FEDERAL DISPOSAL REGULATIONS. Handling And Storage Precautions: OPEN CONTAINER IN A WELL VENTILATED AREA. AVOID BREATHING VAPORS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions: WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. EMPTY CONTAINER CONTAINS PRODUCT RESIDUE WHICH MAY EXHIBIT HAZARDS OF PRODUCT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 171F,77C Extinguishing Media: USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. USE FOAM, DRY CHEMICAL OR WATER TO EXTINGUISH FIRE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: TOXIC FUMES, GASES OR VAPOR MAY EVOLVE ON BURNING. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH APPRVD FULL FACE RESPIRATOR W/COMBINATION ORGANIC VAPOR & HIGH EFFICIENCY FILTER CARTRIDGE IF EXPOSURE LIMIT IS EXCEEDED. USE NIOSH APPRVD SELF CONTAINED BREATHING APPARATUS FOR ENTRY INTO C ONFINED SPACE & FOR OTHER (SUPDAT) Ventilation: USE LOCAL EXHAUST VENTILATION TO CONTROL MISTS OR VAPORS AT A LEVEL BELOW THE ESTABLISHED EXPOSURE LIMITS. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). LONG SLEEVE SHIRT & LONG PANTS RECOMD. USE PROTECTIVE BOOTS (SUPDAT) Work Hygienic Practices: DO NOT WEAR RINGS, WATCHES/SIMILAR APPAREL THAT COULD ENTRAP MATL & CAUSE SKIN RXN. LAUNDER CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health: HAZ DECOMP PRODS: OXIDES OF THE FOLLOWING ELEMENTS MAY BE FORMED: NOT DETERMINED. FIRST AID PROC: OF WATER. GET IMMED MED ATTN. RESP PROT: POORLY VENTILATED AREAS & FOR LARGE SPILL CLEAN-UP SITES. OTH ER PROT EQUIP: WHEN NECESSARY TO AVOID CONTAMINATING SHOES. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 0.9 @ 60F Solubility in Water: INSOLUBLE Appearance and Odor: DARK RED LIQUID; MILD AROMATIC ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE, ALDEHYDES AND OTHER PRODUCTS OF INCOMPLETE COMBUSTION. UNDER COMBUSTION CONDITIONS, (SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: OTR PREMIUM PLUS 4, 44-20-2 Cage: XNDEX Company Name: INDEX INDUSTRIES INC Street: 1645 EASTERN AVD SE Zipcode: 49507 Label Required IND: Y Date Of Label Review: 12/17/1996 Status Code: C Label Date: 12/17/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: EYES: IRRITANT. SKIN: IRRITANT. INHALATION: RESPIRATORY IRRITATION. INGESTION: IRRITATION OF GASTROINTESTINAL LINING, NAUSEA, VOMITING, DIARRHEA AND ABDOMINAL PAIN. CHRONIC: PROLON GED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS WITH REDNESS, EDEMA, DRYING, DEFATTING AND CRACKING OF SKIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HARDNER 20 (EPOXY HARDNER) Kit Part:Y Preparer's Name:DAVID HAAS CAGE:GO416 CAGE:GO416 CAGE:18565 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER (INGREDIENT #1 & 2 ARE USED TO MAKE SILVER-PLATED COPPER= >90%) CAS:7440-22-4 RTECS #:VW3500000 Other REC Limits:NONE SPECIFIED. OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Other REC Limits:NONE SPECIFIED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2MG/M3 FUME; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POLYAMIDE RESIN CAS:68410-23-1 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED BY M. Ingred Name:TRIETHYLENE TETRAMINE CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: <2% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:CORROSIVE. MAY CAUSE BURNS AND PERMANENT CORNEAL INJURY RESULTING IN LOSS OF EYESIGHT. SKIN;CORROSIVE, MAY CAUSE SEVERE BURNS/BLISTERING, SENSITIZATION/ALLERGIC REACTIONS. INHALATION:VAPORS MAY CA USE IRRITATION, NAUSEA AND HEADACHE. INGESTION:HARMFUL,BURNS TO GI TRACT. CHRONIC-LIVER/KIDNEY INJURYAND ARGYRIA. Effects of Overexposure:EYE:BURNS,REDNESS, PAIN, BLURRED VISIONS. INHAL:IRRITATION, NAUSEA & HEADACHES. INGEST:BURNS TO MOUTH, STOMACHACHE, DIARRHEA. EXCESSIVE OR PROLONGED CONTACT WITH SILVER OR SILVER COMPOUNDS HAS BEEN KN OWN TO CAUSE ARGYRIA, A BLUE-GRAY DISCOLORATION OF THE SKIN. Medical Cond Aggravated by Exposure:SKIN AND EYE DISORDERS. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED. EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIS T. INGESTION:DO NOT INDUCE VOMITING, DRINK 1-2 GLASSES OF WATER. GET MEDICAL HELP IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. CLOSED CONTAINERS MAY VIOLENTLY RUPTURE UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL:ACTIVATE AVAILABLE EXHAUST VENT EQUIP IN IMMED SPILL AREA. WIPE UP/ABSORB W/VERMICULITE OR SIMILAR MATL. WASH AREA W/SOAPY WATER TO REMOVE RESIDUE. COLLECT ABSORBED MATL & WATER RINSES IN APPROP CNTNRS. LGE SPILLS:LIMIT ACCESS, DIKE TO SPILL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY LOCATION W/ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN USE. KEEP AWAY FROM OPEN FLAMES AND HEAT SOURCES. Other Precautions:AVOID CONTACT WITH SKIN OR EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROPRIATE, NIOSH APPROVED PROPERLY FITTED RESPIRATOR IF EXPOSURES EXCEED TLV VALUES. Ventilation:MECHANICAL/LOCAL EXHAUST RECOMMENDED TO DRAW VAPORS, MISTS OR FUMES AWAY FROM WORKERS. Other Protective Equipment:CHEM RESISTANT APRON, IMPERVIOUS CLTHG. EMERG EYE WASH & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS/FACE AFTER HANDLING, BEFORE EATING, DRINKING, SMOKING. WORK CLTHG SHOULD BE WASHED BEFORE RE-USE. Supplemental Safety and Health THIS IS PART B OF A TWO PART KIT. PART A IS CHO-BOND 360, SEE PART A, SAME NSN. FOR BEST RESULTS MIX PART A & B IN 1:1 RATIO JUST BEFORE USE. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:>1.5 Appearance and Odor:SILVER PASTE, AMINE ODOR. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, OXIDIZERS, BASES. Stability Condition to Avoid:STORAGE IN OPEN CONTAINERS,OPEN FLAMES,UNCONTROLED EXPOSURE TO HEAT, UNCONTROLED MIXING W/CURING AGENTS,EXPOS TO INCOMP Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN AND OTHER ORGANIC SUBSTANCES MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS. ALL COMPONENTS ARE EITHER TSCA OR SARA REGULATED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LITHIUM-ALLOY THERMAL BATTERIES Resp. Party Other MSDS Num.:EAP-12035 (CROSSOVER BATTERY) Preparer's Name:HMIS CAGE:81855 Contract Num:SP0430-00-C0836 CAGE:81855 ============= Composition/Information on Ingredients ============= Ingred Name:LITHIUM ALUMINUM OR LITHIUM SILICON ALLOY (ANODE ELECTRODE) Other REC Limits:NONE RECOMMENDED Ingred Name:FERROUS DISULFIDE (CATHODE ELECTRODE) Other REC Limits:NONE RECOMMENDED Ingred Name:MIXTURE OF CHLORIDE, BROMIDE & IODIDE SALTS OF LITHIUM & POTASSIUM (ELECTROLYTE) Other REC Limits:NONE RECOMMENDED Ingred Name:IRON POTASSIUM PERCHLORATE (PYROTECHNIC THERMAL ENERGY SOURCE) Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MANUFACTURER REGARDS THIS BATTERY AS AN "ARTICLE" AS DEFINED IN 29CFR 1910.1200. BATTERY IS HERMETICALLY SEALED. PRIMARY HAZARD TO A PERSON DURING NORMAL OPERATION OF A THERM BATERY IS THE HEAT DISSI PATED TO OUTER CASE (350-650 F), SUFFICIENT TO CAUSE SEVERE BURNS TO EXPOSED SKIN. THERMAL BATTERIES SHOULD NEVER BE HANDLED DURING ACTIVATION AND SHOULD BE TREATED AS ANY OTHER "LIVE" SOURCE OF ELEC TRIC POWER, AND CAN CAUSE ELECTRIC SHOCK. IF INTERNAL SHORTING OCCURS, TOXIC GASES MAY BE VENTED. Effects of Overexposure:SEVERE BURNS TO SKIN, SEVERE ELECTRIC SHOCK. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:HMIS:FOLLOW AMERICAN RED CROSS FIRST AID PROCEDURES. IN CASE OF SKIN BURNS OR ELECTRIC SHOCK GET IMMEDIATE MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:SMOTHER FIRE WITH ANHYDROUS (DRY) SALT SUCH AS POTASSIUM CHLORIDE OR SODIUM CHLORIDE. DO NOT USE WATER OR CO2- BASED FIRE EXTINGUISHING EQUIPMENT. Fire Fighting Procedures:SPRAY LARGE AMOUNTS OF WATER UNTIL ALL BATTERIES ARE COOL. WEAR PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:IF BATTERY IS IN FIRE, IT MAY RUPTURE. RISK OF EXPLOSION IS POSSIBLE. SPRAY WITH LARGE AMOUNTS OF WATER UNTIL ALL BATTEIES ARE COOL. THEN PLACE ALL BATTERIES IN A STEEL DRUM OR CONTAINER. ================== Accidental Release Measures ================== Spill Release Procedures:IF NOT DAMAGED, BATTERIES CAN BE PICKED UP. AVOID SHORTING. IF RUPTURED BUT NOT HOT, THE BATTERY CAN BE PLACED IN A STEEL CONTAINER. IF BATTERY IS IN WATER OR SPRAYED WATER, RISK OF FIRE IS PRESENT BU T NO EXPLOSION. IF BATTERY IS HOT &/OR RUPTURED SPRAY WITH LARGE AMOUNTS OF WATER TO KEEP COOL. AFTER BATTERY IS COOL, NO HEALTH HAZARD IS PRESENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SORE BELOW 165 F. STORAGE AT 200 - 650 F CAN CAUSE DEGRADATION OF THE SQUIB OR PRIMER. THIS WILL CAUSE THE BATTERY NOT TO ACTIVATE. STORAGE ABOVE 650 F WILL CAUSE PERMANENT DEGRADATION OF THE ACTIVATI ON DEVICE & THE BATTERY CELLS. Other Precautions:IF BATTERY IS STORED ABOVE 650F, BATTERY BECOMES ACTIVATED & CURRENT BEGINS TO FLOW BETWEEN ANODE & CATHODE. THE BATTERY WILL GRADUALLY SELF DISCHARGE. ACTIVATED BATTERY IS HAZARDOUS TO HANDLE WITH B ARE HANDS. DANGER OF ELECTRIC SHOCK & SKIN BURNS ! ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. NONE REQUIRED UNDER NORMAL USE. Ventilation:VENTILATE AREA W/FRESH AIR IF INTERNAL SHORTING HAS BEGUN. Other Protective Equipment:STANDARD OSHA APPROVED WORKPLACE ATTIRE. AT Work Hygienic Practices:PHYSICAL SIGNS OF AN IMPEDING RUPTURE INCLUDE A SUDDEN DROP IN OUTPUT VOLTAGE, & THE DEVELOPMENT OF A RED GLOWING DOT ON THE BATTERY SURFACE. SHOULD THIS HAPPENS, IMMEDIATELY EVACUATE THE AREA. Supplemental Safety and Health NOTE:MSDS GENERATED FROM THE INFO PROVIDED BY MR. DAVE PATTISON & MR. BRUCE HAYS (EAGLE-PICHER, 417-623-8000), & EP-MP-1299 GENERAL SAFE HNDLG PROCEDURES/HAZ INFO FOR LITHIUM-ALLOY THERMAL BATTERIES. NAVAL SEA SYSTEMS COMMAND PART # 6300534-01. ================== Physical/Chemical Properties ================== HCC:Z6 Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:NA pH:NA Viscosity:NA Evaporation Rate & Reference:NA Solubility in Water:NA Appearance and Odor:NOT PROVIDED Percent Volatiles by Volume:NA Corrosion Rate:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHEMICALS THAT DEGRADES STAINLESS STEEL. Stability Condition to Avoid:HIGH TEMPERATURES, ABUSE HNDLG, STATIC ELECTRICITY. IGNITION SOURCES WHEN VENTING (HYDROGEN GAS). Hazardous Decomposition Products:GASES VENTED: HYDROGEN, NITROGEN, CO, SULFUR DIOXIDE, HYDROGEN SULFIDE, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS THE SOLE RESPONSBILITY OF THE END USER TO CONFORM TO LOCAL, STATE & FEDERAL WASTE-MANAGEMENT REGULATIONS. EAGLE-PICHER WILL SUPPLY ON REQUEST LIST OF CONTENTS OF THERMAL BATTERY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GLIDSAFE PREPSOLVE CAGE:84397 CAGE:84397 ============= Composition/Information on Ingredients ============= Ingred Name:PROPRIETARY COMPONENT Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: UNDILUTED LIQUID MAY BE IRRITATING TO SKIN AND EYES. INHALATION OF VAPOR IS IRRITATING TO THROAT AND LUNGS. CHRONIC: THIS PRODUCT MAY CONTAIN TRACE AMOUNTS OF DEGRADATION COMPONENTS THAT RAE AL LERGIC TO SENSITIVE INDIVIDUALS. AVOID REPEATED AND PROLONGED CONTACT WITH SKIN. Explanation of Carcinogenicity:NOT CONSIDERED A CARCINOGEN BY: NTP AND IARC. Effects of Overexposure:CAN CAUSE EYE DAMAGE AND SKIN IRRITATION. HARMFUL IF SWALLOWED. INHALATION MAY CAUSE NAUSEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE-REMOVE CONTACT LENSES. FLUSH WITH WATER FOR 15-20 MIN SEE PHYSICIAN IMMEDIATELY. SKIN-REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA WITH PLENTY OF SOAP & WATER. IF IRRITATION DEVELOPS SEE PHYSI CIAN. INHALATION-SEEK FRESH AIR IMMEDIATELY. IF BREATHING IS DIFFICULT, SEE PHYSICIAN. INGESTION-DRINK WATER TO DILUTE SUBSTANCE. SEE PHYSICIAN IMMEDIATLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:122F,50C Autoignition Temp:Autoignition Temp Text:460F Lower Limits:0.7 Upper Limits:6.1 Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. IF WATER MUST BE USED, USE AS A SPRAY. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. AVOID HEAT, SPARKS AND OPEN FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:LARGE SPILL: MAY BE DIKED WITH EARTH AND PUMPED TO CLOSED CONTAINER FOR RECOVERY OR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:USUAL PRECAUTIONS FOR FLAMMABLE LIQUIDS. STORE IN COOL, DRY LOCATION. AVOID PROLONGED EXPOSURE TO AIR. Other Precautions:D-LIMONENE SLOWLY REACTS WITH OXYGEN TO FORM COMPOUNDS THAT AREA ALLERGENIC TO SENSITIVE INDIVIDUALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. IF VAPOR CONCENTRATION IS HIGH, USE A NIOSH APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:NOT NORMALLY REQUIRED. MECHANICAL EXHAUST MAY BE NEEDED IN CONFINED SPACES. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:325F,163C Vapor Pres:1.0 Vapor Density:4.7 Spec Gravity:0.844 Appearance and Odor:CLEAR, NEARLY COLORLESS LIQUID WITH A STRONG CITRUS ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AT A GOVERNMENT APPROVED LANDFILL, INCINERATION, OR RECOVERY FACILITY. OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9510-M SUPERCOTE RUBERIZED VOC Preparer's Name:JOSEPH FOGEL CAGE:DO691 CAGE:24072 CAGE:DO691 ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT FUMES, ASPHALT, CUTBACK ASPHALT CAS:8052-42-4 RTECS #:CI9900000 Fraction by Wt: 40-70% Other REC Limits:5 MG/CUM OSHA PEL:5 MG/CUM (RESP DUST) ACGIH TLV:5 MG/CUM Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 1-5% Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 15-40% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-5% ACGIH TLV:25 PPM Ingred Name:SILICA, MICA, MUSCOVITE CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 5-10% OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (LAB ANIMAL): >5 G/KG SEE SUP Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT/MUCOUS MEMBRANE IRRITATION, CNS EFFECTS, RESPIRATORY FAILURE. INGESTION: HARMFUL/FATAL, MOUTH/THROAT/GI TRACT IRRITATION. SKIN: DEFATTING/DERMATITIS. ASPIRATION INTO THE LUNGS CAN CAUSE SEVERE CHEMICAL PNEUMONITIS, WHICH CAN BE FATAL. VAPORS AFFECTS: HEART/LIVER/BRAIN/KIDNEYS/RESPIRATORY SYSTEM. Explanation of Carcinogenicity:ASPHALT IS KNOWN TO BE AN ANIMAL CARCINOGEN. Effects of Overexposure:INHALATION: DIZZINESS/HEADACHES/LOSS OF APPETITE/NAUSEA/GENERAL WEAKNESS/LOSS OF MEMORY/JITTERS/MIMICKING DRUNKENNESS EFFECTS/UNCONSCIOUSNESS/DEATH. SKIN: ASPHALT FUMES CAN INCREASE SENSITIVITY TO SUN & CAUSE DISCOLORATION/RASHES. EYES: IRRITATION/REDNESS/TEARING/BLURRED VISION. INGESTION: NAUSEA/VOMITING/DIARRHEA. Medical Cond Aggravated by Exposure:EYE, SKIN & RESPIRATORY PROBLEMS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER WHILE HOLDING EYELIDS OPEN. SKIN: REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE. FLUSH W/WATER/WATERLESS HAND CLEANER, ALONG W/SOAP/WATER. INHALATION: REMOVE TO FRESH AIR . GIVE OXYGEN/CPR IF NECESSARY. INGESTION: INDUCE VOMITING UNDER MEDICAL SUPERVISION. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS. ASPIRATION HAZARD. KEEP WARM/QUIET. OBTAIN MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F Lower Limits:0.8% Upper Limits:5.0% Extinguishing Media:USE FOAM, CO2, OR DRY CHEMICALS Fire Fighting Procedures:FLAMMABLE, CLEAR AREA. DON'T ENTER UNTIL CONTROLLED W/OUT FULL PROTECTIVE EQUIPMENT, INCLUDING SCBA. COOL FIRE-EXPOSED CONTAINERS W/WATER. Unusual Fire/Explosion Hazard:FLAMMABLE. SOLVENT NAPHTHA LIGHT AROMATIC & MINERAL SPIRITS ARE COMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. EVACUATE AREA UNTIL UNDER CONTROL. SOAK UP RESIDUE W/AN ABSORBENT SUCH AS SAND OR EARTH. PREVENT MATERIAL FROM ENTERING SEWERS OR WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY SOURCES OF IGNITION SUCH AS HEAT OR FLAME. AVOID REPEATED CONTACT WITH SKIN. KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:DON'T WEAR CONTACT LENSES WHEN HANDLING THIS MATERIAL. DON'T SMOKE IN ANY CHEMICAL HANDLING OR STORAGE AREA. FOOD OR BEVERAGES SHOULD NOT BE CONSUMED IN THE AREAS IMMEDIATE TO THE USE OF THIS PRODUCT. MATERIAL IS SENSITIVE TO STATIC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED USE NIOSH/MSHA APPROVED BREATHING APPARATUS. Ventilation:NOT REQUIRED. USE POSITIVE VENTILATION IF SPRAYED IN AN ENCLOSED AREA. Other Protective Equipment:NORMAL LONG-SLEEVED & LONG-PANTS WORK CLOTHES. PROTECTIVE CREAMS, RUBBER APRON. Work Hygienic Practices:WASH HANDS BEFORE EATING/SMOKING OR USING TOLIET. A COMPLETE SOAP/WATER SHOWER SHOULD BE TAKEN AT THE END OF EACH DAY. Supplemental Safety and Health LD50-MINERAL SPIRITS. NOTE TO PHYSICIAN: IF MORE THAN 2 ML PER KG HAS BEEN INGESTED & VOMITING HASN'T OCCURRED, EMESIS SHOULD BE INDUCED W/SUPERVISION. IF GAG REFLEX/CONVULSIONS/UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. 40 TIMES SLOWER THAN ETHYL ETHER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300-390F Vapor Pres:5 Vapor Density:3.9 Spec Gravity:0.94 Evaporation Rate & Reference:SEE SUPP Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK LIQUID, MINERAL SPIRITS ODOR Percent Volatiles by Volume:25-35 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Stability Condition to Avoid:SOURCES OF IGNITION SUCH AS HEAT OR FLAME Hazardous Decomposition Products:CO, CO2, & UNIDENTIFIED ORGANIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO ALL FEDERAL, STATE & LOCAL CODES. FLAMMABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PROPRIETARY MIXTURE OF HIGH FUSING POLYMERS Preparer's Name:L D HOCHHAUSER CAGE:2W369 CAGE:2W369 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: SLIGHTLY IRRITATING. MOLTEN WAX CAN CAUSE BURNS. EYES: MAY CAUSE IRRITATION. INHALATION: MILD IRRITATION TO RESPIRATORY TRACT IF HEATED TO DECOMPOSTION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS ======================= First Aid Measures ======================= First Aid:SKIN: MOTEN WAX: RINSE IMMEDIATELY W/COOL WATER, TREAT FOR ANY THERMAL BURNS. EYES: FLUSH W/LARGE AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:400F Extinguishing Media:DRY CHEMICAL, FOAM/CO2 Fire Fighting Procedures:AVOID SKIN CONTACT. MOLTEN WAX WILL CAUSE THERMAL BURNS UNLESS COOLED PROMPTLY. Unusual Fire/Explosion Hazard:WATER SPRAY MAY BE INEFFECTIVE/SPREAD MELTED BURNING WAX. COULD GENERATE IRRITATING FUMES/SMOKE. ================== Accidental Release Measures ================== Spill Release Procedures:CAN BE SWEPT UP & DISPOSED OF IN ANY APPROPRIATE TRASH. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS WELL CLOSED. STORE IN COOL, DRY, WELL VENTILATED AREA. FOR LABORATORY/OFFICE USE ONLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID HEAT/DIRECT SUNLIGHT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED IN NORMAL USE. Ventilation:LOCAL EXHAUST NOT NECESSARY IN NORMAL USE, UNLESS MUCH FUMES ARE GENERATED. MECHANICAL (GENERAL): IS ACCEPTABLE. Other Protective Equipment:EYE WASH STATION. Work Hygienic Practices:NORMAL PRECAUTIONS OF LABORATORY GOOD HOUSEKEEPING PRACTICES SHOULD BE FOLLOWED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:240F Spec Gravity:<1 Solubility in Water:INSOLUBLE Appearance and Odor:ORANGE-RED WAXY SOLID W/VERY SLIGHT WAXY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXTREME HEAT, DIRECT SUNLIGHT Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: CARBON OXIDES, FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:LAB QUANTITIES CAN ENTER REGULAR TRASH. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METAL FRAMING BATTS CAGE:45255 CAGE:45255 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS, OXIDE *92/3* CAS:65997-17-3 Fraction by Wt: 85-96% Other REC Limits:10 MG/CUM 8 HR TWA Ingred Name:UREA EXTENDED PHENOL FORMALDEHYDE RESIN CURED *92-3* CAS:25104-55-6 Fraction by Wt: 4-15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: UPPER RESPIRATORY TRACT, MOUTH, NOSE, & THROAT IRRITATION. SKIN: ITCHING & TEMPORARY MECHANICAL IRRITATION. EYES: TEMPORARY MECHANICAL IRRITATION. INGESTION: DIGESTIVE TRACT TEMPORARY MECH ANICAL IRRITATION. Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY OR SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/MILD SOAP & RUNNING WATER. USE A WASHCLOTH TO HELP REMOVE FIBERS. TO AVOID FURTHER IRRITATION DO NOT RUB OR SCRATCH IRRITATION AREAS. RUBBING OR SCRATCHIN G MAY FORCE FIBERS INTO SKIN. USE OF BARRIER CREAM CAN BE HELPFUL. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, DRY CHEMICAL Fire Fighting Procedures:IN A SUSTAINED FIRE, SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. Unusual Fire/Explosion Hazard:VINYL FACED IN FIRE CONDITIONS MAY GIVE OFF HYDROGEN CHLORIDE, A HIGHLY IRRITATING & TOXIC GAS. EVACUTE THE BUILDING IMMEDIATELY. ================== Accidental Release Measures ================== Spill Release Procedures:USE VACUUM EQUIPMENT TO CLEAN DUSTS & FIBERS. AVOID SWEEPING OR USING COMPRESSED AIR AS THESE TECHNIQUES RESUSPEND DUSTS & FIBERS INTO THE AIR. ======================Handling and Storage ====================== Handling and Storage Precautions:INSULATION SHOULD BE STORED IN A DRY PLACE. FACED MATERIAL SHOULD BE STORED WELL AWAY FROM SOURCES OF IGNITION. Other Precautions:AVOID DUST & FIBERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A PROPERLY FITTED NIOSH OR MSHA APPROVED AIR PURIFYING RESPIRATOR SUCH AS THE 3M MODEL 8710, MODEL 9900 OR EQUIVALENT. Ventilation:GENERAL DILUTION. LOCAL EXHAUST SHOULD BE PROVIDED. Other Protective Equipment:WEAR LOOSE FITTING, LONG SLEEVED SHIRT, LONG PANTS, SAFETY SHOWERS & EYE WASH FOUNTAINS. Work Hygienic Practices:WASH CLOTHES SEPARATELY & WIPE OUT WASHER, TO PREVENT FIBERS FROM GETTING ON OTHER CLOTHES. WASH HANDS THOROUGHLY. Supplemental Safety and Health APPEAR CON'T: SOME PRODUCTS HAVE A VINYL, KRAFT PAPER, FOIL OR POLYPROPYLENE FACING. ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:PINK, YELLOW, OR TAN W/FAINT RESIN ODOR. SEE SUPP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO, CO2, AMMONIA, WATER, & HYDROGEN CHLORIDE. VINYL FACED PRODUCTS WILL RELEASE HYDROGEN CHLORIDE IN A FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. THE PRIMARY METHOD OF DISPOSAL IS IN A MUNICIPAL OR INDUSTRIAL LANDFILL.
1
eyes_protection_mandatory
======================================================= Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 812-043-200 Cage: FO436 ======================================================= Contractor Summary ======================================================= Cage: 94174 Cage: FO436 Box: NK/ ======================================================= Ingredients ======================================================= Cas: 409-21-2 RTECS #: VW0450000 % Wt: 20-50 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ % Wt: 15-60 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 10-40 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL IRRITATION. SKIN/INGESTION:NO ADVERSE HEALTH EFFECTS EXPECTED. INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYST EM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEING ABRADED. CHRONIC:NOT AVAILABLE. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NOT AVAILABLE. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP N). EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES & CALL MD IF IRRITATION PERSISTS. INHAL:PROVIDE FRESH AIR , TREAT FOR SUBSTRATE MATERIAL BEING ABRADED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NO SPECIAL PROCEDURES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: COLLECT MATERIAL & DISPOSE IN A LOCAL SANITARY LANDFILL. FOLLOW FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED. NO SPECIAL HANDLING PRECAUTIONS. Other Precautions: AVOID BREATHING DUST FROM MATERIAL BEING GROUND. PREVENT SKIN OR EYE CONTACT W/DUST CREATED FROM GRINDING SUBSTRATE. NO UNUSUAL FIRE OR SPILL HAZARD; NUISANCE-LEVEL HEALTH RISK. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Lower Limits: NONE Upper Limits: NONE Extinguishing Media: WATER, CARBON DIOXIDE, FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NON-FLAMMABLE. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A NIOSH APPROVED PARTICULATE FACE MASK WHERE DUST IS GENERATED. Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: SOLID ABRASIVE PRODUCT; NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NOT DETERMINED. Hazardous Decomposition Products: THERMAL DEGRADATION WILL PRODUCE CARBON MONOXIDE, CARBON DIOXIDE & SMOKE PARTICULATES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ABRASIVE DISCS, SILICONE CARBIDE, 812-043-200 Cage: FO436 Assigned IND: Y Company Name: LECO CORPORATION Street: 3000 LAKEVIEW AVENUE PO Box: NK/ Zipcode: 49085 Label Required IND: Y Date Of Label Review: 11/16/1998 Status Code: C Label Date: 11/16/1998 Origination Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:EYES:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL IRRITATION. INHALATION:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYSTEM IRRITATION. HAZARD DEGREE BASED ON MATERIAL BEIN G ABRADED. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETONE, QUANT00184 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE; (2-PROPANONE) (SARA 313) (CERCLA). LD50: (ORAL, RAT) 5800 MG/KG. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 99% OSHA PEL:1000 PPM ACGIH TLV:750 PPM; 1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FIRST AID PROC: TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: TREAT SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: SOLDER, DRILL, GRIND OR EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS OR OPEN FLAMES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: PRDCES IRRIT CHARACTERIZED BY BURNING SENSATION, REDNESS, TEARING, INFLAMMATION & POSS CORNEAL INJURY. SKIN: EXPOS MAY CAUSE IRRIT CHARACTERIZED BY REDNESS, DRYNESS & INFLAMMATION. INGEST: MAY C AUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, KIDNEY DMG & LIVER DMG. SYMPS MAY INCL: HDCH, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: EXCITEMENT, FATIGUE, NAUS, VOMIT, STUPOR & COMA. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON & COMA. CAUSES RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DM G. MAY CAUSE MOTOR INCOORD & SPEECH ABNORMS. CHRONIC: PRLNGD/RPTD SKIN CONTACT MAY CAUSE DERMATITIS. CHRONIC (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPSOR PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MED AID IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS (ING 2) ===================== Fire Fighting Measures ===================== Flash Point:-4F,-20C Lower Limits:2.5% Upper Limits:12.8% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. FOR LARGE FIRES, USE (SUPDAT) Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNITION & FLASH BACK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CNTNRS COOL. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL WITH INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. REMOVE ALL SOURCES OF IGNITION . Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. Other Precautions:WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. AVOID CONTACT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE DANGEROUS. DO NOT PR ESSURIZE, CUT, WELD, BRAZE, (ING 4) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE PROCESS ENCLOSURE, LOC EXHST VENT OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOM EXPOS LIMITS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA: WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. MATLS TO AVOID: ANHYDRIDE, CHROMYL CHLORIDE, NITROSYL CHLORIDE, HEXACHLOROMELAMINE, NITROSYL PERCHLORATE, NITRYL PERCHLORATE, PERMONOSULFURIC ACID, THIODIGLYCOL + HYDROGEN PEROXIDE.EFTS OF OVEREXP: INHAL MAY CAUSE EFTS SIMILAR TO THOSE OF ACUTE INHAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:133F,56C Melt/Freeze Pt:M.P/F.P Text:-140F,-95C Vapor Pres:180 Vapor Density:2.0 Spec Gravity:0.79 (H*2O=1) pH:7 Evaporation Rate & Reference:7.7 (N-BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID; SWEETISH ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FORMS EXPLOSIVE MIXTURE W/HYDROGEN PEROXIDE, ACETIC ACID, NITRIC ACID, NITRIC ACID + SULFURIC ACID, CHROMIC (SUPDAT) Stability Condition to Avoid:HIGH TEMPERATURES, TEMPERATURES ABOVE 220C. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA U SERIES: CAS #67-64-1: WASTE NUMBER U002 (IGNITABLE WASTE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:02112 URSA SUPER PLUS SAE 30 CAGE:2R503 CAGE:TEXLU CAGE:0TTJ3 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED (SEVERE), HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038501 Fraction by Wt: 80-95% Other REC Limits:NONE RECOMMENDED Ingred Name:ALKENYLSUCCINIMIDE DISPERSANT Fraction by Wt: 3-10% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD 50 ORAL RAT IS > 5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: LOW HEALTH HAZARD. MINIMAL IRRITATION. INHALATION OF VAPORS OR MISTS WHEN SPRAYING MAY CAUSE IRRITATION AND DROWSINESS. CHRONIC: NONE KNOWN. Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES: MINIMAL IRRITATION. SKIN: IRRITATION, SKIN DRYING ON PROLONGED CONTACT. INHALATION: IRRITATION OF NOSE AND THROAT, HEADACHE, NAUSEA, DROWSINESS. INGESTION: DISCOMFORT, NAUSEA, DIARRHEA. Medical Cond Aggravated by Exposure:BECAUSE OF ITS DEFATTING PROPERTIES, PROLONGED AND REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, SEE DOCTOR. SKIN: WASH WITH SOAP. IF IRRITATION PERSISTS, SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR. SEE DOCT OR. INGESTION: GIVE 2 GLASSES OF WATER.DO NOT INDUCE VOMITING. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>430F,>221C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER OR FOAM MAY CAUSE FROTHING. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL. ELIMINATE IGNITION SOURCES. VENTILATE AREA. WEAR PROTECTIVE CLOTHING AND EQUIPMENT. ABSORB IN INERT MATERIAL AND PLACE IN APPROPIATE DISPOSAL CONTAINER AND COVER. ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURES SHOULD BE MINIMIZED. AVOID WATER CONTAMINATION. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:MECHANICAL (GENERAL) VENTILATION OR LOCAL EXHAUST VENTILATION TO KEEP EXPOSURE LEVELS BELOW PEL. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health USED GASOLINE MOTOR OILS HAVE BEEN SHOWN TO CAUSE SKIN CANCER WHEN REPEATEDLY APPLIED TO MOUSE SKIN WITHOUT ANY EFFORT TO REMOVE THE MATERIAL BETWEEN APPLICATIONS. THERE IS NO EVIDENCE OF A CAUSAL REL ATIONSHIP BETWEEN SKIN CANCER IN HUMANSAND EXPOSURE TO USED MOTOR OIL. ================== Physical/Chemical Properties ================== HCC:V6 Vapor Density:NKNOWN Spec Gravity:0.8916 Viscosity:111 CST @104F Solubility in Water:NEGLIGIBLE Appearance and Odor:BRIGHT AND CLEAR LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES, KETONES, OXIDES OF NITROGEN, SULFUR, CALCIUM, ZINC, PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:436 PRIMA SEAL PRIMER/SEALER/SURFACER/ISOLA Preparer's Name:S ABDUL RAZZAK CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <30% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: <2% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <1% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: <5% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:CAN CAUSE IRRITATION, REDNESS, TEARING. SKIN:PRLNGD/RPTD CONTACT MAY CAUSE IRRITATION, DEFATTING, DERMATITIS. INHAL:EXCESSIVE INHAL OF VAPORS MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, DROWSINES S, RESPIRATORY IRRITATION, POSSIBLE UNCONSCIOUSNESS & EVEN ASPHYXIATION. INGEST:CAN CAUSE GASTRO- (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:INTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA, BLINDNESS & DEATH. CHRONIC:REPORTS HAVE ASSOCIATED PRLNGD/RPTD OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING LIDS OCCASIONALLY. GET MD. SKIN:WASH W/SOAP & WATER. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. IF BREATHING DIFFICULT, GIVE OXYGEN. IF BREATHING STOPPED, GIVE ARTIFICIAL RESPIRATION. CALL MD. INGEST:DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:0F,-18C Lower Limits:2.6% Upper Limits:19% Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY. DO NOT USE WATER JET. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR. KEEP AWAY FROM SPARKS, HEAT OR OPEN FLAME. NEVER USE WELDING OR CUTTING TORCH. VAPOR MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SML SPILLS W/PAPER, VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL & TRANSFER TO HOOD. LG:REMOVE ALL SOURCES OF IGNITION & VENTILATE AREA WELL. DIKE TO PREVENT RUNOFF. TRANSFER LIQUID TO CNTNRS FO R SALVAGE/DISP & DIKING MATL TO SEPARATE CNTNRS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE W/CARE AT ALL TIMES. INSURE THAT CONTAINERS ARE TIGHTLY CLOSED. STORE AWAY FROM HEAT AND OPEN FLAMES. KEEP OUT OF REACH OF CHILDREN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF SPRAYING IS IN CONFINED, POORLY VENTILATED ARE & TLV IS EXCEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC SOLVENT VAPORS AND MIST/DUST. APPROPRIATE RESPIRATOR SELECTION DEPENDS UPON TYPE AND MAGNITUDE OF EXPOSURE. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:130F,54C Vapor Pres:97 @ 68F Vapor Density:1.11 Spec Gravity:1.6 Evaporation Rate & Reference:2.53 (BUTYL ACETATE = 1). Solubility in Water:SOLUBLE Appearance and Odor:SANDY COLOR, ACETONE/ALCOHOL ODOR. Percent Volatiles by Volume:55 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG ALKALIES, STRONG MINERAL ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CO2, CO, VARIOUS HYDROCARBONS, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MDF-474 FIXER CAGE:91345 CAGE:91345 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM CHLORIDE (SARA III) CAS:12125-02-9 RTECS #:BP4550000 Fraction by Wt: 1-5% Other REC Limits:ACGIH STEL 20 MG/CUM OSHA PEL:10 MG/M3/20 STEL ACGIH TLV:10 MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Ingred Name:ACETIC ACID CAS:64-19-7 RTECS #:AF1300000 Fraction by Wt: <1% OSHA PEL:10 PPM ACGIH TLV:10 PPM STEL 15 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT WILL IRRITATE EYES,SKIN,MUCOUS MEMBRANES,G/I TRACT. PRODUCT IS NOT NORMALLY AN INHALATION HAZARD. UNDER UNUSUAL CONDITIONS MAY PRODUCE FUMES OF ACETIC ACID OR SULFUR DIOXIDE. Effects of Overexposure:MAY CAUSE IRRITATION OF CONTACTED TISSUES. Medical Cond Aggravated by Exposure:NONE REPORTED ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. INGESTED:GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NONE REPORTED - USE MEDIA APPROPRIATE FOR THE SURROUNDING FIRE. Fire Fighting Procedures:NONE REPORTED Unusual Fire/Explosion Hazard:NONE REPORTED ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON INERT MATERIAL. Neutralizing Agent:SODIUM BICARBONATE MAY BE USED,BUT WILL NOT NORMALLY BE NECESSARY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. USE NIOSH ACID FUME RESPIRATOR IF TLV'S ARE EXCEEDED. Ventilation:NORMAL ROOM VENTILATION IS NORMALLY SUFFICIENT. USE LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:PLASTIC/RUBBER APRON Work Hygienic Practices:USE NORMAL CHEMICAL HYGIENE PRACTICE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F/100C Spec Gravity:1.280 pH:5.30 Solubility in Water:100% Appearance and Odor:CLEAR COLORLESS LIQUID,VINEGAR ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR:DILUTE 20:1;FLUSH TO DRAIN WILL BE OFTEN ACCEPTABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3120 TRV Kit Part:Y CAGE:5D028 CAGE:5D028 CAGE:71984 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== Effects of Overexposure:MAY CAUSE TEMPORARY DISCOMFORT TO EYES ======================= First Aid Measures ======================= First Aid:FLUSH W WATER ===================== Fire Fighting Measures ===================== Flash Point:>250F, 121C Extinguishing Media:CO2, FOAM ================== Accidental Release Measures ================== Spill Release Procedures:MOP, WIPE OR SOAK WITH ABSORBENT MAT'L. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL Other Protective Equipment:AS REQ'D BY YOUR COMPANY Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:<5 Vapor Density:NA Spec Gravity:1.45 Evaporation Rate & Reference:<1/ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:PASTE LIKE-VERY LITTLE ODOR Percent Volatiles by Volume:<5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:FE203, S1O2, CO2, CARBON PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE LANDFILLED OR BURNED IN ACCORD W LOCAL REGS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TOLUENE Preparer's Name:J.C. WILLETT CAGE:86961 CAGE:86961 CAGE:4W432 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC CONTENT AS LISTED ON MSDS: 7.16 LBS/GAL RTECS #:9999999VC Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 5,000 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, BRAIN, LIVER, KIDNEY, LUNG. ACUTE- MAY CAUSE EYE & SKIN IRRITATION. INGESTION MAY CAUSE VOMITING; ASPIRATION INTO LUNGS MAY CAUSE LUNG DAMAGE. INHALATION OF HIGH VAPOR CO NCENTRATIONS MAY CAUSE CNS DEPRESSION. INTENTIONAL ABUSE MAY CAUSE BRAIN, LIVER, KIDNEY DAMAGE. CHRONIC- DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, NAUSEA, VOMITING, MENTAL CONFUSION, FATIGUE, LOSS OF APPETITE, COUGH, DEFATTING, DERMATITIS, LABOR BREATHING, UNCONSCIOUSNESS, DEATH Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, LIVER, KIDNEYS, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, RINSE MOUTHWITH WATER. SEEK MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF VOMITUS INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=4.4C, 40.F Lower Limits:1 Upper Limits:7 Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL/CARBON DIOXIDE. DON'T USE DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. TOXIC GASES MAY BE PRESENT. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS SAND, EARTH OR EXPLOSION PROOF PUMP. TRANSFER TO A SUITABLE CONTAINER FOR D ISPOSAL. DO NOT FLUSH TO SEWER OR WATERWAYS. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED PLACE AWAY FROM IGNITION SOURCES AND STRONG OXIDIZING AGENTS. DO NOT TAKE INTERNALLY. Other Precautions:FLAMMABLE. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. AVOID INHALATION OF VAPORS. KEEP OUT OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD/HOUSEHOLD USE. USE WITH ADEQUATE VENTILATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING. IF REQUIRED, WORK IN A FUME HOOD OR WEAR A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR. IN EMERGENCY, WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPA RATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health NOTE TO PHYSICIAN: IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSION OR UNCONSCIOUSNESS OCCUR, GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=111.C, 231.8F Melt/Freeze Pt:=-95.C, -139.F Vapor Pres:22 @ 68F Vapor Density:3.2 Spec Gravity:0.87 Evaporation Rate & Reference:2.0 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS, MOBILE LIQUID; AROMATIC, BENZENE-LIKE ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, FLAMES, STATIC ELECTRICITY AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSIDER RECLAIMATION BY DISTILLATION OR DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. MAY BE DISPOSED OF IN AN APPROVED INCINERATOR OR CONTRACT WITH A LICENSED WASTE DISPOSA L SERVICE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PH 3.0 BUFFER SOLUTION CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: <0.1% OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM HYDROGEN PHTHALATE Fraction by Wt: >1% Ingred Name:FORMALDEHYDE (SARA III) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.04% OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM; A2; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 0.05% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 99% ===================== Hazards Identification ===================== Effects of Overexposure:EYE, SKIN/MUCOUS MEMBRANE IRRITANT, NAUSEA, VOMITING, DIARRHEA, CONJUNCTIVITIS, DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: REMOVE CONTAMINATED CLOTHING/SHOES. WASH AFFECTED W/SOAP OR MILD DETERGENT & WATER 15-20 MINS. INGESTION: GIVE 2 TO 4 GLASSES OF WATER & INDUCE VOMITING. GETTING MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY, FOG, ALCOHOL FOAM Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. NO ACUTE HAZARD. Unusual Fire/Explosion Hazard:NEGL FIRE/EXPLOSION HAZARD WHEN EXPOSED TO HEAT/FLAME. AVOID BREATHING VAPORS/DUSTS; KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE VENTILATION. ABSORB WITH VERMICULITE OR OTHER SUITABLE MATERIAL. PLACE IN A ITABLE CONTAINER (PLASTIC OR METAL), FOR LATER DISPOSAL. KEEP OUT OF SEWS AND WATER SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:PROVIDE GENERAL DILUTION VENTILATION. Other Protective Equipment:DON'T WEAR CONTACT LENSES WHEN WORKING W/CHEMICALS. Supplemental Safety and Health MSDS DATE: 09/24/85. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:14 Vapor Density:0.7 Spec Gravity:1.0 Evaporation Rate & Reference:(ETHER = 1) >1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OLEUM, SODIUM Stability Condition to Avoid:AVOID CONTACT W/STORAGE W/INCOMPATIBLE MATERIALS Hazardous Decomposition Products:A SMALL AMT OF HYDROGEN CHLORIDE GAS/TRACE OF FORMALDEHYDE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TEFLON, 30B Preparer's Name:W.H. MARTIN CAGE:18873 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE, TETRAFLUORO-, POLYMER; (POLY(TETRAFLUOROETHYLENE)) CAS:116-14-3 RTECS #:KX4025000 Fraction by Wt: 5-62% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OCTYLPHENOXY POLYETHOXY ETHANOL (SURFACTANT) CAS:9036-19-5 Fraction by Wt: 0-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NONYLPHENOL POLY ETHOXATE; (NONYLPHENOL POLYETHYLENE OXIDE) CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: 0-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 33-40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OCTANOIC ACID, PENTADECAFLUORO-,AMMONIUM SALT; (AMMONIUM PERFLUOROOCTANOATE) CAS:3825-26-1 RTECS #:RH0782000 Fraction by Wt: <0.5% OSHA PEL:N/K ACGIH TLV:0.1 MG/M3 Ingred Name:SUPP DATA:AT ABOUT 400 DEG C (750 DEG F), WITH LARGER AMOUNTS AT HIGHER TEMPERATURES. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP:CAN OCCUR IN AMTS CAPABLE OF PRODUCING EFTS OF SYSTEMIC TOXICITY. EYE CNTCT MAY CAUSE EYE IRRIT (ING 8) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 7:W/DISCOMFORT, TEARING/BLURRING OF VISION. INHAL MAY CAUSE IRRIT OF UPPER RESP PASSAGES, W/COUGHING (ING 9) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 8:DISCOMFORT. INGEST MAY CAUSE GI TRACT IRRIT; ABNORMAL LIVER FUNCTION AS DETECTED BY LAB TESTS/ABNORMAL (ING 10) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 9:BLOOD FORMING SYS FUNCTION W/ANEMIA. INDIVIDUALS W/PREEXISTING DISEASES OF LIVER/BONE MARROW MAY HAVE INCR(ING 11) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 10:SUSCEPTIBILITY TO TOXICITIY OF EXCESS EXPOS. CMPD IS ABSORBED BY BODY & MAY BE DETECTED IN BLOOD STREAM (ING 12) RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 11:FOLLOWING INGEST, INHAL/SKIN CNTCT. ANIMAL & HUMAN EXPERIENCE INDICATE THAT CMPD HAS LONG HALF-LIFE IN (ING 13) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 12:BLOOD, AND MAY BE DETECTED YEARS AFTER EXPOSURE. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FIRST AID:FOR THERMAL BURNS. EYES:IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN. CALL MD. INGEST:IMMED (ING 15) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 14:GIVE 2 GLASSES OF WATER & INDUCE VOM. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL MD. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WASTE DISP METH:ONLY IF INCIN IS CAPABLE OF SCRUBBING OUT HYDROGEN FLUORIDE & OTHER ACIDIC COMBUST PRODS. (ING 17) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 16:TREATMENT, STOR, TRANSPORTATION, & DISPOSAL MUST BE IN ACCORD W/APPLIC FED, STATE/PROVINCIAL, & LOCAL REGS. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESP PROT:FLUORIDE & CARBONYL FLUORIDE CONC BELOW EXPOS LIMITS, USE A NIOSH/MSHA APPROVED POS PRESS AIR SUPPLIED RESP. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL OF FUMES FROM OVERHEATING "TEFLON" PTFE MAY CAUSE POLYMER FUME FEVER/TEMP FLU-LIKE ILLNESS W/FEVER, CHILLS, SOMETIMES COUGH OF APPROX 24HRS DURATION. ING 2&3:SKIN CNTCT MAY CAUSE SKIN IRRIT W/DI SCOMFORT/RASH. EYE CNTCT MAY CAUSE EYE IRRIT W/DISCOMFORT, TEARING/BLURRING OF VISION. PERM EYE DAM MAY(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OCCUR FROM PRLNGD EXPOS. INHAL MAY CAUSE UPPER RESP TRACT IRRIT W/COUGHING & DISCOMFORT. INGEST MAY CAUSE GI IRRIT W/UPPER ABDOMINAL PAIN, "HEART BURN", NASAL, VOM, & DIARR; HOWEVER, THERE MA Y BE NO SYMPS AT ALL. ING 5:SKIN CNTCT MAY CAUSE SKIN IRRIT W/DISCOMFORT/RASH. EVIDENCE SUGGESTS SKIN PERMEATION (ING 7) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURE FROM THERMAL DECOMPOSITION PRODUCTS. ======================= First Aid Measures ======================= First Aid:INHAL:NO SPEC INTERVENTION IS INDICATED AS CMPD IS NOT LIKELY TO BE HAZ BY INHAL. CONSULT MD IF NECESSARY. IF EXPOSED TO FUMES FROM OVERHEATING/COMBUST, MOVE TO FRESH AIR. CONSULT MD IF SYMPS PERSIST. SKIN:FLUSH SKIN W/WATER AFTER CONTACT.WASH CONTAM CLTHG BEFORE REUSE. IF MOLTEN MATL GETS ON SKIN, COOL RAPIDLY W/COLD WATER. DO NOT ATTEMPT TO REMOVE MATL FROM SKIN. OBTAIN MED TREATMENT (ING 14) ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:DOES NOT FLASH Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2 Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DOES NOT BURN W/OUT AN EXTERNAL FLAME. PROT FROM HYDROGEN FLUORIDE FUMES WHICH REACT W/WATER TO FORM ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP WITH SAWDUST, SAND, OIL DRY OR OTHER ABSORBENT MATERIAL. SHOVEL OR SWEEP UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED TO AVOID CONTAMINATION. AVOID FREEZING TEMPS. TEMPS BETWEEN 60 AND 80 DEGREES (16 TO 27 DEG C) RECOMMENDED. Other Precautions:AVOID CONTAMINATION OF CIGARETTES OR TOBACCO. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AT PROCESSING TEMPS LESS THAN 400 DEG C (750 DEG F) NIOSH/MSHA APPRVD AIR PURIFYING RESP W/HIGH EFFICIENCY DUST/MIST CARTRIDGE/CANISTER. FOR PROCESSING TEMPS ABOVE 400 DEG C (750 DEG F), IF VENT IS IN ADEQ TO MAINTAIN HYDROGEN (ING 18) Ventilation:USE LOCAL EXHAUST TO COMPLETELY REMOVE VAPORS AND FUMES LIBERATED DURING HOT PROCESSING FROM THE WORK AREA. Other Protective Equipment:WEAR IMPERVIOUS APRON, BOOTS OR WHOLE BODYSUIT MADE FROM NEOPRENE, AS APPROP TO AVOID SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SOL IN H*2O:SOLIDS INSOL; DISPERSION MAY BE DILUTED. EXPLO HAZ:HNDLG REFUSE FROM FIRE INVOLVING "TEFLON". MATLS TO AVOID:FLUORINE (F*2) & RELATED CMPDS (E.G., CHLORINE TRIFLUORIDE, CLF*3). CNTCT W/INC OMPATIBLES CAN CAUSE FIRE/AN EXPLO. HAZDECOMP:TRACE AMTS OF HYDROGEN FLUORIDE & CARBONYL FLUORIDE MAY BE EVOLVED(ING 6) ================== Physical/Chemical Properties ================== Spec Gravity:2.1-2.3 pH:10 Solubility in Water:SUPP DATA Appearance and Odor:MILKY LIQUID, SLIGHT AMMONIA ODOR. Percent Volatiles by Volume:33-40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE/CAN REACT W/FINELY DIVIDED METAL POWDERS (E.G., ALUMINUM & MAGNESIUM) & POTENT OXIDIZERS LIKE (SUPP DATA) Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE CONDITIONS. Hazardous Decomposition Products:HEATING ABOVE 300 C (572 DEG F) MAY CAUSE EVOLUTION OF PARTICULATE MATTER, WHICH CAN CAUSE POLYMER FUME FEVER (SUP DAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:(1)SEPARATE SOLIDS FROM LIQ BY PRECIPITATION & DECANTING/FILTERING. DISP OF DRY SOLIDS IN LANDFILL THAT IS PERMITTED, LICENSED/REGISTERED BY STATE TO MANAGE INDUSTRIAL SOLID WASTE. DISCHARGE LIQ FILTR ATE TO WASTEWATER TREATMENT SYS. (2)INCIN (ING 16)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BRITE Resp. Party Other MSDS Num.:110140015 CAGE:32204 CAGE:TO440 CAGE:32204 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL MONOETHYL ETHER CAS:111-90-0 RTECS #:KK8750000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:AMMONIUM HYDROXIDE CAS:1336-21-6 RTECS #:BQ9625000 Minumum % Wt:1. Maxumum % Wt:5. EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:STYRENE ACRYLIC POLYMER Minumum % Wt:10. Maxumum % Wt:20. Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:75. Maxumum % Wt:85. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:(ALSO, SEE SECTION 11, TOXICOLOGY INFORMATION.) EFFECTS OF ACUTE EXPOSURE: EYE: MAY CAUSE MODERATE EYE IRRITATION. SKIN: NONE KNOWN. INHALATION: NONE KNOWN. INGESTION: NONE KNOWN. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGESTION: CALL MD IMMEDIATELY . NO SPECIAL REQUIREMENTS. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NO SPECIAL REQUIREMENTS. SKIN: FLUSH WITH COPIOUS AMOUNTS OF W ATER. CALL MD . NO SPECIAL REQUIREMENTS. EYE CONTACT: RINSE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM. CO*2. DRY CHEMICAL. WATER FOG. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . NORMAL FIRE FIGHTING PROCEDURE MAY BE USED. Unusual Fire/Explosion Hazard:NO SPECIAL REQUIREMENTS. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE LARGE SPILLS. ABSORB WITH OIL-DRI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP AND CONTAINERIZE. RINSE AFFECTED AREA THOROUGHLY WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:CAUTION: EYE IRRITANT. AVOID CONTACT WITH EYES. KEEP OUT OF REACH OF CHILDREN. KEEP FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NO SPECIAL REQUIREMENTS. NORMAL USE CONDITIONS. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . OTHER PROTECTIVE MEASURES: NO SPECIAL REQUIREMENTS. Supplemental Safety and Health PHYSICAL DATA: VOC: NOT AVAILABLE; THEORETICAL VOC (LB/GAL): NOT AVAILABLE. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:NOT AVAILABLE Vapor Density:NOT AVAIL Spec Gravity:1.0 (H*2O=1) pH:9.6-9.9 Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:COMPLETE Appearance and Odor:OPAQUE LIQUID; LEMON ODOR. Percent Volatiles by Volume:85.8-87.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. =================== Toxicological Information=================== Toxicological Information:(ALSO SEE SECTION 3, HEALTH HAZARDS IDENTIFICATION.) EFFECTS OF CHRONIC EXPOSURE: NONE KNOWN. OTHER INFO: PRODUCT IDENTIFICATION: REASON FOR CHANGE: NO SIGNIFICANT CHANGES. SECTION 9. PRODUCT USE: HOME CARE FLOOR CARE. UPC / SCJ CODE: 62300 00752 / 752, QTY: 12, CANADIAN SIZE: 470 ML. UPC / SCJ CODE: 62300 10753 / 20753, QTY: 6, CANADIAN SIZE 940 ML. UPS / SCJ CODE: 19800 08512 / 20753, QTY: 6,US SIZE: 64 OZ, CANADIAN SIZE 1.9 L. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL DATA: NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL METHOD. OBSERVE ALL APPLICABLE FEDERAL/PROVINCIAL/STATE AND LOCAL/MUNICIPAL ORDINANCES REGARDING DISPOSAL OF NON-HAZARDOUS MATERIALS. =================== MSDS Transport Information =================== Transport Information:US DOT INFORMATION - PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE SHIPPING INFORMATION. ===================== Regulatory Information ===================== Federal Regulatory Information:ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON THE US TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY. State Regulatory Information:THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER CALIFORNIA'S PROPOSITION 65. ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: SILVER (HARD, HEAVY BUILD) PLATING SOLUTION, 30308305 Cage: DO645 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 11924 Cage: DO645 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: DANGER! MAY BE FATAL IF SWALLOWED, INHALED, ABSORBED THRU SKIN. HIGHLY TOX LIQ, VAP, & GAS. CORR LIQS & MIST. CAUSES BURNS. MAY CAUSE ALLERGIC SKIN RXN. MAY LIBERATE FLAMM GAS. ACUTE:INGEST & INHAL AB SORPTION THRU SKIN:AVG FATAL DOSE 50-60MG CYANIDE. AMTS ABOVE MILD CAUSES IMMED UNCONSCIOUSNESS, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:CONVLS, DEATH W/IN 1-15 MIN. AMTS NEAR MLD CAUSE DIZZ, RAPID RESP, VOMIT, FLUSHING, HDCH, DROW, DROP IN BLOOD PRESS, RAPID PULSE, UNCONSCIOUSNESS, CONVLS, (DEATH W/IN 4 HRS POSS). EYE/SKIN CN TCT:SEVERITY OF ALKALINE CORR EFT ON TISS DEPENDS ON DURATION OF CNTCT. CHRONIC:DIZZ, WEAK, LOSS OF APPETITE, (SUPDAT) Medical Cond Aggravated By Exposure: PREEXISTING RESPIRATORY, CEREBROVASCULAR, CENTRAL NERVOUS SYSTEM CONDITIONS; LIVER OR KIDNEY DISORDERS; DERMATITIS, SENSITIZATION TO AMINES. First Aid: FIRST AIDERS MUST TAKE PROPER PREC FOR THEIR OWN SAFETY BEFORE ENTERING CONTAMD AREAS TO ASSIST CHEM ACCIDENT VICTIMS & HNDLG THEIR CONTAMD CLTHG & EQUIP. ALWAYS, HAVE ANOTHER PERS IMMED CALL YOUR EME R MED SERVICE, POIS CTL CTR, 911-OPERATOR, HOSPITAL, MD/OPHTHALMOLOGIST AS DESCRIPTION OF ACCIDENT, NAME OF ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NOTIFY YOUR FACILITY EMER COORDINATOR. DO NOT RELS INTO SOIL, SEWER, STREAM, POND/SOURCES OF DRINKING H*2O. PROVIDE MAX VEN. ELIM ALL SOURCES OF IGNIT. WEAR PRESCRIBED PERS PROT EQUIP. ABSORB SMALL SP ILL ON PAPER TOWELS, PLACE IN DISH IN Neutralizing Agent: SODIUM OR CALCIUM HYPOCHLORITE AT PH 8.5-10. Waste Disposal Methods: COLLECT IN TIGHTLY CLOSED PLASTIC CONTAINER. SHIP TO APPROVED TREATMENT/DISPOSAL FACILITY OR COMMERCIAL PRECIOUS METAL REFINER. DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: USE "BUDDY SYSTEM" WHEN WORKING WITH CHEMICALS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATH DUST, MIST, GAS, USE ONLY WITH ADEQUATE VENT. Other Precautions: KEEP CNTNR TIGHTLY CLSD IN UPRIGHT POSITION. KEEP AWAY FROM HEAT, SPARKS, & FLAME. STORE AT 50-90F AWAY FROM INCOMPAT MATLS. PROTECT CNTNRS AGAINST SPILLAGE & PHYSICAL INJURY. TRIPLE RINSE CNTNR CLEAN BEFORE DISCARDING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Lower Limits: NONE Upper Limits: NONE Extinguishing Media: ALCOHOL FOAM, ALKALINE DRY CHEMICAL. DO NOT USE CO*2, WATER, WATER FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). DO NOT FLUSH INTO SEWER OR STREAM. Unusual Fire/Explosion Hazard: EXCESSIVE HEAT MAY CAUSE CONTAINERS TO BURST. THERMAL DECOMPOSITION, ACIDIC WATER OR STEAM MAY LIBERATE HIGHLY TOXIC AND FLAMMABLE HYDROGEN CYANIDE GAS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED FOR CYANIDE OR SELF-CONTAINED BREATHING APPARATUS. Ventilation: LOCAL EXHAUST REQUIRED TO MEET PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment: ANSI APPRVD EMER EYE WASH & DELUGE SHOWER (FP N). IMPERVIOUS BOOTS, APRON, PROT CLTHG AS REQUIRED BY JOB CONDITIONS. Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). SPEC GRAV: 1.107-1.117 (H*2O=1) EFTS OF OVEREXP: WEIGHT LOSS, MENTAL DETERIORATION, THYROID INSUFFICIENCY, NAUSEA, RASH, IRRIT OF UPPER RESP TRACT & EYES. MAY CAUSE SENSIT LEADING TO ASTHMA, ALLERGIC DERM. REMOVE FROM EXPOSURE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >212F,>100C M.P/F.P Text: <32F,<0C Decomp Text: 68.0F,20.0C Spec Gravity: SUPDAT PH: 11-12 Evaporation Rate & Reference: SLOWER (ETHYL ETHER = 1) Solubility in Water: COMPLETE Appearance and Odor: COLORLESS TO LIGHT YELLOW LIQUID. BITTER ALMONDS ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: CONTACT WITH CO*2 IN AIR GENERATES HCN-GAS. Materials To Avoid: HEAT, STEAM, ACIDS, ACID FUMES, OXIDIZERS, NITRATES, NITRITES, FLUORIDES, PEROXIDES, MAGNESIUM. Hazardous Decomposition Products: HCN, CO*X, NO*X, AG. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SILVER (HARD, HEAVY BUILD) PLATING SOLUTION, 30308305 Cage: DO645 Assigned IND: Y Company Name: SIFCO SELECTIVE PLATING, DIV OF SIFCO INDUSTRIES INC Street: 5708 SCHAAF ROAD Zipcode: 44131-1394 Label Required IND: Y Date Of Label Review: 07/16/1997 Status Code: C Label Date: 07/16/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: Slight Hazard And Precautions: DECOMPOSITION MAY BE HAZARDOUS. ACUTE: FATAL, HIGHLY TOXIC. CORROSIVE BURNS. ALLERGIC SKIN REACTION. UNCONSCIOUSNESS, CONVULSIONS, DEATH, DIZZINESS, RAPID RESPIRATION, VOMITING, FLUSHING, HEADACHE, DR OWSINESS, DROP IN BLOOD PRESSURE, RAPIDPULSE, UNCONSCIOUSNESS, CONVULSIONS. EYE/SKIN: CORROSIVE. CHRONIC: DIZZINESS, WEAKNESS, LOSS OF APPETITE, WEIGHT LOSS, RASH, IRRITATION, SENSITIZATION OF RESPIRA TORY SYSTEM AND SKIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DOW CORNING 999 SIL. GLAZING COMPOUND-CLEAR Preparer's Name:JACK L.SHENEBERGER CAGE:71984 CAGE:3R796 CAGE:71984 ============= Composition/Information on Ingredients ============= Ingred Name:ACETOXYSILANE Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED Ingred Name:UNIDENTIFIED COMPONENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE: EYES-IRRITATION, SLIGHT PAIN, REDNESS, POSSIBLE MINOR CORNEAL INJURY. SKIN-SLIGHT IRRITATION ON PROLONGED CONTACT. INHALATION: SLIGHT RESPIRATORY IRRITATION. CHRONIC: NO DATA AVAILABLE. Effects of Overexposure:EYES: IRRITATION,SLIGHT PAIN,REDNESS AND POSSIBLE MINOR CORNEAL INJURY. SKIN: SLIGHT IRRITATION ON PROLONGED CONTACT. INHALATION: SLIGHT IRRITATION TO RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. NO KNOWN MEDICAL CONDITIONS THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH COPIOUS AMOUNT OF WATER. OBTAIN IMMEDIATE MEDICAL ATTENTION. SKIN: WIPE OFF AND FLUSH WITH WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN IMMEDIATE MEDICAL ATTENTION. INGESTION: OBTAIN IMMEDIATE MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:>250F/121C Extinguishing Media:WATER; WATER FOG; CARBON DIOXOIDE; DRY CHEMICAL; AND FOAM. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS. Unusual Fire/Explosion Hazard:NONE KNOWN TO DOW CORNING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PRODUCT AND USE ABSORBENT MATERIAL TO TAKE CARE OF ANY OIL-LIKE RESIDUES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 90F. USE REASONABLE CARE & CAUTION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATORY PROTECTION REQUIRED. IF DESIRED, ACID GAS/ORGANIC VAPOR TYPE RESPIRATOR IS SUITABLE. Ventilation:MECHANICAL(GENERAL) RECOMMENDED,LOCAL EXHAUST IF NEEDED Other Protective Equipment:NONE Work Hygienic Practices:WASHING AT MEALTIME AND END OF SHIFT. Supplemental Safety and Health MSDS DATED 10-3-85 ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:<5 @77F Spec Gravity:1.05 @77F Evaporation Rate & Reference:<1.0 (ETHER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:ACETIC ACID-LIKE,PASTE,CLEAR Percent Volatiles by Volume:<5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS CAN CAUSE A REACTION. Stability Condition to Avoid:AIR OR MOISTURE CAUSES POLYMERIZATION & ACETIC ACID VAPORS. Hazardous Decomposition Products:SILICON DIOXIDE, CARBON DIOXIDE, AND TRACES OF INCOMPLETED BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER. REVIEW ALL LOCAL, STATE, AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION TO DETERMINE APPROVED DISPOSAL PROCEDURES.
1
eyes_protection_mandatory
======================================================= NIIN: 01-206-8929 Product ID: RTV106 Cage: GESIL Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: GESIL Cage: 01139 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: ADHESIVE Unit of Issue: CA Quantitative Expression: 10000000054OZ UI Container Qty: 0 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INGESTION: MAY BE HARMFUL IF SWALLOWED. SKIN: UNCURED PRODUCT CONTACT WILL IRRITATE LIPS, GUMS & TONGUE; MAY IRRITATE SKIN. INHALATION: CAUSES IRRITATION OF MOUTH, NOSE & THROAT. APPLIES ONLY IN UNCUR ED STATE. EYES: UNCURED PRODUCT CONTACTIRRITATES EYES. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: INGESTION: RINSE MOUTH WITH WATER SEVERAL TIMES. SKIN: TO CLEAN FROM SKIN, REMOVE COMPLETELY WITH DRY CLOTH OR PAPER TOWEL BEFORE WASHING WITH DETERGENT & WATER. INHALATION: MOVE PERSON TO FRESH AIR.EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES & GET MEDICAL ATTENTION IF IRRITATION PERSISTS. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WIPE, SCRAPE OR SOAK UP IN AN INERT MATERIAL AND PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES WITH DETERGENT & WATER TO REDUCE SLIPPING HAZARD. WEAR PROPER PROTECTIVE EQUIPMENT AS SPECIFIED IN PROTECTIVE EQUIPMENT SECTION. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. BURY IN A LICENSED LANDFILL OR BURN IN AN APPROVED INCINERATOR ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions: AVOID CNTCT W/SKIN & EYES. CAUTION! REMOVE CNTCT LENSES BEFORE USING SEALANT. DO NOT HANDLE LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM FINGERTIPS, NAILS & CUTICLES. RESIDUAL SEALANT MAY REMAIN ON FINGERS FOR SEVERAL DAYS & (SUPDAT) ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: ALL STANDARD FIREFIGHTING MEDIA. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER. ======================================================= Control Measures ======================================================= Respiratory Protection: USE IN A WELL VENTILATED AREA. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: USE ONLY IN WELL VENTILATED AREA. USE MECH VENT TO STAY BELOW TLV OF 10 PPM ACETIC ACID. Other Protective Equipment: EYEWASH STATIONS. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: OTHER PREC: TRANSFEER TO LENSES & CAUSE SEV EYE IRRIT. PROD RELS ACETIC ACID DURING APPLICATN & CURING. UNCURED PRODUCT CONTACT IRRITATES EYES & MAY IRRITATE SKIN. USE IN A WELL VENTILATED AREA TO PRE VENT IRRITATION BY VAPORS. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 Spec Gravity: 1.07 (H2O=1) Solubility in Water: INSOLUBLE Appearance and Odor: RED PASTE; ACETIC ACID ODOR. Percent Volatiles by Volume: <5 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, SILICON DIOXIDE, ACETIC ACID. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 115065 Product ID: RTV106 Review Date: 04/21/1992 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: CA Container QTY: 0 Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: RTV106 Cage: GESIL Company Name: GE SILICONES Street: 260 HUDSON RIVER ROAD Zipcode: 12188 Label Required IND: Y Date Of Label Review: 02/16/1995 Status Code: C Label Date: 02/16/1995 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INGESTION: MAY BE HARMFUL IF SWALLOWED. SKIN: UNCURED PRODUCT CONTACT WILL IRRITATE LIPS, GUMS & TONGUE; MAY IRRITATE SKIN. INHALATION: UNCURED PRODUCT CAUSES IRRITATION OF MOUTH, NOSE & THROAT . EYES: UNCURED PRODUCT CONTACT IRRITATES EYES. CHRONIC: NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S80801819QA SEVIN BRAND XLR PLUS CARBARYL INSECTICIDE CAGE:9Z675 CAGE:9Z675 ============= Composition/Information on Ingredients ============= Ingred Name:CARBARYL (SEVIN) (SARA III) CAS:63-25-2 RTECS #:FC5950000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 642 MG/KG BODY WEIGHT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION/INHALATION: HARMFUL/NAUSEA/VOMITING/ABDOMINAL PAIN/DIARRHEA/PINPOINT PUPILS/BLURRED VISION/PROFUSE SWEATING/SALIVATION/TREMOR/MUSCLE TWITCHING/PARALYSIS/POISONING RESPIRATORY DEPRESSION/CONV ULSIONS. SKIN: ABSORPTION W/AFFECTS OF INGESTION. EYES: IRRITATION/TEARING/REDNESS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION/INHALATION: HARMFUL/NAUSEA/VOMITING/ABDOMINAL PAIN/DIARRHEA/PINPOINT PUPILS/BLURRRED VISION/PROFUSE SWEATING/SALIVATION/TREMOR/MUSCLE TWITCHING/PARALYSIS/RESPIRATORY DEPRESSION/CONVULSIONS. SKIN: ABSORPTION W/AFFECTS OF INGESTION. EYES: IRRITATION/TEARING/REDNESS. Medical Cond Aggravated by Exposure:EXISTING SKIN LESIONS, ACUTE OR CHRONIC ASTHMA, CHRONIC PULMONARY DISEASE SUCH AS EMPHYSEMA OR BRONCHITIS, CHRONIC CARDIOVASCULAR OR RESPIRATORY DISEASE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/ARTIFICIAL RESPIRATION. INGESTION: GIVE 2-3 GLASSES OF WATER/MILK. GIVE 1 TBL OF SYRUP OF IPECAC TO INDUCE VOMITING. (REPEAT IF VOMITING HAS NOT OCCURRED IN 2 0 MINS) OR INDUCE VOMITING BY TOUCHING BACK OF THROAT W/FINGER. IF UNCONSCIOUS, DON'T INDUCE VOMITING. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE APPROPRIATE EXTINGUISHING MEDIA FOR SURROUNDING MATERIAL. Fire Fighting Procedures:WEAR PROTECTICE CLOTHING, EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS. EVACUATE AREA. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITON PRODUCTS MAY BE HAZARDOUS. ================== Accidental Release Measures ================== Spill Release Procedures:LARGE: DIKE W/ABSORBENT/IMPERVIOUS MATERIALS (CLAY/SAND). RECOVER/CONTAIN CONTAMINATED ABSORBENT/DIKE MATERIAL FOR DISPOSAL. SMALL: ABSORB ON SAND/VERMICULITE & REMOVE AREA TO A DEPTH OF 1-2 INCHES ON THE GROUND & PLACE IN CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE UNUSED PRODUCT IN ORIGINAL CONTAINER ONLY, & IN COOL, DRY AREA. DON'T STORE >100F OR CONTAMINATE WATER, FOOD, FEED BY STORAGE OR DISPOSAL. Other Precautions:KEEP OUT OF REACH OF CHILDREN & ANIMALS. DON'T INGEST. AVOID CONTACT W/EYES/SKIN/CLOTHING. ENSURE ADEQUATE DECONTAMINATION OF TOOLS & EQUIPMENT FOLLOWING CLEANUP. PERFORM BASELINE & PERIODICALLY CHECK RED BLOOD CELLS CHOLINESTERASE LEVELS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE MIST. USE POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS IF >TLV. Ventilation:LOCAL EXHAUST: RECOMMENDED Other Protective Equipment:FULL BODY PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. LAUNDER SEPARATELY. Supplemental Safety and Health TREAT SYMPTOMATICALLY. PRODUCT IS A CHOLINESTERASE INHIBITOR. EFFECTS ARE SPONTANEOUS & RAPIDLY REVERSIBLE. IMPROVE TISSUE OXYGENATION. TREAT W/ATROPINE SULFATE. DON'T OVER ATROPINIZE OR USE NARCOTICS OR SEDATIVES. DRUGS LIKE 2-PAM ARE NOTRECOMMENDED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:217.9F Melt/Freeze Pt:M.P/F.P Text:26.6F Vapor Pres:17 Vapor Density:0.62 Spec Gravity:1.10 pH:4-5 Solubility in Water:MISCIBLE Appearance and Odor:WHITE TO CREAM LIQUID W/MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS, STRONG ACIDS Stability Condition to Avoid:TEMPERATURES >100F Hazardous Decomposition Products:OXIDES OF NITROGEN, SULFUR, CARBON, & METHYL ISOCYANATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. PREVENT RUNOFF & CONTAMINATION OF WATER SOURCES. DON'T FLUSH MATERIAL TO PUBLIC SEWERS SYSTEMS OR ANY WATERWAYS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMALGAMATED CADMIUM FILINGS. SUSPENSION. AP CAGE:0E6V4 CAGE:0E6V4 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM (SARA III) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: 100% OSHA PEL:SEE 1910.1027 ACGIH TLV:0.01 MG/M3 DUST;9394 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL RAT)225 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:CAUTION! INGEST:METAL AND SOL COMPOUNDS CAUSES INCREASED SALIVATION, CHOKING, VOMITING, ABDOMINAL PAIN, ANEMIA, RENAL DYSFUNCTION, DIARRHEA, TENESMUS. INHAL:(DUST/FUMES):THROAT DRYNESS, COUGH, HEADAHC E, VOMITING, CHEST PAIN, EXTREME RESTLESSNESS AND IRRITABILITY, PNEUMONITIS, POSSIBLY BRONCHPNEUMONIA. Explanation of Carcinogenicity:CONTAINS 2-A [53-96-3] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INHAL:MOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFE RBLEY MOUTH TO MOUTH. IF BREATHING DIFFICULT, GIVE OXYGEN. CALL MD. SKIN:FULUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP, PLACE IN A BAG AND HOLD FOR DISPOSAL. WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL SAFETY Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT HANDLE UNTIL THE MANUFACTURERS SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. Other Precautions:WARNING! HARMFUL IF SWALLOWED, INHALED, ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. DO NOT GET IN EYES. AVOID SKIN CONTACT. PREVENT PROLONGED OR REPEATED BREATHING OF VAPOR OR SPRAY MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:HOOD. Other Protective Equipment:LAB COAT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR PT#/TRADE NAME:FOR NITRATE CADMIUM. GRANULATED. 40-60 MESH, EPA, FOR NITRATE CADMIUM, COARSE, GRANULATED. ================== Physical/Chemical Properties ================== HCC:T7 Appearance and Odor:GREYISH COLORED GRANULES UNDER A COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATLS. REACTS VIOLENTLY W/POTASSIUM. OXIDIZING AGENTS/ACIDS. SULFUR/ZINC/AMMONIUM NITRATE/SELENIUM, TELLURIUM. Stability Condition to Avoid:HEAT, FLAME. Hazardous Decomposition Products:TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N,N-DIMETHYLFORMAMIDE, 99%, BP11604 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:N,N-DIMETHYLFORMAMIDE LD50: (ORAL, RAT) 2800 MG/KG CAS:68-12-2 RTECS #:LQ2100000 = Wt:100. OSHA PEL:30 MG/M3;10 PPM ACGIH TLV:30 MG/M3;10 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: CAUSES SEVERE EYE IRRITATION. VAPORS MAY CAUSE EYE IRRITATION. SKIN: PROLONGED AND/OR REPEATED CONTACT MAY CAUSE IRRITATION AND/OR DERMATITIS. SUBSTANCE IS RAPIDLY ABSORBED THROUGH THE SKIN. IF A BSORBED, CAUSES SYMPTOMS SIMILAR TO INHALATION. STRONG IRRITANT OF THE SKIN. INGESTION: MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE EFFECTS SIMILAR TO THOSE FOR INHALATION EXPOSURE. INHALAT ION: MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE KIDNEY DAMAGE. MAY BE HARMFUL IF INHALED. INHALATION MAY PRODUCE NAUSEA, VOMITING, ANOREXIA, COLIC, HIGH BLOOD PRESSURE, HEPATOMEGALY, JAUNDICE A ND (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:DIMETHYLFORMAMIDE: IARC MONOGRAPHS ON EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 47, PAGE 171, 1989:GROUP 2B. Effects of Overexposure:HEALTH HAZARDS: ALTERED LIVER FUNCTION. CHRONIC: POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKINW/PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH T O UNCONSCIOUS PERSON. GET MEDICAL AID IMMEDIATELY. INHAL: GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIF FICULT, GIVE OXYGEN. NOTES TO MD: NONE. ===================== Fire Fighting Measures ===================== Flash Point:=58.C, 136.4F Autoignition Temp:=445.C, 833.F Lower Limits:2.2% Upper Limits:15.2% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEM, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL FIRE-EXPOSED CNTNRS. WATER MAY BE INEFTIVE. FOR LARGE FIRES, USE (SUPDAT) Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . CONTACT PROFESSIONAL FIRE-FIGHTERS IMMEDIATELY. COOL CONTAINERS W/FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. NFPA RATING: HEALTH-1; FLAMMABILITY-2; REACTIVITY-0. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO SOURCE OF IGNITION & FLASH BACK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. FLAMMABLE LIQUID. VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW OR CONFINED AREAS. VAPORS MAY FORM AN EXPLOSIVE MIXTURE W/AIR. CONTAINERS MAY EXPLODE WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION. ABSORB SPILL W/INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO CHEMICAL WASTE CONTAINER. DO NOT FLUSH INTO A SEWER. REMOVE ALL SOURCES OF IGNIT. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER SPRAY MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR. KEEP FROM CONTACT W/OXIDIZING MATLS. STORE IN A COOL, DRY, WELL-VENTD AREA AWAY FROM INCOMPATIBLE S UBSTANCES. WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT W/HEAT, SPKS & F LAME. AVOID INGEST & INHAL. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHES AND WASH BEFORE REUSE. Supplemental Safety and Health EXTING MEDIA: WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. DO NOT USE STRAIGHT STREAMS OF WATER. OTHER PRECS: SPKS/OPEN FLAMES. EXPOS LIMITS: N,N-DIMETHYLFORMAMIDE - ACGIH: 10 PPM; 30 MG/M3; SKIN-POTNT L FOR CUTANEOUS ABSORPTION. NIOSH: 10 PPM TWA; 30 MG/M3 TWA 500 PPM IDLH. OSHA-FINAL PELS: 10 PPM TWA; 30 MG/M3 TWA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:153760C Melt/Freeze Pt:=-61.C, -77.8F Decomp Temp:=350.C, 662.F Vapor Pres:3.725 MM HG Vapor Density:2.5(AIR=1) Spec Gravity:0.9450 pH:6.7 Viscosity:0.8 MPAS 20 DEG Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID - CLEAR; AMINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS (MINERAL, NON-OXIDIZING, EG HYDROCHLORIC ACID, HYDROFLUORIC ACID, MURIATIC ACID, PHOSOPHORIC ACID), ACIDS (MINERAL, OXIDIZING, EG CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID), METALS (ALKALI & ALKALINE Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES, STRONG OXIDANTS. Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN, CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:CAS # 68-12-2. LD50/LC50: INHALATION, MOUSE: LC50 = 9400 MG/M3/2H; ORAL, MOUSE: LD50 = 3700 MG/KG; SKIN, RABBIT: LD50 = 4720 MG/KG. CARCINOGENICITY: ACGIH: A4 - NOT CLASSIFIABLE AS HUMAN CARCINOGEN. O SHA: POSSIBLE SELECT CARCINOGEN. IARC:GROUP 2B CARCINOGEN. EPIDEMIOLOGY: A SIGNIFICANT EXCESS OF PROSTATE CANCER WAS OBSERVED AMONG WORKERS EXPOSED TO DMF AND ACRYLONITRILE. TERATOGENICITY: EXPERIMENT AL TERATOGEN EFFECTS HAVE BEEN REPORTED. REPRODUCTIVE EFFECTS: EXPERIMENTAL REPRODUCTIVE EFFECTS HAVE BEEN REPORTED. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: HUMAN MUTATION DATA REPORTED. OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:EXOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: SUBSTANCE EXPECTED TO BIODEGRADE RAPIDLY IN ENVIRONMENT & SHOULD BE HIGHLY MOBILE IN SOIL. PHYSICAL/CHEM:NOT AVAIL. OTHER:NOT AVAIL. --FED REG INFO:POLLUTAN TS UNDER CWA. NONE OF CHEMS IN PROD CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN INTERNATIONAL REGS - EUROPEAN LABELING I/A/W EC DIRECTIVES. HAZ SYMBOLS: T. RISK PHRASES: R 20/21 HARMFUL BY INHAL & IN CNTC T W/SKIN. R 36 IRRIT TO EYES. R 61 MAY CAUSE HARM TO UNBORN CHILD. SFTY PHRASES: S 45 IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LABEL WHERE POSS). S 53 AVOID EXPOS - OBTAIN S PEC INSTRUCTIONS (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME - US DOT: N,N-DIMETHYLFORMAMIDE, IATA:NO INFO AVAIL, RID/ADR:NO INFO AVAIL, IMO:NO INFO AVAIL, CANADA TDG: N,N-DIMETHYLFORMAMIDE. HAZ CLASS - US DOT:3; CANADA TDG:3. UN NUMBER: US DOT:UN 2265; CANADA TDG:UN2265. PACKING GROUP-US DOT:III; CANADA TDG:III. ADDNL INFO: CANADA TDG: FL PT 58C. --ECOLOGICAL INFO: BEFORE USE. WGK (WATER DANGER/PROT) - CAS #68-12-2:1. CANADA - CAS #68-12-2 LIS TED ON CANADA'S DSL/NDSL LIST. PROD HAS WHMIS CLASSIFICATION OF B3, D2B. NOT LISTED ON CANADA'S INGRED DISCLOSURE LIST. EXPOS LIMS: CAS #68-12-2: OEL-AUSTRALIA:TWA 10PPM (30MG/M3); SKIN OEL-BELGIUM: T WA 10PPM (30MG/M3); (SARA REG INFO) ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ):NONE OF THE CHEMS IN MATL HAVE RQ. SECTION 302 (TPQ):NONE OF CHEMS IN PROD HAVE TPQ. SARA CODES CAS #68-12-2; ACUTE, FLAM. SECTION 313: MATL CONTAINS N,N-DIMETHYLFORMAMIDE (CAS #68-12 -2, 100%), WHICH IS SUBJECT TO REPORTINGREQS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. --TRANSPORT INFO: SKIN OEL-CZECHOSLOVAKIA:TWA 30MG/M3; STEL 60 MG/M3 OEL-DENMARK:TWA 10PPM (30MG/M3); S KIN OEL-FINLAND:TWA 10PPM (30MG/M3); STEL 20PPM (60MG/M3); SKIN OEL-FRANCE:TWA 10PPM (30MG/M3); SKIN OEL-GERMANY:TWA 20PPM (60MG/M3); SKIN OEL-HUNGARY:TWA 10MG/M3; STEL 20MG/M3; SKIN OEL-JAPAN:TWA 10P PM (30MG/M3); SKIN OEL- (STATE REG INFO) Federal Regulatory Information:CAS #68-12-2 - LISTED ON THE TSCA INVENTORY. HLTH & SAFETY REPORTING LIST: EFTIVE DATE: APRIL 13,1989; SUNSET DATE: 12/19/1995. CHEM TEST RULES:NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: #68-12-2 IS LISTED AS HAZ AIR POLLUTANT. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. MATL D OES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ S UBSTANCES UNDER CWA. NONE OF CHEMS ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD LISTED AS TOXIC (ECOLOGICAL INFO) State Regulatory Information:CAS #68-12-2 CAN BE FOUND ON FOLLOWING STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CA NO SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN PROD LISTED. --SARA TITLE III: NETHERLANDS:TWA 10PPM (30MG/M3); SKIN OEL-PHILLIPPINES:TWA 10PPM (30MG/M3); SKIN OEL-POLAND:TWA 10MG/M3 OEL-RUSSIA:TWA 10PPM; STEL 10MG/M3; SKIN OEL-SWEDEN:TWA 10PPM (30MG/M3); STEL 15PPM (45MG/M3); SKIN OEL-SWITZERLAND:TWA 10PPM 930 MG/M3); STEL 20PPM; SKIN OEL-TURKEY:TWA 10PPM (30MG/M3); SKIN OEL-UNITED KINGDOM:TWA 10PPM (30MG/M3) ; STEL 20PPM; SKIN OEL BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV. OEL NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALLOY STEEL/LEAD 4130/4140/4340/8620/86L20 CAGE:4F063 CAGE:4F063 ============= Composition/Information on Ingredients ============= Ingred Name:BASE METAL (SEE SUPPLEMENTAL FOR INGREDIENTS) Ingred Name:IRON ION (FE +2) CAS:15438-31-0 RTECS #:NO6925000 Fraction by Wt: 99% OSHA PEL:1 MG/M3 (FE) ACGIH TLV:1 MG/M3 (FE); 8990 Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <5% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <5% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VANADIUM PENTOXIDE(SARA III) CAS:1314-62-1 RTECS #:YW2460000 Fraction by Wt: <5% OSHA PEL:C,0.5 MG/M3 ACGIH TLV:0.05 MG/M3RDUST;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATION OF EYES/RESPIRATORY SYSTEM/IRRITATION OF THE THROAT/INFLUENZA-LIKE SYMPTOMS. ======================= First Aid Measures ======================= First Aid:IF EXPOSED TO EXCESSIVE LEVELS OF METAL FUMES, REMOVE TO FRESH AIR, SEEK MEDICAL AID IMMEDIATELY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:STEEL PRODUCTS IN THE SOLID STATE PRESENT NO FIRE OR EXPLOSION HAZARD. ======================Handling and Storage ====================== Handling and Storage Precautions:IN WELDING, PRECAUTIONS SHOULD BE TAKEN FOR AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMNENTS OF THE WELDING ROD. Other Precautions:ARC OR SPARK GENERATED WHEN WELDING OR BURNING COULD BE A SOURCE OF IGNITION FOR COMBUSTABLE AND FLAMMABLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA-APPROVED DUST & FUME RESPIRATOR FOR PARTICLES WHEN >TLV. Ventilation:LOCAL EXHAUST VENT WELDING/BURN/SAW/GRINDING WHEN >TLV. Other Protective Equipment:AS REQUIRED Supplemental Safety and Health 11/25/85. MN (OO9275000)<2%/C (FF5250100)<2%/MO (QA4680000)<2%/V (VV0450000)<2%/AL (BD0330000)<2%/S (WS4250000)<2%/P (TH35000)<1%/BI (EB2600000)<1%/CU (GL5325000)<1%/PB (OF7525000)<1%. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Spec Gravity:7 Evaporation Rate & Reference:NONE Solubility in Water:NONE Appearance and Odor:GREY/BLACK, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH STRONG ACID TO PRODUCE HYDROGEN GAS Hazardous Decomposition Products:METALLIC DUST/FUME MAY BE PROD DURING WELDING/BURNING/GRIND. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE MUST COMPLY WITH FEDERAL, STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS.
1
eyes_protection_mandatory
======================================================= NIIN: 01-381-3410 Product ID: H-4 PUT A HALT TO RUST Cage: 52790 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 52790 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: DETERGENT,GENERAL PURPOSE Specification Number: NONE Type/Grade/Class: NONE Unit of Issue: DR Quantitative Expression: 00000000055GL UI Container Qty: 1 Type of Container: DRUM ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE SLIGHT SKIN RASH. NAUSEA MAY OCCUR IF SWALLOWED; NON-TOXIC. NAUSEA OR DIZZINESS MAY OCCUR-RARE. COULD IRRITATE MUCOUS MEMBRANES. MAY CAUSE EYE DAMAGE ON EXTENDED CONTACT. CHRONIC: NO NE SPECIFIED BY MANUFACTURER. Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Signs And Symptions Of Overexposure: SKIN RASH, EYE DAMAGE, NAUSEA, DIZZINESS. Medical Cond Aggravated By Exposure: COULD CAUSE SLIGHT SKIN RASH IF OVER EXPOSURE OCCURS. COULD CAUSE EYE DAMAGE ON EXTENDED CONTACT. First Aid: IF TAKEN INTERNALLY, DRINK COPIOUS AMOUNTS OF WATER. USE REGULAR SOAP, BLAST OFF OR PLAIN WATER TO WASH MATERIAL OFF SKIN OR CLOTHING. GET MEDICAL ATTENTION IF IRRITATION OR SYMPTOMS SEEM AGGRAVATED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ABSORB SPILLS WITH DRY SAND OR EARTH, THEN PLACE IN A CHEMICAL WASTE CONTAINER FOR DISPOSAL. FLUSH RESIDUAL AREA WITH WATER. Neutralizing Agent: SODA ASH OR OTHER ALKALINE MATERIALS. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED. STORE IN PLASTIC, RUBBER LINED OR 316 STAINLESS STEEL CONTAINERS. STORE AWAY FROM EXTREME HEAT. Other Precautions: DO NOT MIX WITH OTHER CHEMICALS. DO NOT GET IN EYES, ON SKIN OR CLOTHES. AVOID BREATHING MIST. KEEP ADEQUATE VENTILATIOIN. KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: OC Flash Point Text: NONE Lower Limits: NONE Upper Limits: NONE Extinguishing Media: NONE SPECIFIED BY MANUFACTURER. DLA-: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures: NONE SPECIFIED BY MANUFACTURER. WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER. ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID BREATHING VAPOR. IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ACID MIST CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation: USE ADEQUATE ADEQUATE VENTILATION-MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment: IF SPRAYING IN WINDY CONDITIONS, WEAR CHEMICAL PROTECTIVE CLOTHING. DLA-: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health: PER MFR MSDS-INHIBITED ACID BATH ROOM CLEANER--METAL PROTECTOR & RUST REMOVER. ======================================================= Physical/Chemical Properties ======================================================= HCC: C3 B.P. Text: 270F,132C M.P/F.P Text: UNKNOWN Decomp Text: UNKNOWN Vapor Pres: 85 Vapor Density: UNKNOWN Spec Gravity: 1.11 PH: 1.8 Viscosity: 25 CPS Evaporation Rate & Reference: 1.42 (WATER=1) Solubility in Water: APPRECIABLE (98.8%) Appearance and Odor: VISCOUS, PURPLE LIQUID; LILAC ODOR. Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: EXCESSIVE WATER, ALKALINE, SULFIDES, SULFIDE PRODUCTS. Hazardous Decomposition Products: NONE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 131823 Product ID: H-4 PUT A HALT TO RUST Review Date: 01/10/1997 Tech Entry NOS Shipping Nm: CONTAINS PHOSPHORIC ACID AND HYDROCHLORIC ACID Net Unit Weight: 508.4 LBS Multiple KIT Number: 0 Review IND: Y Unit Of Issue: DR Container QTY: 1 Type Of Container: DRUM Additional Data: U/I IS 55 GALLON DRUM. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: DWF Symbols: G DOT Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Hazard Class: 8 UN ID Num: UN3264 DOT Packaging Group: III Label: CORROSIVE Special Provision: T7 Packaging Exception: 154 Non Bulk Pack: 203 Bulk Pack: 241 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: A Water/Ship/Other Req: 40 ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ESE IMO Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. o IMDG Page Number: 8147-1 UN Number: 3264 UN Hazard Class: 8 IMO Packaging Group: I/II/III Subsidiary Risk Label: - EMS Number: 8-15 MED First Aid Guide NUM: 760 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: HLF IATA UN ID Num: 3264 IATA Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. * IATA UN Class: 8 IATA Label: CORROSIVE UN Packing Group: III Packing Note Passenger: 818 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 820 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: HKW AFI Symbols: * AFI Proper Shipping Name: CORROSIVE LIQUID, N.O.S. AFI Hazard Class: 8 AFI UN ID NUM: UN1760 AFI Packing Group: III Special Provisions: P5 Back Pack Reference: A12.3 ======================================================= HAZCOM Label ======================================================= Product ID: H-4 PUT A HALT TO RUST Cage: 52790 Company Name: ELSCO INTERNATIONAL Street: 3407 E ST Zipcode: 92102 Label Required IND: Y Date Of Label Review: 01/10/1997 Status Code: C Label Date: 01/10/1997 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: Slight Hazard And Precautions: CORROSIVE!MAY CAUSE SLIGHT SKIN RASH. NAUSEA MAY OCCUR IF SWALLOWED; NON-TOXIC. NAUSEA OR DIZZINESS MAY OCCUR-RARE. COULD IRRITATE MUCOUS MEMBRANES. MAY CAUSE EYE DAMAGE ON EXTENDED CONTACT. TARGET O RGANS: SKIN, EYES. IN CASE OF SPILL: ABSORB SPILLS WITH DRY SAND OR EARTH, THEN PLACE IN A CHEMICAL WASTE CONTAINER FOR DISPOSAL. FLUSH RESIDUAL AREA WITH WATER. FIRST AID: IF TAKEN INTERNALLY, DRINKCOPIOUS AMOUNTS OF WATER. USE REGULAR SOAP, BLAST OFF OR PLAIN WATER TO WASH MATERIAL OFF SKIN OR CLOTHING. GET MEDICAL ATTENTION IF IRRITATION OR SYMPTOMS SEEM AGGRAVATED. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:300S LACQUER CLEARS Preparer's Name:T R LOUER CAGE:23027 CAGE:90227 CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL(IARC CANCER REVIEW GROUP 3) *96-2* CAS:67-63-0 RTECS #:NT8050000 Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:MIXED DIBASIC ESTERS Ingred Name:BUTANOL, N-BUTYL ALCOHOL, PROPYL CARBINOL, BUTYL ALCOHOL CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 7% Other REC Limits:300 MG/CUM OSHA PEL:100 PPM ACGIH TLV:C 152 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-2* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 23% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 6% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FATTY ACIDS, TALL-OIL, REACTION PRODUCTS CAS:96591-18-3 Ingred Name:METHYL METHACRYLATE BUTYL ACRYLATE POLYMER *96-2* CAS:25852-37-3 Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA, C8&10 AROMATIC HYDROCARBON *96-2* CAS:64742-95-6 RTECS #:WF3400000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NOSE & THROAT IRRITATION. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. EYES: IRRITATION/BURNING. SKIN: IRRITATION & DERMATITIS. INGESTION: GI DISTRESS. Explanation of Carcinogenicity:NONE Effects of Overexposure:GI DISTRESS, IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, BREATHING DIFFICULTY, BURNING, DISCOMFORT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:<73F Lower Limits:0.2 Upper Limits:36.5 Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:WHEN HEATED > FLASH POINT, EMITS FLAMMABLE VAPORS WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPS < THE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION. PREVENT SKIN CONTACT & BREATHING OF VAPOR. WEAR A PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR(NIOSH/MSHA TC-23C). CONFINE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. DON'T STORE >120F. Other Precautions:OBSERVE LABEL PRECAUTIONS. DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O A NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. DON'T BREATHE VAPORS/MISTS. DON'T PERMIT ANYONE W/O PROTECTION IN THE PAINTING AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA(TC-23C)DURING APPLICATION. IN CONFINED SPACES, WEAR A POSITIVE PRESSURE, SUPPLIED AIR RESPIRATOR(TC-19C). Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA LIMITS. Other Protective Equipment:COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:129-710F Vapor Density:>1 VOC Grams/Liter:6.7 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Percent Volatiles by Volume:73-98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:HEAT, SPARKS, FLAME, TEMPS >120F. Hazardous Decomposition Products:CO, CO2, SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE/DISPOSE OF ABSORBED MATERIAL IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. DON'T INCINERATE IN CLOSED CONTAINERS. FLAMMABLE LIQUID, UN126 3.
1
eyes_protection_mandatory
======================================================= Product ID: NOVOS 151 CURING AGENT, 1510-00000 Cage: 1CA02 Box: 580669 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 1CA02 Box: 580669 Cage: CTNDU Box: UNKNOW ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHAL: PROD IS NON-VOLAT BUT IF SPRAY MIST IS INHALED IT MAY BE HARMFUL W/IRRIT OF THROAT & RESP TRACT. PRLNGD EXPOS MAY CAUSE AN ASTHMATIC RXN. EYE: IRRIT WHICH MAY AGGRAVATE EXISTING DISORDERS. SKIN : PRLNGD/RPTD DERM CONTACT CAN RSLT IN IRRIT & SKIN SENSIT. WARNING! THIS MATL CNTNS 4,4'METHYLENE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: DIANILINE(MDA). NIOSH HAS ISSUED AN ALERT TO POTNL FOR LIVER DMG AMONG THOSE WORKERS EXPOSED TO MDA. TOXIC HEPATITIS MAY RESULT FROM EXPOS TO MDA BY INGEST/DERM ABSORP. AS PART OF NTP, THE D IHYDROCHLORIDE SALT OF 4,4' MDA WAS GIVEN TO RATS & MICE IN DRINKING WATER AT LEVELS OF 150 & 300 PPM, (THE (SUPDAT) Medical Cond Aggravated By Exposure: CAUTION: PRE-EXISTING EYE, SKIN & RESP DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD, EXERCISE CAUTION IN HANDLING. First Aid: SKIN/EYE: IMMED FLUSH W/FRESH WATER HOLDING LIDS APART FOR AT LEAST 15 MINS, WASHING W/IN ONE MINUTE IS ESSENTIAL TO ACHIEVE MAX EFTIVENESS. REMOVE FROM SKIN USING SOAP & WATER. REMOVE CONTAMD SHOES & CLTHG. CALL MD. INGEST: QUICKLY GIVE CONSCIOUS PERS SEVERAL GLASSES OF MILK OR WATER, THEN INDUCE VOMITING BY TICKLING THROAT W/FINGER. KEEP AIRWAY CLEAR. GET MED ATTN. NEVER GIVE ANYTHING BY(SUPDAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SCRAPE/WIPE UP SPILLED MATL. TRANSFER LIQUID TO CNTNRS FOR RECOVERY OR DISPOSAL. TRANSFER DISPOSABLE MATL TO PROPER CNTNRS FOR DISP. KEEP SPILLS & RUNOFF OUT OF SEWERS & OPEN BODIES OF WATER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: OBSERVE ALL FEDERAL, STATE & LOCAL LAWS REGARDING HEALTH AND THE ENVIRONMENT. Handling And Storage Precautions: AVOID CONTACT W/EYES, SKIN AND CLOTHES. WASH AFTER HANDLING. STORE IN COOL, DRY AREA IN CLOSED CONTAINERS. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >234F,>112C Extinguishing Media: WATER, SPRAY, FOAM, DRY CHEMICAL. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N). Unusual Fire/Explosion Hazard: GENERATION OF TOXIC PRODUCTS. ======================================================= Control Measures ======================================================= Respiratory Protection: ORGANIC CHEMICAL CARTRIDGE RESPIRATOR AS NEEDED, OTHERWISE WEAR NIOSH/MSHA APPROVED SCBA. Ventilation: MECHANICAL LOCAL EXHAUST AT POINT OF CONTAMINANT RELEASE IF CONDITIONS WARRANT. Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER(FP N). WEAR LONG SLEEVED SHIRTS, COVERALLS AS REQD TO PVNT SKIN CONT. Supplemental Safety and Health: USERS OF THE "L" VERSION OF TO CONSULT "LR" VERSION FOR FURTHER INFO(FP N). CNDTN TO AVOID: EXOTHERM W/25-30 MINUTES AT 70F. FIRST AID PROC: MOUTH TO AN UNCON PERS. INHAL: IMMED MOVE TO FRESH AIR . IF BRTHG IS DFCLT GIVE OXYGEN. CALL MD. EFTS OF OVEREXP: MAX TOLERATED AMT. TUMOR INCIDENCE WAS INCREASED TO ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: 9.6 @ 20C Spec Gravity: 1.15 Solubility in Water: NEGLIGIBLE Appearance and Odor: BROWN LIQUID PASTE W/SWEET ODOR. Percent Volatiles by Volume: <0.5 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: MIXING LGE VOLS W/EPOXY BASED MATLS SUCH AS NOVOS BASE. VOLS OF 1 GAL ARE SAFE HOWEVER EXPECT SIGNIFICANT (SUPDAT) Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: CO, CO*2, MDA UNSPECIFIED OTHERS. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: NOVOS 151 CURING AGENT, 1510-00000 Cage: 1CA02 Company Name: CTI INDUSTRIES INC Street: 10 SASCO HILL ROAD PO Box: 580669 Zipcode: 08430 Label Required IND: Y Date Of Label Review: 02/09/1996 Status Code: C Label Date: 02/09/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION: PRODUCT IS NON-VOLATILE BUT IF SPRAY MIST IS INHALED IT MAY BE HARMFUL WITH IRRITATION OF THROAT AND RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE AN ASTHMATIC REACTION. EYE: IRRI TATION WHICH MAY AGGRAVATE EXISTING DISORDERS. SKIN: PROLONGED OR REPEATED DERMAL CONTACT CAN RESULT IN IRRITATION AND SKIN SENSITIZATION. CHRONIC: WARNING! THIS MATERIAL CONTAINS 4,4'METHYLENE, WHICH MAY CAUSE LIVER DAMAGE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MICROLITE-COATED Preparer's Name:RONALD L BATTLES CAGE:MANVI CAGE:MANVI CAGE:75165 ============= Composition/Information on Ingredients ============= Ingred Name:FIBROUS GLASS CAS:65997-17-3 Fraction by Wt: 70% OSHA PEL:5 MG/M3 RDUST ACGIH TLV:10 MG/M3 Ingred Name:PHENOL FORMALDEHYDE RESIN CURED CAS:25104-55-6 Fraction by Wt: 10% Ingred Name:COATING, VINYL BASED Fraction by Wt: 20% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:(ACUTE) PRODUCT IS A MECHANICAL IRRITANT TO SKIN, EYES AND UPPER RESPIRATORY SYSTEM. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:INHAL: IRRIT OR SORENESS IN THROAT & NOSE. IN EXTREME EXPOSURES SOME CONGESTION MAY OCCUR. SKIN: TEMPORARY IRRITATION OR RASH. INGEST: NOT HAZARDOUS WHEN INGESTED. MAY CAUSE TEMPORARY IRRITATION TO GITRACT. EYES: TEMPORARY IRRITATION OR INFLAMMATION. Medical Cond Aggravated by Exposure:AS WITH ANY DUST, PRE-EXISTING UPPER RESPIRATORY AND LUNG DISEASES MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. DRINK WATER TO CLEAR THROAT AND BLOW NOSE TO EVACUATE FIBERS. SKIN: WASH AFFECTED AREAS GENTLY WITH SOAP AND WARM WATER. INGEST: CALL MD IMMEDIATELY . EYES: FLUSH WIT H COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS CONSULT MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, WATER, WATER FOG, DRY CHEMICAL ABC RATED. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:RESIN AND PAPER OR PLASTIC FACINGS WILL BURN CAUSING DENSE ACRID SMOKE. ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP PIECES. VACUUM CLEAN DUSTS. IF SWEEPING IS NECESSARY USE A DUST SUPPRESSANT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALWAYS SEGREGATE MATERIALS BY MAJOR HAZARD CLASS. KEEP MATERIAL DRY. USE ADEQUATE VENTILATION TO KEEP DUST LEVEL TO BELOW PEL/TLV/WEG. Other Precautions:FOR ADDTNL INFO, REFER TO MANVILLE SALES CORP BULLETIN HSE-64C, 9/87, AVAIL FROM: HLTH, SAFETY & ENVIRONMENT DEPT, MANVILLE SALES CORP, P.O. BOX 5108, DENVER, CO 80217. WASH WORK CLOTHES SEPARATELY FR OM OTHER CLTHG. RINSE WASHER THORO. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:<10 F/CC, USE NIOSH/MSHA APPRVD 3M 9900; <50 F/CC, USE NIOSH/MSHA APPRVD ULTRA TWIN WITH H FILTER OR EQUIVALENTS. FOR SPECIFIC RESPIRATOR RECOMMENDATIONS, SEE MANVILLE SALES CORP BULLETIN HSE-64C. Ventilation:USE SUFFICIENT NATL/MECH VENT TO KEEP DUST LEVEL TO BELOW PEL/TLV/WEG. Other Protective Equipment:LOOSE FITTING, LONG SLEEVED CLOTHING. Work Hygienic Practices:WASH EXPOSED AREAS WITH SOAP AND WATER AFTER HANDLING. Supplemental Safety and Health HAZ DECOMP PRODS: DECOMPOSITION OF ANY ORGANIC CHEMICAL. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:>1300F Spec Gravity:VAR Solubility in Water:NIL Appearance and Odor:FIBER GLASS MAT, BLACK COATING - SLIGHT PHENOLIC ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID. Stability Condition to Avoid:NONE IN DESIGNED USE. Hazardous Decomposition Products:CO*2, CO, CARBON PARTICULATE & TRACES OF HYDROGEN CYANIDE DERIVED FROM PYROLYSIS OF RESIN AS IS TYPICAL OF (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTES ARE NOT HAZARDOUS AS DEFINED BY RCRA (40 CFR PART 261). COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. METHOD OF DISPOSAL - LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CALCIUM NITRATE Resp. Party Other MSDS Num.:CC110 Preparer's Name:MICHAEL RASZEJA CAGE:6V042 CAGE:6V042 Contract Num:MDA414-99-P-5173 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM NITRATE TETRAHYDRATE CAS:13477-34-4 RTECS #:EW3000000 > Wt:98. ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:DATA LACKING FOR THIS COMPOUND. GENERAL TOXICITY; LARGE AMOUNTS TAKEN BY MOUTH MAY HAVE SERIOUS OR EVEN FATAL EFFECTS. Effects of Overexposure:LARGE: THE SYMPTOMS ARE DIZZINESS, ABDOMINAL CRAMPS, VOMITING, BLOODY DIARRHEA, WEAKNESS, CONVULSIONS AND COLLAPSE. SMALL REPEATED DOSES MAY LEAD TO WEAKNESS, GENERAL DEPRESSION, HEADACHE AND MENTAL I MPAIRMENT. ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE 2 GLASSES OF WATER TO DRINK. INDUCE VOMITING AND CALL A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYES: FLUSH THOROUGHLY WITH WATERFOR 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER, THEN WASH WITH MILD SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. I F ILLNESS DEVELOPS, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER; DRY CHEMICAL (ABC); CARBON DIOXIDE (CO2). Fire Fighting Procedures:IN FIRE CONDITIONS,WEAR A NIOSH/MSHA-APPROVED SELF-CONTAINED BREATHING APPARATUS. USE FLOODING AMOUNTS OF WATER IN EARLY STAGES OF FIRE. Unusual Fire/Explosion Hazard:STRONG OXIDIZER; IN CONTACT WITH EASILY OXIDIZABLE SUBSTANCES IT MAY REACT RAPIDLY ENOUGH TO CAUSE IGNITION, VIOLENT COMBUSTION OR EXPLOSION. INCRESES THE FLAMMABILITY OF ANY COMBUSTIBLE SUBSTANCE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN A SUITABLE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE AWAY FROM COMBUSTIBLE MATERIALS. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:REMOVE AND WASH CONTAMINATED CLOTHING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. FOR LABORATORY USE ONLY. KEEP OUT OF REACH OF CHILDREN. READ LABEL ON CONTAINER BEFORE USING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY HANDLING. IF DUSTY CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR NIOSH-MSHA-APPROVED DUST MASK. Ventilation:LOCAL:RECOMMENDED. MECHANICAL:NOT REQUIRED Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING. Supplemental Safety and Health WARD'S P/N: 37J0951 ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:=45.C, 113.F Vapor Pres:NEGLIGIBLE AS SOLID Vapor Density:8.17 Spec Gravity:2.36 Solubility in Water:112 G IN 100ML H20 Appearance and Odor:COLORLESS CRYSTALS,GRANULAR,PRILLS,DELIQUESCENT;NO ODOR. Percent Volatiles by Volume:NEG AS SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLE MATERIALS AND STRONG REDUCING AGENTS. Stability Condition to Avoid:KEEP AWAY FROM COMBUSTIBLE MATERIALS. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY PRODUCE NITROUS OXIDES =================== Toxicological Information=================== Toxicological Information:TLV: NONE ESTABLISHED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISSOLVE IN WATER AND FLUSH TO SEWER WITH COPIO US AMOUNTS OF WATER. =================== MSDS Transport Information =================== Transport Information:D.O.T.: CALCIUM NITRATE, 5.1, UN1454, PG III. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PH 8 SO-B-112 BUFFER SOLUTION CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PHOSPHATE, DIBASIC, ANHYDROUS, DISODIUM PHOSPHATE CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: 0.5-6% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:POTASSIUM PHOSPHATE (MONOBASIC) *97-2* CAS:7778-77-0 Fraction by Wt: 0.6-9% Ingred Name:POTASSIUM PHOSPHATE, DIBASIC *97-2* CAS:7758-11-4 Fraction by Wt: <2% Ingred Name:AMMONIUM CHLORIDE *97-2* CAS:12125-02-9 RTECS #:BP4550000 Fraction by Wt: <0.15% OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC; ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *97-2* CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <0.04% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 93-98.9% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 17 G/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:POTASSIUM PHOSPHATE MONOBASIC-INHALATION: MAY CAUSE IRRITATION OF NOSE & THROAT. SKIN: MAY CAUSE IRRITATION & DERMATITIS. EYES: MAY CAUSE MILD IRRITATION. INGESTION: PHOSPHATES ARE SLOWLY & INCOMPLETE LY ABSORBED. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:POTASSIUM PHOSPHATE MONOBASIC-IRRITATION, COUGHING, CHOKING, DIARRHEA, NAUSEA, VOMITING, CRAMPS, HYPOCALCEMIC TETANY, SLOW/IRREGULAR HEARTBEAT, WEAKENING OF CARDIAC CONTRACTILITY W/HYPOTENSION, RAPIDBREATHING/SHORTNESS OF BREATH, DIZZINESS, MENTAL CONFUSION, WEAKNESS/HEAVINESS OF LEG, TIREDNESS, PARALYSIS. Medical Cond Aggravated by Exposure:POTASSIUM PHOSPHATE MONOBASIC-PREEXISTING KIDNEY DAMAGE. ======================= First Aid Measures ======================= First Aid:INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. KEEP WARM & QUIET. TREAT SYMPTOMATICALLY & SUPPORTIVELY. SKIN: WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LARGE AMOUNTS OF WATER FOR 15 -20 MINS. EYES: WASH IMMEDIATELY W/LARGE AMOUNTS OF WATER/NORMAL SALINE FOR 15-20 MINS. INGESTION: TREAT SYMPTOMATICALLY & SUPPORTIVELY. (SEE SUPP) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS/DUSTS. KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL PRECAUTIONS INDICATED. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR BASED ON CONTAMINATION LEVELS FOUND IN WORK PLACE & MUST NOT EXCEED WORKING LIMITIS OF RESPIRATOR. Ventilation:GENERAL DILUTION. EMERGENCY EYE WASH FOUNTAIN, APPROPRIATE IMPERVIOUS CLOTHING Work Hygienic Practices:IMMEDIATELY REMOVE CONTAMINATED CLOTHING & SHOES. Supplemental Safety and Health ORAL LD50 INFORMATION IS FOR SODIUM PHOSPHATE, DIBASIC. FIRST AID: IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Melt/Freeze Pt:M.P/F.P Text:32F Vapor Density:0.7 Spec Gravity:>1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID (RED, YELLOW/BLUE FOR COLOR CODED SOLUTIONS). ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES, ALUMINUM, STEEL. Stability Condition to Avoid:HEAT, FLAME. Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: SODIUM OXIDE & OXIDES OF PHOSPHOROUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:462-468 COLORSET Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:COPPER COMPOUND Fraction by Wt: 2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EC-801A ACCELERATOR (CLASS A&B) CAGE:76381 CAGE:04963 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD PEROXIDE (LEAD DIOXIDE), (OSHA PEL FROM 29CFR 1910.1025) CAS:1309-60-0 RTECS #:OG0700000 Fraction by Wt: 73%. OSHA PEL:0.05 MG/M3 (PB) ACGIH TLV:0.15 MG/M3(PB); 8990 Ingred Name:FATTY ACID BODYING AGENT (SEE FOURTH NIOSH ENTRY) Fraction by Wt: UNK ACGIH TLV:UNK Ingred Name:TERPHENYL PLASTICIZER (SEE FOURTH NIOSH ENTRY) Fraction by Wt: UNK ACGIH TLV:UNK Ingred Name:MFR'S MSDS SHOWS NIOSH ENTRY(2 & 3) TO BE A COMBINED % OF:(RANGE 22-38 % ) RTECS #:9999999ZZ ===================== Hazards Identification ===================== Effects of Overexposure:EYE: IRRITATION. SKIN:IRRITATION. PROLONGED CONTACT MAY PRODSYSTEMIC PROBLEMS FROM ABSORPTION. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN,CALL A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2,FOAM,DRY CHEM ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SPILLED MATERIAL USING ABSORBENT MATERIAL. PLACE IN CLOSED METAL CONTAINER. AVOID CONTACT WITH SKIN OR EYES. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE,SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL Supplemental Safety and Health PART B OF TWO PART EC-801(B4)SLNT KIT.STORE W/PART A & DO NOT SEPARATE. PT B ISR1 OXIDIZER IN BULK. OTER P/N: EC-1622 ACCELERATOR. QTY:UNKN. KEY1:D2. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>600F/315C Vapor Pres:<2 Spec Gravity:2.8 Solubility in Water:NEGLIGIBLE Appearance and Odor:BROWN PASTE - SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH REDUCING AGENTS. Hazardous Decomposition Products:CO,CO2,& SMOKE PARTICALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN A SECURE LANDFILL AT A HAZARDOUS WASTE MANAGEMENT FACILITY. EPA HAZARDOUS WASTE NUMBER D-0008. COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:812 1188,WKG SOL,KODAK T-MAX 100 DIRECT (SEE SUPPL DATA) Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:85. Maxumum % Wt:90. Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Minumum % Wt:10. Maxumum % Wt:15. Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 < Wt:1. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN Routes of Entry: Inhalation:UNKNOWN Skin:UNKNOWN Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: MATERIAL HAS LOW POT ENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): SULFUR DIOXIDE, SOME SULFITES, BISULFITES AND METASULFITES GROUP 3 NOT CLASSIFIABLE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACG IH): NONE - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY TRACT. SOME ASTHMATICS O R HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: MATERIAL HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; CASES OF HUMAN SKIN SENSITIZATION REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL TRACT IF SWALLOWED. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCO NSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION). Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT. Supplemental Safety and Health SUPPL DATA CONTD; 812 1188,WKG SOL,KODAK T-MAX 100 DIRECT POSITIVE FILM CLEARING BATH. THIS IS A FIVE PART KIT, SAME NSN AND CAGE. FOR OTHER PARTS, SEE MSDS #CLGZH, CLGZK, CLGZD, CLGZC. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:>100.C, 212.F Vapor Pres:68F: 24MBAR (18 MM HG) Vapor Density:0.6 Spec Gravity:1.09 pH:10.1 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, NO ODOR Percent Volatiles by Volume:85-90 WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:STABLE Hazardous Decomposition Products:SULFUR DIOXIDE. =================== Toxicological Information=================== Toxicological Information:MATERIAL HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GASTROINTESTINAL TRAC T IF SWALLOWED. ===================== Ecological Information ===================== Ecological:POTENTIAL TOXICITY: FISH LC50 MG/L : >100. DAPHNID EC50 MG/L:> 100. ALGAL IC50 MG/L: N/A. ORGANICS: N/A. POTENTIAL BIOACCUMULATION: LOG POW <1. COD=20, BOD5=20. WASTE TREATMENT MICROORGANISMS EC50 (MG /L)= N/A. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:CALL KODAK HOT LINE 716-722-2400. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SEC 313/TITLE III (40CFR372): NONE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHLOROMYCETIN HYDROCORTISONE OPHTHALMIC Preparer's Name:ROY MUELLER CAGE:93874 CAGE:93874 CAGE:91378 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORAMPHENICOL (CHLOROMYCETIN) CAS:56-75-7 Other REC Limits:0.5 MG/M3 Ingred Name:HYDROCORTISONE ACETATE CAS:50-03-3 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT):2500MG/KG CHLORAMPHENICL Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION-IRRITATING TO RESPIRATORY TRACT. INGESTION-MAY CAUSE GI IRRITATION. ESTIMATED TO BE MODERATELY TOXIC. SKIN-IRRITATION. EYE-IRRITATION. CHRONIC: SKIN SENSITIZATION, ANEMIA, LEUKEMIA. Explanation of Carcinogenicity:CHLORAMPENICOL IS LISTED BY IARC AS A POSSIBLE CARCINOGEN. Effects of Overexposure:INHALATION-BREATHING DIFFICULTIES. INGESTION-CAN CAUSE NAUSEA, DIARRHEA, MALABSORPTION. EYE/SKIN-IRRITATION. Medical Cond Aggravated by Exposure:MAY BE SKIN DISEASES. ======================= First Aid Measures ======================= First Aid:EYE-FLUSH PROMPTLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN-WASH WITH SOAP & WATER; THEN FLUSH WITH WATER UNTIL CHEMICAL IS REMOVED. INGESTION-IF CONSCIOUS, IMMEDIATELY GIVE 2 TO 4 GLASSES O F WATER AND IMMEDIATELY GET MEDICAL HELP. INHALATION-REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR ABSORB IN INERT MATERIAL AND PLACE IN A CONTAINER FOR DISPOSAL. FLUSH RESIDUE AWAY WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED, DRY AREA OF LOW FIRE RISK. KEEP CONTAINER TIGHTLY CLOSED. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. Ventilation:NATURAL VENTILATION IS ADEQUATE. Other Protective Equipment:WEAR REGULAR WORK CLOTHES, INCLUDING LONG-SLEEVED SHIRT & TROUSERS. Work Hygienic Practices:USE NORMAL PERSONAL HYGIENE AND FOLLOW GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health THIS MEDICINE IS USED AS ANTIBIOTIC, MINIMAL OCCUPATIONAL HAZARD IS INVOLVED. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.011 Appearance and Odor:SOLID, WHITE TO OFF-WHITE CAKE, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG STRONG ACIDS AND ALKALIS. Stability Condition to Avoid:HIGH HEAT. Hazardous Decomposition Products:OXIDES OF CARBON, NITROGEN AND HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RAGE-586 CAGE:29431 CAGE:29431 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-ETHOXYETHOXY)-, ACETATE CAS:112-15-2 RTECS #:KK8925000 Fraction by Wt: 8-11.3% Ingred Name:CYCLOHEXANONE (SARA III) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: 12.1-17% Other REC Limits:TRANS PEL: 50 PPM OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE) CAS:123-42-2 RTECS #:SA9100000 Fraction by Wt: 8-11.3% OSHA PEL:50 PPM ACGIH TLV:50 PPM; 9192 Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 12-16.8% OSHA PEL:100 PPM (MFR) ACGIH TLV:50 PPM (MFR) Ingred Name:2(3H)-DIHYDROFURANONE CAS:96-48-0 RTECS #:LU3500000 Fraction by Wt: 4.8-6.8% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: LIQ CNTCT CAUSES IRRIT & MAY CAUSE REVERSIBLE CORNEAL DMG. VAPS MAY CAUSE IRRIT. SKIN: PRLNG/RPTD LIQ CNTCT CAN CAUSE IRRIT & DERM. INHAL: MAY CAUSE RESP TRACT IRRIT. HIGH VAP CONC CAUSE ANESTHE SIA & POSS UNCON. PRLNG/RPTD CNTCT MAY CAUSE LIVER & KIDNEY DMG. INGEST: CAN CAUSE GI IRRIT, NAUS, VOMIT, NARCOSIS. Effects of Overexposure:EYES: BURNING SENSATION, REDNESS, TEARING, BLURRED VISION. SKIN: REDNESS, DRYNESS, CRACKING, DERMATITIS. INHAL: NOSE, THROAT & LUNG IRRITATION, HEADACHE, NAUSEA, DIZZINESS, TIREDNESS, LOSS OF COORDINA TION, POSSIBLE UNCON. INGEST: DIGESTIVETRACT IRRITATION, NAUSEA, VOMITING, DIARRHEA, TIREDNESS, LOSS OF COORDINATION. Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MD. INGEST: IF VICTIM IS ALERT, GIVE 8-16 OZ OF MILK OR WATER AND GET MD IMMEDIATELY. DO NOT INDUCE VOMITING. SKIN: WASH THORO UGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. LAUNDER OR CLEAN BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:111F,44C Lower Limits:0.6% Upper Limits:9.0% Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM, WATER FOG Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT WHEN FIGHTING FIRE IN ENCLOSED AREAS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. PICK UP WITH SUITABLE ABSORBENT AND PLACE IN COVERED CONTAINERS FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID BREATHING MIST/VAPOR. AVOID CNTCT W/EYES, SKIN OR CLOTHING. AVOID PRLNG/RPTD CNTCT W/SKIN. KEEP AWAY FROM HEAT & FLAME. Other Precautions:DANGER! HARMFUL OR FATAL IF SWALLOWED. HARMFUL IF INHALED. CAUSES EYE, SKIN & RESP TRACT IRRIT. HARMFUL IF ABSORBED THROUGH THE SKIN. CONTAINS MATERIAL WHICH MAY CAUSE BLOOD CELL, LIVER & KIDNEY DAMAG E. COMBUSTIBLE LIQUID AND VAPOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ONLY WITH ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES . Supplemental Safety and Health % VOLAT: 61.5-68.0. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:308F,153C Vapor Pres:1.54 Vapor Density:3.81 Spec Gravity:1.012-1.283 Evaporation Rate & Reference:SLOWER (BUTYL ACETATE=1) Solubility in Water:< 0.1% Appearance and Odor:CLEAR OR COLORED PASTE. MILD SOLVENT ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, STRONG MINERAL ACIDS. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:NOXIOUS SMOKE, CO*X, NO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W ALL LOCAL, STATE AND FEDERAL REGULATIONS, PREFERABLY BY INCINERATION. EPA HAZARDOUS WASTE NUMBER IS D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ILFOSPEED 2000 FIXER/REPLENISHER CAGE:64145 CAGE:64145 CAGE:NO672 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 40-45% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM ACETATE CAS:127-09-3 RTECS #:AJ4300010 Fraction by Wt: 3-6% Other REC Limits:NONE RECOMMENDED Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: 2-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG BORATES/M3 ACGIH TLV:5 MG BORATES/M3 Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-45% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYES;MAY CAUSE IRRITATION. SKIN;MAY CAUSE IRRITATION. INHALATION;LOW HAZARD WITH TYPICAL USE CONDITIONS. INGESTION;MAY IRRITATE G/I TRACT. CHRONIC-NOT KNOWN. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO SUBSTANCES LISTED AS CARCINOGENS BY NTP, OSHA, IARC AND ACGIH. Effects of Overexposure:SEE HEALTH HAZARDS. MFR GAVE NO INFORMATION OF MSDS. Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:WASH AFFECTED AREAS W/SOAP & WATER. INHALATION:REMOVE TO FRESH AIR. INGESTION:IF CONSCIOUS, GIVE 3-4 GLASSES OF WATER. INDUC E VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Autoignition Temp:Autoignition Temp Text:N/A. Lower Limits:N/A. Upper Limits:N/A. Extinguishing Media:USE MEDIA PROPER TO PRIMARY SOURCE OF FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES Unusual Fire/Explosion Hazard:FIRE AND EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/WATER & FLUSH TO SEWER. DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO LIMITATIONS IMPOSED BY FEDERAL, STATE OR LOCAL REGULATIONS. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:TO USE PRODUCT SAFELY, READ MSDS, LABELS AND INSTRUCTIONS AND CARRY APPROPRIATE PRECAUTIONS. STORE IN A COOL DRY AREA AWAY FROM ACIDS & ALKALIES. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION 10-12 ROOM VOLUME CHANGES PER HOUR. Other Protective Equipment:MFR GAVE NO INFORMATION OF MSDS. Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health THIS CHEMICAL FORMULATION HAS NOT BEEN TESTED FOR HEALTH EFFECTS. THEREFORE, EXPOSURE EFFECTS ARE BASED ON EXISTING HEALTH HAZARD DATA FOR INDIVIDUAL COMPONENTS WHICH COMPRISE THE MIXTURE. UNDER CONDI TIONS OF TYPICAL USE, THIS PRODUCT DOESNOT PRESENT A SERIOUS HAZARD. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:N/A. Vapor Pres:AS WATER Vapor Density:AS WATER Spec Gravity:1.280 pH:5.1 Evaporation Rate & Reference:SLOW Solubility in Water:COMPLETE Appearance and Odor:COLORLESS TO LIGHT YELLOW - VINEGAR ODOR Percent Volatiles by Volume:45 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG MINERAL ACIDS & STRONG ALKALIS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:OXIDES OF NITROGEN, SULFUR OR AMMONIA GAS Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DILUTE W/WATER. FLUSH TO SEWER W/PLENTY OF WATER IF PERMITTED BY APPLICABLE DISPOSAL REGULATIONS. MAY REQUIRE DISPOSAL BY AN APPROVED CONTRACTOR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INDUSTRIAL HIGH GLOSS ENAMEL BASE, 800007G GREEN CAGE:FO133 CAGE:97903 CAGE:FO133 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYD RESIN Fraction by Wt: 40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL SPIRITS). MFR'S CAS NO:644742-88-7. VP:2 @ 68F. LEL:1%. CAS:64742-88-7 Fraction by Wt: 40% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:LINSEED OIL; (RAW LINSEED OIL) CAS:8001-26-1 RTECS #:OI9690000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:XYLENE; (MIXED ISOMERS) (SARA 313) (CERCLA). VP:5.1 @ 68F. LEL:1%. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHTHALOCYANINE GREEN PIGMENT; (PHTHALOCYANINE GREEN) CAS:14302-13-7 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS (LESS WATER): 416 G/L. RTECS #:9999999VO Ingred Name:SUPP DATA:APPARENT. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:RESP PROT:WEAR NIOSH/MSHA APPRVD CHEM/MECH FILTERS DESIGNED TO REMOVE COMBINATION OF PARTICULATES & VAP. WHEN (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPRVD AIR SUPPLY RESPS/HOODS. USE NIOSH/MSHA APPRVD RESPS WHEN (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:FLAME CUTTING, WELDING, BRAZING & SANDING MATL COATED W/THIS PROD. FOLLOW RESP MFR'S DIRECTIONS FOR RESP USE. RTECS #:9999999ZZ Ingred Name:VENT:MIXING, APPLICATION & CURING AREAS & TO REMOVE SANDING DUSTS OF DRIED COATING & DECOMP PROD DURING WELDING (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:& FLAME CUTTING ON SURFACES COATED W/THIS PRODUCT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT; MAY AFFECT BRAIN/NERV SYS CAUSING DIZZ, HDCH, NAUS. EYE/SKIN CONT:CAUSES IRRIT. INGEST:CAN CAUSE STOM &/OR INTEST IRRIT, NAUS, VOMIT & DIARR. ASPIR OF VOMITUS CAN CAUS E CHEM PNEUM, WHICH CAN BE FATAL. CHRONIC:PRLNG & RPTD BRTHG OF SPRAY MIST &/OR SANDING DUST OVER A (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:PERIOD OF YEARS MAY CAUSE DUST DISEASE OF THE LUNGS. Medical Cond Aggravated by Exposure:NONE WHEN USED I/A/W SAFE HANDLING & USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE W/SOAP & WATER. REMOVE SOILED CLOTHING. INGEST:DRINK 1-2 GLASSES OF WATER. DO NOT INDUCE VOMITING. CONSULT MD IMMEDIATELY. TREAT SYMPTOMATICALLY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:102F,39C Lower Limits:SEE INGS Extinguishing Media:IN CASE OF FIRE, USE CO*2, DRY CHEM, FOAM/OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. IF(SUPDAT) Unusual Fire/Explosion Hazard:COMBUST LIQ - CLASS II. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT & FLAME. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. NEVER(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WASH W/WATER. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD INFO IN OTHER SECTIONS OF THIS MSDS. CONTAIN SPILLED MATERIAL & REMOVE W/INERT ABSORBENT. STORE IN CLOSED CONTAINERS UNTIL PROPERLY DISPOSED O F. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPORS, SPRAY MIST OR SANDING DUST. USE ONLY W/ADEQUATE VENTILATION. DO NOT GET IN EYES. STORE BELOW 110F. KEEP FROM FREEZING. Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS W/UNRESTRICTED VENT & DURING SANDING/GRINDING OPERATIONS, USE NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST . WHEN USED IN RESTRICTED AREAS, (ING 9) Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP AIR CONC BELOW CURRENT APPLIC SFTY HLTH STDS IN (ING 12) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . NOT REQUIRED. Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health FIRE FIGHT PROC:EXPOS TO FIRE/EXTREME HEAT, WATER SHOULD BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP/AUTO-IGNIT. EXPLO HAZ:USE WELDING/CUTTING TORCH ON/NEAR CNTNR (EVEN IF EMPTY) AS PROD/ITS RE SIDUE MAY IGNITE. DURING EMER CNDTNS, OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE PRESENT/IMMED (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>302F,>150C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.96 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:52.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/MATERIALS THAT ARE UNSTABLE W/WATER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE HAZ FUMES WHEN HEATED TO DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OXIDES OF INGS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZINCPRIME 42 WATER BASE LIQ,PT A (105L0270) Kit Part:Y CAGE:IO398 CAGE:IO398 CAGE:30806 ============= Composition/Information on Ingredients ============= Fraction by Wt: 15% Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:CALCIUM THETA SILICATE CAS# Fraction by Wt: <5% Ingred Name:WATER CAS# 7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80% ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:RESP TRACT IRRIT.HDCH,NAUS,DIZZ,WEAK,FATIGUE.INGEST:STOMACH,INTEST IRRIT,NAUS,VOMIT,DIARR.SUPP ======================= First Aid Measures ======================= First Aid:INHAL:GET FRESH AIR.IF CONTINUED DIFFICULTY BREATH,CALL MD IMMED.IF BREATH STOPS,USE CPR,CALL MD IMMED.EYE:FLUSH IMMED W/ LARGE AMT OF WATER FOR 15 MIN OR MORE.CALL MD.SKIN:WASH W/SOAP/WATER.REMOVE CL OTH.CALL MD IF IRRIT PERSISTS.ORAL:CALLMD IMMED. ===================== Fire Fighting Measures ===================== Flash Point:NONE(PER MFR) Lower Limits:0 Extinguishing Media:CO*2,DRY CHEM,FOAM OR OTHER NFPA APPRVD METH - CLASS B FIRE Fire Fighting Procedures:ISOLATE CONTNR FROM IGNIT SRCE.WATER SPRAY WAY BE INEFF.SUPP Unusual Fire/Explosion Hazard:CLOSED CONTNRS MAY EXPLO.NEVER USE WELDING OR CUTTING TORCH ON OR NEAR CONTNR(EVEN EMPTY),MAY IGNITE ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION(FLAMES,HOT SURFACES & ELEC,STATIC OR FRICTIONAL SPARKS).VENT AREA.DO NOT BREATH VAP.BEFORE CLEAN-UP,READ WHOLE HMIS REC.CONTAIN SPILL MATL,REMOVE W/ INERT ABSORBENT ANDNON-SPARKING TOOLS.STORE IN CLSD CONTNRTIL DISPOS ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE >120F OR NEAR FIRE,OPEN FLAME.CLOSE CONTNRS AFTER USE.DO NOT REUSE EMPTY CONTNR.DO NOT SMOKE.MIXT OF PART A & B WILL HAVE HAZ OF BOTH. Other Precautions:RESPIR:RESTRICT VENY,USE NIOSH/MSHA APPRVD CHEM/MECH FILT.IN CONFINED AREA,USE NIOSH/MSHA APPRVD AIR SUPPLY RESPIR OR HOODS.USE NIOSH/MSHA APPRVD RESP WHEN FLAME CUT,WELD,BRAZE OR SAND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP REQD. CONSULT SAFETY OFF./I.H. SEE OTHR PRECT Ventilation:GENL DILUT,LOCAL EXHST.REMOVE HEAVY SOLV VAP FROM LOWER REVL Other Protective Equipment:SOLVENT IMPERMEABLE CLOTHING AND BOOTS. Supplemental Safety and Health MSDS PREP:86112.OVEREXPO:SKIN & EYE:PRIME IRRIT.FIREFIGHT:VAP MAY CAUSE FLASH FIRE,IGNIT EXPLO,SPREAD LONG DISTANCE,BEYOND DOORS.USE SCBA.USE FOG NOZ W/ WATER.PROD IS PART A OF A 2-PART KIT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:>1 Spec Gravity:1.18 Evaporation Rate & Reference:<1(ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:NEUTRAL COLOR Percent Volatiles by Volume:89.3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:HAZ FUMES CONTAINING CO & CO*2 WHEN HEATED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.INCINERATE ONLY IN APPROVED FACILITY.DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GC BOND CEMENT 10-4308 Preparer's Name:V. HAGEMAN CAGE:EO032 CAGE:EO032 CAGE:72653 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 80% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NITRILE RUBBER RESIN Fraction by Wt: 20% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY IRRITATION, HEADACHE, DIZZINESS, NAUSEA, PARALYSIS, DELIRUM. SKIN: IRRITATION, & DERMATITIS. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: RESPIRATORY TRACT IRRITATION, HEADACHE, DIZZINESS, NAUSEA, PARALYSIS, DELIRUM. EYES: IRRITATION. SKIN: IRRITATION, & DERMATITIS. Medical Cond Aggravated by Exposure:SKIN BLOOD OR NERVOUS SYSTEM DISEASES ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR, GIVE OR OXYGEN, ARTIFICIAL RESPIRATION IF NECESSARY. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:22F Lower Limits:1.8% Upper Limits:10% Extinguishing Media:CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures:TREAT AS FLAMMABLE SOLVENT FIRE ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS W/ABSORBENT MATERIAL. SOLVENT WILL QUICKLY EVAPORATE FROM SMALL SPILLS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. AVOID INHALING FUMES. Other Precautions:AVOID CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST/MECHANICAL VENTILATION TO KEEP <TLV Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175F Vapor Pres:71.2 Vapor Density:2.41 Spec Gravity:0.87 Evaporation Rate &amp; Reference:(BU AC = 1): <1 Solubility in Water:INSOLUBLE Appearance and Odor:TAN LIQUID-KETONE ODOR Percent Volatiles by Volume:20% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:IGNITION SOURCES SUCH AS HEAT, SPARKS, & OPEN FLAMES. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:AUTHORIZED SOLID WASTE LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CRISTOBALITE INLAY INVESTMENT CAGE:EO529 CAGE:33339 CAGE:EO529 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 73.0% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: DRY. INHALATION: LUNG INJURY (SILICOSIS), PULMONARY FIBROSIS & DEATH. INGESTION: HARDENS WHEN WETTED & MAY RESULT IN AN OBSTRUCTION. Explanation of Carcinogenicity:IARC REPORTS LIMITED EVIDENCE OF THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS. IARC CLASS 2A. Effects of Overexposure:EYE: IRRITATION. SKIN: DRY. INHALATION: LUNG INJURY (SILICOSIS), PULMONARY FIBROSIS & DEATH. INGESTION: HARDENS WHEN WETTED & MAY RESULT IN AN OBSTRUCTION. ======================= First Aid Measures ======================= First Aid:EYE: WASH W/LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MED ATT. SKIN: WASH W/SOAP & WATER. INHALATION: MOVE EXPOSED PERSON TO FRESH AIR. INGESTION: CONSULT PHYSICIAN. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL OR RELEASE. SWEEP UP. AVOID UNNECESSARY STIRRING OR HANDLING IN ORDER TO PREVENT FORMATION OF DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T BREATHE DUST. KEEP CONTAINER CLOSED. USE ACCORDING TO DIRECTIONS. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH-APPROVED EQUIPMENT. Ventilation:USE SUFFICIENT LOCAL EXHAUST TO REDUCE THE LEVEL OF RESPIRABLE CRYSTALLINE SILICA TO THE PEL. Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2230C Melt/Freeze Pt:M.P/F.P Text:1600F Vapor Pres:0 Spec Gravity:2.6 Solubility in Water:INSOLUBLE Appearance and Odor:OFF WHITE, ODORLESS SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, HYDROFLUORIC ACID WHICH PRODUCES THE CORROSIVE GAS SILICON TETRAFLUORIDE Stability Condition to Avoid:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0299-4 ISOOCTANE Preparer's Name:NOT PROVIDED. CAGE:1B464 Contract Num:SP0450-00-M-D496 CAGE:8E930 Contract Num:SP0450-01-M-D377 CAGE:8E930 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ISOOCTANE CAS:540-84-1 RTECS #:SA3320000 = Wt:100. Other REC Limits:NOT PROVIDED. OSHA PEL:NOT PROVIDED. ACGIH TLV:NOT PROVIDED. EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT AVAILABLE. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: CENTRAL NERVOUS SYSTEM (CNS). EYE: MAY CAUSE IRRITATION. SKIN: CAUSES IRRITATION. PROLONGED AND/OR REPEATED CONTACT MAY CAUSE DEFATTING AND DERMATITIS. INGESTION: ASPIRATION HAZARD. CAU SES GASTROINTESTINAL IRRITATION. MAY CAUSE CNS DEPRESSION, COMA AND POSSIBLE DEATH DUE TO RESPIRATORY FAILURE. INHALATION: INHALATION OF HIGH CONCENTRATIONS MAY CAUSE CNS EFFECTS, IRRITATION. MAY CAUS E NARCOTIC EFFECTS IN HIGH CONCENTRATION. ASPIRATION MAY LEAD TO PULMONARY EDEMA. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DEFATTING AND DERMATITIS. MAY CAUSE TRANSIENT KIDNEY DISTURBANCE S. Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. Effects of Overexposure:EYE: MAY CAUSE IRRITATION. SKIN: CAUSES IRRITATION. PROLONGED AND/OR REPEATED CONTACT MAY CAUSE DEFATTING AND DERMATITIS. INGESTION: ASPIRATION HAZARD. CAUSES GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. MAY CAUSE CNS DEPRESSION, CHARACTERIZED BY EXCIETMENT, HEADACHE, DIZZINESS, DROWSINESS, COMA AND POSSIBLE DEATH DUE TO RESPIRATORY FAILURE. INHALATION: INHALATION OF HIGH CONCEN TRATIONS MAY CAUSE CNS EFFECTS CHARACTERIZED BY HEADACHE, DIZZINESS, UNCONSCIOUSNESS AND COMA. MAY CAUSE IRRITATION, COUGHING, WHEEZING, SHORTNESS OF BREATH. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING THE LIDS. GET MEDICAL AID. SKIN: GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGESTION: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID IMMEDIA TELY. INHALATION: GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. ===================== Fire Fighting Measures ===================== Flash Point:=-12.C, 10.4F Autoignition Temp:=417.C, 782.6F Lower Limits:1.1 Upper Limits:6.0 Extinguishing Media:USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. THIS MATERIAL IS LIGHTER THAN WATER AND INSOLUBLE IN WATER. USE DRY CHEMICAL, CARBON DIOXIDE, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:AS WITH ANY FIRE, WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, AND FULL PROTECTIVE GEAR. FIRE COULD EASILY BE SPREAD BY THE USE OF WATER IN AN AREA WHERE WATER CANNOT BE CONTAINED. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. EXTREMELY FLAMMABLE LIQUID. VAPORS MAY CAUSE FLASH FIRE. CONTAINERS MAY EXPLODE IN THE HEAT OF FIRE. LIQUID WILL FLOAT AND MAY REIGNITE ON THE SURFACE OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT. ABSORB SPILL WITH INERT MATERIAL, (E.G., DRY SAND OR EARTH), THEN PLACE IN CHEMICAL WASTE CONTAINER. AVOID RUNOFF TO STORM SEWER, DITCHES WHICH LEAD TO WATERW AYS. REMOVE ALL SOURCES OF IGNITION. USE A SPARK-PROOF TOOL. PROVIDE VENTILATION. A VAPOR SUPPRESSING FOAM MAY USED TO REDUCE VAPORS. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE DANGEROUS. Other Precautions:USE ONLY IN A WELL VENTILATED AREA. GROUND AND BOND CONTAINERS WHEN TRANSFERRING MATERIAL. USE SPARK-PROOF TOOLS & EXPLOSION-PROOF EQUIPMENT. AVOID CONTACT WITH EYES, SKIN, CLOTHING. DO NOT PRESSURIZE , CUT, WELD, BRAZE, SOLDER, DRILL OR EXPOSE EMPTY CONTAINER TO SPARKS OR OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN STANDARD EN149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Ventilation:VENTILATION FANS AND OTHER ELECTRICAL SERVICE MUST BE NON-SPARKING AND HAVE AN EXPLOSION-PROOF DESIGN. 1910.133 OR EN166. Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NO DATA PROVIDED BY MANUFACTURER. Supplemental Safety and Health NOTE TO PHYSICIAN: TREAT SYMPTOMTICALLY AND SUPPORTIVELY. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=99.C, 210.2F B.P. Text:98-99C Melt/Freeze Pt:=-107.C, -160.6F Vapor Pres:39 @20C/68F Vapor Density:3.94 Spec Gravity:0.69 pH:NOT AVAILABLE Viscosity:<32 SUS Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID - GASOLINE-LIKE ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, REDUCING AGENTS, STRONG ACIDS, STRONG BASES Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES, EXCESS HEAT, ELECTRICAL SPARKS Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE Conditions to Avoid Polymerization:MAY OCCUR. =================== Toxicological Information=================== Toxicological Information:RTECS#: CAS# 540-84-1: SA3320000. LC/LD50: NOT AVAILABLE. CARCINOGENICITY: ISOOCTANE: NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. EPIDEMIOLOGY: NOT AVAILABLE. TERATOGENICITY: NOT AVAILABLE. REPROD UCTIVE EFFECTS: NOT AVAILABLE. NEUROTOXICITY: NOT AVAILABLE. MUTAGENCITY: SEE RTECS. OTHER STUDIES: NOT AVAILABLE. ===================== Ecological Information ===================== Ecological:NO INFORMATION AVAILABLE. . ==================== Disposal Considerations ==================== Waste Disposal Methods:CHEMICAL WASTE GENERATORS MUST DETERMINE WHETHER A DISCARDED CHEMICAL IS CLASSIFIED AS A HAZARDOUS WASTE. US EPA GUIDELINES FOR THE CLASSIFICATION DETERMINATION ARE LISTED IN 40 CFR 261. ADDITIONALLY, WASTE GENERATORS MUST CONSULT STATE & LOCAL HAZARDOUS WASTE REGULATIONS TO ENSURE COMPLETE & ACCURA TE CLASSIFICATION. RCRA P & U SERIES: NOT LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: OCTANES, HAZARDS CLASS: 3, UN NUMBER: UN1262, PACKING GROUP II. CANADIAN TDG: SHIPPING NAME: OCTANES, HAZARDS CLASS: 3, UN NUMBER: UN1262, OTHER INFORMATION: FLASHPOINT: -12C. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311.312: ACUTE, FLAMMABLE. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. SARA SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ):NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A TPQ. Federal Regulatory Information:CAS # 68476-50-6 IS LISTED ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY. OSHA: NONE OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA. CLEAN AIR ACT: C AS # 540-84-1 IS LISTED AS A HAZARDOUS AIR POLLUTANT (HAP). THIS MATERIAL DOE NOT CONTAIN ANY CLASS 1 OR CLASS 2 OZONE DEPLETING CHEMICALS. CLEAN WATER ACT: NONE OF THE CHEMICALS IN THIS PRODUCT ARE L ISTED AS HAZARDOUS SUBSTANCES UNDER CWA; OR AS PRIORITY POLLUTANTS OR TOXIC POLLUTANTS UNDER THE CWA .TSCA HEALTH AND SAFETY REPORTING LIST: CAS# 540-84-1: EFFECTTIVE DATE: JUNE 1, 1987; SUNSET DATE: DECEMBER 19, 1995. State Regulatory Information:ISOOCTANE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: NEW JERSEY, FLORIDA, PENNSYLVANIA, MASSACHUSETTS. CALIFORNIA NO SIGNIFIGANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LIS TED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPON(R) RESIN 828 Preparer's Name:JOHN P. SEPESI CAGE:SHELL CAGE:86961 CAGE:SHELL ============= Composition/Information on Ingredients ============= Ingred Name:EPON RESIN 828 CAS:25068-38-6 RTECS #:KC2100000 Fraction by Wt: 100% Ingred Name:EPICHLOROHYDRIN (SARA III) CAS:106-89-8 RTECS #:TX4900000 OSHA PEL:S, 5 PPM ACGIH TLV:S, 2 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:INGESTION: LOW ORDER OF ACUTE ORAL TOXICITY. SKIN SENSITIZATION (ALLERGY) MAY BEEVIDENCED BY RASHES. ESPECIALLY HIVES. IRRITATION AS NOTED. Effects of Overexposure:EYE: MOD IRRI. SKIN: MOD IRRI, SKIN SENSITIZATION. INHALE: BECAUSE OF ITS VERYLOW VOLATILITY THIS PRODUCT IS NOT LIKELY TO PRODUCE ANY ADVERSE EFFECTS FROMINHALE. INGESTION: BASED ON PRODUCT TEST ING PRODUCT IS GENERALLY CONSIDERED TOHAVE A LOW ORDER OF ACUTE ORAL TOXICITY. IRRI, SKIN SENSITIZER (ALLERGY) RASHES Medical Cond Aggravated by Exposure:PREEXISTING SKIN ALLERGIES MAY INCREASE THE CHANCEOF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOSURE TO THIS PRODUCT. SKIN & EYE DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/PLENTY OF WTR 15 MIN LIFTING LIDS. GET MED ATTN. SKIN: IMMED REMOVE CONTAM CLOTH/SHOES, FLUSH W/PLENTY OF WTR 15 MIN USE SOAP & WTR. DON'T REUSE CLOTHES UNTIL THORO CLEANED. GET MED ATTN. CONTAM LEATHER CAN'T BE DECONTAMDESTROY. INHALE: REMOVE TO FRESH AIR PROVIDE CPR/OXYGEN IF NEEDED. GET MED ATTN.INGEST: DON'T INDUCE VOMIT. NO TREAT IS NECESSARY UNLESS LG AMTS. GET MED ADVISE ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:480 F/ 298 C Lower Limits:NA Upper Limits:NA Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CO2 Fire Fighting Procedures:DON'T ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR MATERIAL WILL NOT BURN UNLESS PREHEATED. (HELMET, FACE Unusual Fire/Explosion Hazard:ALSO USE A POSITIVE PRESSURE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. ================== Accidental Release Measures ================== Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. CAUTIOUS JUDGMENT WHEN CLEANING UP LG SPILLS. WEAR RESPIR &PROTECTIVE CLOTHES. SHUT OFF SOURCES OF LEAK IF SAFE. DIKE & CONTAIN. REMOVE W/VACUUM TRUCK/PUMP STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILA- TION. KEEP AWAY FROM OPEN FLAME/HIGH TEMP. HANDLE IN ACCORD W/HAZARD POTENTIAL OF CURING AGENTS USED Other Precautions:CAUTION: MAY CAUSE IRRITATION. AVOID CONTACT WITH EYES. AVOID PROLOGNED OR REPEATED CONTACT WITH SKIN OR BREATHING OF VAPORS. WASH THOROUGHLY AFTER USE. LAUNDERCONTAMINATED CLOTHING BEFORE REUSE. CONT AM LEATHER ARTICLES SHOULD BE DESTROYED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT ORDINARILY REQUIRED. IF RESIN IS WARM/HEATED VAPORS OR MISTS MAY BE PRODUCEDUSE NIOSH-APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE. USE EITHER ANATMOSPHERE SUPPLYING RESPIRATOR OR AN AI R PURIFYING RESPIRATOR FOR ORGANIC VAPOR Ventilation:AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. (IF HEATED, VAPORS OR MIST MAY BE PRODUCED) Other Protective Equipment:AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICALRESISTANT CLOTHING AS REQUIRED TO MINIMIZE CONTACT Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHESBEFORE REUSE. Supplemental Safety and Health THIS PRODUCT IS LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. ALTHOUGH THE SIGNIFICANCE IS UNKNOWN, EPON RESIN 828 HAS BEEN SHOWN TO BE MUTAG-ENIC IN SOME MICROBIAL TEST. BUT HAS FAI LED TO SHOW MUTAGENICITY IN OTHERS. CHROMOSOMAL ABERRATIONS WERE OBSERVED IN CULTURED RAT LIVER CELLS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:1.17 Evaporation Rate & Reference:NA Solubility in Water:NEGLIGIBLE Appearance and Odor:VERY LIGHT YELLOW, VERY VISCOUS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAN REACT VIGOROUSLY WITH STRONG OXIDIZING AGENTS AND STRONGLEWIS OR MINERAL ACIDS. Stability Condition to Avoid:IN REACTIONS WITH MAY CURING AGENTS, CONSIDERABLE HEAT IS RELEASED. Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES & ACIDS MAY BE FORMED DURING COMBUSTION. REACT W/CURING AGENTS MAY PRODUCE CONSIDERABLE HEAT Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMP-LIANCE WITH LOCAL REGULATIONS. SOAK UP RESIDUE W/ AN ABOSRBENT SUCH AS CLAY, SAND OR OTHER SUITABLE MATERIAL. FLUSH AREA W/WTR TO REMOVE TRACE OF RES- IDUE. SM SPILL TAKE UP WITH ABSORBENT &DISPOSE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:07510 LDS 751 Preparer's Name:LARRY KNAAK CAGE:9Z504 CAGE:9Z504 ============= Composition/Information on Ingredients ============= Ingred Name:LDS 751 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. SKIN: WASH IMMEDIATELY W/SOAP & LARGE AMOUNTS OF WATER. EYES: FLUSH IMMEDIATELY W/PLENTY OF WATER FOR 15 MINS. INGESTION: DRINK 1-2 GLASSES OF W ATER/MILK. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2 Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:FIRE/EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP MATERIAL & PACKAGE FOR SAFE FEED TO AN INCINERATOR. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT W/OXIDIZING MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED DUST RESPIRATOR IF NEEDED. Ventilation:GOOD GENERAL ROOM, LOCAL EXHAUST MAY BE NEEDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:546.8F Vapor Pres:NEGLIGIBLE Evaporation Rate & Reference:(N-BU AC = 1): NEGLIGIBLE Solubility in Water:INSOLUBLE Appearance and Odor:DARK GREEN CRYSTALS W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:FIRE, EXCESSIVE HEAT Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, HYDROGEN CHLORIDE GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE BY INCINERATION/CONTRACT W/LICENSED CHEMICAL WASTE DISPOSAL AGENCY IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:865 CRYOSPRAY POWDERS Preparer's Name:KEN HEARREAN CAGE:67292 CAGE:67292 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON, ACTIVATED CARBON, GRAPHITE CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: <1% OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:CHROMIUM, CHROMIUM METAL, CHROME (CARCINOGEN BY NTP; IARC GROUP 3) *98-1* CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 11-30% ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:IRON *98-1* CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 1-10% Ingred Name:MANGANESE *98-1* CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1-10% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *98-1* CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 61-100% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:SILICON *98-1* CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 1-10% ACGIH TLV:10 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILDUP IN THE LUNGS, BONE EROSIO N, REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON BUILDUP IN THE LUNGS, BONE EROSIO N, REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGETIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:REMOVE VICTIM TO FRESH AIR; EMPLOY FIRST AID TECHNIQUES RECOMMEDNED BY THE RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY POWDER, DRY SAND, DRY DOLOMITE, DRY GRAPHITE Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS W/A FULL FACEPIECE. Unusual Fire/Explosion Hazard:MOST METAL POWDERS CAN FORM EXPLOSIVE MIXTURES W/AIR. FIRE/EXPLOSION HAZARD WHEN EXPOSED TO HEAT/FLAME. WELDING ARCS/SPARKS CAN IGNITE COMBUSTIBLES. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT MATERIAL FOR RECLAMATION/DISPOSAL IN SELAED CONTAINERS. AVOID INHALATION OF DUSTS. REMOVE SOURCES OF HEAT/IGNITION. KEEP AIRBORNE DUST AT A MINIMUM WHEN CLEANING UP. ======================Handling and Storage ====================== Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS ARE <THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK. Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE THEMSELVES FROM WORK & GROUND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION DOES NOT KEEP EXPOSURE <TLV. Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES <TLV IN WORKER'S BREATHING ZONE & GENERAL AREA. Other Protective Equipment:ARM PROTECTOR, APRON, HAT, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING. Supplemental Safety and Health PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ================== Physical/Chemical Properties ================== Appearance and Odor:METAL ALLOY POWDERS FOR BUILDUP & HARDSURFACING ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, SULFUR (SEE SUPPLEMENTAL DATA) Stability Condition to Avoid:HEAT, FLAME, FIRE. (SEE SUPPLEMENTAL DATA) Hazardous Decomposition Products:HYDROGEN GAS, COMPLEX OXIDES OF IRON, MANGANESE, SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM, TITANIUM ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SCOTCHSEAL 800 INDUSTRIAL SEALANT Kit Part:Y CAGE:52152 CAGE:31435 DIV CAGE:52152 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 40-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACRYLONITRILE BUTADIENE POLYMER CAS:9003-18-3 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED Ingred Name:RESIN ACIDS & ROSIN ACIDS, ESTERS W/GLYCEROL CAS:8050-31-5 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTOXYETHANOL PHOSPHATE CAS:78-51-3 RTECS #:KJ9800000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED Ingred Name:CALCIUM ALUMINUM SILICATE CAS:1327-39-5 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5MG(FE)/M3FUME,B2;96 Ingred Name:ZINC OXIDE (SARA 313) (CERCLA) CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:SALICYLIC ACID CAS:69-72-7 RTECS #:VO0525000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED Ingred Name:VOLATILE ORGANIC CONTENT: 604 GM/L, SCAQMD RULE 443.1 RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT MAY CAUSE SKIN DEFATTING/DERMATITIS & EYE IRRITATION. INHALATION MAY CAUSE CNS IMPAIRMENT. INGESTION MAY CAUSE GI TRACT IRRITATION. CHRONIC: REPEATED EXPOSURE MAY CAUSE LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:EYES-REDNESSS, SWELLING, PAIN, TEARING. SKIN-DRYNESS, CRACKING. INGESTED-GI TRACT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH LOTS OF WATER FOR 10 MINUTES, HOLD LIDS OPEN. CALL A PHYSICIAN. SKIN-WASH AFFECTED AREA WITH SOAP & WATER. INHALED-REMOVE TO FRESH AIR. CALL A PHYSICIAN. INGESTED-DO NOT INDUCE VOMITIN G! IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER. ===================== Fire Fighting Measures ===================== Flash Point:20.0F,-6.7C Lower Limits:1.4 Upper Limits:11.5 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. OVERHEATED, CLOSED CONTAINERS ADJACENT TO FIRE COULD EXPLODE DUE TO INTERNAL PRESSURE BUILD-UP. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. OBSERVE PRECAUTIONS FROM OTHER SECTIONS. CONTAIN SPILL. COVER WITH ABSORBENTS AS NEEDED. COLLECT SPILLED MATERIAL USING NON-SPARKING TOOLS. PLACE IN AN APPROVED METAL CONTAINER AND SEAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. USE ONLY IN WELL-VENTILATED AREAS. Other Precautions:BOND & GROUND CONTAINERS PROPERLY WHEN TRANSFERRING CONTENTS. VAPORS RELEASED ARE EASILY IGNITED. AVOID EYE & SKIN CONTACT. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATHING OF VAPORS, MIST OR SPRAY. Ventilation:USE IN A WELL-VENTILATED AREA. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health KEY1=F3. PART B OF TWO PART KIT, SEE PNI A THIS NSN/CAGE FOR PART A. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175F,79C Vapor Pres:80 @ 68F Vapor Density:2.5 Spec Gravity:1.04 Viscosity:28,736 CP Evaporation Rate & Reference:<1 (WATER=1) Solubility in Water:SLIGHT Appearance and Odor:REDDISH-BROWN, HEAVY SYRUP; KETONE ODOR. Percent Volatiles by Volume:48 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE, SMOKE PARTICLES WHEN SUBJECTED TO EXCESSIVE HEAT OR FLAME. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE ABSORBED & BULK PRODUCT AFTER MIXING WITH FLAMMABLE MATERIAL IN A LICENSED HAZARDOUS WASTE FACILITY. DISPOSAL SHOULD BE IAW APPLICABLE REGULATIONS. US EPA RCRA HAZWASTE NO.: D001 (IGNITABLE ).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:279 PWC POLYURETHANE AEROSOL COLORS CAGE:58977 CAGE:58977 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <5% Other REC Limits:525 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: <5% Other REC Limits:1000 PPM OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:BUTANE, N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 5% Other REC Limits:800 PPM OSHA PEL:600 PPM ACGIH TLV:600 PPM Ingred Name:VOLATILE ORGANIC CONTENT: 5.07 LBS/GAL RTECS #:9999999VO Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-1* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 13% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 34% OSHA PEL:750 PPM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *95-1* CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:150 PPM OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 9750 MG/KG ACETONE Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ANESTHETIC, RESPIRATORY TRACT IRRITATION, NERVOUS SYSTEM DEPRESSION. EYES: IRRITATION. SKIN: PRIMARY IRRITATION, DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, DIZZINESS, HEADACHE, UNCONSCIOUSNESS, BURNING SENSATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. SKIN: WASH AFFECTED AREA. EYES: FLUSH IMMEDIATELY W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-14.8F Lower Limits:0.7 Upper Limits:12.8 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE, BUT WATER SPRAY MAY BE USED TO COOL CONTAINERS EXPOSED TO HEAT/FIRE TO PREVENT PRESSURE BUILD UP. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO BUILD UP OF PRESSURE FROM EXTREME HEAT/FIRE. AEROSOL SPRAY IS EXTREMELY FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA & SOAK UP W/INERT ABSORBENT USING NON-SPARKING TYPE TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F, NEAR IGNITION SOURCES. Other Precautions:AVOID CONTACT W/EYES & SKIN, PROLONGED/REPEATED CONTACT. DON'T BREATHE VAPORS, TAKE INTERNALLY. SMOKING SHOULD BE STRICTLY PROHIBITED WHILE USING PRODUCT. DUST FROM SANDING DRY PAINT FILMS SHOULD BE T REATED AS A NUISANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOORS: APPROVED PARTICULATE FILTER TO REMOVE ANY AIRBORNE OVERSPRAY. RESTRICTED AREAS W/POOR VENTILATION & CLOSE TO TLV:WEAR A NIOSH APPROVED RESPIRATOR W/ORGANIC VAPOR CARTRIDGE. Ventilation:ADEQUATE TO KEEP BELOW TLV. Other Protective Equipment:EYE WASH FOUNTAIN, SAFETY SHOWER, IMPERVIOUS APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-10F Vapor Density:>1 Spec Gravity:0.7 Evaporation Rate & Reference:FASTER THAN N-BU AC Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID W/SOLVENT BASED ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPS, EXTREME HEAT, FIRE, SPARKS, FLAME & OTHER IGNITION SOURCES. Hazardous Decomposition Products:CO, CO2, HYDROGEN CHLORIDE, TRACES OF PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS. FLAMMABLE LIQUID UN1950 CLASS 9.
1
eyes_protection_mandatory
======================================================= NIIN: 01-254-0300 Product ID: 32530 SPEEDBONDER 325 STRUCTURAL ADHESIVE Cage: 7K128 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 7K128 ======================================================= Contractor Summary ======================================================= Cage: 7K128 Cage: 05972 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: ADHESIVE Unit of Issue: BT Quantitative Expression: 00000000100CC UI Container Qty: 0 ======================================================= Ingredients ======================================================= % Wt: 55-60 ----------------------------- Cas: 109-16-0 RTECS #: OZ4100000 % Wt: 25-30 ------------------------------ Cas: 27813-02-1 % Wt: 5-10 ------------------------------ Cas: 79-10-7 RTECS #: AS3475000 % Wt: 3-5 Other REC Limits: 2 PPM = IC OSHA PEL: 10 PPM ACGIH TLV: 2 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 614-45-9 RTECS #: SD9450000 % Wt: 1-3 ------------------------------ Cas: 80-15-9 RTECS #: MX2450000 ISOPROPYLBENZENE HYDROPEROXIDE *96-1* % Wt: 1-3 EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 81-07-2 RTECS #: DE4200000 % Wt: 0.1-1 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 2530-85-0 RTECS #: UC0230000 GAMMA-METHACRYLOXYPROPYLTRIMETHOXYSILANE % Wt: 0.1-1 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50(LAB ANIMAL): >5000 MG/KG Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: LIQUID WILL CAUSE IRRITATION OF THE EYES & SKIN. VAPORS MAY CAUSE IRRITATION OF EYES, NOSE & THROAT. MAY CAUSE DERMATITIS IN SENSITIVE INDIVIDUALS. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION. Medical Cond Aggravated By Exposure: ACRYLIC ACID: UPPER RESPIRATORY & LUNG DISEASES, DERMATITIS. First Aid: INGESTION: DON'T INDUCE VOMITING. KEEP CALM. INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SOAK UP IN AN INERT ABSORBENT. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. Waste Disposal Methods: INCINERATE IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE <100F. AVOID PROLONGED SKIN CONTACT. KEEP AWAY FROM EYES. AVOID PROLONGED BREATHING OF VAPORS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >200F Lower Limits: 2 (SEE SUPP) Upper Limits: 8 (SEE SUPP) Extinguishing Media: CO2, FOAM, DRY CHEMICAL. Fire Fighting Procedures: NONE Unusual Fire/Explosion Hazard: NONE ======================================================= Control Measures ======================================================= Ventilation: SUFFICIENT TO MAINTAIN VAPOR CONCENTRATIONS <TLVS. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 B.P. Text: >300F Vapor Pres: <10 Spec Gravity: 1.11 VOC Grams/Liter: 344 Solubility in Water: SLIGHT Appearance and Odor: YELLOWISH LIQUID W/SHARP, IRRITATING ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: NONE Hazardous Decomposition Products: FIRE/THERMAL: IRRITATING ORGANIC VAPORS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 32530 SPEEDBONDER 325 STRUCTURAL ADHESIVE Cage: 7K128 Company Name: LOCTITE CORP Street: 705 N MT RD Zipcode: 06111 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: LIQUID WILL CAUSE IRRITATION OF THE EYES & SKIN. VAPORS MAY CAUSE IRRITATION OF EYES, NOSE & THROAT. MAY CAUSE DERMATITIS IN SENSITIVE INDIVIDUALS. IRRITATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2718 MINWAX WOOD FINISH EBONY CAGE:EO256 CAGE:EO256 CAGE:0K1A4 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED (C10-C15 SATURATED HYDROCARBONS 97%, C10 AROMATICS 3%) (SUSP CARC IARC) * 96-4 * CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 0-3% Other REC Limits:200 PPM EXXON Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA, C8&10 AROMATIC HYDROCARBON *96-4* CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 0-2% Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS *96-4* CAS:64742-88-7 Fraction by Wt: 72-87% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS *96-4* CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 0-12% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:VOLATILE ORGANIC CONTENT: 720 GM/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITANT. INGESTION: HARMFUL/FATAL. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:INHALATION: IMMEDIATELY REMOVE TO FRESH AIR. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:106F Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL/CO2 Fire Fighting Procedures:DON'T USE A DIRECT STREAM OF WATER. PRODUCT MAY BE REIGNITED ON SURFACE OF WATER. WEAR SCBA & PROTECTIVE CLOTHING. USE WATERSPRAY TO COOL FIRE-EXPOSED CONTAINER Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED W/WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/SAND/OTHER SUITABLE ABSORBENT MATERIAL & PLACE IN A CONTAINER FOR DISPOSAL. LARGE: AREA MAY BE SLIPPERY. DIKE AROUND W/ABSORBENT. TRANSFER LIQUIDS & CONTAMINATED DIKING MATERIAL TO SUITABLE C ONTAINERS FOR RECOVERY/DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T USE/STORE NEAR HEAT/SPARKS/OTHER IGNITION SOURCES. CLOSE CONTAINER AFTER EACH USE. USE ONLY W/ADEQUATE VENTILATION. KEEP OUT CHILDREN'S REACH. Other Precautions:DON'T TAKE INTERNALLY. AVOID CONTACT W/SKIN & EYES. AVOID INHALATION. IF USING INDOORS, OPEN ALL WINDOWS & DOORS TO MAKE SURE THERE IS FRESH AIR MOVEMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REQUIRED Ventilation:REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.805-0.878 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR AMBER TO OPAQUE EARTH-TONE, SLIGHTLY VISCOUS LIQUID W/HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:USING/STORING NEAR HEAT, SPARKS, FLAME/OTHER IGNITION SOURCES Hazardous Decomposition Products:HYDROCARBON FUMES, SMOKE, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7173-202-270 JUST ONE BITE NIBBLERS CAGE:2J367 CAGE:2J367 ============= Composition/Information on Ingredients ============= Ingred Name:BROMADIOLONE CAS:28772-56-7 RTECS #:GN4934700 Fraction by Wt: 0.005% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (LAB ANIMAL): 35 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT REDUCES THE CLOTTING ABILITY OF THE BLOOD & MAY CAUSE BLEEDING IN EXTREME CASES. CHRONIC EXPOSURE MAY RESULT IN AN ACCUMULATION IN THE SYSTEM RESULTING IN BLEEDING. INHALATION: >4 HRS MAY BE SUFFICIENT TO AFFECT CLOTTING ABILITY OF BLOOD. IF CLOTTING TIMES ARE EXTENDED, THEN ANTICOAGULANT POISONING (SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:BLEEDING ======================= First Aid Measures ======================= First Aid:SKIN: IMMEDIATELY WASH W/SOAP & WATER, THEN FLUSH W/LARGE AMOUNTS OF WATER FOR 5 MINS. EYES: FLUSH W/LARGE AMOUNTS OF RUNNING WATER FOR 5 MINS. INHALATION: REMOVE TO FRESH AIR. MONITOR PROTHROMBIN TIM NES FOR 5-7 DAYS. GIVE VITAMIN K1 IN CASE OF HEMORRHAGE CAUSED BY OVERDOSE OF BISHYDROXYCOUMARIN. INGESTION: DRINK 2 GLASSES OF WATER. DONT' GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. (SUPP) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CO2, FOAM, WATER FOG Fire Fighting Procedures:WEAR SCBA (FULL FACEPIECE) & PROTECTIVE CLOTHING. FIGHT FROM UPWIND, STAY OUT OF SMOKE. DIKE CONTROL WATERS TO PREVENT ENTRY INTO SEWERS/BODIES OF WATER. Unusual Fire/Explosion Hazard:EQUIPMENT USED IN FIGHTING PESTICIDE MAY REQUIRE DECONTAMINATION PRIOR TO REUSE. ================== Accidental Release Measures ================== Spill Release Procedures:LIMIT ACCESS. REMOVE BROKEN/LEAKING CONTAINERS TO A SAFE PLACE, IF FEASIBLE. WEAR PROTECTIVE EQUIPMENT WHEN CLEANUP. SCOOP UP MATERIAL. WIPE UP ANY REMAINING DUST W/DAMP ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T CONTAMINATE FEED/FOODSTUFF. STORE IN ORIGINAL CONTAINER IN A COOL, DRY PLACE INACCESSIBLE TO CHILDREN/PETS/WILDLIFE. Other Precautions:DON'T GET IN EYES, ON SKIN/CLOTHING. DON'T TAKE INTERNALLY. DON'T CONTAMINATE WATER, FOOD/ANIMAL FEED BY STORAGE/DISPOSAL. THIS PRODUCT IS TOXIC TO FISH & WILDLIFE. KEEP OUT OF LAKES, STREAMS & PONDS. DON'T INHALE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST RESPIRATOR UNDER HEAVY USE Ventilation:LOCAL EXHAUST AS NEEDED FOR CONTROL MEASURES Other Protective Equipment:COVERALLS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health HEALTH HAZARDS CONT'D: IS PROBABLE. INGESTION: 1 OZ MA AFFECT PROTHROMBIN TIMES. PRODUCT DOES HAVE A PROLONGED ANTI CONAGULANT ACTION WHICH MAY PERSIST TO 4-5 DAYS. MONITOR PROTHROMBIN FOR 5-7 DAYS. I NTRAVENOUS/ORAL ADMINISTRATION OF VITAMIN K1 SHOULD BE GIVEN IF LAB RESULTS INDICATE AN EFFECT ON BLOOD CLOTTING. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:239F Appearance and Odor:BLOND COLORED BLOCK SHAPED BAIT W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES Stability Condition to Avoid:LIGHT, MOISTURE Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE WASTE IN SUITABLE CONTAINER FOR DISPOSAL ON SITE/AT AN APPROVED WASTE DISPOSAL FACILITY/BY INCINERATION IF APPROVED BY STATE, FEDERAL & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NOX RUST X110 Preparer's Name:J KUKSUK CAGE:7X108 CAGE:7X108 CAGE:6X798 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: 0-44% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:PETROLEUM HYDROCARBON, CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 0-44% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 0-44% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9394 Ingred Name:ALIPHATIC PETROLEUM SOLVENT CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:CALCIUM HYDROXIDE CAS:1305-62-0 RTECS #:EW2800000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3; 9394 Ingred Name:PETROLEUM OIL Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:OXIDIZED ALIPHATIC PETROLEUM FRACTION CAS:64743-01-7 Fraction by Wt: >40% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE EFFECTS:EXCESSIVE INHALATION MAY PRODUCE DIZZINESS,NAUSEA,HEADACHE AND UNCOORDINATION. MAY CAUSE REVERSIBLE EYE AND SKIN IRRITATION. PROLONGED SKIN EXPOSURE MAY CAUSE DERMATITIS OR OIL ACNE. BRE ATHING MISTS MAY CAUSE DIZZINESS OR PULMONARY IRRITATION. CHRONIC EFFECTS:NOT DETERMINED. Explanation of Carcinogenicity:NONE OF THE COMPONENTS OF THIS PRODUCT ARE LISTED AS CARCINOGENS BY NTP, IARC OR OSHA 1910 (Z). Effects of Overexposure:INHALATION:PULMONARY IRRITATION,DIZZINESS,NAUSEA,HEADACHE AND UNCOORDINATION. EYE:IRREVERSABLE IRRITATION. SKIN:IRREVERSABLE IRRITATION. PROLONGED SKIN EXPOSURE:DERMATITIS OR OIL ACNE. Medical Cond Aggravated by Exposure:EXPOSURE MAY AGGRAVATE PRE-EXISTING RESPIRATORY OR SKIN PROBLEMS. ======================= First Aid Measures ======================= First Aid:INHALATION:MOVE TO FRESH AIR & CALL EMERGENCY CARE. AID OR RESTORE BREATHING AS NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER AT LEAST 15 MINUTES. SEEK IMMEDIATE MEDICAL ATTENTION. SKIN:WASH WITH SOAP & W ATER. REMOVE & ISOLATE CONTAMINATED CLOTHING & SHOES AT SITE. INGESTION:DO NOT INDUCE VOMITING. CONSULT PHYSICIAN. IF VOMITING OCCURS, KEEP HEAD DOWN TO MINIMIZE ASPIRATION OF LIQUID INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:0.6 Upper Limits:7.0 Extinguishing Media:SMALL:DRY CHEMICAL,CARBON DIOXIDE,WATER SPRAY & FOAM. LARGE:WATER,FOAM. APPLY COOLING WATER TO SIDES OF CONTAINERS. Fire Fighting Procedures:MAY PRODUCE IRRITATING/POISONOUS GASES. POSITIVE PRESSURE SCBA &STRUCTURAL PROTCTIVE CLOTHING WILL PROVIDE LIMITED PROTECTION. LIMIT AREA TO ESSENTIAL PERSONNEL Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL AND 'FLASH BACK' FROM A DISTANT IGNITION SOURCE. VAPOR EXPLOSION HAZARD INDOORS,OUTDOORS & IN SEWERS. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNITION SOURCES. STOP LEAK IF W/O RISK. SMALL SPILL:TAKE UP W/NON-COMBUSTIBLE ABSORBENT & PLACE IN CONTAINERS FOR LATER DISPOSAL. LARGE SPILL:DIKE FAR AHEAD ON LIQUID SPILL FOR LATER DISPOS AL. Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, WELL-VENTILATED AREA. KEEP AWAY FROM FLAME, SPARKS, HOT SURFACES. NEVER USE A TORCH TO CUT OR WELD ON/NEAR CONTAINER. Other Precautions:EMPTY CONTAINERS CAN CONTAIN EXPLOSIVE VAPORS. NEVER WEAR OIL SOAKED CLOTHING. LAUNDER/DRY CLEAN BEFORE WEARING. DISCARD OIL SOAKED SHOES. WASH THROUGHLY W/SOAP & WATER AFTER USING AND BEFORE SMOKING OR EATING. AVOID EXCESSIVE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH-APPROVED RESPIRATOR FOR ORGANIC VAPOR AND MIST TO CONTROL EXPOSURE WHERE VENTILATION IS INADEQUATE. Ventilation:GENERAL AND LOCAL EXHAUST Other Protective Equipment:IF SPLASHING IS ANTICIPATED, WEAR RUBBER APRON, BOOTS OR OTHER PROTECTIVE EQUIPMENT TO MINIMIZE CONTACT. Work Hygienic Practices:MFR: ?HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING OR DRINKING Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:3.4 Vapor Density:>1 Spec Gravity:0.88 Evaporation Rate & Reference:<1 (N-BUAC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK VISCOUS LIQUID; PETROLEUM SOLVENT ODOR Percent Volatiles by Volume:60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZERS Stability Condition to Avoid:NO INFORMATION GIVEN BY MFR ON MSDS. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE, SULFUR OXIDES, MISCELLANEOUS HYDROCARBONS Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH STATE LOCAL AND FEDERAL REGULATIONS. MATERIALS MAY BECOME A HAZARDOUS WASTE THROUGH USE. IF PERMITTED, INCINERATION MAY BE PRACTICED. CONSIDER RECYCLING SOLVENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ASTRO-DRI ENAMEL 1100-1195 CAGE:HO443 CAGE:HO443 CAGE:3F871 ============= Composition/Information on Ingredients ============= Ingred Name:BENZIN (PETROLEUM NAPHTHA) CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 39% Other REC Limits:100 PPM (MFR) OSHA PEL:100 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 3% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: MAY CAUSE IRRIT, REDNESS, ITCHING, BURNING SENSATION OR WATERING OF EYES. SKIN: EXCESSIVE OR PROLONGED CONTACT MAY CAUSE IRRIT OR DEFATTING ACTION. INHAL: MAY CAUSE IRRIT OR CNS DEPRESS: HDCH, DI ZZ, DROWSINESS, NAUS, VOMIT & POSS UNCON. INGEST: MAY CAUSE NAUS OR VOMIT. ASPIRATION OF VOMITUS (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MAY RESULT IN CHEMICAL PNEUMONITIS WHICH MAY BE FATAL. CHRONIC: DERMATITIS. MFR IDENTIFIES SKIN AND INGESTION AS ROUTES OF ENTRY. Medical Cond Aggravated by Exposure:EYE, SKIN, KIDNEY, LIVER, RESPIRATORY OR CNS DISEASES. ======================= First Aid Measures ======================= First Aid:EYES: RINSE W/WATER FOR AT LEAST 15 MIN, HOLDING LIDS OPEN. IF IRRIT PERSISTS, GET MD. SKIN: WASH AFFECTED AREA W/ SOAP & WATER. REMOVE & LAUNDER CONTAMD CLTHG BEFORE REUSE. IF IRRIT PERSISTS, GET MD. INGEST: DO NOT INDUCE VOMIT. IF SPONT VOMIT OCCURS, KEEP HEAD BELOW HIPS TO PVNT ASPIR OF LIQ IN LUNGS. GET MD IMMED. INHAL: REMOVE FROM CONTAMD AREA IF POSS W/OUT EXPOSING (SEE SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:26.0F,-3.3C Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:CO2, DRY CHEMICAL, WATER FOG OR FOAM. DO NOT USE A DIRECT STREAM OF WATER. Fire Fighting Procedures:EVACUATE AREA OF UNPROTECTED PERSONNEL. WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:EMPTY CONTAINERS PRESENT A HAZARD DUE TO RESIDUAL FUMES. VAPORS ARE HEAVIER THAN AIR AND MAY BE IGNITED BY SPARKS, PILOT LIGHTS, ETC. ================== Accidental Release Measures ================== Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION IN VICINITY OF SPILL OR VAPORS. CONTAIN SPILL AND PICK UP WITH ABSORBENT MATERIAL SUCH AS DIACTOMACEOUS EARTH OR CLAY. STORE IN AIRTIGHT METAL CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:FLAM LIQ. VAP HARMFUL. AVOID PRLNGD/RPTD CONT W/LIQ OR VAPS. USE W/ADEQ VENT. KEEP CNTNRS TIGHTLY CLOSED WHEN NOT IN USE. (SEE OTHER PREC) Other Precautions:HNDLG/STOR PREC: DO NOT WELD, CUT, HEAT/DRILL ON/NEAR CNTNR, EVEN WHEN EMPTY. STORE IN A COOL DRY PLACE W/GOOD VENT, AWAY FROM HEAT, SPARKS/OPEN FLAMES. GROUND ALL EQUIP & CNTNRS. KEEP OUT OF REACH OF CHILDREN. HARMFUL/FATAL IF SWALLOWED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE. Ventilation:LOCAL EXHAUST. USE EXPLOSION PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATION. Other Protective Equipment:CHEM RESISTANT BOOTS AND APRONS AS REQUIRED. EYE WASH AND FULL DRENCHING FACILITIES SHOULD BE ACCESSIBLE IN WORK AREAS. Work Hygienic Practices:WASH HANDS FREQUENTLY AND THOROUGHLY DURING CONTACT WITH MATERIAL AND AT END OF WORKDAY . Supplemental Safety and Health FIRST AID PROC: RESCUER TO DANGER. IF CONSCIOUS, KEEP WARM AND UNDER OBSERVATION. IF UNCONSCIOUS, PERFORM ARTIFICIAL RESPIRATION OR CPR AS REQUIRED. GET MD IMMED. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:198F,92C Vapor Pres:APPROX 55 Vapor Density:3.5 Spec Gravity:0.75-0.79 Evaporation Rate & Reference:2.15 (BUTYL ACETATE = 1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR COLORLESS LIQUID WITH A CHARACTERISTIC ODOR. Percent Volatiles by Volume:60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL AUTHORITIES FOR PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TIPAQUE YELLOW TY-55 Preparer's Name:Y. ISHIMURA CAGE:S4017 CAGE:S4017 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 70-85% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:ANTIMONY PENTOXIDE; (ANTIMONY OXIDE) CAS:1314-60-9 RTECS #:CC6300000 Fraction by Wt: 5-15% OSHA PEL:0.5 MG/M3 (SB) ACGIH TLV:0.5 MG/M3 (SB) Ingred Name:NICKEL (III) OXIDE CAS:1313-99-1 RTECS #:QR8400000 Fraction by Wt: 2-5% OSHA PEL:1 MG/M3 (NI) ACGIH TLV:0.05 MG/M3 (NI) ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) >5000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL: TEMPORARY IRRITATION TO MUCOUS MEMBRANES OF NOSE AND MOUTH MAY RESULT FROM EXCESSIVE EXPOSURE. SKIN: NO ERYTHEMA, NO EDEMA, AND NO OTHER SKIN IRRITATION FOUND IN RABBITS. SKIN ABSORP: INSOLUBIL ITY OF NICKEL ANTIMONY TITANIUM YELLOW RUTILE RENDERS ANY SKIN ABSORPTION HIGHLY UNLIKELY. EYE: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL OXIDE:ANTIC TO BE A CARCIN (NTP 6TH ANN RPT, 1991).ANTIMONY OXIDE:IARC GP2B (IARC MNGRPH VOL 47, P291, 1989. Effects of Overexposure:HLTH HAZ: INERT DUST HAZARD ONLY. NO SIGN OF EYE IRRITATION FOUND IN RABBITS. INGEST: NO INDICATION OF TOXICITY IN RATS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH WATER AND MILD SOAP. INHAL: REMOVE TO FRESH AIR. INGEST: IN CASE OF EXCESSIVE INGESTION, DRINK A QUART OR MORE OF WATER, FOLLOWED BY A GLASSFUL OF MILK, AND CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:INCOMBUSTIBLE Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID GENERATING AIRBORNE DUST DURING CLEANUP. USE VACUUM OR WET PROCEDURES. DRY SWEEPING SHOULD BE AVOIDED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST RESPIRATORS IF AIRBORNE DUST CONCENTRATIONS EXCEEDS THE TLV LEVEL. Ventilation:LOCAL EXHAUST TO MAINTAIN AIRBORNE DUST CONCENTRATIONS BELOW THE TLV LEVEL. Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 6.5-8.5 IN 200 G/L AQ. SOL'N. WASTE DISP METH: ACT OF 1986, TITLE III, SECTION 313. REVIEW APPROPRIATENESS OF THIS REGULATION PERTAINING TO YOUR USAGE. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:3092F,1700C Spec Gravity:4.4 pH:SUPDAT Solubility in Water:INSOLUBLE Appearance and Odor:PINE YELLOW POWDER, SOLID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PROD WHEN SPILLED CAN BE DISP OF INTO SANITARY LANDFILL OR INDUST WASTE DISP LANDFILL. PLEASE REVIEW APPROP FEDERAL, STATE & LOCAL INDUST WASTE DISP REGS. ANTIMONY & NICKEL CMPNDS ARE LISTED UNDE R SUPERFUND AMENDMENT & REAUTHORIZATION(SUPP DATA)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:URSA SUPER PLUS MOTOR OILS,26412,02112 SAE 30 CAGE:OTTJ3 CAGE:OTTJ3 CAGE:2R503 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED (MILD), HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: 65 - 80% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES,HYDROTREATED (MILD),HEAVY PARAFFINIC CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: 10 - 20% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:MINERAL OIL, SOLVENT REVFINED HEAVY PARAFFINIC, SEVERELY HYDROTREATED CAS:64741-88-4 RTECS #:PY8040501 Fraction by Wt: 3 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:SOLVENT REFINED LIGHT PARAFFINIC PETROLEUM DISTILLATES/PETROLEUM OIL CAS:64741-89-5 RTECS #:PY8041500 Fraction by Wt: 0 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 0 - 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:MODIFIED POLYOLEFIN AMIDE ALKYLENEAMINE DISPERSANT Fraction by Wt: 3 - 10% Other REC Limits:NONE RECOMMENDED Ingred Name:ZINC ALKYL DITHIOPHOSPHATE/PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1) (ZDDP) CAS:68649-42-3 Fraction by Wt: 1 - 3% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >5000 MG/KG. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- EYE:MAY IRRITATE SLIGHTLY. SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION. INHALE:MIST/VAPOR (GENERATED AT HIGH TEMPERATURES) IRRITATES R ESPIRATORY TRACT. ORAL:IF MORE THAN SEVERAL MOUTHFULS ARE SWALLOWED, NAUSEA, DIARRHEA MAY OCCUR. CHRONIC- NONE. Explanation of Carcinogenicity:NONE. Effects of Overexposure:IRRITATION, REDNESS, SWELLING, NAUSEA, VOMITING, DIARRHEA, DISCOMFORT Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUCCEPTIBLE TO THE EFFECTS FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WIPE OFF EXCESS & WASH SKIN WITH SOAP & WATER. ORAL:IF MORE THAN SEVERAL MOUTHFULLS ARE SWALLOWED, DRINK 2 GLASSES OF WATER. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Extinguishing Media:WATER FOG/SPRAY, CARBON DIOXIDE, FOAM/DRY CHEMICAL. DIRECTLY SPRAYING WATER/FOAM ONTO BURNING OIL MAY CAUSE FROTHING. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:TOXIC GASES ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. WIPE UP OR PICK-UP SPILL WITH INERT ABSORBENT MATERIAL SUCH AS DIATOMACEOUS EARTH, SAND OR VERMICULITE. SWEEP UP AND TRANSFER TO A CONTAINER FOR PROPER DISPOSAL. IF >840,265 LBS ARE SPILLED, REPORT TO AUTHORITIES. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM STRONG OXIDIZING AGENTS. KEEP CONTAINERS TIGHTLY CLOSED. KEEP OUT OF REACH OF CHILDREN. AVOID WATER CONTAMINATION. Other Precautions:DO NOT GET IN EYES. MINIMIZE SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES INCLUDING SHOES THAT CANNOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. IF WORKING IN CONFINED AREAS, IF EXCESSIVE MISTING IS EXPECTED OR IF EXPOSURE MAY OR DOES EXCEED RECOMMENDED PERMISSIBLE EXPOSURE LIMITS, WEAR NIOSH-APPROVED ORGANIC VAPOR AND MI ST RESPIRATOR (REFER TO 29 CFR 1910.134) Ventilation:USE ADEQUATE VENTILATION TO KEEP OIL MISTS OF THIS MATERIAL BELOW APPLICABLE STANDARD(S). Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 NRC/State Lic Num:NOT RELEVANT Spec Gravity:0.88 - 0.91 Viscosity:45-215CST104F Appearance and Odor:BRIGHT AND CLEAR LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE Hazardous Decomposition Products:SMOKE, CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES, KETONES, SULFUR COMPOUNDS MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. THIS PRODUCT HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS AND DOES NOT MEET THE CRITERIA OF A HAZARDOUS WASTE IF DISCARDED IN ITS PUR CHASED FORM.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KAOGUN 26 RFT CAGE:19740 CAGE:19740 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0-15% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: 0-15% Other REC Limits:30 MG/CUM TOTAL DUST OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:PARTICULATES NOT OTHERWISE REGULATED (NUISANCE DUST) Fraction by Wt: >80% OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST; 8990 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE DELAYED LUNG INJRY (SILICOSIS). EYES/SKIN: MAY CAUSE TEMPORARY IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION. NUSIANCE DUST CAUSE NASAL. THROAT/LUNG IRRITATION/DISCOMFORT MAY AGGRAVATE BRONCHIAL. Medical Cond Aggravated by Exposure:NO ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK PLENTY OF WATER. SKIN: WASH W/MILD SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER. IF IRRITATION PLERSISTS, CALL A PHYSICIAN. ================== Accidental Release Measures ================== Spill Release Procedures:FOLLOW ROUTINE HOUSEKEEPING PROCEDURES. COLLECT SPILLED PRODUCT IN CLOSED CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:REMOVAL OF THIS PRODUCT AFTER USE MAY RESULT IN THE GENERATION OF DUST. Other Precautions:REPEATED INHALATION OF RESPIRABLE FREE CRYSTALLINE SILICA DUST MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FULL FACEPIECE RESPIRATOR W/APPROPRIATE FILTER PAD OR CARTRIDGE(S) Ventilation:LOCAL EXHAUST AND MECHANICAL Other Protective Equipment:AS REQUIRED TO MEET APPLICABLE OSHA STANDARDS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.9-3.1 Solubility in Water:INSOLUBLE Appearance and Odor:COARSE AGGREGATE W/FINE POWDERED MATRIX. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTES ARE NOT HAZARDOUS WASTES AS DEFINED BY RCRA (40 CFR 261). COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS. METHOD OF DISPOSAL IS LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ADRIAMYCIN PFS CAGE:58750 CAGE:58750 ============= Composition/Information on Ingredients ============= Ingred Name:DOXORUBICIN HYDROCHLORIDE CAS:25316-40-9 Fraction by Wt: 0.2% Other REC Limits:NONE SPECIFIED OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:NONE STATED. Explanation of Carcinogenicity:INFORMATION PROVIDED BY MFR. Effects of Overexposure:ACUTE OVEREXPOSURE: CAUSES EYE, SKIN, AND/OR RESPIRATORY IRRITATION; MYELOSUPPRESSION AND CARDIOTOXICITY. CHRONIC OVEREXPOSURE: MYELOSUPPRESSION AND CARDIOTOXICITY; POSSIBLE HYPERSENSITIZATION; SKIN P IGMENTATION. Medical Cond Aggravated by Exposure:CARDIOVASCULAR. HEPATIC. RENAL. BONE MARROW IMPAIRMENT. ======================= First Aid Measures ======================= First Aid:INHALE: SEEK MEDICAL ATTENTION; SKIN: WASH WITH SOAP AND WATER; INGEST: SEEK MEDICAL ATTENTION; EYE: IRRIGATE IMMEDIATELY WITH SALINE OR WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:EVACUATE PERSONNEL TO SAFET AREA. FIREFIGHTERS SHOULD USE SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SOLUTION AND DEACTIVATE WITH DILUTE BLEACH SOLUTION; ALLOW AT LEAST 5 MINUTES REACTION TIME TO A LIGHT YELLOW TO COLORLESS SOLUTION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ADRIAMYCIN PFS IS A POTENT ANTI-CANCER DRUG. HANDLE THE SOLUTION WITH CARE. IF SOLUTION CONTACTS SKIN OR MUCOSA, IMMEDIATELY WASH WITH SOAP AND WATER. Other Precautions:SEE PRODUCT INSERT FOR FURTHER INFORMATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED TOXIC AEROSOL RESPIRATOR. Ventilation:USE LOCAL EXHAUST WITH VERTICAL LAMINAR FLOW HOOD. Other Protective Equipment:LONG SLEEVED IMPERMEABLE, DISPOSABLE GOWN Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T7 Boiling Pt:B.P. Text:212F/100C Spec Gravity:1.006 Solubility in Water:MISCIBLE Appearance and Odor:RED, ODORLESS SOLUTION Percent Volatiles by Volume:99.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, > 204C, IT EMITS VERY TOXIC FUMES OF OXIDES OF NITROGEN AND HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DEACTIVATE WITH DILUTE BLEACH SOLUTION. DISPOSE OF THE WASTE IN ACCORDANCE WITH YOUR PROCEDURE FOR HAZARDOUS WASTE DISPOSAL TO MEET LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T324S-4 23590 TOLUENE CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-4* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: >99% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, RESULTING IN CORNEAL INJURY. SKIN: PROLONGED/REPEATED CONTACT CAUSES IRRITATION/DERMATITIS. INGESTION: IRRITATION OF DIGESTIVE TRACT. ASPIRATION OF MATERIAL INTO LUNGS CAUSES CHEMICA L PNEUMONITIS/FATAL. INHALATION: CNS EFFECTS, RESPIRATORY TRACT IRRITANT, CARDIAC ARREST/DEATH. KIDNEY/LIVER DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, UNCONSCIOUSNESS, COMA, HEART DISTURBANCES ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. DON'T ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT, GIVE 2- 4 CUPFULS OF MILK/WATER. ASPIRATION HAZARD. INHALATION: REMOVE TO FRESH AIR IMMEDIATELY. GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:40F Lower Limits:1.1 Upper Limits:7.1 Extinguishing Media:DRY CHEMICAL, CO2/ALCOHOL-RESISTANT FOAM Fire Fighting Procedures:WEAR A SCBA IN PRESSURE-DEMAND, MSHA/NIOSH APPROVED & FULL PROTECTIVE GEAR. DIKE/COLLECT WATER USED. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT/FIRE. VAPORS CAN TRAVEL TO IGNITION SOURCES, FLASH BACK/FORM EXPLOSIVE MIXTURES AT TEMPS >THE FLASHPOINT. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PROTECTIVE EQUIPMENT. AVOID RUNOFF INTO STORM SEWERS & DITCHES/WATERWAYS. SCOOP UP W/A NONSPARKING TOOL, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. USE WATER SPRAY TO DISPERSE THE G AS/VAPOR. REMOVE ALL IGNITION SOURCES. ABSORB LEAK ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM SOURCES OF IGNITION. Other Precautions:EMPTY CONTAINERS RETAIN PRODUCT RESIDUE & CAN BE DANGEROUS. DON'T PRESSURIZE/CUT/WELD/BRAZE/SOLDER/DRILL/GRIND/EXPOSE CONTAINERS TO HEAT/SPARKS/OPEN FLAMES. DON'T GET ON SKIN/IN EYES. DON'T INGEST/INH ALE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALWAYS USE A NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE. MATERIAL IS LIGHTER THAN WATER & A FIRE MAY SPREAD BY THE USE OF WATER. HEALTH HAZ CONT'D: OVEREXPOSURE MAY CAUSE CARDIAC SENSITIZATION & SEVERE HEART ABNO RMALITIES. INCOMPATIBILITIES CONT'D: NITRIC ACID & SULFURIC ACID/SILVER PERCHLORATE/STRONG OXIDIZERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:232F Melt/Freeze Pt:M.P/F.P Text:-139F Vapor Pres:10 Vapor Density:3.1 Spec Gravity:0.9 Evaporation Rate & Reference:(BUTYL ACETATE=1): 2.4 Solubility in Water:0.6 MG/L Appearance and Odor:COLORLESS LIQUID W/AROMATIC, SWEET ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BROMINE TRIFLUORIDE/1,3-DICHLORO-5,5-DIMETHYL-2,4-IMIDAZOLIDIDIONE, DINITROGEN TETROXIDE/CONCENTRATED NITRIC ACID (SUPP) Stability Condition to Avoid:EXCESSIVE HEAT & OTHER IGNITION SOURCES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7261 WHITE, 8060195 CAGE:DO804 CAGE:DO804 CAGE:38360 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID, TRIBUTYL ESTER; (TRIBUTYL PHOSPHATE) CAS:126-73-8 RTECS #:TC7700000 Fraction by Wt: 40-60% Other REC Limits:5 MG/M3 (MFR) OSHA PEL:5 MG/M3 ACGIH TLV:0.2 PPM; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE/SKIN:SEVERE IRRITANT. INHAL:SLIGHT IRRITANT. INGEST:SLIGHT IRRITANT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MIN. CALL A MD IMMED. SKIN:WASH W/SOAP & WATER. LAUNDER CONTAM CLTHG BEFORE REUSE. GET MD ATTN. INHAL:REMOVE TO FRESH AIR. BEGIN RESUSCITATION. GET MD ATTN. INGEST:I F EMPLOYEE IS CONSCIOUS, GIVE 2 GLASSESOF WATER & INDUCE VOMIT. GET MD ATTN IMMED. NOTE TO MD:POSSESSES ONLY WEAK ANTICHOLINESTERASE ACTIVITY WHICH SHOULD NOT REQUIRE SPECIFIC TREATMENT. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND AND MAY BE IGNITED AT DISTANT LOCATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ABSORB SPILLED MATERIAL WITH VERMICULITE OR FLOOR ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:USE OF A HAZ CHEM MAY REQ SUPPLEMENTAL VENT FOR PROTECTION OF PERSONNEL AND FOR CONTROLLING FIRE/EXPLOS HAZ. A QUALIFIED INDEPENDENT TESTING COMPANY CAN DETERMINE IF EXISTING CONC ARE WITHIN ESTABLISH ED RECOMMENDED/PERMISSIBLE EXPOS LEV. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW OCCUPATIONAL EXPOSURE STANDARDS. (SEE OTHER PRECAUTIONS). Ventilation:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW OCCUPATIONAL EXPOSURE STANDARDS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health DISP METH:HAZARDOUS. AS A RESULT, CONTACT LOCAL, STATE AND FEDERAL AUTHORITIES FOR DISPOSAL INFORMATION. ================== Physical/Chemical Properties ================== HCC:T6 Vapor Pres:VERY LOW Evaporation Rate & Reference:VERY LOW Solubility in Water:VERY SLIGHT Appearance and Odor:INK WITH MILD ODOR. Percent Volatiles by Volume:LOW ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT AND FLAME. Hazardous Decomposition Products:CO, CO*2, PHOSPHORUS OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:UNDER RCRA, IT IS RESPONSIBILITY OF GENERATOR OF WASTE MATL TO DETERMINE, AT TIME OF DISP, WHETHER WASTE GENERATED MEETS FED/STATE HAZ WASTE CRITERIA. THIS IS BECAUSE USES, TRANSFORMATIONS, MIXTURES,PROCESSES, ETC MAY RENDER RESULTING MATL (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LUNG DIFFUSION GAS MIXES CAGE:18264 CAGE:18264 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON MONOXIDE. %:1,000 - 5,000 MOLAR PERCENT. CAS:630-08-0 RTECS #:FG3500000 Fraction by Wt: <0.1% OSHA PEL:50 PPM ACGIH TLV:25 PPM Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HELIUM. %:10 MOLAR PERCENT. CAS:7440-59-7 RTECS #:MH6520000 Fraction by Wt: 10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: TRACE OSHA PEL:5000 PPM ACGIH TLV:5000 PPM;30000 STEL Ingred Name:NEON CAS:7440-01-9 RTECS #:QP4450000 Fraction by Wt: TRACE OSHA PEL:N/K ACGIH TLV:ASPHYXIANT Ingred Name:ACETYLENE CAS:74-86-2 RTECS #:AO9600000 Fraction by Wt: TRACE OSHA PEL:N/K ACGIH TLV:ASPHYXIANT Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:ASPHYXIANT Ingred Name:FIRST AID PROC:REMOVAL FROM CONTAM AREA IS MOST IMPORTANT. UNCON PERS SHOULD BE MOVED TO UNCONTAM AREA & BE GIVEN(ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ARTF RESP & OXYG AT SAME TIME. ADMIN OF OXYG AT ELEVATED PRESS (2-2.5 ATMS) HAS SHOWN TO BE BENEFICIAL AS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:HAS TREATMENT IN HYPERBARIC CHAMBER. MD SHOULD BE INFORMED THAT PATIENT HAS INHALED TOX QTYS OF CARBON MONOXIDE. RTECS #:9999999ZZ Ingred Name:OTHER PREC:DISCHARGE RATE OF PROD FROM CYL. USE CHECK VALVE/TRAP IN DISCHARGE LINE TO PVNT HAZ BACK FLOW INTO (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:CYL. PROT CYLS FROM PHYSICAL DMG. STORE IN COOL, DRY, WELL-VENTED AREA AWAY FROM HEAVILY TRAFFICKED AREAS(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:& EMER EXITS & AWAY FROM FULL/EMPTY STORED CYLS WHICH CNTN FLAMM PRODS. DO NOT ALLOW TEMP WHERE CYLS ARE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:STORED TO EXCEED 130F (54C). CYLS SHOULD BE STORED UPRIGHT & FIRMLY SECURED TO PVNT FALLING/BEING KNOCKED(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:OVER. FULL/EMPTY CYLS SHOULD BE SEGREGATED. USE "FIRST IN-FIRST OUT" INVENTORY SYS TO PVNT FULL CYLS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:BEING STORED FOR EXCESSIVE PERIOD OF TIME. FOR ADDNL HNLDG/STOR RECS CONSULT COMPRESSED GAS ASSOC'S (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:PAMPHLET P-1. THESE GAS MIXTS CAN BE HNDLD IN MOST COMMON STRUCTURAL MATLS. EQUIP TO CNTN HIGH OXYG (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:CONTENT MIXTS MUST BE "CLEANED FOR OXYG SERVICE". SEE COMPRESSED GAS ASSOC PAMPHLET G-4.1. COMPRESSED GAS(ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:CYLS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED PRDCRS OF COMPRESSED GASES. SHIPMENT OF COMPRESSED GAS (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:CYL WHICH HAS NOT BEEN FILLED BY OWNER/WITH HIS (WRITTEN) CONSENT IS VIOLATION OF FED LAW (49CFR). DO NOT(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:USE PROD IF COMPONENT CONC DATA IS NOT CLEARLY LEGIBLE ON CYL LABEL. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CARBON MONOXIDE:DEPENDING ON LEVELS & DURATION OF EXPOS, SYMPS MAY INCL HDCH, DIZZ, HEART PALPITATIONS, WEAK, CONFUSN & NAUS TO CONVLS, EVENTUAL UNCON & DEATH. BECAUSE IT IS COLORLESS & ODORLESS POIS GAS, THERE IS NO WARNING OF ITS PRESENCE OTHER THAN ABOVE SYMPS. ANALYTICAL MONITORS, W/ALARMS, SHOULD (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:BE EMPLOYED WHERE POSSIBILITY OF RELS OF TOX QTYS EXISTS. OXYG TRANSPORT FUNC OF HEMOGLOBIN OF BLOOD IS REDUCED SINCE IT REACTS W/INHALED CARBON MONOXIDE TO FORM CARBOXY HEMOGLOBIN INSTEAD OF ITS NORMAL RXN W/OXYG IN LUNGS TO FORMOXYHEMOGLOBIN. AFFINITY OF HEMOGLOBIN FOR CARBON MONOXIDE IS 200-300 (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP TO CARBON MONOXIDE. RESCUE PERS SHOULD BE EQUIPPED W/NIOSH/MSHA APPRVD SCBA. INGEST:CALL MD IMMED . EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MINS, SEEK ASSISTANCE FROM MD SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD . INHAL:CONSCIOUS PERS SHOULD BE ASSISTED TO UNCONTAM AREA & BE TREATED W/SUPP OXYG. QUICK (ING 8) ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NONFLAMMABLE GAS MIXTURE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERS FROM AFFECTED AREA. USE APPROP PROT EQUIP. IF LEAK IS IN USER'S EQUIP, BE CERTAIN TO PURGE PIPING W/INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CNTNR/CNTNR VALVE, CONT YOUR CLOSEST SUPPLIER LOCATION/CALL EMER (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:VALVE PROT CAPS & VALVE OUTLET THREADED PLUGS MUST REMAIN IN PLACE UNLESS CNTNR IS SECURED W/VALVE OUTLET PIPED TO USE POINT. Other Precautions:USE ONLY IN WELL-VENTED AREAS. DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR CYL MOVEMENT. USE PRESS REDUCING REGULATOR WHEN CONNECTING CYL TO LOWER PRESS (<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR LINE RESPIRATOR W/MASK OR NIOSH/MSH APPROVED SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE. Ventilation:LOCAL EXHAUST: TO PREVENT ACCUMULATION ABOVE TWA FOR CARBON MONOXIDE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . SAFETY SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OVEREXP:TIMES GREATER THAN ITS AFFINITY FOR OXYG. ALL OF DISORDERS ARE D UE TO MARKEDLY REDUCED CELLULLAR RESP &MAY INCL CNS IMPAIRMENT, CVS COLLAPSE, RENAL INSUFFICIENCY, COMA, ETC. ================== Physical/Chemical Properties ================== Solubility in Water:GAS MIXTURE Appearance and Odor:COLORLESS, ODORLESS GAS UNLESS IT CNTNS ACETYLENE WHICH HAS DISTINCTIVE (SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISP OF WASTE/UNUSED QTYS. RETURN IN SHIPPING CNTNR PROPERLY LABELED, W/ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROT CAP IN PLACE TO YOUR SUPPLIER. FOR EMER DISP ASSISTANCE, CONTYOUR CLOSEST SUPPLIER LOCATION/CALL EMER (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GALLIC ACID, R-7046 Preparer's Name:STEPHEN BACON CAGE:EO526 CAGE:EO526 CAGE:89975 ============= Composition/Information on Ingredients ============= Ingred Name:GALLIC ACID CAS:149-91-7 RTECS #:LW7525000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: DUST IRRITATING TO SKIN, EYES, AND RESPIRATORY TRACT. CONTACT W/SKIN CAN CAUSE IRRITATION. CONTACT W/EYES CAUSES MODERATE TO SEVERE IRRITATION. INGESTION CAN CAUSE GI IRRITATION WITH NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF BREATHING DIFFICULT, CONTACT PHYS & GIVE OXYGEN AS NEEDED. SKIN: WASH THORO W/SOAP & WATER. IF IRRIT PERSISTS, SEEK MED ATTN. EYES: FLUSH WELL FOR @ LST 15 MIN W/WATER. IF IRRIT PERSISTS, GET MED ATTN. INGEST: CONTACT PHYS & GIVE LG AMTS OF WATER. INDUCE VOMITING UNDER DIRECTION OF PHYS. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MAY EMIT ACRID SMOKE AND FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & CONTAINERIZE FOR LATER DISPOSAL. AVOID RAISING DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING DUST & UNNECESSARY CONTACT W/POWDER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK SHOULD BE WORN WHEN HANDLING LARGE QTY. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:LAB COAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health HMIS(LEVIEN) NOTES THAT THE ORAL LD50 (RBT) IS 5G/KG. MATL TO AVOID: CARBONATES, AND SILVER SALTS. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:SLIGHTLY Appearance and Odor:WHITE, ODORLESS POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONT W/FERRIC SALTS, OXIDIZERS, CHLORATES, PERMANGANATE, AMMONIA, LEAD ACETATE, ALKALI HYDROXIDES & (SUPP DATA) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF BY INCINERATION OR OTHER METHOD APPROVED OF BY LOCAL, STATE, OR FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPECTRUM YELLOW TONER PREMIX FOR C2552, C2558, C2562, C2568 CAGE:1AU05 CAGE:1AU05 CAGE:50804 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED HEAVY NAPHTHA CAS:64742-48-9 Fraction by Wt: 90% Other REC Limits:NONE SPECIFIED Ingred Name:POLYMER, UNSPECIFIED Other REC Limits:NONE SPECIFIED Ingred Name:PIGMENT Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 > 10 G/KG (RAT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION POSES MAXIMUM RISK OF SEVERE RESPIRATORY DISTRESS BY ASPIRATION, AS WELL AS CENTRAL NERVOUS SYSTEM DEPRESSION. INTENTIONAL INHALATION MAY RESULT IN ABNORMAL HEART RHYTHMS, RESPIRATORY ARREST , CENTRAL NERVOUS SYSTEM TOXICITY. CHRONIC: PROLONGED AND/OR REPEATED SKIN CONTACT MAY LEAD TO DERMATITIS. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:RESPIRATORY TRACT IRRITATION/DAMAGE, CENTRAL NERVOUS SYSTEM DEPRESSION, RESPIRATORY ARREST, DERMATITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY WITH WATER. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE.OBSERVE FOR ANY DIFFICULTY BREATHING. INGESTION: DILUT E CONTENTS WITH SEVERAL GLASSES OF WATER. DO NOT INDUCE VOMITING. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:102F,39C Lower Limits:0.8 % Upper Limits:7.0 % Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER FOG Fire Fighting Procedures:USE AIR-SUPPLIED BREAATHING EQUIPMENT FOR ENCLOSED AREAS. COOL EXPOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPOROR FUMES. Unusual Fire/Explosion Hazard:DO NOT MIX OR STORE WITH STRONG OXIDANTS LIKE LIQUID CHLORINE OR CONCENTRATED OXYGEN. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. RECOVER FREE LIQUID USING ABSORBENT MATERIAL (VERMICULITE, FIRE RETARDANT SAWDUST, ETC.) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. AVOID HANDLING NEAR HEAT, STRONG LIGHT, SPARKS, OPEN FLAMES, STRONG OXIDANTS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE WHEN USED AS INTENDED Ventilation:GENERAL ROOM VENTILATION SHOULD BE SUFFICIENT Other Protective Equipment:NONE WHEN USED AS INTENDED Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:320F,160C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:1 Vapor Density:5.0 Spec Gravity:0.77 Evaporation Rate & Reference:0.3 (N-BUTYLACETATE=1) Solubility in Water:IMMISCIBLE Appearance and Odor:YELLOW LIQUID/SLIGHT ODOR Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS SUCH AS LIQUID CHLORINE, CONCETRATED OXYGEN, SODIUM OR CALCIUM HYPOCHLORITE. Stability Condition to Avoid:HEAT, STRONG LIGHT, SPARKS, OPEN FLAMES Hazardous Decomposition Products:FUMES, SMOKE, AND CARBON MONOXIDE IN THE CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:THE WASTE TONER MAY BE CLASSIFIED AS AN IGNITABLE HAZARDOUS WASTE UNDER FEDERAL AND/OR STATE REGULATIONS AND SHOULD BE DISPOSED AT AN APPROVED DISPOSAL SITE OR FACILITY IN ACCORDANCE WITH FEDERAL, STA TE AND LOCAL REGULATIONS.
0
eyes_protection_not_mandatory